Cross-Linked Polymeric Micelles as Catalytic Nanoreactors

Qu, Peiyuan; Kuepfert, Michael; Ahmed, Eman; Liu, Fangbei; Weck, Marcus

doi:10.1002/ejic.202100013

Cross-Linked Polymeric Micelles as Catalytic Nanoreactors

Journal Article · 25 March 2021 · European Journal of Inorganic Chemistry

DOI:https://doi.org/10.1002/ejic.202100013· OSTI ID:1849452

Qu, Peiyuan ^[1]; Kuepfert, Michael ^[1]; ^[1]; Liu, Fangbei ^[1]; ^[1]

Molecular Design Institute and Department of Chemistry New York University 100 Washington Square East New York, NY 10003 USA

Not provided.

Research Organization:: Georgia Institute of Technology, Atlanta, GA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: FG02-03ER15459

OSTI ID:: 1849452

Journal Information:: European Journal of Inorganic Chemistry, Vol. 2021, Issue 15; ISSN 1434-1948

Publisher:: ChemPubSoc Europe

Country of Publication:: United States

Language:: English

References (78)

Sustainable Fe-ppm Pd nanoparticle catalysis of Suzuki-Miyaura cross-couplings in water Handa, S.; Wang, Y.; Gallou, F. Science, Vol. 349, Issue 6252 https://doi.org/10.1126/science.aac6936	journal	September 2015
Acid–Base Bifunctional Shell Cross-Linked Micelle Nanoreactor for One-Pot Tandem Reaction Lee, Li-Chen; Lu, Jie; Weck, Marcus ACS Catalysis, Vol. 6, Issue 2 https://doi.org/10.1021/acscatal.5b02538	journal	January 2016
50th Anniversary Perspective : RAFT Polymerization—A User Guide Perrier, Sébastien Macromolecules, Vol. 50, Issue 19 https://doi.org/10.1021/acs.macromol.7b00767	journal	September 2017
Synthesis of Core Functionalized Polymer Micelles and Shell Cross-Linked Nanoparticles Ievins, Alexander D.; Wang, Xiaofan; Moughton, Adam O. Macromolecules, Vol. 41, Issue 9 https://doi.org/10.1021/ma702702j	journal	April 2008
Shell Cross‐Linked Micelles as Nanoreactors for Enantioselective Three‐Step Tandem Catalysis Kuepfert, Michael; Cohen, Aaron E.; Cullen, Olivia Chemistry – A European Journal, Vol. 24, Issue 70 https://doi.org/10.1002/chem.201804956	journal	November 2018
Cascade Reactions in Multicompartmentalized Polymersomes Peters, Ruud J. R. W.; Marguet, Maïté; Marais, Sébastien Angewandte Chemie International Edition, Vol. 53, Issue 1 https://doi.org/10.1002/anie.201308141	journal	November 2013
Alternative approaches for the aqueous–organic biphasic hydroformylation of higher alkenes Obrecht, Lorenz; Kamer, Paul C. J.; Laan, Wouter Catal. Sci. Technol., Vol. 3, Issue 3 https://doi.org/10.1039/C2CY20538F	journal	January 2013
Multicompartment Block Polymer Micelles Moughton, Adam O.; Hillmyer, Marc A.; Lodge, Timothy P. Macromolecules, Vol. 45, Issue 1 https://doi.org/10.1021/ma201865s	journal	December 2011
Catalytic polymeric nanoreactors: more than a solid supported catalyst Cotanda, Pepa; Petzetakis, Nikos; O'Reilly, Rachel K. MRS Communications, Vol. 2, Issue 4 https://doi.org/10.1557/mrc.2012.26	journal	October 2012
Biocatalysis in Polymersomes: Improving Multienzyme Cascades with Incompatible Reaction Steps by Compartmentalization Klermund, Ludwig; Poschenrieder, Sarah T.; Castiglione, Kathrin ACS Catalysis, Vol. 7, Issue 6 https://doi.org/10.1021/acscatal.7b00776	journal	May 2017
The Heck Reaction as a Sharpening Stone of Palladium Catalysis Beletskaya, Irina P.; Cheprakov, Andrei V. Chemical Reviews, Vol. 100, Issue 8 https://doi.org/10.1021/cr9903048	journal	August 2000
