Reaction Mechanism Optimization of Solid-State Li–S Batteries with a PEO-Based Electrolyte

Fang, Ruyi; Xu, Henghui; Xu, Biyi; Li, Xinyu; Li, Yutao; Goodenough, John B.

doi:10.1002/adfm.202001812

Title: Reaction Mechanism Optimization of Solid-State Li–S Batteries with a PEO-Based Electrolyte

Journal Article · Wed May 13 00:00:00 EDT 2020 · Advanced Functional Materials

DOI:https://doi.org/10.1002/adfm.202001812· OSTI ID:1848566

Fang, Ruyi ^[1];

^[1]; Xu, Biyi ^[1]; Li, Xinyu ^[1]; Li, Yutao ^[1]; Goodenough, John B. ^[1]

Materials Science and Engineering Program and Texas Materials Institute The University of Texas at Austin Austin TX 78712 USA

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Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

DOE Contract Number:: EE0007762

OSTI ID:: 1848566

Journal Information:: Advanced Functional Materials, Vol. 31, Issue 2; ISSN 1616-301X

Publisher:: Wiley

Country of Publication:: United States

Language:: English

References (33)

Use of Tween Polymer To Enhance the Compatibility of the Li/Electrolyte Interface for the High-Performance and High-Safety Quasi-Solid-State Lithium–Sulfur Battery Liu, Jie; Qian, Tao; Wang, Mengfan Nano Letters, Vol. 18, Issue 7 https://doi.org/10.1021/acs.nanolett.8b01882	journal	June 2018
Direct tracking of the polysulfide shuttling and interfacial evolution in all-solid-state lithium–sulfur batteries: a degradation mechanism study Song, Yue-Xian; Shi, Yang; Wan, Jing Energy & Environmental Science, Vol. 12, Issue 8 https://doi.org/10.1039/C9EE00578A	journal	January 2019
Solid-State Lithium–Sulfur Batteries Operated at 37 °C with Composites of Nanostructured Li ₇ La ₃ Zr ₂ O ₁₂ /Carbon Foam and Polymer Tao, Xinyong; Liu, Yayuan; Liu, Wei Nano Letters, Vol. 17, Issue 5 https://doi.org/10.1021/acs.nanolett.7b00221	journal	April 2017
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
Influence of cations in lithium and magnesium polysulphide solutions: dependence of the solvent chemistry Bieker, Georg; Wellmann, Julia; Kolek, Martin Physical Chemistry Chemical Physics, Vol. 19, Issue 18 https://doi.org/10.1039/C7CP01238A	journal	January 2017
Single step transformation of sulphur to Li2S2/Li2S in Li-S batteries Helen, M.; Reddy, M. Anji; Diemant, Thomas Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep12146	journal	July 2015
Enhanced Ionic Conductivity of Polymer Electrolytes Containing Nanocomposite ${S i O}_{2}$ Particles Nan, Ce-Wen; Fan, Lizhen; Lin, Yuanhua Physical Review Letters, Vol. 91, Issue 26 https://doi.org/10.1103/PhysRevLett.91.266104	journal	December 2003
Computational Criteria for Evaluating Polysulfide Cohesion, Solvation, and Stabilization: Approach for Screening Effective Anchoring Substrates Zhou, Chenggang; Ji, Zhuan; Han, Bo The Journal of Physical Chemistry C, Vol. 121, Issue 1 https://doi.org/10.1021/acs.jpcc.6b09577	journal	December 2016
Progress and Perspective of Solid-State Lithium-Sulfur Batteries Lei, Danni; Shi, Kai; Ye, Heng Advanced Functional Materials, Vol. 28, Issue 38 https://doi.org/10.1002/adfm.201707570	journal	March 2018
Nanocomposite polymer electrolytes for lithium batteries Croce, F.; Appetecchi, G. B.; Persi, L. Nature, Vol. 394, Issue 6692 https://doi.org/10.1038/28818	journal	July 1998
Designing Safe Electrolyte Systems for a High-Stability Lithium-Sulfur Battery Chen, Wei; Lei, Tianyu; Wu, Chunyang Advanced Energy Materials, Vol. 8, Issue 10 https://doi.org/10.1002/aenm.201702348	journal	January 2018
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium Kresse, G.; Hafner, J. Physical Review B, Vol. 49, Issue 20, p. 14251-14269 https://doi.org/10.1103/PhysRevB.49.14251	journal	May 1994
Impedance study of (PEO)10LiClO4–Al2O3 composite polymer electrolyte with blocking electrodes Qian, Xinming; Gu, Ningyu; Cheng, Zhiliang Electrochimica Acta, Vol. 46, Issue 12 https://doi.org/10.1016/S0013-4686(00)00723-4	journal	March 2001
A highly efficient polysulfide mediator for lithium–sulfur batteries Liang, Xiao; Hart, Connor; Pang, Quan Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms6682	journal	January 2015
