Two-Dimensional Pd Rafts Confined in Copper Nanosheets for Selective Semihydrogenation of Acetylene

Fu, Xianbiao; Liu, Jian; Kanchanakungwankul, Siriluk; Hu, Xiaobing; Yue, Qin; Truhlar, Donald G.; Hupp, Joseph T.; Kang, Yijin

doi:10.1021/acs.nanolett.1c01124

Two-Dimensional Pd Rafts Confined in Copper Nanosheets for Selective Semihydrogenation of Acetylene

Journal Article · 25 June 2021 · Nano Letters

DOI:https://doi.org/10.1021/acs.nanolett.1c01124· OSTI ID:1849847

^[1]; ^[2]; ^[3]; ^[4]; Yue, Qin ^[5]; ^[3]; ^[2]; ^[6]

Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu, Sichuan 610054, China; Institute for Sustainability and Energy at Northwestern, Northwestern University, Evanston, Illinois 60208, United States; OSTI
Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States
Department of Chemistry, Chemical Theory Center, and Minnesota Supercomputing Institute, University of Minnesota, Minneapolis, Minnesota 55455, United States
Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, United States
Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu, Sichuan 610054, China
Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu, Sichuan 610054, China; Institute for Sustainability and Energy at Northwestern, Northwestern University, Evanston, Illinois 60208, United States

Not provided.

Research Organization:: Northwestern Univ., Evanston, IL (United States); Univ. of Minnesota, Minneapolis, MN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: FG02-08ER15967; SC0012702

OSTI ID:: 1849847

Journal Information:: Nano Letters, Journal Name: Nano Letters Journal Issue: 13 Vol. 21; ISSN 1530-6984

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

References (42)