Core-crosslinked polymeric micelles: Principles, preparation, biomedical applications and clinical translation Talelli, Marina; Barz, Matthias; Rijcken, Cristianne J. F. Nano Today, Vol. 10, Issue 1 https://doi.org/10.1016/j.nantod.2015.01.005	journal	February 2015
Multifunctional Heterogeneous Catalysts: SBA-15-Containing Primary Amines and Sulfonic Acids Zeidan, Ryan K.; Hwang, Son-Jong; Davis, Mark E. Angewandte Chemie, Vol. 118, Issue 38 https://doi.org/10.1002/ange.200602243	journal	September 2006
Polymeric micelle stability Owen, Shawn C.; Chan, Dianna P. Y.; Shoichet, Molly S. Nano Today, Vol. 7, Issue 1 https://doi.org/10.1016/j.nantod.2012.01.002	journal	February 2012
Small-molecule delivery by nanoparticles for anticancer therapy Chen, Zhuo (Georgia) Trends in Molecular Medicine, Vol. 16, Issue 12 https://doi.org/10.1016/j.molmed.2010.08.001	journal	December 2010
Functionalized Organocatalytic Nanoreactors: Hydrophobic Pockets for Acylation Reactions in Water Cotanda, Pepa; Lu, Annhelen; Patterson, Joseph P. Macromolecules, Vol. 45, Issue 5 https://doi.org/10.1021/ma2027462	journal	February 2012
Water-Soluble Nanospheres of Poly(2-cinnamoylethyl methacrylate)- block -poly(acrylic acid) Henselwood, Fred; Liu, Guojun Macromolecules, Vol. 30, Issue 3 https://doi.org/10.1021/ma961401v	journal	February 1997
Compartmentalized Nanoreactors for One-Pot Redox-Driven Transformations Qu, Peiyuan; Kuepfert, Michael; Jockusch, Steffen ACS Catalysis, Vol. 9, Issue 4 https://doi.org/10.1021/acscatal.8b04667	journal	February 2019
A review of stimuli-responsive nanocarriers for drug and gene delivery Ganta, Srinivas; Devalapally, Harikrishna; Shahiwala, Aliasgar Journal of Controlled Release, Vol. 126, Issue 3 https://doi.org/10.1016/j.jconrel.2007.12.017	journal	March 2008
Thermosensitive core-shell microgel as a “nanoreactor” for catalytic active metal nanoparticles Lu, Yan; Proch, Sebastian; Schrinner, Marc Journal of Materials Chemistry, Vol. 19, Issue 23 https://doi.org/10.1039/b822673n	journal	January 2009
Recent Developments in the Area of Click‐Crosslinked Nanocarriers for Drug Delivery Dai, Yu; Chen, Xin; Zhang, Xiaojin Macromolecular Rapid Communications, Vol. 40, Issue 3 https://doi.org/10.1002/marc.201800541	journal	November 2018
Metal-complex-bearing star polymers by metal-catalyzed living radical polymerization: Synthesis and characterization of poly(methyl methacrylate) star polymers with Ru(II)-embedded microgel cores Terashima, Takaya; Ouchi, Makoto; Ando, Tsuyoshi Journal of Polymer Science Part A: Polymer Chemistry, Vol. 44, Issue 17 https://doi.org/10.1002/pola.21597	journal	January 2006
Oxidation of sec‐alcohols with Ru(II)‐bearing microgel star polymer catalysts via hydrogen transfer reaction: Unique microgel‐core catalysis Terashima, Takaya; Ouchi, Makoto; Ando, Tsuyoshi Journal of Polymer Science Part A: Polymer Chemistry, Vol. 49, Issue 5 https://doi.org/10.1002/pola.24501	journal	January 2011
Aldol reactions catalyzed by l-proline functionalized polymeric nanoreactors in water Lu, Annhelen; Cotanda, Pepa; Patterson, Joseph P. Chemical Communications, Vol. 48, Issue 78 https://doi.org/10.1039/c2cc35170f	journal	January 2012
Metal Nanoparticles Derived from Polysilane Shell Cross-linked Micelle Templates Sanji, Takanobu; Ogawa, Yuya; Nakatsuka, Yuriko Chemistry Letters, Vol. 32, Issue 10 https://doi.org/10.1246/cl.2003.980	journal	October 2003
