HydG, the “dangler” iron, and catalytic production of free CO and CN - : implications for [FeFe]-hydrogenase maturation

Shepard, Eric M.; Impano, Stella; Duffus, Benjamin R.; Pagnier, Adrien; Duschene, Kaitlin S.; Betz, Jeremiah N.; Byer, Amanda S.; Galambas, Amanda; McDaniel, Elizabeth C.; Watts, Hope; McGlynn, Shawn E.; Peters, John W.; Broderick, William E.; Broderick, Joan B.

doi:10.1039/d1dt01359a

HydG, the “dangler” iron, and catalytic production of free CO and CN ^- : implications for [FeFe]-hydrogenase maturation

Journal Article · 01 January 2021 · Dalton Transactions

DOI:https://doi.org/10.1039/d1dt01359a· OSTI ID:1850938

Shepard, Eric M. ^[1]; Impano, Stella ^[1]; ^[1]; ^[1]; Duschene, Kaitlin S. ^[1]; Betz, Jeremiah N. ^[1]; ^[1]; Galambas, Amanda ^[1]; McDaniel, Elizabeth C. ^[1]; Watts, Hope ^[1]; ^[2]; ^[3]; ^[1]; ^[1]

Department of Chemistry & Biochemistry; Montana State University; Bozeman; USA
Earth-Life Science Institute; Tokyo Institute of Technology; Meguro-ku; Japan
Institute of Biological Chemistry; Washington State University; Pullman; USA

The hydrogenase maturase HydG produces multiple equivalents of free CO and CN^-during catalysis. This production correlates with the activation of hydrogenase, supporting a model in which free CO and CN^-are relevant to maturation.

Research Organization:: Montana State Univ., Bozeman, MT (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0005404

OSTI ID:: 1850938

Journal Information:: Dalton Transactions, Vol. 50, Issue 30; ISSN 1477-9226

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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