Investigation of the preparation methodologies of Pd-Cu single atom alloy catalysts for selective hydrogenation of acetylene Cao, Xinxiang; Mirjalili, Arash; Wheeler, James Frontiers of Chemical Science and Engineering, Vol. 9, Issue 4 https://doi.org/10.1007/s11705-015-1547-x	journal	November 2015
Precisely Controlled Porous Alumina Overcoating on Pd Catalyst by Atomic Layer Deposition: Enhanced Selectivity and Durability in Hydrogenation of 1,3-Butadiene Yi, Hong; Du, Hongyi; Hu, Yingli ACS Catalysis, Vol. 5, Issue 5 https://doi.org/10.1021/acscatal.5b00129	journal	March 2015
Surface coordination layer passivates oxidation of copper Peng, Jian; Chen, Bili; Wang, Zhichang Nature, Vol. 586, Issue 7829 https://doi.org/10.1038/s41586-020-2783-x	journal	October 2020
Alternative route for electrochemical ammonia synthesis by reduction of nitrate on copper nanosheets Fu, Xianbiao; Zhao, Xingang; Hu, Xiaobing Applied Materials Today, Vol. 19 https://doi.org/10.1016/j.apmt.2020.100620	journal	June 2020
Adsorption Site Regulation to Guide Atomic Design of Ni–Ga Catalysts for Acetylene Semi‐Hydrogenation Cao, Yueqiang; Zhang, Hao; Ji, Shufang Angewandte Chemie International Edition, Vol. 59, Issue 28 https://doi.org/10.1002/anie.202004966	journal	May 2020
Pt/Cu single-atom alloys as coke-resistant catalysts for efficient C–H activation Marcinkowski, Matthew D.; Darby, Matthew T.; Liu, Jilei Nature Chemistry, Vol. 10, Issue 3 https://doi.org/10.1038/nchem.2915	journal	January 2018
Selective hydrogenation of phenylacetylene over bimetallic Pd–Cu/Al2O3 and Pd–Zn/Al2O3 catalysts Wang, Zhanqi; Yang, Lei; Zhang, Rui Catalysis Today, Vol. 264 https://doi.org/10.1016/j.cattod.2015.08.018	journal	April 2016
Preparation and investigation of Pd doped Cu catalysts for selective hydrogenation of acetylene Cao, Xinxiang; Lyu, Tengteng; Xie, Wentao Frontiers of Chemical Science and Engineering, Vol. 14, Issue 4 https://doi.org/10.1007/s11705-019-1822-3	journal	June 2019
Dish-like higher-ordered palladium nanostructures through metal ion-ligand complexation Yin, Xi; Shi, Miao; Kwok, Kam Sang Nano Research, Vol. 11, Issue 6 https://doi.org/10.1007/s12274-018-1993-0	journal	May 2018
Thiol Treatment Creates Selective Palladium Catalysts for Semihydrogenation of Internal Alkynes Zhao, Xiaojing; Zhou, Lingyun; Zhang, Wuyong Chem, Vol. 4, Issue 5 https://doi.org/10.1016/j.chempr.2018.02.011	journal	May 2018
Acetylene Coupling on Cu(111): Formation of Butadiene, Benzene, and Cyclooctatetraene Kyriakou, Georgios; Kim, Jisu; Tikhov, Mintcho S. The Journal of Physical Chemistry B, Vol. 109, Issue 21 https://doi.org/10.1021/jp044213c	journal	June 2005
Tackling CO Poisoning with Single-Atom Alloy Catalysts Liu, Jilei; Lucci, Felicia R.; Yang, Ming Journal of the American Chemical Society, Vol. 138, Issue 20 https://doi.org/10.1021/jacs.6b03339	journal	May 2016
Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limit Lucci, Felicia R.; Liu, Jilei; Marcinkowski, Matthew D. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9550	journal	October 2015
Two-dimensional copper nanosheets for electrochemical reduction of carbon monoxide to acetate Luc, Wesley; Fu, Xianbiao; Shi, Jianjian Nature Catalysis, Vol. 2, Issue 5 https://doi.org/10.1038/s41929-019-0269-8	journal	April 2019
Controllable assembly of Pd nanosheets: a solution for 2D materials storage Shan, Hao; Liu, Lei; He, Jiaqing CrystEngComm, Vol. 19, Issue 25 https://doi.org/10.1039/C7CE00712D	journal	January 2017
Single atom alloy surface analogs in Pd0.18Cu15 nanoparticles for selective hydrogenation reactions Boucher, Matthew B.; Zugic, Branko; Cladaras, George Physical Chemistry Chemical Physics, Vol. 15, Issue 29 https://doi.org/10.1039/c3cp51538a	journal	January 2013
Freestanding palladium nanosheets with plasmonic and catalytic properties Huang, Xiaoqing; Tang, Shaoheng; Mu, Xiaoliang Nature Nanotechnology, Vol. 6, Issue 1 https://doi.org/10.1038/nnano.2010.235	journal	December 2010
Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous Hydrogenations Kyriakou, Georgios; Boucher, Matthew B.; Jewell, April D. Science, Vol. 335, Issue 6073 https://doi.org/10.1126/science.1215864	journal	March 2012
PdZn Intermetallic Nanostructure with Pd–Zn–Pd Ensembles for Highly Active and Chemoselective Semi-Hydrogenation of Acetylene Zhou, Huiran; Yang, Xiaofeng; Li, Lin ACS Catalysis, Vol. 6, Issue 2 https://doi.org/10.1021/acscatal.5b01933	journal	January 2016
Facet engineering accelerates spillover hydrogenation on highly diluted metal nanocatalysts Jiang, Lizhi; Liu, Kunlong; Hung, Sung-Fu Nature Nanotechnology, Vol. 15, Issue 10 https://doi.org/10.1038/s41565-020-0746-x	journal	August 2020
Understanding catalysis Roduner, Emil Chem. Soc. Rev., Vol. 43, Issue 24 https://doi.org/10.1039/C4CS00210E	journal	January 2014
Hanoi Tower-like Multilayered Ultrathin Palladium Nanosheets Yin, Xi; Liu, Xinhong; Pan, Yung-Tin Nano Letters, Vol. 14, Issue 12 https://doi.org/10.1021/nl503879a	journal	November 2014
Modern Trends in Catalyst and Process Design for Alkyne Hydrogenations Crespo-Quesada, Micaela; Cárdenas-Lizana, Fernando; Dessimoz, Anne-Laure ACS Catalysis, Vol. 2, Issue 8 https://doi.org/10.1021/cs300284r	journal	July 2012