Effect of nano-porous Al2O3 on thermal, dielectric and transport properties of the (PEO)9LiTFSI polymer electrolyte system Jayathilaka, P. A. R. D.; Dissanayake, M. A. K. L.; Albinsson, I. Electrochimica Acta, Vol. 47, Issue 20 https://doi.org/10.1016/S0013-4686(02)00243-8	journal	August 2002
Influence of TiO2 nano-particles on the transport properties of composite polymer electrolyte for lithium-ion batteries Lin, C. W.; Hung, C. L.; Venkateswarlu, M. Journal of Power Sources, Vol. 146, Issue 1-2 https://doi.org/10.1016/j.jpowsour.2005.03.028	journal	August 2005
More Reliable Lithium-Sulfur Batteries: Status, Solutions and Prospects Fang, Ruopian; Zhao, Shiyong; Sun, Zhenhua Advanced Materials, Vol. 29, Issue 48 https://doi.org/10.1002/adma.201606823	journal	April 2017
Lithium Bis(fluorosulfonyl)imide/Poly(ethylene oxide) Polymer Electrolyte for All Solid-State Li–S Cell Judez, Xabier; Zhang, Heng; Li, Chunmei The Journal of Physical Chemistry Letters, Vol. 8, Issue 9 https://doi.org/10.1021/acs.jpclett.7b00593	journal	April 2017
Unraveling the Correlation between Solvent Properties and Sulfur Redox Behavior in Lithium-Sulfur Batteries He, Qi; Gorlin, Yelena; Patel, Manu U. M. Journal of The Electrochemical Society, Vol. 165, Issue 16 https://doi.org/10.1149/2.0991816jes	journal	January 2018
Rechargeable Lithium–Sulfur Batteries Manthiram, Arumugam; Fu, Yongzhu; Chung, Sheng-Heng Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500062v	journal	July 2014
Manipulating electrolyte and solid electrolyte interphase to enable safe and efficient Li-S batteries Zheng, Jing; Fan, Xiulin; Ji, Guangbin Nano Energy, Vol. 50 https://doi.org/10.1016/j.nanoen.2018.05.065	journal	August 2018
Ionic conductivity promotion of polymer electrolyte with ionic liquid grafted oxides for all-solid-state lithium–sulfur batteries Sheng, Ouwei; Jin, Chengbin; Luo, Jianmin Journal of Materials Chemistry A, Vol. 5, Issue 25 https://doi.org/10.1039/C7TA03699J	journal	January 2017
High Ionic Conductivity of Composite Solid Polymer Electrolyte via In Situ Synthesis of Monodispersed SiO ₂ Nanospheres in Poly(ethylene oxide) Lin, Dingchang; Liu, Wei; Liu, Yayuan Nano Letters, Vol. 16, Issue 1 https://doi.org/10.1021/acs.nanolett.5b04117	journal	December 2015
Li–O₂ and Li–S batteries with high energy storage Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J. Nature Materials, Vol. 11, Issue 1, p. 19-29 https://doi.org/10.1038/nmat3191	journal	January 2012
PEO-coated sulfur-carbon composite for high-performance lithium-sulfur batteries Li, LinYan; Liu, Xiaoyan; Zhu, Kunlei Journal of Solid State Electrochemistry, Vol. 19, Issue 11 https://doi.org/10.1007/s10008-015-2961-1	journal	July 2015
Pre-modified Li3PS4 based interphase for lithium anode towards high-performance Li-S battery Lu, Yang; Gu, Sui; Hong, Xiaoheng Energy Storage Materials, Vol. 11 https://doi.org/10.1016/j.ensm.2017.09.007	journal	March 2018
The effect of nano-particle TiO2 fillers on structure and transport in polymer electrolytes Forsyth, M. Solid State Ionics, Vol. 147, Issue 3-4 https://doi.org/10.1016/S0167-2738(02)00017-6	journal	April 2002
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries Ji, Xiulei; Lee, Kyu Tae; Nazar, Linda F. Nature Materials, Vol. 8, Issue 6, p. 500-506 https://doi.org/10.1038/nmat2460	journal	May 2009
Investigation of ZrO2 nanoparticles concentration and processing time effect on the localized PEO coatings formed on AZ91 alloy Ur Rehman, Zeeshan; Choi, Dongjin Journal of Magnesium and Alloys, Vol. 7, Issue 4 https://doi.org/10.1016/j.jma.2019.10.001	journal	December 2019
Revisiting Scientific Issues for Industrial Applications of Lithium-Sulfur Batteries Liu, Bo; Fang, Ruyi; Xie, Dong Energy & Environmental Materials, Vol. 1, Issue 4 https://doi.org/10.1002/eem2.12021	journal	December 2018
Combining theory and experiment in lithium–sulfur batteries: Current progress and future perspectives Chen, Xiang; Hou, Tingzheng; Persson, Kristin A. Materials Today, Vol. 22 https://doi.org/10.1016/j.mattod.2018.04.007	journal	January 2019

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