Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Polymer Chromophore–Catalyst Assembly for Photocatalytic CO 2 Reduction

Journal Article · · ACS Applied Energy Materials

Not provided.

Research Organization:
Univ. of North Carolina, Chapel Hill, NC (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0001011
OSTI ID:
1850676
Journal Information:
ACS Applied Energy Materials, Vol. 4, Issue 7; ISSN 2574-0962
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (44)

Photocatalytic reduction of CO2 using metal complexes December 2015
Heterogeneous Molecular Systems for Photocatalytic CO 2 Reduction with Water Oxidation October 2016
Recent Improvements in the Production of Solar Fuels: From CO 2 Reduction to Water Splitting and Artificial Photosynthesis January 2019
Artificial photosynthesis: opportunities and challenges of molecular catalysts January 2019
Light-Driven Heterogeneous Reduction of Carbon Dioxide: Photocatalysts and Photoelectrodes August 2015
Homogeneously Catalyzed Electroreduction of Carbon Dioxide—Methods, Mechanisms, and Catalysts January 2018
The Artificial Leaf January 2012
Finding the Way to Solar Fuels with Dye-Sensitized Photoelectrosynthesis Cells September 2016
Making solar fuels by artificial photosynthesis March 2011
Stable Molecular Photocathode for Solar-Driven CO 2 Reduction in Aqueous Solutions February 2019
Stabilization of Ruthenium(II) Polypyridyl Chromophores on Mesoporous TiO 2 Electrodes: Surface Reductive Electropolymerization and Silane Chemistry February 2019
Functional Polyelectrolytes December 2009
Light-Driven Water Oxidation Using Polyelectrolyte Layer-by-Layer Chromophore–Catalyst Assemblies July 2016
Polymer Chromophore-Catalyst Assembly for Solar Fuel Generation August 2016
Estimation of excited-state redox potentials by electron-transfer quenching. Application of electron-transfer theory to excited-state redox processes August 1979
The photophysics of photoredox catalysis: a roadmap for catalyst design January 2016
Efficient Photocatalysts for CO 2 Reduction January 2015
Photocatalytic CO2 reduction with high turnover frequency and selectivity of formic acid formation using Ru(II) multinuclear complexes August 2012
Light Harvesting Arrays of Polypyridine Ruthenium(II) Chromophores Prepared by Reversible Addition–Fragmentation Chain Transfer Polymerization March 2012
Ru(bpy) 3 2+ derivatized polystyrenes constructed by nitroxide-mediated radical polymerization. Relationship between polymer chain length, structure and photophysical properties January 2015
Polymer-Based Ruthenium(II) Polypyridyl Chromophores on TiO 2 for Solar Energy Conversion March 2016
Polymer-based chromophore–catalyst assemblies for solar energy conversion December 2017
Light Harvesting and Charge Separation in a π-Conjugated Antenna Polymer Bound to TiO 2 November 2014
Photocathode Chromophore–Catalyst Assembly via Layer-By-Layer Deposition of a Low Band-Gap Isoindigo Conjugated Polyelectrolyte January 2018
Ultrafast Dynamics in Multifunctional Ru(II)-Loaded Polymers for Solar Energy Conversion February 2015
Activating a Low Overpotential CO 2 Reduction Mechanism by a Strategic Ligand Modification on a Ruthenium Polypyridyl Catalyst December 2015
Judicious Ligand Design in Ruthenium Polypyridyl CO 2 Reduction Catalysts to Enhance Reactivity by Steric and Electronic Effects July 2016
Electrocatalytic CO 2 Reduction with a Ruthenium Catalyst in Solution and on Nanocrystalline TiO 2 May 2019
Click Chemistry beyond Metal-Catalyzed Cycloaddition June 2009
‘Click’ Chemistry in Polymer and Materials Science January 2007
Click Chemistry: A Powerful Tool to Create Polymer‐Based Macromolecular Chimeras July 2008
Optical absorption spectrum of excited ruthenium tris-bipyridyl (Ru(bpy)2+3) April 1979
Femtosecond Transient Absorption Anisotropy Study on [Ru(bpy) 3 ] 2+ and [Ru(bpy)(py) 4 ] 2+ . Ultrafast Interligand Randomization of the MLCT State June 2005
Experimental and Computational Exploration of Ground and Excited State Properties of Highly Strained Ruthenium Terpyridine Complexes July 2013
Ultrafast Excited-State Energy Migration Dynamics in an Efficient Light-Harvesting Antenna Polymer Based on Ru(II) and Os(II) Polypyridyl Complexes October 2001
Energy Transfer between Ru(II) and Os(II) Polypyridyl Complexes Linked to Polystyrene March 2002
Energy Migration Dynamics in a Ru(II)- and Os(II)-Based Antenna Polymer Embedded in a Disordered, Rigid Medium February 2004
Efficient photochemical reduction of CO 2 to CO by visible light irradiation of systems containing Re(bipy)(CO) 3 X or Ru(bipy) 3 2+ –Co 2+ combinations as homogeneous catalysts January 1983
One- and two-electron pathways in the electrocatalytic reduction of CO 2 by fac-Re(bpy)(CO) 3 Cl (bpy = 2,2′-bipyridine) January 1985
Efficient photocatalytic CO2 reduction using [Re(bpy) (CO)3{P(OEt)3}]+ May 1996
Involvement of a Binuclear Species with the Re−C(O)O−Re Moiety in CO 2 Reduction Catalyzed by Tricarbonyl Rhenium(I) Complexes with Diimine Ligands:  Strikingly Slow Formation of the Re−Re and Re−C(O)O−Re Species from Re(dmb)(CO) 3 S (dmb = 4,4‘-Dimethyl-2,2‘-bipyridine, S = Solvent) October 2003
Re(bipy-tBu)(CO) 3 Cl−improved Catalytic Activity for Reduction of Carbon Dioxide: IR-Spectroelectrochemical and Mechanistic Studies October 2010
Direct observation of the reduction of carbon dioxide by rhenium bipyridine catalysts January 2013
Development of highly efficient supramolecular CO 2 reduction photocatalysts with high turnover frequency and durability January 2012