Multicompartment Polymeric Nanoreactors for Non-Orthogonal Cascade Catalysis Womble, C. Tyler; Kuepfert, Michael; Weck, Marcus Macromolecular Rapid Communications, Vol. 40, Issue 1 https://doi.org/10.1002/marc.201800580	journal	October 2018
Covalently cross-linked amphiphilic block copolymer micelles van Nostrum, Cornelus F. Soft Matter, Vol. 7, Issue 7 https://doi.org/10.1039/c0sm00999g	journal	January 2011
Reactions in Micellar Systems Dwars, Torsten; Paetzold, Eckhard; Oehme, Günther Angewandte Chemie International Edition, Vol. 44, Issue 44 https://doi.org/10.1002/anie.200501365	journal	November 2005
Amphiphilic Homopolymer as a Reaction Medium in Water: Product Selectivity within Polymeric Nanopockets Arumugam, Selvanathan; Vutukuri, Dharma Rao; Thayumanavan, S. Journal of the American Chemical Society, Vol. 127, Issue 38 https://doi.org/10.1021/ja051107v	journal	September 2005
Recent advances in shell cross-linked micelles Read, Elizabeth S.; Armes, Steven P. Chemical Communications, Issue 29 https://doi.org/10.1039/b701217a	journal	January 2007
Micelle-based nanoreactors containing Ru-porphyrin for the epoxidation of terminal olefins in water Lu, Jie; Liang, Linus; Weck, Marcus Journal of Molecular Catalysis A: Chemical, Vol. 417 https://doi.org/10.1016/j.molcata.2016.02.033	journal	June 2016
Auf dem Weg zu “grüneren” übergangsmetallkatalysierten Verfahren: Quantifizierung durch den E-Faktor Lipshutz, Bruce H.; Isley, Nicholas A.; Fennewald, James C. Angewandte Chemie, Vol. 125, Issue 42 https://doi.org/10.1002/ange.201302020	journal	September 2013
Multienzyme Cascade Reactions—Status and Recent Advances Sperl, Josef M.; Sieber, Volker ACS Catalysis, Vol. 8, Issue 3 https://doi.org/10.1021/acscatal.7b03440	journal	January 2018
Supramolecular self-assemblies as functional nanomaterials Busseron, Eric; Ruff, Yves; Moulin, Emilie Nanoscale, Vol. 5, Issue 16 https://doi.org/10.1039/c3nr02176a	journal	January 2013
The chemistry of poly(2-oxazoline)s Verbraeken, Bart; Monnery, Bryn D.; Lava, Kathleen European Polymer Journal, Vol. 88 https://doi.org/10.1016/j.eurpolymj.2016.11.016	journal	March 2017
Self-Assembled Block Copolymer Aggregates: From Micelles to Vesicles and their Biological Applications Blanazs, Adam; Armes, Steven P.; Ryan, Anthony J. Macromolecular Rapid Communications, Vol. 30, Issue 4-5 https://doi.org/10.1002/marc.200800713	journal	February 2009
Core Cross‐Linked Micelle‐Based Nanoreactors for Efficient Photocatalysis Zheng, Min; Sun, Zaicheng; Xie, Zhigang Chemistry – An Asian Journal, Vol. 8, Issue 11 https://doi.org/10.1002/asia.201300668	journal	August 2013
Nitroxide-Mediated Radical Polymerization: Limitations and Versatility Grubbs, Robert B. Polymer Reviews, Vol. 51, Issue 2 https://doi.org/10.1080/15583724.2011.566405	journal	April 2011
Formation of Complex Micelles with Double-Responsive Channels from Self-Assembly of Two Diblock Copolymers Li, Guiying; Shi, Linqi; Ma, Rujiang Angewandte Chemie, Vol. 118, Issue 30 https://doi.org/10.1002/ange.200600172	journal	July 2006
Strategies to improve micelle stability for drug delivery Lu, Yang; Zhang, Ershuai; Yang, Jianhai Nano Research, Vol. 11, Issue 10 https://doi.org/10.1007/s12274-018-2152-3	journal	August 2018