Palladium assisted copper/alumina catalysts for the selective hydrogenation of propyne, propadiene and propene mixed feeds McCue, Alan J.; Gibson, Andrew; Anderson, James A. Chemical Engineering Journal, Vol. 285 https://doi.org/10.1016/j.cej.2015.09.118	journal	February 2016
Precise Control of Cu Nanoparticle Size and Catalytic Activity through Pore Templating in Zr Metal–Organic Frameworks Mian, Mohammad Rasel; Redfern, Louis R.; Pratik, Saied Md Chemistry of Materials, Vol. 32, Issue 7 https://doi.org/10.1021/acs.chemmater.0c00059	journal	March 2020
Intermetallic Ni _x M _y ( M = Ga and Sn) Nanocrystals: A Non-precious Metal Catalyst for Semi-Hydrogenation of Alkynes Liu, Yuxi; Liu, Xiangwen; Feng, Quanchen Advanced Materials, Vol. 28, Issue 23 https://doi.org/10.1002/adma.201600603	journal	April 2016
A DFT study and micro-kinetic analysis of acetylene selective hydrogenation on Pd-doped Cu(111) surfaces Ma, Ling-Ling; Lv, Cun-Qin; Wang, Gui-Chang Applied Surface Science, Vol. 410 https://doi.org/10.1016/j.apsusc.2017.01.084	journal	July 2017
Selective Hydrogenation of Acetylene to Ethylene in the Presence of a Carbonaceous Surface Layer on a Pd/Cu(111) Single-Atom Alloy Kruppe, Christopher M.; Krooswyk, Joel D.; Trenary, Michael ACS Catalysis, Vol. 7, Issue 12 https://doi.org/10.1021/acscatal.7b02862	journal	October 2017
Ultrastable atomic copper nanosheets for selective electrochemical reduction of carbon dioxide Dai, Lei; Qin, Qing; Wang, Pei Science Advances, Vol. 3, Issue 9 https://doi.org/10.1126/sciadv.1701069	journal	September 2017
Theoretical Study of the Interaction of Molecular Hydrogen with PdCu(111) Bimetallic Surfaces Sousa, Carmen; Bertin, Virineya; Illas, Francesc The Journal of Physical Chemistry B, Vol. 105, Issue 9 https://doi.org/10.1021/jp003349h	journal	February 2001
Size-controlled synthesis of Pd nanosheets for tunable plasmonic properties Li, Yi; Yan, Yucong; Li, Yuheng CrystEngComm, Vol. 17, Issue 8 https://doi.org/10.1039/C4CE02062F	journal	January 2015
Breaking the scaling relationship via thermally stable Pt/Cu single atom alloys for catalytic dehydrogenation Sun, Guodong; Zhao, Zhi-Jian; Mu, Rentao Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06967-8	journal	October 2018
Novel surfactant-directed synthesis of ultra-thin palladium nanosheets as efficient electrocatalysts for glycerol oxidation Xu, Dongdong; Liu, Ying; Zhao, Shulin Chemical Communications, Vol. 53, Issue 10 https://doi.org/10.1039/C6CC08953D	journal	January 2017
Surface and Subsurface Hydrogen: Adsorption Properties on Transition Metals and Near-Surface Alloys Greeley, Jeff; Mavrikakis, Manos The Journal of Physical Chemistry B, Vol. 109, Issue 8 https://doi.org/10.1021/jp046540q	journal	March 2005
Modulating fcc and hcp Ruthenium on the Surface of Palladium–Copper Alloy through Tunable Lattice Mismatch Yao, Yancai; He, Dong Sheng; Lin, Yue Angewandte Chemie International Edition, Vol. 55, Issue 18 https://doi.org/10.1002/anie.201601016	journal	March 2016
Active Sites of Pd-Doped Flat and Stepped Cu(111) Surfaces for H ₂ Dissociation in Heterogeneous Catalytic Hydrogenation Fu, Qiang; Luo, Yi ACS Catalysis, Vol. 3, Issue 6 https://doi.org/10.1021/cs400267x	journal	April 2013
Catalytic performance of Pd-promoted Cu hydrotalcite-derived catalysts in partial hydrogenation of acetylene: effect of Pd–Cu alloy formation Liu, Yanan; He, Yufei; Zhou, Daran Catalysis Science & Technology, Vol. 6, Issue 9 https://doi.org/10.1039/C5CY01516B	journal	January 2016
Copper Can Still Be Epitaxially Deposited on Palladium Nanocrystals To Generate Core–Shell Nanocubes Despite Their Large Lattice Mismatch Jin, Mingshang; Zhang, Hui; Wang, Jinguo ACS Nano, Vol. 6, Issue 3 https://doi.org/10.1021/nn2050278	journal	February 2012
Isolated Single-Atom Pd Sites in Intermetallic Nanostructures: High Catalytic Selectivity for Semihydrogenation of Alkynes Feng, Quanchen; Zhao, Shu; Wang, Yu Journal of the American Chemical Society, Vol. 139, Issue 21 https://doi.org/10.1021/jacs.7b01471	journal	May 2017
Platinum–copper single atom alloy catalysts with high performance towards glycerol hydrogenolysis Zhang, Xi; Cui, Guoqing; Feng, Haisong Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-13685-2	journal	December 2019
Performance of Cu-Alloyed Pd Single-Atom Catalyst for Semihydrogenation of Acetylene under Simulated Front-End Conditions Pei, Guang Xian; Liu, Xiao Yan; Yang, Xiaofeng ACS Catalysis, Vol. 7, Issue 2 https://doi.org/10.1021/acscatal.6b03293	journal	January 2017
Ionic Layer Epitaxy of Nanometer-Thick Palladium Nanosheets with Enhanced Electrocatalytic Properties Yin, Xin; Chen, Qinyi; Tian, Peng Chemistry of Materials, Vol. 30, Issue 10 https://doi.org/10.1021/acs.chemmater.8b00575	journal	April 2018

Similar Records

Decoding Active Sites for Highly Efficient Semihydrogenation of Acetylene in Palladium–Copper Nanoalloys

Journal Article · 2024 · Nano Letters · OSTI ID:2568029

Two-dimensional copper nanosheets for electrochemical reduction of carbon monoxide to acetate

Journal Article · 2019 · Nature Catalysis · OSTI ID:1614352

Cubine, a Quasi Two-Dimensional Copper–Bismuth Nanosheet

Journal Article · 2017 · Chemistry of Materials · OSTI ID:1470176

Related Subjects

Chemistry
Materials Science
Physics
Science & Technology - Other Topics

Two-Dimensional Pd Rafts Confined in Copper Nanosheets for Selective Semihydrogenation of Acetylene

Citation Formats

References (42)

Similar Records

Related Subjects