Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Reductive Coupling of Xylyl Isocyanide Mediated by Low-Valent Uranium

Journal Article · · Organometallics
 [1];  [1];  [2];  [1];  [2];  [1]
  1. Department of Chemistry and Biochemistry, University of California, Santa Barbara, Santa Barbara, California 93106, United States
  2. Department of Chemistry and Biochemistry, University of Texas at El Paso, El Paso, Texas 79968, United States

Not provided.

Research Organization:
Univ. of California, Santa Barbara, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0001861
OSTI ID:
1850762
Journal Information:
Organometallics, Vol. 40, Issue 17; ISSN 0276-7333
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (56)

Uranium-Carbon Multiple Bonding: Facile Access to the Pentavalent Uranium Carbene [U{C(PPh 2 NSiMe 3 ) 2 }(Cl) 2 (I)] and Comparison of U V C and U IV C Bonds February 2011
Actinide Metals with Multiple Bonds to Carbon: Synthesis, Characterization, and Reactivity of U(IV) and Th(IV) Bis(iminophosphorano)methandiide Pincer Carbene Complexes July 2011
The ThC double bond: an experimental and computational study of thorium poly-carbene complexes January 2011
Silyl-Phosphino-Carbene Complexes of Uranium(IV) March 2018
Nature of the Arsonium‐Ylide Ph 3 As=CH 2 and a Uranium(IV) Arsonium–Carbene Complex June 2020
Phosphorano-Stabilized Carbene Complexes with Short Thorium(IV)– and Uranium(IV)–Carbon Bonds June 2018
Formation of Methane versus Benzene in the Reactions of (C 5 Me 5 ) 2 Th(CH 3 ) 2 with [CH 3 PPh 3 ]X (X=Cl, Br, I) Yielding Thorium-Carbene or Thorium-Ylide Complexes September 2017
Synthesis, Thermochemistry, Bonding, and 13 C NMR Chemical Shift Analysis of a Phosphorano-Stabilized Carbene of Thorium April 2017
Synthesis of a Uranium(VI)-Carbene: Reductive Formation of Uranyl(V)-Methanides, Oxidative Preparation of a [R 2 C═U═O] 2+ Analogue of the [O═U═O] 2+ Uranyl Ion (R = Ph 2 PNSiMe 3 ), and Comparison of the Nature of U IV ═C, U V ═C, and U VI ═C Double Bonds June 2012
Towards uranium catalysts September 2008
Recent developments in actinide–ligand multiple bonding January 2013
The Renaissance of Non-Aqueous Uranium Chemistry June 2015
Uranium carbene compounds April 2013
Fragmentation, catenation, and direct functionalisation of white phosphorus by a uranium( iv )–silyl–phosphino–carbene complex January 2021
Double dative bond between divalent carbon(0) and uranium November 2018
Synthesis and structure of Cp3UCHPMe3: A compound with a UC multiple bond March 1988
A uranium-carbon multiple bond. Crystal and molecular structure of (.eta.5-C5H5)3UCHP(CH3)2(C6H5) June 1981
Synthesis of a Phosphorano-Stabilized U(IV)-Carbene via One-Electron Oxidation of a U(III)-Ylide Adduct May 2011
Metal–ligand multiple bonding in uranium: structure and reactivity January 2010
Exploring the Uranyl Organometallic Chemistry: From Single to Double Uranium−Carbon Bonds April 2011
Uranium(IV) Nucleophilic Carbene Complexes June 2011
Easy access to uranium nucleophilic carbene complexes January 2010
Terminal Iron Carbyne Complexes Derived from Arrested CO 2 Reductive Disproportionation July 2017
Mechanism of Molybdenum-Mediated Carbon Monoxide Deoxygenation and Coupling: Mono- and Dicarbyne Complexes Precede C–O Bond Cleavage and C–C Bond Formation December 2016
A CO-Derived Iron Dicarbyne That Releases Olefin upon Hydrogenation August 2013
Four-electron deoxygenative reductive coupling of carbon monoxide at a single metal site December 2015
Tris((hexamethyldisilyl)amido)uranium(III): preparation and coordination chemistry June 1979
A Convenient Entry into Trivalent Actinide Chemistry: Synthesis and Characterization of AnI3(THF)4 and An[N(SiMe3)2]3 (An = U, Np, Pu) May 1994