Water-Soluble Knedel-like Structures: The Preparation of Shell-Cross-Linked Small Particles Thurmond, K. Bruce; Kowalewski, Tomasz; Wooley, Karen L. Journal of the American Chemical Society, Vol. 118, Issue 30 https://doi.org/10.1021/ja961299h	journal	January 1996
On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors Lipshutz, Bruce H.; Isley, Nicholas A.; Fennewald, James C. Angewandte Chemie International Edition, Vol. 52, Issue 42 https://doi.org/10.1002/anie.201302020	journal	September 2013
Aqueous phase homogeneous catalysis using core–shell nanoreactors: Application to rhodium-catalyzed hydroformylation of 1-octene Cardozo, Andrés F.; Julcour, Carine; Barthe, Laurie Journal of Catalysis, Vol. 324 https://doi.org/10.1016/j.jcat.2015.01.009	journal	April 2015
Reversible Photoswitching in Poly(2‐oxazoline) Nanoreactors Kuepfert, Michael; Qu, Peiyuan; Cohen, Aaron E. Chemistry – A European Journal, Vol. 26, Issue 51 https://doi.org/10.1002/chem.202000179	journal	August 2020
Reaktionen in micellaren Systemen Dwars, Torsten; Paetzold, Eckhard; Oehme, Günther Angewandte Chemie, Vol. 117, Issue 44 https://doi.org/10.1002/ange.200501365	journal	November 2005
Formation of Complex Micelles with Double-Responsive Channels from Self-Assembly of Two Diblock Copolymers Li, Guiying; Shi, Linqi; Ma, Rujiang Angewandte Chemie International Edition, Vol. 45, Issue 30 https://doi.org/10.1002/anie.200600172	journal	July 2006
Overcoming the barriers in micellar drug delivery: loading efficiency, in vivo stability, and micelle–cell interaction Kim, Sungwon; Shi, Yunzhou; Kim, Ji Young Expert Opinion on Drug Delivery, Vol. 7, Issue 1 https://doi.org/10.1517/17425240903380446	journal	December 2009
Self-Folding Polymer Iron Catalysts for Living Radical Polymerization Azuma, Yusuke; Terashima, Takaya; Sawamoto, Mitsuo ACS Macro Letters, Vol. 6, Issue 8 https://doi.org/10.1021/acsmacrolett.7b00498	journal	July 2017
Chemoenzymatic one-pot reaction of noncompatible catalysts: combining enzymatic ester hydrolysis with Cu( i )/bipyridine catalyzed oxidation in aqueous medium Sand, Henning; Weberskirch, Ralf RSC Advances, Vol. 7, Issue 53 https://doi.org/10.1039/C7RA05451C	journal	January 2017
Formation of Nanoarchitectures Including Subnanometer Palladium Clusters and Their Use as Highly Active Catalysts Okamoto, Kuniaki; Akiyama, Ryo; Yoshida, Hisao Journal of the American Chemical Society, Vol. 127, Issue 7 https://doi.org/10.1021/ja047095f	journal	February 2005
Amphiphilic core-cross-linked micelles functionalized with bis(4-methoxyphenyl)phenylphosphine as catalytic nanoreactors for biphasic hydroformylation Chen, Si; Cardozo, Andrés F.; Julcour, Carine Polymer, Vol. 72 https://doi.org/10.1016/j.polymer.2015.02.024	journal	August 2015
From precision polymers to complex materials and systems Lutz, Jean-François; Lehn, Jean-Marie; Meijer, E. W. Nature Reviews Materials, Vol. 1, Issue 5 https://doi.org/10.1038/natrevmats.2016.24	journal	April 2016
Polymeric micelles for drug delivery Aliabadi, Hamidreza Montazeri; Lavasanifar, Afsaneh Expert Opinion on Drug Delivery, Vol. 3, Issue 1 https://doi.org/10.1517/17425247.3.1.139	journal	December 2005
Understanding the catalytic activity of single-chain polymeric nanoparticles in water Artar, Müge; Terashima, Takaya; Sawamoto, Mitsuo Journal of Polymer Science Part A: Polymer Chemistry, Vol. 52, Issue 1 https://doi.org/10.1002/pola.26970	journal	October 2013
