In-Depth Analysis of the Degradation Mechanisms of High-Nickel, Low/No-Cobalt Layered Oxide Cathodes for Lithium-Ion Batteries

Lee, Steven; Li, Wangda; Dolocan, Andrei; Celio, Hugo; Park, Hyoju; Warner, Jamie H.; Manthiram, Arumugam

doi:10.1002/aenm.202100858

In-Depth Analysis of the Degradation Mechanisms of High-Nickel, Low/No-Cobalt Layered Oxide Cathodes for Lithium-Ion Batteries

Journal Article · 24 June 2021 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.202100858· OSTI ID:1848792

Lee, Steven ^[1]; Li, Wangda ^[1]; Dolocan, Andrei ^[1]; Celio, Hugo ^[1]; Park, Hyoju ^[2]; Warner, Jamie H. ^[3]; ^[3]

Materials Science and Engineering Program and Texas Materials Institute The University of Texas at Austin Austin TX 78712 USA
Walker Department of Mechanical Engineering The University of Texas at Austin Austin TX 78712 USA
Materials Science and Engineering Program and Texas Materials Institute The University of Texas at Austin Austin TX 78712 USA; Walker Department of Mechanical Engineering The University of Texas at Austin Austin TX 78712 USA

Not provided.

Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

DOE Contract Number:: EE0008445

OSTI ID:: 1848792

Journal Information:: Advanced Energy Materials, Vol. 11, Issue 31; ISSN 1614-6832

Publisher:: Wiley

Country of Publication:: United States

Language:: English

References (65)

