A perspective on single-crystal layered oxide cathodes for lithium-ion batteries

Langdon, Jayse; Manthiram, Arumugam

doi:10.1016/j.ensm.2021.02.003

Title: A perspective on single-crystal layered oxide cathodes for lithium-ion batteries

Journal Article · Thu Feb 04 00:00:00 EST 2021 · Energy Storage Materials

DOI:https://doi.org/10.1016/j.ensm.2021.02.003· OSTI ID:1848570

Langdon, Jayse ^[1]; Manthiram, Arumugam ^[1]

Univ. of Texas, Austin, TX (United States). Texas Materials Inst. McKetta Dept. of Chemical Engineering

As the demand for lithium-ion batteries grows exponentially to feed the nascent electric-vehicle and grid-storage markets, the need for higher energy density and longer cycle life becomes more apparent. Increasing the nickel content in the layered-oxide cathodes has been a dominant strategy to increase energy density, but this has exacerbated the surface reactivity concerns. Furthermore, the high states of charge associated with increased capacity lead to cracking of the polycrystalline cathode particles, which exposes fresh surfaces and accelerates capacity fade. Single-crystal cathode particles with low susceptibility to cracking have recently taken on intense interest due to their remarkable cyclability. Many different approaches to single-crystal synthesis have been explored, but there has been no systematic analysis of the different techniques to date. Furthermore, many reports have taken on a trial-and-error approach, ignoring well established literature on grain growth outside the battery field. This perspective reviews the literature on single-crystal cathode synthesis through the lens of classic grain growth theories, providing insight and hopefully accelerating the adoption of the promising single-crystal cathode morphology.

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Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); USDOE

Grant/Contract Number:: EE0007762

OSTI ID:: 1848570

Alternate ID(s):: OSTI ID: 1781206; OSTI ID: 2217341

Journal Information:: Energy Storage Materials, Vol. 37, Issue C; ISSN 2405-8297

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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25 ENERGY STORAGE
36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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Title: A perspective on single-crystal layered oxide cathodes for lithium-ion batteries

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