Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

A 70-Year-Old Mystery in Technetium Chemistry Explained by the New Technetium Polyoxometalate [H 7 O 3 ] 4 [Tc 20 O 68 ]∙4H 2 O

Journal Article · · Chemistry - A European Journal
 [1];  [1];  [1];  [2];  [3];  [4];  [3];  [5];  [5];  [5]
  1. Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences Leninsky pr.31-4 Moscow Russian Federation
  2. Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences Leninsky pr.31-4 Moscow Russian Federation; Kurnakov Institute of General and Inorganic Chemistry Russian Academy of Sciences Moscow Leninsky pr.31 Russian Federation
  3. CEA, DES, ISEC, DMRC Univ Montpellier Marcoule France
  4. Université Côte d'Azur CNRS, ICN 06100 Nice France
  5. Department of Chemistry and Biochemistry University of Nevada Las Vegas 4505 Maryland Parkway Las Vegas NV 89154 USA
+ Show Author Affiliations

Not provided.

Research Organization:
Univ. of Texas at San Antonio, TX (United States); Stanford Univ., CA (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA)
DOE Contract Number:
NA0003948; AC02-76SF00515
OSTI ID:
1850429
Journal Information:
Chemistry - A European Journal, Vol. 27, Issue 54; ISSN 0947-6539
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English

References (31)

The Nature of the Technetium Species Formed During the Oxidation of Technetium Dioxide with Oxygen and Water: The Nature of the Technetium Species Formed During the Oxidation of Technetium Dioxide with Oxygen and Water March 2018
Speciation and reactivity of heptavalent technetium in strong acids January 2018
Preparation, magnetism and electronic structures of cadmium technetates January 2011
A Survey of Applications of Polyoxometalates February 1998
Assignment of pre-edge peaks in K-edge x-ray absorption spectra of 3d transition metal compounds: electric dipole or quadrupole? November 2008
Chemistry of Technetium and Rhenium Species during Low-Level Radioactive Waste Vitrification May 1996
Properties of Pertechnic Acid September 2019
Molecular and Electronic Structures of M 2 O 7 (M = Mn, Tc, Re) February 2017
Oxidation by permanganate: synthetic and mechanistic aspects January 2009
Heteropoly and isopoly anions as oxo complexes and their reducibility to mixed-valence blues August 1972
The heat capacity of potassium pertechnetate from 10 to 310 K. Entropy and Gibbs energy. Entropy of the aqueous pertechnetate ion January 1972
Production and Properties of a Long-Lived Radio-Isotope of Element 43 December 1947
Technetium chemistry, oxidation states and species March 1967
Technetium: The First Radioelement on the Periodic Table February 2017
Coordination of pertechnetate [TcO4]? to actinides January 2004
χ-Octamolybdate [MoV4MoVI4O24]4−: An Unusual Small Polyoxometalate in Partially Reduced Form from Nonaqueous Solvent Reduction March 2011
Polyoxometalates: Building Blocks for Functional Nanoscale Systems March 2010
Speciation of heptavalent technetium in sulfuric acid: structural and spectroscopic studies January 2010
Spontaneous reductive decomposition behavior of hydrogen permanganate in water for chemical decontamination of nuclear power plants July 2018
On the nature of heptavalent technetium in concentrated nitric and perchloric acid March 2013
Reactivity of HTcO4 with methanol in sulfuric acid: Tc-sulfate complexes revealed by XAFS spectroscopy and first principles calculations January 2013
Bond-valence parameters for solids April 1991
Molecular and Electronic Structure of New Technetium Complexes December 1993
Chemistry of Technetium. I. Preparation of Technetium Heptoxide January 1952
Density and activity of pertechnetic acid aqueous solutions at T = 298.15 K December 2015
Synthesis, structures and applications of electron-rich polyoxometalates February 2018
Hexamanganato(VII)-mangan(IV)-säure: eine „Pseudopermangansäure” September 1974
Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines January 1991
The nature of the volatile technetium species formed during vitrification of borosilicate glass May 2015
PLATON SQUEEZE: a tool for the calculation of the disordered solvent contribution to the calculated structure factors January 2015
Van der Waals Radii of Elements September 2001

Similar Records

A 70‐Year‐Old Mystery in Technetium Chemistry Explained by the New Technetium Polyoxometalate [H 7 O 3 ] 4 [Tc 20 O 68 ] ⋅ 4H 2 O
Journal Article · 2021 · Chemistry - A European Journal · OSTI ID:1811927
+7 more
Technetium(III) complexes with the tetradentate umbrella ligand tris (o-mercaptophenyl)phosphinate: X-ray structural characterization of Tc(P(o-C sub 6 H sub 4 S) sub 3 )(CNC sub 3 H sub 7 ) and Tc(P(o-C sub 6 H sub 4 S) sub 3 )(CNC sub 3 H sub 7 ) sub 2
Journal Article · 1991 · Inorganic Chemistry; (United States) · OSTI ID:6109028
+1 more
Retention of structural cores in the synthesis of high-nuclearity polyoxoalkoxomolybdate clusters encapsulating [Na(H{sub 2}O){sub 3}]{sup +} and [MoO{sub 3}] moieties. Hydrothermal syntheses and structures of (NH{sub 4}){sub 7}[NaH{sub 12}Mo{sub 16}O{sub 52}]{center_dot}4H{sub 2}O and (Me{sub 3}NH){sub 4}K{sub 2}[H{sub 14}Mo{sub 16}O{sub 52}]{center_dot}8H{sub 2}O and their structural relationships to the class of superclusters [XH{sub n}Mo{sub 42}O{sub 109}((OCH{sub 2}){sub 3}CR){sub 7}]{sup m{minus}} (X = Na(H{sub 2}O){sub 3}{sup +}: n=13, m=9; n=15, m=7. X = MoO{sub 3}: n = 14, m=9; n=13, m=10)
Journal Article · 1996 · Inorganic Chemistry · OSTI ID:264064
+2 more

Related Subjects

Chemistry