An Analysis Protocol for Three-Electrode Li-Ion Battery Impedance Spectra: Part I. Analysis of a High-Voltage Positive Electrode Landesfeind, Johannes; Pritzl, Daniel; Gasteiger, Hubert A. Journal of The Electrochemical Society, Vol. 164, Issue 7 https://doi.org/10.1149/2.0131709jes	journal	January 2017
Investigation into Mechanical Degradation and Fatigue of High-Ni NCM Cathode Material: A Long-Term Cycling Study of Full Cells Schweidler, Simon; de Biasi, Lea; Garcia, Grecia ACS Applied Energy Materials, Vol. 2, Issue 10 https://doi.org/10.1021/acsaem.9b01354	journal	September 2019
Is Cobalt Needed in Ni-Rich Positive Electrode Materials for Lithium Ion Batteries? Li, Hongyang; Cormier, Marc; Zhang, Ning Journal of The Electrochemical Society, Vol. 166, Issue 4 https://doi.org/10.1149/2.1381902jes	journal	January 2019
Synthesis of Mg and Mn Doped LiCoO ₂ and Effects on High Voltage Cycling Liu, Aaron; Li, Jing; Shunmugasundaram, Ramesh Journal of The Electrochemical Society, Vol. 164, Issue 7 https://doi.org/10.1149/2.1381707jes	journal	January 2017
Long-Term Cyclability of NCM-811 at High Voltages in Lithium-Ion Batteries: an In-Depth Diagnostic Study Li, Wangda; Liu, Xiaoming; Xie, Qiang Chemistry of Materials, Vol. 32, Issue 18 https://doi.org/10.1021/acs.chemmater.0c02398	journal	August 2020
Facilitating the Operation of Lithium-Ion Cells with High-Nickel Layered Oxide Cathodes with a Small Dose of Aluminum Li, Jianyu; Li, Wangda; Wang, Shanyu Chemistry of Materials, Vol. 30, Issue 9 https://doi.org/10.1021/acs.chemmater.8b01077	journal	April 2018
An Unavoidable Challenge for Ni-Rich Positive Electrode Materials for Lithium-Ion Batteries Li, Hongyang; Liu, Aaron; Zhang, Ning Chemistry of Materials, Vol. 31, Issue 18 https://doi.org/10.1021/acs.chemmater.9b02372	journal	August 2019
Fluorinated Carbonate-Based Electrolyte for High-Voltage Li(Ni _0.5 Mn _0.3 Co _0.2 )O ₂ /Graphite Lithium-Ion Battery Im, Jinsol; Lee, Jieun; Ryou, Myung-Hyun Journal of The Electrochemical Society, Vol. 164, Issue 1 https://doi.org/10.1149/2.0591701jes	journal	January 2017
Al Doping for Mitigating the Capacity Fading and Voltage Decay of Layered Li and Mn-Rich Cathodes for Li-Ion Batteries Nayak, Prasant Kumar; Grinblat, Judith; Levi, Mikhael Advanced Energy Materials, Vol. 6, Issue 8 https://doi.org/10.1002/aenm.201502398	journal	February 2016
Editors' Choice—Capacity Fading Mechanisms of NCM-811 Cathodes in Lithium-Ion Batteries Studied by X-ray Diffraction and Other Diagnostics Friedrich, Franziska; Strehle, Benjamin; Freiberg, Anna T. S. Journal of The Electrochemical Society, Vol. 166, Issue 15 https://doi.org/10.1149/2.0821915jes	journal	January 2019
Effect of electrolyte on the nanostructure of the solid electrolyte interphase (SEI) and performance of lithium metal anodes Jurng, Sunhyung; Brown, Zachary L.; Kim, Jiyeon Energy & Environmental Science, Vol. 11, Issue 9 https://doi.org/10.1039/C8EE00364E	journal	January 2018
Binding energy referencing for XPS in alkali metal-based battery materials research (I): Basic model investigations Oswald, S. Applied Surface Science, Vol. 351 https://doi.org/10.1016/j.apsusc.2015.05.029	journal	October 2015
High-nickel layered oxide cathodes for lithium-based automotive batteries Li, Wangda; Erickson, Evan M.; Manthiram, Arumugam Nature Energy, Vol. 5, Issue 1 https://doi.org/10.1038/s41560-019-0513-0	journal	January 2020
Phase Behavior during Electrochemical Cycling of Ni‐Rich Cathode Materials for Li‐Ion Batteries Xu, Chao; Reeves, Philip J.; Jacquet, Quentin Advanced Energy Materials, Vol. 11, Issue 7 https://doi.org/10.1002/aenm.202003404	journal	December 2020
Towards high-performance cathode materials for lithium-ion batteries: Al2O3-coated LiNi0.8Co0.15Zn0.05O2 Yin, Hong; Yu, Xiang-Xiang; Zhao, Han Journal of Solid State Electrochemistry, Vol. 22, Issue 8 https://doi.org/10.1007/s10008-018-3904-4	journal	April 2018
Structural and Electrochemical Impacts of Mg/Mn Dual Dopants on the LiNiO ₂ Cathode in Li-Metal Batteries Mu, Linqin; Kan, Wang Hay; Kuai, Chunguang ACS Applied Materials & Interfaces, Vol. 12, Issue 11 https://doi.org/10.1021/acsami.0c00111	journal	March 2020
High‐Nickel NMA: A Cobalt‐Free Alternative to NMC and NCA Cathodes for Lithium‐Ion Batteries Li, Wangda; Lee, Steven; Manthiram, Arumugam Advanced Materials, Vol. 32, Issue 33 https://doi.org/10.1002/adma.202002718	journal	July 2020
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review Cheng, Xin-Bing; Zhang, Rui; Zhao, Chen-Zi Chemical Reviews, Vol. 117, Issue 15 https://doi.org/10.1021/acs.chemrev.7b00115	journal	July 2017
Clarification of Decomposition Pathways in a State‐of‐the‐Art Lithium Ion Battery Electrolyte through ¹³ C‐Labeling of Electrolyte Components Henschel, Jonas; Peschel, Christoph; Klein, Sven Angewandte Chemie International Edition, Vol. 59, Issue 15 https://doi.org/10.1002/anie.202000727	journal	February 2020
Comparison of Single Crystal and Polycrystalline LiNi _0.5 Mn _0.3 Co _0.2 O ₂ Positive Electrode Materials for High Voltage Li-Ion Cells Li, Jing; Cameron, Andrew R.; Li, Hongyang Journal of The Electrochemical Society, Vol. 164, Issue 7 https://doi.org/10.1149/2.0991707jes	journal	January 2017
Synthesis of Single Crystal LiNi _0.6 Mn _0.2 Co _0.2 O ₂ with Enhanced Electrochemical Performance for Lithium Ion Batteries Li, Hongyang; Li, Jing; Ma, Xiaowei Journal of The Electrochemical Society, Vol. 165, Issue 5 https://doi.org/10.1149/2.0951805jes	journal	January 2018
Collapse of LiNi _{1– x – y} Co _x Mn _y O ₂ Lattice at Deep Charge Irrespective of Nickel Content in Lithium-Ion Batteries Li, Wangda; Asl, Hooman Yaghoobnejad; Xie, Qiang Journal of the American Chemical Society, Vol. 141, Issue 13 https://doi.org/10.1021/jacs.8b13798	journal	March 2019
High-voltage positive electrode materials for lithium-ion batteries Li, Wangda; Song, Bohang; Manthiram, Arumugam Chemical Society Reviews, Vol. 46, Issue 10 https://doi.org/10.1039/C6CS00875E	journal	January 2017
Stable cycling of high-voltage lithium metal batteries in ether electrolytes Jiao, Shuhong; Ren, Xiaodi; Cao, Ruiguo Nature Energy, Vol. 3, Issue 9 https://doi.org/10.1038/s41560-018-0199-8	journal	July 2018
Improved electrochemical properties of LiNi0.91Co0.06Mn0.03O2 cathode material via Li-reactive coating with metal phosphates Min, Kyoungmin; Park, Kwangjin; Park, Seong Yong Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-07375-6	journal	August 2017
Impact of Microcrack Generation and Surface Degradation on a Nickel-Rich Layered Li[Ni _0.9 Co _0.05 Mn _0.05 ]O ₂ Cathode for Lithium-Ion Batteries Sun, Ho-Hyun; Manthiram, Arumugam Chemistry of Materials, Vol. 29, Issue 19 https://doi.org/10.1021/acs.chemmater.7b03268	journal	September 2017
Effects of cation mixing on the electrochemical lithium intercalation reaction into porous Li1 − δNi1 − yCoyO2 electrodes Choi, Y. Solid State Ionics, Vol. 89, Issue 1-2 https://doi.org/10.1016/0167-2738(96)00269-X	journal	August 1996
Single-crystal nickel-rich layered-oxide battery cathode materials: synthesis, electrochemistry, and intra-granular fracture Qian, Guannan; Zhang, Youtian; Li, Linsen Energy Storage Materials, Vol. 27 https://doi.org/10.1016/j.ensm.2020.01.027	journal	May 2020
Zinc-Doped High-Nickel, Low-Cobalt Layered Oxide Cathodes for High-Energy-Density Lithium-Ion Batteries Cui, Zehao; Xie, Qiang; Manthiram, Arumugam ACS Applied Materials & Interfaces, Vol. 13, Issue 13 https://doi.org/10.1021/acsami.1c01824	journal	March 2021
In-situ formation of hybrid Li3PO4-AlPO4-Al(PO3)3 coating layer on LiNi0.8Co0.1Mn0.1O2 cathode with enhanced electrochemical properties for lithium-ion battery Feng, Ze; Rajagopalan, Ranjusha; Sun, Dan Chemical Engineering Journal, Vol. 382 https://doi.org/10.1016/j.cej.2019.122959	journal	February 2020
A first-principles study of the preventive effects of Al and Mg doping on the degradation in LiNi _0.8 Co _0.1 Mn _0.1 O ₂ cathode materials Min, Kyoungmin; Seo, Seung-Woo; Song, You Young Physical Chemistry Chemical Physics, Vol. 19, Issue 3 https://doi.org/10.1039/C6CP06270A	journal	January 2017
Bulk fatigue induced by surface reconstruction in layered Ni-rich cathodes for Li-ion batteries Xu, Chao; Märker, Katharina; Lee, Juhan Nature Materials, Vol. 20, Issue 1 https://doi.org/10.1038/s41563-020-0767-8	journal	August 2020
Mn versus Al in Layered Oxide Cathodes in Lithium-Ion Batteries: A Comprehensive Evaluation on Long-Term Cyclability Li, Wangda; Liu, Xiaoming; Celio, Hugo Advanced Energy Materials, Vol. 8, Issue 15 https://doi.org/10.1002/aenm.201703154	journal	February 2018
The cathode–electrolyte interface in the Li-ion battery Edström, K.; Gustafsson, T.; Thomas, J. O. Electrochimica Acta, Vol. 50, Issue 2-3 https://doi.org/10.1016/j.electacta.2004.03.049	journal	November 2004
Long-Life, Ultrahigh-Nickel Cathodes with Excellent Air Storage Stability for High-Energy Density Lithium-Based Batteries Xie, Qiang; Manthiram, Arumugam Chemistry of Materials, Vol. 32, Issue 17 https://doi.org/10.1021/acs.chemmater.0c02374	journal	August 2020
An in-depth understanding of the effect of aluminum doping in high-nickel cathodes for lithium-ion batteries Zhou, Kai; Xie, Qiang; Li, Baohua Energy Storage Materials, Vol. 34 https://doi.org/10.1016/j.ensm.2020.09.015	journal	January 2021
Impact of Dopants (Al, Mg, Mn, Co) on the Reactivity of Li _x NiO ₂ with the Electrolyte of Li-Ion Batteries Cormier, Marc M. E.; Zhang, Ning; Liu, Aaron Journal of The Electrochemical Society, Vol. 166, Issue 13 https://doi.org/10.1149/2.0491913jes	journal	January 2019
Aluminum-doped lithium nickel cobalt oxide electrodes for high-power lithium-ion batteries Chen, C. H.; Liu, J.; Stoll, M. E. Journal of Power Sources, Vol. 128, Issue 2 https://doi.org/10.1016/j.jpowsour.2003.10.009	journal	April 2004
Tailoring grain boundary structures and chemistry of Ni-rich layered cathodes for enhanced cycle stability of lithium-ion batteries Yan, Pengfei; Zheng, Jianming; Liu, Jian Nature Energy, Vol. 3, Issue 7 https://doi.org/10.1038/s41560-018-0191-3	journal	June 2018
Direct Observation of Lattice Aluminum Environments in Li Ion Cathodes LiNi _{1– y – z} Co _y Al _z O ₂ and Al-Doped LiNi _x Mn _y Co _z O ₂ via ²⁷ Al MAS NMR Spectroscopy Dogan, Fulya; Vaughey, John T.; Iddir, Hakim ACS Applied Materials & Interfaces, Vol. 8, Issue 26 https://doi.org/10.1021/acsami.6b04516	journal	June 2016
Armoring LiNi _1/3 Co _1/3 Mn _1/3 O ₂ Cathode with Reliable Fluorinated Organic–Inorganic Hybrid Interphase Layer toward Durable High Rate Battery Chen, Yu; Zhao, Weimin; Zhang, Quanhai Advanced Functional Materials, Vol. 30, Issue 19 https://doi.org/10.1002/adfm.202000396	journal	March 2020
Dopant Distribution in Co-Free High-Energy Layered Cathode Materials Mu, Linqin; Zhang, Rui; Kan, Wang Hay Chemistry of Materials, Vol. 31, Issue 23 https://doi.org/10.1021/acs.chemmater.9b03603	journal	November 2019
Formation and Inhibition of Metallic Lithium Microstructures in Lithium Batteries Driven by Chemical Crossover Li, Wangda; Kim, Un-Hyuck; Dolocan, Andrei ACS Nano, Vol. 11, Issue 6 https://doi.org/10.1021/acsnano.7b01494	journal	May 2017
Effect of Vinylene Carbonate and Fluoroethylene Carbonate on SEI Formation on Graphitic Anodes in Li-Ion Batteries Nie, Mengyun; Demeaux, Julien; Young, Benjamin T. Journal of The Electrochemical Society, Vol. 162, Issue 13 https://doi.org/10.1149/2.0021513jes	journal	January 2015
Role of Mn Content on the Electrochemical Properties of Nickel-Rich Layered LiNi _{0.8– x} Co _0.1 Mn _{0.1+ x} O ₂ (0.0 ≤ x ≤ 0.08) Cathodes for Lithium-Ion Batteries Zheng, Jianming; Kan, Wang Hay; Manthiram, Arumugam ACS Applied Materials & Interfaces, Vol. 7, Issue 12 https://doi.org/10.1021/acsami.5b00788	journal	March 2015
The Effect of Vinylene Carbonate Additive on Surface Film Formation on Both Electrodes in Li-Ion Batteries El Ouatani, L.; Dedryvère, R.; Siret, C. Journal of The Electrochemical Society, Vol. 156, Issue 2 https://doi.org/10.1149/1.3029674	journal	January 2009
A reflection on lithium-ion battery cathode chemistry Manthiram, Arumugam Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-15355-0	journal	March 2020
Investigating the Effects of Magnesium Doping in Various Ni-Rich Positive Electrode Materials for Lithium Ion Batteries Liu, Aaron; Zhang, Ning; Li, Hongyang Journal of The Electrochemical Society, Vol. 166, Issue 16 https://doi.org/10.1149/2.1101915jes	journal	January 2019
Identifying Contact Resistances in High-Voltage Cathodes by Impedance Spectroscopy Pritzl, Daniel; Bumberger, Andreas E.; Wetjen, Morten Journal of The Electrochemical Society, Vol. 166, Issue 4 https://doi.org/10.1149/2.0451904jes	journal	January 2019
Core/Double-Shell Type Gradient Ni-Rich LiNi _0.76 Co _0.10 Mn _0.14 O ₂ with High Capacity and Long Cycle Life for Lithium-Ion Batteries Liao, Jin-Yun; Oh, Seung-Min; Manthiram, Arumugam ACS Applied Materials & Interfaces, Vol. 8, Issue 37 https://doi.org/10.1021/acsami.6b06172	journal	September 2016
Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries Assat, Gaurav; Tarascon, Jean-Marie Nature Energy, Vol. 3, Issue 5 https://doi.org/10.1038/s41560-018-0097-0	journal	April 2018
Solid electrolyte coated high voltage layered–layered lithium-rich composite cathode: Li1.2Mn0.525Ni0.175Co0.1O2 Martha, Surendra K.; Nanda, Jagjit; Kim, Yoongu Journal of Materials Chemistry A, Vol. 1, Issue 18 https://doi.org/10.1039/c3ta10586e	journal	January 2013
Investigating the Reversibility of Structural Modifications of Li _x Ni _y Mn _z Co _{1– y – z} O ₂ Cathode Materials during Initial Charge/Discharge, at Multiple Length Scales Hwang, Sooyeon; Kim, Seung Min; Bak, Seong-Min Chemistry of Materials, Vol. 27, Issue 17 https://doi.org/10.1021/acs.chemmater.5b02457	journal	August 2015
Understanding the Degradation Mechanisms of LiNi _0.5 Co _0.2 Mn _0.3 O ₂ Cathode Material in Lithium Ion Batteries Jung, Sung-Kyun; Gwon, Hyeokjo; Hong, Jihyun Advanced Energy Materials, Vol. 4, Issue 1 https://doi.org/10.1002/aenm.201300787	journal	August 2013
Intrinsic Role of Cationic Substitution in Tuning Li/Ni Mixing in High-Ni Layered Oxides Wang, Dawei; Xin, Chao; Zhang, Mingjian Chemistry of Materials, Vol. 31, Issue 8 https://doi.org/10.1021/acs.chemmater.8b04673	journal	March 2019
Identifying the chemical and structural irreversibility in LiNi _0.8 Co _0.15 Al _0.05 O ₂ – a model compound for classical layered intercalation Liu, Haodong; Liu, Hao; Seymour, Ieuan D. Journal of Materials Chemistry A, Vol. 6, Issue 9 https://doi.org/10.1039/C7TA10829J	journal	January 2018
Cobalt‐Free High‐Capacity Ni‐Rich Layered Li[Ni _0.9 Mn _0.1 ]O ₂ Cathode Aishova, Assylzat; Park, Geon‐Tae; Yoon, Chong S. Advanced Energy Materials, Vol. 10, Issue 4 https://doi.org/10.1002/aenm.201903179	journal	December 2019
The Importance of Interphase Contacts in Li Ion Electrodes: The Meaning of the High-Frequency Impedance Arc Gaberscek, Miran; Moskon, Joze; Erjavec, Bostjan Electrochemical and Solid-State Letters, Vol. 11, Issue 10 https://doi.org/10.1149/1.2964220	journal	January 2008
XPS-Surface Analysis of SEI Layers on Li-Ion Cathodes: Part II. SEI-Composition and Formation inside Composite Electrodes Schulz, Natalia; Hausbrand, René; Wittich, Carolin Journal of The Electrochemical Society, Vol. 165, Issue 5 https://doi.org/10.1149/2.0881803jes	journal	January 2018
Capacity fade of LiAlyNi1−x−yCoxO2 cathode for lithium-ion batteries during accelerated calendar and cycle life tests (surface analysis of LiAlyNi1−x−yCoxO2 cathode after cycle tests in restricted depth of discharge ranges) Watanabe, Shoichiro; Kinoshita, Masahiro; Hosokawa, Takashi Journal of Power Sources, Vol. 258 https://doi.org/10.1016/j.jpowsour.2014.02.018	journal	July 2014
Surface Structural and Chemical Evolution of Layered LiNi _0.8 Co _0.15 Al _0.05 O ₂ (NCA) under High Voltage and Elevated Temperature Conditions Mukherjee, Pinaki; Faenza, Nicholas V.; Pereira, Nathalie Chemistry of Materials, Vol. 30, Issue 23 https://doi.org/10.1021/acs.chemmater.7b05305	journal	November 2018
A Mg-Doped High-Nickel Layered Oxide Cathode Enabling Safer, High-Energy-Density Li-Ion Batteries Xie, Qiang; Li, Wangda; Manthiram, Arumugam Chemistry of Materials, Vol. 31, Issue 3 https://doi.org/10.1021/acs.chemmater.8b03900	journal	January 2019
Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries Li, Wangda; Dolocan, Andrei; Oh, Pilgun Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14589	journal	April 2017
Oxygen Release and Its Effect on the Cycling Stability of LiNi _x Mn _y Co _z O ₂ (NMC) Cathode Materials for Li-Ion Batteries Jung, Roland; Metzger, Michael; Maglia, Filippo Journal of The Electrochemical Society, Vol. 164, Issue 7 https://doi.org/10.1149/2.0021707jes	journal	January 2017
Peak position differences observed during XPS sputter depth profiling of the SEI on lithiated and delithiated carbon-based anode material for Li-ion batteries Oswald, S.; Hoffmann, M.; Zier, M. Applied Surface Science, Vol. 401 https://doi.org/10.1016/j.apsusc.2016.12.223	journal	April 2017

Similar Records

In–Depth Analysis of the Degradation Mechanisms of High–Nickel, Low/No–Cobalt Layered Oxide Cathodes for Lithium–Ion Batteries

Journal Article · 2021 · Advanced Energy Materials · OSTI ID:1972443

Lee, Steven; Li, Wangda; Dolocan, Andrei; +4 more

Related Subjects

Chemistry
Energy & Fuels
Materials Science
Physics

In-Depth Analysis of the Degradation Mechanisms of High-Nickel, Low/No-Cobalt Layered Oxide Cathodes for Lithium-Ion Batteries

Citation Formats

References (65)

Similar Records

Related Subjects