Influence of ZCuOH, Z 2 Cu, and Extraframework Cu x O y Species in Cu-SSZ-13 on N 2 O Formation during the Selective Catalytic Reduction of NO x with NH 3

Shih, Arthur J.; González, Juan M.; Khurana, Ishant; Ramírez, Lucía Pérez; Peña L., Andres; Kumar, Ashok; Villa, Aída Luz

doi:10.1021/acscatal.1c01871

Influence of ZCuOH, Z ₂ Cu, and Extraframework Cu _x O _y Species in Cu-SSZ-13 on N ₂ O Formation during the Selective Catalytic Reduction of NO _x with NH ₃

Journal Article · 05 August 2021 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.1c01871· OSTI ID:1848400

^[1]; González, Juan M. ^[2]; ^[3]; Ramírez, Lucía Pérez ^[3]; Peña L., Andres ^[3]; Kumar, Ashok ^[4]; ^[5]

Charles D. Davidson School of Chemical Engineering, Purdue University, 480 Stadium Mall Drive, West Lafayette, Indiana 47907, United States; Leiden Institute of Chemistry, Leiden University, Einsteinweg 55, 2300 RA Leiden, The Netherlands
Charles D. Davidson School of Chemical Engineering, Purdue University, 480 Stadium Mall Drive, West Lafayette, Indiana 47907, United States; Environmental Catalysis Research Group, Chemical Engineering Department, Engineering Faculty, Universidad de Antioquia, Calle 70, No. 52-21, Medellín 050010, Colombia
Charles D. Davidson School of Chemical Engineering, Purdue University, 480 Stadium Mall Drive, West Lafayette, Indiana 47907, United States
Cummins Inc., 1900 McKinley Avenue, MC 50183, Columbus, Indiana 47201, United States
Environmental Catalysis Research Group, Chemical Engineering Department, Engineering Faculty, Universidad de Antioquia, Calle 70, No. 52-21, Medellín 050010, Colombia

Not provided.

Research Organization:: Univ. of Notre Dame, IN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

DOE Contract Number:: EE0003977

OSTI ID:: 1848400

Journal Information:: ACS Catalysis, Vol. 11, Issue 16; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (80)

Catalytic NOx Reduction in Net Oxidizing Exhaust Gas Held, Wolfgang; König, Axel; Richter, Thomas International Congress & Exposition, SAE Technical Paper Series https://doi.org/10.4271/900496	conference	February 1990
The impact of automotive catalysis on the United Nations sustainable development goals Wang, Aiyong; Olsson, Louise Nature Catalysis, Vol. 2, Issue 7 https://doi.org/10.1038/s41929-019-0318-3	journal	July 2019
Current state of the art and future needs for automotive exhaust catalysis Lambert, Christine K. Nature Catalysis, Vol. 2, Issue 7 https://doi.org/10.1038/s41929-019-0303-x	journal	July 2019
N2O emissions from global transportation Wallington, T. J.; Wiesen, P. Atmospheric Environment, Vol. 94 https://doi.org/10.1016/j.atmosenv.2014.05.018	journal	September 2014
Formation and control of N2O in nitric acid production Pérez-Ramı́rez, J.; Kapteijn, F.; Schöffel, K. Applied Catalysis B: Environmental, Vol. 44, Issue 2 https://doi.org/10.1016/S0926-3373(03)00026-2	journal	August 2003
A comprehensive quantification of global nitrous oxide sources and sinks Tian, Hanqin; Xu, Rongting; Canadell, Josep G. Nature, Vol. 586, Issue 7828 https://doi.org/10.1038/s41586-020-2780-0	journal	October 2020
Identification of two types of Cu sites in Cu/SSZ-13 and their unique responses to hydrothermal aging and sulfur poisoning Luo, Jinyong; Wang, Di; Kumar, Ashok Catalysis Today, Vol. 267 https://doi.org/10.1016/j.cattod.2015.12.002	journal	June 2016
Nature of Cu Active Centers in Cu-SSZ-13 and Their Responses to SO ₂ Exposure Jangjou, Yasser; Do, Quan; Gu, Yuntao ACS Catalysis, Vol. 8, Issue 2 https://doi.org/10.1021/acscatal.7b03095	journal	January 2018
Reversible and irreversible deactivation of Cu-CHA NH3-SCRcatalysts by SO2 and SO3 Hammershøi, Peter S.; Jangjou, Yasser; Epling, William S. Applied Catalysis B: Environmental, Vol. 226 https://doi.org/10.1016/j.apcatb.2017.12.018	journal	June 2018
Spectroscopic and kinetic responses of Cu-SSZ-13 to SO2 exposure and implications for NOx selective catalytic reduction Shih, Arthur J.; Khurana, Ishant; Li, Hui Applied Catalysis A: General, Vol. 574 https://doi.org/10.1016/j.apcata.2019.01.024	journal	March 2019
Deactivation mechanism of Cu active sites in Cu/SSZ-13 — Phosphorus poisoning and the effect of hydrothermal aging Wang, Aiyong; Xie, Kunpeng; Bernin, Diana Applied Catalysis B: Environmental, Vol. 269 https://doi.org/10.1016/j.apcatb.2020.118781	journal	July 2020
Identification of the active Cu site in standard selective catalytic reduction with ammonia on Cu-SSZ-13 Bates, Shane A.; Verma, Anuj A.; Paolucci, Christopher Journal of Catalysis, Vol. 312 https://doi.org/10.1016/j.jcat.2014.01.004	journal	April 2014
Turnover Rates in Heterogeneous Catalysis Boudart, M. Chemical Reviews, Vol. 95, Issue 3 https://doi.org/10.1021/cr00035a009	journal	May 1995
Two different cationic positions in Cu-SSZ-13? Hun Kwak, Ja; Zhu, Haiyang; Lee, Jong H. Chemical Communications, Vol. 48, Issue 39 https://doi.org/10.1039/c2cc31184d	journal	January 2012
Revisiting the nature of Cu sites in the activated Cu-SSZ-13 catalyst for SCR reaction Borfecchia, E.; Lomachenko, K. A.; Giordanino, F. Chemical Science, Vol. 6, Issue 1 https://doi.org/10.1039/C4SC02907K	journal	January 2015
Catalysis in a Cage: Condition-Dependent Speciation and Dynamics of Exchanged Cu Cations in SSZ-13 Zeolites Paolucci, Christopher; Parekh, Atish A.; Khurana, Ishant Journal of the American Chemical Society, Vol. 138, Issue 18 https://doi.org/10.1021/jacs.6b02651	journal	April 2016
Controlling the Isolation and Pairing of Aluminum in Chabazite Zeolites Using Mixtures of Organic and Inorganic Structure-Directing Agents Di Iorio, John R.; Gounder, Rajamani Chemistry of Materials, Vol. 28, Issue 7 https://doi.org/10.1021/acs.chemmater.6b00181	journal	March 2016
Dynamic multinuclear sites formed by mobilized copper ions in NO _x selective catalytic reduction Paolucci, Christopher; Khurana, Ishant; Parekh, Atish A. Science, Vol. 357, Issue 6354 https://doi.org/10.1126/science.aan5630	journal	August 2017
Isolation of the Copper Redox Steps in the Standard Selective Catalytic Reduction on Cu-SSZ-13 Paolucci, Christopher; Verma, Anuj A.; Bates, Shane A. