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Technetium electrochemistry at the turn of the century

Journal Article · · Journal of Electroanalytical Chemistry

Not provided.

Research Organization:
Univ. of California, Oakland, CA (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA)
DOE Contract Number:
NA0000979; NA0003180
OSTI ID:
1850285
Journal Information:
Journal of Electroanalytical Chemistry, Vol. 893, Issue C; ISSN 1572-6657
Publisher:
Elsevier
Country of Publication:
United States
Language:
English

References (106)

Technetium: The First Radioelement on the Periodic Table journal February 2017
Some Chemical Properties of Element 43 journal September 1937
Nature’s uncommon elements: plutonium and technetium journal January 1999
Electrochemical reduction of MnO4−, TcO4− and ReO4− in organic solvents journal January 1976
Disproportionation of the technetate ion in aqueous alkaline media. An electrochemical study journal September 1969
Mechanism and kinetics of the stepwise voltammetric reduction of pertechnetate in alkaline solution to Tc(VI, Tc(V) and Tc(IV) journal March 1987
Intermediate oxidation states of technetium in alkaline solutions journal November 2018
Reactivity of HTcO4 with methanol in sulfuric acid: Tc-sulfate complexes revealed by XAFS spectroscopy and first principles calculations journal January 2013
Electrochemical and spectroelectrochemical studies of pertechnetate electroreduction in acidic media journal August 2012
Thin layer spectroelectrochemical studies of pertechnetate reduction on the gold electrodes in acidic media journal March 2014
Characterization of Electrodeposited Technetium on Gold Foil journal January 2011
Thermodynamic Properties of Technetium and Rhenium Compounds. II. Heats of Formation of Technetium Heptoxide and Pertechnic Acid, Potential of the Technetium-(IV)-Technetium(VII) Couple, and a Potential Diagram for Technetium 1,2 journal December 1953
Some aspects of the polarographic behaviour of technetium and rhenium journal August 1959
Technetium: Chemistry and Radiopharmaceutical Applications book February 2000
Recent Advances in Technetium Halide Chemistry journal December 2013
The influence of deviations in process parameters on the purification of uranium from different radionuclides journal July 2016
New Approach to the Nuclear Fuel Reprocessing in Non-acidic Aqueous Solutions journal October 2001
Technetium transmutation and production of artificial stable ruthenium journal December 2004
XAS study of technetium(IV) polymer formation in mixed sulphate/chloride media journal January 2002
The Electrode Potential of the Tc(IV)-Tc(VII) Couple journal July 1991
Speciation of technetium and rhenium complexes by in situ XAS-electrochemistry journal May 2006
Solubility control of technetium release from Saltstone by TcO2·xH2O journal June 2013
Technetium behaviour in Boom Clay – a laboratory and field study journal September 2002
Differential pulse voltammetric determination of U(VI)-Tc(VII) and U(VI)-Cr(VI) in alkaline solutions journal March 2001
Redox chemistry of Tc(VII)/Tc(IV) in dilute to concentrated NaCl and MgCl2 solutions journal January 2015
Thermodynamic description of Tc( iv ) solubility and hydrolysis in dilute to concentrated NaCl, MgCl 2 and CaCl 2 solutions journal January 2016
Products of Pertechnetate Radiolysis in Highly Alkaline Solution:  Structure of TcO2·xH2O journal February 2002
Current Status of the Thermodynamic Data for Technetium and Its Compounds and Aqueous Species journal January 2005
Dissolution of Technetium(IV) Oxide by Natural and Synthetic Organic Ligands under both Reducing and Oxidizing Conditions journal June 2011
Activity coefficients and pitzer parameters in the systems Na+/Cs+/Cl-/TcO 4 - or ClO 4 - /H2O at 25°C journal June 1997
Pertechnic Acid : an Aperiodic Variation in Acid Strength journal July 1963
Speciation and reactivity of heptavalent technetium in strong acids journal January 2018
On the nature of heptavalent technetium in concentrated nitric and perchloric acid journal March 2013
Properties of Pertechnic Acid journal September 2019
Thermodynamic considerations and prediction of the primary coolant activity of 99Tc journal April 2005
Design and evaluation of “3 + 1” mixed ligand oxorhenium and oxotechnetium complexes bearing a nitroaromatic group with potential application in nuclear medicine oncology journal October 2006
Technetium and rhenium: coordination chemistry and nuclear medical applications journal January 2006
Electrochemistry and spectroelectrochemistry of perrhenates in sulfuric acid solutions journal January 2021
Electrochemistry of pertechnetate on ultramicroelectrode: A new quality control for radiopharmaceuticals manufactured at hospital in nuclear medicine journal February 2015
A novel electrochemical technique for the production of clinical grade 99mTc using (n, γ)99Mo journal January 2010
Electrochemical behavior of platinum and gold electrodes in the aprotic ionic liquid N,N-Trimethylbutylammonium Bis(trifluoromethanesulfonyl)imide journal August 2018
Electrochemical and Spectroscopic Properties of Technetium in Fused Alkali Metal Chlorides journal October 2010
Electrochemical behaviour of technetium(VII) in acidic medium journal October 1979
Technetium Ëlectrodeposition from Aqueous Formate Solutions : Electrolysis Kinetics and Material Balance Study journal October 1998
Production, detection, and characterization of transient hexavalent technetium in aqueous alkaline media by pulse radiolysis and very fast scan cyclic voltammetry journal January 1978
Radiolysis of TcO 4 - in Alkaline, Nitrate Solutions:  Reduction by NO 3 2- journal October 2001
Surprising formation of quasi-stable Tc( vi ) in high ionic strength alkaline media journal January 2018
Anodic dissolution of Tc metal in HNO3 solutions journal January 2015
Stability of technetium in the moderate oxidation states in acidic media journal May 2016
Intermediate oxidation states of technetium in concentrated sulfuric acid solutions journal April 2018
Redox interactions of technetium with neptunium in acid solutions journal May 2018
Photoreduction of 99 Tc Pertechnetate by Nanometer-Sized Metal Oxides: New Strategies for Formation and Sequestration of Low-Valent Technetium journal November 2011
99 Tc and Re Incorporated into Metal Oxide Polyoxometalates: Oxidation State Stability Elucidated by Electrochemistry and Theory journal July 2012
Predominance Diagrams of Spent Nuclear Fuel Materials in LiCl-KCl and NaCl-KCl Molten Salt Eutectics journal December 2016
Electrochemical behaviour of technetium in acetic buffer journal January 1999
Electroreduction of pertechnetate ions in concentrated acetate solutions journal July 2020
Technetium electrochemistry. 5. Spectroelectrochemical studies on the hexachlorotechnetate(IV) and hexabromotechnetate(IV) complexes in aqueous media journal November 1987
Electrochemical studies on halide and pseudo-halide complexes of technetium and rhenium journal January 1979
Bis(tetraphenylarsonium) hexafluoridotechnetate(IV) dihydrate: preparation, structure and spectroscopic analysis journal November 2019
Technetium electrochemistry. 7. Electrochemical and spectroelectrochemical studies on technetium(III) and -(II) complexes containing polypyridyl ligands journal February 1991
Technetium electrochemistry. 6. Electrochemical behavior of cationic rhenium and technetium complexes in aqueous and aqueous micellar solutions journal October 1988
Technetium electrochemistry. 3. Spectroelectrochemical studies on the mixed-ligand technetium(III) complexes trans-[Tc(PR2R')2L]+ where L is a tetradentate Schiff base ligand and PR2R' is a monodentate tertiary phosphine ligand journal July 1985
Technetium electrochemistry. 2. Electrochemical and spectroelectrochemical studies of the bis(tertiary phosphine) (D) complexes trans-[TcIIID2X2]+ (X =chlorine or bromine) journal April 1984
Technetium electrochemistry. 1. Spectroelectrochemical studies of halogen, diars, and diphos complexes of technetium in nonaqueous media journal October 1981
Mixed-ligand complexes of technetium XIII. A new and facile synthesis, structure and electrochemical behaviour of trans-[Tc(dppe)2(butNC)2](PF6)· ethanol (dppe = bis(diphenylphosphino)ethane, butNC= tert-butylisocyanide) journal March 1995
Photophysics and Luminescence Spectroelectrochemistry of [Tc(dmpe) 3 ] +/2+ (dmpe = 1,2- bis (dimethylphosphino)ethane) journal November 2013
Fluoridonitrosyl Complexes of Technetium(I) and Technetium(II). Synthesis, Characterization, Reactions, and DFT Calculations journal May 2014
[Tc II (NO)(trifluoroacetate) 4 F] 2− – synthesis and reactions journal January 2017
Chemistry of trans-aquonitrosyltetraamminetechnetium(I) and related studies journal August 1976
Technetium bis(.mu.-oxo) dimers of 1,4,7-triazacyclonane-N,N',N''-triacetate (TCTA). Synthesis and characterization of [(TCTA)Tc(.mu.-O)2Tc(TCTA)]n- (n = 2, 3) and the crystal structure of Ba2[(TCTA)Tc(.mu.-O)2Tc(TCTA)](ClO4).9H2O journal October 1989
Hydrothermal synthesis and solid-state structure of Tc2(μ-O2CCH3)4Cl2 journal July 2013
Hydrothermal synthesis and solid-state structures of polynuclear technetium iodide compounds journal January 2015