Carbon Monoxide and Isocyanide Complexes of Trivalent Uranium Metallocenes October 1999
Bis[η5-bis(trimethylsilyl)cyclopentadienyl]bromouranium(III) bis(tert-butyl isocyanide) August 1989
Bis[bis(trimethylsilyl)cyclopentadienyl](chloro)uranium(III) bis(2,6-dimethylphenylisocyanide) July 1989
Synthesis and characterization of seven-coordinate tantalum(I) and niobium(I) complexes with cis carbonyl and alkyl isocyanide ligands December 1992
Mechanistic studies of the reductive coupling of isocyanides in seven-co-ordinate molybdenum complexes; X-ray crystal structures of [Mo(CNBu t ) 6 ] and [Mo{CN(Bu t )(SiMe 2 Bu t )}(CNBu t ) 5 ][O 3 SCF 3 ] January 1991
Higher coordinate cyanide and isocyanide complexes. Part 12. Dealkylation and reductive coupling of tert-butyl isocyanide ligands in heptakis(tert-butyl isocyanide)molybdenum(II). Structure of cyanotetrakis(tert-butyl isocyanide)((N,N'-di-tert-butyldiamino)acetylene)molybdenum(II) tetraphenylborate December 1981
Reduktive CC-kupplung von zwei isocyanid-liganden an Mo(II)- und W(II)-zentren, eine reaktionssequenz über isocyanid- und aminocarbin-komplexe von Mo(0) und W(0) August 1990
Higher coordinate cyanide and isocyanide complexes. 15. Reductive coupling of coordinated alkyl isocyanides in seven-coordinate molybdenum(II) and tungsten(II) complexes. Removal of the coupled ligand as an oxamide March 1982
Reductive coupling of adjacent ligands in a seven-coordinate molybdenum(II) isocyanide complex January 1977
Isocyanide–Group 5 complexes and metal-centred C–C coupling August 1999
Carbynes generated from metal carbonyl and isocyanide complexes; intermediates in the reductive coupling of carbonyl and CNR ligands April 1988
Reductive Coupling of Carbon Monoxide and Alkyl Isocyanide Ligands in Early Transition Metal Complexes: A Review January 1990
Higher coordinate complexes. 23. Reductive coupling of isocyanide ligands in seven-coordinate molybdenum(II) mixed isocyanide bipyridine complexes August 1986
Reactions of dinuclear niobium(III) and tantalum(III) compounds with alkyl isocyanides to give dinuclear products with dimerized isocyanides November 1984
Reactions of tert-butyl isocyanide with a binuclear niobium(III) compound June 1983
F 3 CNCCNCF 3 , a New Bridge Ligand: Formation by CC Linkage of Two CF 3 NC Ligands and Cleavage of a MoMo Bond July 1984
Synthesis and Insertion Chemistry of Monoalkyl and Monoaryl Uranium(IV) Heteroleptic Metallocene Complexes October 2009
Insertion of t BuNC into thorium–phosphorus and thorium–arsenic bonds: phosphaazaallene and arsaazaallene moieties in f element chemistry January 2016
Metal-Mediated and Metal-Catalyzed Reactions of Isocyanides March 2015
The 15 years of reductive coupling: what have we learned? March 1993
Carbon monoxide coupling and functionalisation at a simple uranium coordination complex January 2011
Homologation and functionalization of carbon monoxide by a recyclable uranium complex May 2012
Facile Conversion of CO/H2 into Methoxide at a Uranium(III) Center June 2011
Mechanistic Studies on the Reductive Cyclooligomerisation of CO by U(III) Mixed Sandwich Complexes; the Molecular Structure of [(U(η-C 8 H 6 {Si i Pr 3 -1,4} 2 )(η-Cp*)] 2 (μ-η 11 -C 2 O 2 ) October 2008
Reductive Coupling of Acetonitrile by Uranium and Thorium Hydride Complexes To Give Cyanopentadienyl Dianion (C6N3H7)2− January 2008
Formation of an α-Diimine from Isocyanide Coupling Using Thorium(IV) and Uranium(IV) Phosphido–Methyl Complexes April 2019
The coordination and organometallic chemistry of UI3 and U{N(SiMe3)2}3: Synthetic reagents par excellence December 2012
The synthesis and versatile reducing power of low-valent uranium complexes January 2020