Core phosphine-functionalized amphiphilic nanogels as catalytic nanoreactors for aqueous biphasic hydroformylation Lobry, Emeline; Cardozo, Andrés F.; Barthe, Laurie Journal of Catalysis, Vol. 342 https://doi.org/10.1016/j.jcat.2016.07.023	journal	October 2016
Polymer-supported Lewis acids and bases: Synthesis and applications Yolsal, Utku; Horton, Thomas A. R.; Wang, Meng Progress in Polymer Science, Vol. 111 https://doi.org/10.1016/j.progpolymsci.2020.101313	journal	December 2020
Core-Shell Nanoreactors for Efficient Aqueous Biphasic Catalysis Zhang, Xuewei; Cardozo , Andrés F.; Chen , Si Chemistry - A European Journal, Vol. 20, Issue 47 https://doi.org/10.1002/chem.201403819	journal	October 2014
Shell Cross-Linked Micelle-Based Nanoreactors for the Substrate-Selective Hydrolytic Kinetic Resolution of Epoxides Liu, Yu; Wang, Yu; Wang, Yufeng Journal of the American Chemical Society, Vol. 133, Issue 36 https://doi.org/10.1021/ja206644d	journal	September 2011
Shell crosslinked polymer assemblies: Nanoscale constructs inspired from biological systems Wooley, Karen L. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 38, Issue 9 https://doi.org/10.1002/(SICI)1099-0518(20000501)38:9<1397::AID-POLA1>3.0.CO;2-N	journal	May 2000
Compartmentalization of Incompatible Catalytic Transformations for Tandem Catalysis Lu, Jie; Dimroth, Jonas; Weck, Marcus Journal of the American Chemical Society, Vol. 137, Issue 40 https://doi.org/10.1021/jacs.5b07257	journal	September 2015
Synthesis of pH-Responsive Shell Cross-Linked Micelles and Their Use as Nanoreactors for the Preparation of Gold Nanoparticles Liu, Shiyong; Weaver, Jonathan V. M.; Save, Maud Langmuir, Vol. 18, Issue 22 https://doi.org/10.1021/la020496t	journal	October 2002
Rhodium-catalyzed aqueous biphasic hydrogenation of alkenes with amphiphilic phosphine-containing core-shell polymers Joumaa, Ahmad; Chen, Si; Vincendeau, Sandrine Molecular Catalysis, Vol. 438 https://doi.org/10.1016/j.mcat.2017.06.005	journal	September 2017
Amphiphilic, Thermosensitive Ruthenium(II)-Bearing Star Polymer Catalysts: One-Pot Synthesis of PEG Armed Star Polymers with Ruthenium(II)-Enclosed Microgel Cores via Metal-Catalyzed Living Radical Polymerization Terashima, Takaya; Ouchi, Makoto; Ando, Tsuyoshi Macromolecules, Vol. 40, Issue 10 https://doi.org/10.1021/ma062446r	journal	May 2007
Atom Transfer Radical Polymerization (ATRP): Current Status and Future Perspectives Matyjaszewski, Krzysztof Macromolecules, Vol. 45, Issue 10, p. 4015-4039 https://doi.org/10.1021/ma3001719	journal	April 2012
Thermoregulated phase-transfer catalysis via PEG-armed Ru(II)-bearing microgel core star polymers: Efficient and reusable Ru(II) catalysts for aqueous transfer hydrogenation of ketones: Thermoregulated Phase-Transfer Catalysis Terashima, Takaya; Ouchi, Makoto; Ando, Tsuyoshi Journal of Polymer Science Part A: Polymer Chemistry, Vol. 48, Issue 2 https://doi.org/10.1002/pola.23794	journal	December 2009
Coordination Chemistry Inside Polymeric Nanoreactors: Interparticle Metal Exchange and Ionic Compound Vectorization in Phosphine-Functionalized Amphiphilic Polymer Latexes Chen, Si; Gayet, Florence; Manoury, Eric Chemistry - A European Journal, Vol. 22, Issue 18 https://doi.org/10.1002/chem.201504923	journal	March 2016
Multifunctional Heterogeneous Catalysts: SBA-15-Containing Primary Amines and Sulfonic Acids Zeidan, Ryan K.; Hwang, Son-Jong; Davis, Mark E. Angewandte Chemie International Edition, Vol. 45, Issue 38 https://doi.org/10.1002/anie.200602243	journal	September 2006
Dynamic polymeric micelles versus frozen nanoparticles formed by block copolymers Nicolai, Taco; Colombani, Olivier; Chassenieux, Christophe Soft Matter, Vol. 6, Issue 14 https://doi.org/10.1039/b925666k	journal	January 2010
Cascade Reactions in Multicompartmentalized Polymersomes Peters, Ruud J. R. W.; Marguet, Maïté; Marais, Sébastien Angewandte Chemie, Vol. 126, Issue 1 https://doi.org/10.1002/ange.201308141	journal	November 2013
Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles Liu, Lichen; Corma, Avelino Chemical Reviews, Vol. 118, Issue 10 https://doi.org/10.1021/acs.chemrev.7b00776	journal	April 2018
Advances in Single-Chain Nanoparticles for Catalysis Applications Rubio-Cervilla, Jon; González, Edurne; Pomposo, José Nanomaterials, Vol. 7, Issue 10 https://doi.org/10.3390/nano7100341	journal	October 2017
Nanocatalysis by noble metal nanoparticles: controlled synthesis for the optimization and understanding of activities Rodrigues, Thenner S.; da Silva, Anderson G. M.; Camargo, Pedro H. C. Journal of Materials Chemistry A, Vol. 7, Issue 11 https://doi.org/10.1039/C9TA00074G	journal	January 2019
Poly(norbornene) block copolymer-based shell cross-linked micelles with Co(iii)–salen cores Liu, Yu; Piñón, Victor; Weck, Marcus Polymer Chemistry, Vol. 2, Issue 9 https://doi.org/10.1039/c1py00151e	journal	January 2011
Recent advances in catalysis in micellar media La Sorella, Giorgio; Strukul, Giorgio; Scarso, Alessandro Green Chemistry, Vol. 17, Issue 2 https://doi.org/10.1039/C4GC01368A	journal	January 2015
Characterization of molecular association of poly(2-oxazoline)s-based micelles with various epoxides and diols via the Flory–Huggins theory: a molecular dynamics simulation approach Chun, Byeong Jae; Lu, Jie; Weck, Marcus Physical Chemistry Chemical Physics, Vol. 17, Issue 43 https://doi.org/10.1039/C5CP03854E	journal	January 2015
Surface-Cross-Linked Micelles as Multifunctionalized Organic Nanoparticles for Controlled Release, Light Harvesting, and Catalysis Zhao, Yan Langmuir, Vol. 32, Issue 23 https://doi.org/10.1021/acs.langmuir.6b01162	journal	June 2016
Synthesis, Characterization, and Application of Ultrasmall Nanoparticles Kim, Byung Hyo; Hackett, Michael J.; Park, Jongnam Chemistry of Materials, Vol. 26, Issue 1 https://doi.org/10.1021/cm402225z	journal	September 2013
Catalytic Y-tailed amphiphilic homopolymers – aqueous nanoreactors for high activity, low loading SCS pincer catalysts Patterson, Joseph P.; Cotanda, Pepa; Kelley, Elizabeth G. Polymer Chemistry, Vol. 4, Issue 6 https://doi.org/10.1039/c3py21137a	journal	January 2013

Similar Records

Shell Cross-Linked Micelles as Nanoreactors for Enantioselective Three-Step Tandem Catalysis

Journal Article · 2018 · Chemistry - A European Journal · OSTI ID:1609439

Kuepfert, Michael; Cohen, Aaron E.; Cullen, Olivia; +1 more

Cross‐Linked Polymeric Micelles as Catalytic Nanoreactors

Journal Article · 2021 · European Journal of Inorganic Chemistry · OSTI ID:1779967

Qu, Peiyuan; Kuepfert, Michael; Ahmed, Eman; +2 more

Related Subjects

Chemistry

Cross-Linked Polymeric Micelles as Catalytic Nanoreactors

Citation Formats

References (78)

Similar Records

Related Subjects