Synthesis and Structure of Technetium Trichloride journal November 2010
Molecular and Electronic Structure of New Technetium Complexes journal December 1993
Darstellung, Schwingungsspektren und Normalkoordinatenanalyse der Acetatochloroditechnetate(III), cis-Tc 2 (O 2 CCH 3 ) 2 Cl 4 L 2 (L = axiale Donorbase) sowie Kristallstruktur von cis-Tc 2 (O 2 CCH 3 ) 2 Cl 4 ((CH 3 ) 2 NCOCH 3 ) 2 / Preparation, Vibrational Spectra and Normal Coordinate Analysis of Acetatochloroditechnetates(III), cis-Tc 2 (O 2 CCH 3 ) 2 Cl 4 L 2 (L = Axial Donorbase) and the Crystal Structure of cis-Tc 2 (O 2 CCH 3 ) 2 Cl 4 ((CH 3 ) 2 NCOCH 3 ) 2 journal October 1991
Group 7 Metal-Metal Bonds book January 2015
A Trigonal-Prismatic Hexanuclear Technetium(II) Bromide Cluster: Solid-State Synthesis and Crystallographic and Electronic Structure journal May 2013
Magnetic and electrochemical properties of transition metal complexes with multiple metal-to-metal bonds. I. Octachloroditechnetate(n-) and octachlorodirhenate(n-) with n = 2 and 3 journal February 1975
Metal–metal multiply-bonded complexes of technetium. journal May 1999
Metal-Metal Multiply Bonded Complexes of Technetium. 1. Synthesis and Structural Characterization of Phosphine Complexes That Contain a Tc-Tc Multiple Bond journal May 1994
Metal−Metal Multiply-Bonded Complexes of Technetium. 3. 1 Preparation and Characterization of Phosphine Complexes of Technetium Possessing a Metal−Metal Bond Order of 3.5 journal January 1996
Metal-Metal Multiply-Bonded Complexes of Technetium. 2. Preparation and Characterization of the Fully Solvated Ditechnetium Cation [Tc2(CH3CN)10]4+ journal March 1995
Metal−Metal Multiply-Bonded Complexes of Technetium. 4. 1 Photodissociation of the Tc≡Tc Triple Bond in [Tc 2 (CH 3 CN) 10 ][BF 4 ] 4 journal January 1996
Structural, Spectroscopic, and Multiconfigurational Quantum Chemical Investigations of the Electron-Rich Metal−Metal Triple-Bonded Tc 2 X 4 (PMe 3 ) 4 (X = Cl, Br) Complexes journal July 2010
Radioactive electron-rich metal-metal triple bonds: the Tc2X4(PMe3)4 complexes (X=Cl, Br) journal August 2010
Electrochemistry of quadruply bonded molybdenum dimers. Evidence for metal-to-halide back-bonding journal December 1986
Synthesis, Structures, and Properties of New Chalcogenide-Capped Octahedral Hexatechnetium(III) Complexes [Tc 6 S 8 X 6 ] 4- (X = Br, I), [Tc 6 Se 8 I 2 ], and [Tc 6 Te 15 ] journal March 2010
Synthesis, Spectroscopic and Electrochemical Properties, and Electronic Structures of Octahedral Hexatechnetium(III) Clusters [Tc 6 Q 8 (CN) 6 ] 4− (Q = S, Se) journal June 2010
Electrochemical dissolution of simulated "white inclusions" in nitric acid. Linear voltammetry study with Mo, Re, Ru metals and their alloys electrodes journal July 2003
Metallic fission-product inclusions in irradiated oxide fuels journal February 1968
Physicochemical behavior of uranium and technetium in some new stages of the nuclear fuel cycle journal May 2008
Nanostructure of metallic particles in light water reactor used nuclear fuel journal June 2015
Chemical and electrochemical behavior of metallic technetium in acidic media journal May 2013
Electrochemistry of Actinides and Selected Fission Products in the Head End of Spent Nuclear Fuel Reprocessing journal January 2012
Electrochemical study of corrosion and dissolution of Tc metal in 0.5–6.0 M HNO3 journal January 2013
Electrochemical studies of technetium–ruthenium alloys in HNO3: Implications for the behavior of technetium waste forms journal January 2017
The Corrosion Behavior of Technetium Metal Exposed to Aqueous Sulfate and Chloride Solutions journal January 2017
An Ion Selective Electrode for the Determination of Pertechnetate Ions journal June 2020
An Ion-Selective Plasticized PVC Membrane Electrode for Tc(VII) Determination journal December 2003
A tetradecylphosphonium compounds–based membrane sensor for potentiometric quantitation of pertechnetate-ions in cementitious radioactive waste journal May 2020
Technetium Chemistry in the Fuel Cycle: Combining Basic and Applied Studies journal June 2012
Transmutation in Reactor and Aqueous Corrosion Resistance of Technetium Metal journal January 2005
A preliminary design study for the HYPER system journal February 2003
Technetium transmutation in thin layer coating on PWR fuel rods journal November 2015
Electrodeposition of metallic uranium at near ambient conditions from room temperature ionic liquid journal January 2011
Unusual Electrochemical Properties of Low-Doped Boron-Doped Diamond Electrodes Containing sp 2 Carbon journal January 2020

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