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Mild hydrothermal synthesis of potassium uranyl phosphates with layered and framework structures

Journal Article · · Journal of Solid State Chemistry
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Not provided.

Research Organization:
Univ. of South Carolina, Columbia, SC (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0016574
OSTI ID:
1852312
Journal Information:
Journal of Solid State Chemistry, Vol. 301, Issue C; ISSN 0022-4596
Publisher:
Elsevier
Country of Publication:
United States
Language:
English

References (39)

Influence of Phosphate and Silica on U(VI) Precipitation from Acidic and Neutralized Wastewaters May 2014
A New Uranium(VI) Monophosphate with a Layered Structure:  Ba 3 [UO 2 (PO 4 )(PO 3 (OH))] 2 · x H 2 O ( x ≈ 0.4) November 1998
Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective June 2018
A Revised and Expanded Structure Hierarchy of Natural and Synthetic Hexavalent Uranium Compounds January 2016
General Route to Three-Dimensional Framework Uranyl Transition Metal Phosphates with Atypical Structural Motifs:  The Case Examples of Cs 2 {(UO 2 ) 4 [Co(H 2 O) 2 ] 2 (HPO 4 )(PO 4 ) 4 } and Cs 3+ x [(UO 2 ) 3 CuH 4 - x (PO 4 ) 5 ]·H 2 O March 2006
Synthesis, structure, and spectroscopic characterization of three uranyl phosphates with unique structural units December 2012
An Unprecedented Uranyl Phosphate Framework in the Structure of [(UO 2 ) 3 (PO 4 )O(OH)(H 2 O) 2 ](H 2 O) March 2004
Copper uranyl phosphate and arsenate incorporating an organic ligand with a pillared layer structure: [Cu(4,4′-bpy)(UO2)0.5(HPO4)(H2PO4)]·H2O and [Cu(4,4′-bpy)(UO2)0.5(HAsO4)(H2AsO4)]·1.5H2O January 2013
Syntheses, Structures, and Comparisons of Thallium Uranium Phosphites, Mixed Phosphate-Phosphites, and Phosphate March 2013
Crystal Structures of Three Framework Alkali Metal Uranyl Phosphate Hydrates August 2002
The Crystal Structure of Triuranyl Diphosphate Tetrahydrate January 2002
Structures and syntheses of layered and framework amine-bearing uranyl phosphate and uranyl arsenates August 2004
Organically templated layered uranium(VI) phosphates: hydrothermal syntheses and structures of [NHEt3][(UO2)2(PO4)(HPO4)] and [NPr4][(UO2)3(PO4)(HPO4)2] January 1998
Synthesis and structure of [C6H14N2][(UO2)4(HPO4)2(PO4)2(H2O)]·H2O: An expanded open-framework amine-bearing uranyl phosphate September 2008
Crystal chemistry of anhydrous Li uranyl phosphates and arsenates. II. Tubular fragments and cation–cation interactions in the 3D framework structures of Li6[(UO2)12(PO4)8(P4O13)], Li5[(UO2)13(AsO4)9(As2O7)], Li[(UO2)4(AsO4)3] and Li3[(UO2)7(AsO4)5O)] November 2009
Observation of an Unusual Uranyl Cation–Cation Interaction in the Strongly Fluorescent Layered Uranyl Phosphates Rb 6 [(UO 2 ) 7 O 4 (PO 4 ) 4 ] and Cs 6 [(UO 2 ) 7 O 4 (PO 4 ) 4 ] December 2017
A Family of Layered Phosphates Crystallizing in a Rare Geometrical Isomer of the Phosphuranylite Topology: Synthesis, Characterization, and Computational Modeling of A 4 [(UO 2 ) 3 O 2 (PO 4 ) 2 ] (A = Alkali Metal) Exhibiting Intralayer Ion Exchange March 2018
Crystal Growth and Structure Characterization of Three Layered Uranyl Phosphates and Their Relation to the Phosphuranylite Family December 2018
Observation of the Same New Sheet Topology in Both the Layered Uranyl Oxide-Phosphate Cs11[(UO2)12(PO4)3O13] and the Layered Uranyl Oxyfluoride-Phosphate Rb11[(UO2)12(PO4)3O12F2] Prepared by Flux Crystal Growth August 2019
Cation−Cation Interactions in Sr 5 (UO 2 ) 20 (UO 6 ) 2 O 16 (OH) 6 (H 2 O) 6 and Cs(UO 2 ) 9 U 3 O 16 (OH) 5 November 2006
Synthesis and Structural and Magnetic Characterization of {[(phen) 2 Ni] 2 (μ-P 2 O 7 )}·27H 2 O and {[(phen) 2 Mn] 2 (μ-P 2 O 7 )}·13H 2 O:  Rare Examples of Coordination Complexes with the Pyrophosphate Ligand August 2007
Flux versus Hydrothermal Growth: Polymorphism of A 2 (UO 2 )Si 2 O 6 (A = Rb, Cs) January 2017
Hydrothermal synthesis and structures of the new open-framework uranyl silicates Rb4(UO2)2(Si8O20) (USH-2Rb), Rb2(UO2)(Si2O6)·H2O (USH-4Rb) and A2(UO2)(Si2O6)·0.5H2O (USH-5A; A = Rb, Cs) December 2002
The novel open-framework uranium silicates Na2(UO2)(Si4O10)·2.1H2O (USH-1) and RbNa(UO2)(Si2O6)·H2O (USH-3) January 2002
KNa3(UO2)2(Si4O10)2(H2O)4, a new compound formed during vapor hydration of an actinide-bearing borosilicate waste glass April 2000
Synthesis, Structural Characterization, and Topological Rearrangement of a Novel Open Framework U−O Material:  (NH 4 ) 3 (H 2 O) 2 {[(UO 2 ) 10 O 10 (OH)][(UO 4 )(H 2 O) 2 ]} November 2001
Syntheses, Structures, and Ion-Exchange Properties of the Three-Dimensional Framework Uranyl Gallium Phosphates, Cs 4 [(UO 2 ) 2 (GaOH) 2 (PO 4 ) 4 ]·H 2 O and Cs[UO 2 Ga(PO 4 ) 2 ] January 2005
Overstepping Löwenstein’s Rule—A Route to Unique Aluminophosphate Frameworks with Three-Dimensional Salt-Inclusion and Ion-Exchange Properties December 2018
SHELXT – Integrated space-group and crystal-structure determination January 2015
A short history of SHELX December 2007
OLEX2 : a complete structure solution, refinement and analysis program January 2009
Single-crystal structure validation with the program PLATON January 2003
Bond-valence parameters obtained from a systematic analysis of the Inorganic Crystal Structure Database August 1985
Fluorescence spectroscopy of U(VI)-silicates and U(VI)-contaminated Hanford sediment March 2005
Synthesis and characterization of CeIV(PO4)(HPO4)0.5(H2O)0.5 May 2006
Polymerization and Depolymerization Phenomena in Phosphate–Metaphosphate Systems at Higher Temperatures. Condensation Reactions Involving the Potassium Hydrogen Orthophosphates January 1952
Observation of Multiple Crystal-to-Crystal Transitions in a New Reduced Vanadium Oxalate Hybrid Material, Ba 3 [(VO) 2 (C 2 O 4 ) 5 (H 2 O) 6 ]·(H 2 O) 3 , Prepared via a Mild, Two-Step Hydrothermal Method August 2014
Exfoliation of crystals September 2018
Synthesis and study of potassium uranates K2U6O19 and K2U4O13·2.2H2O November 2015

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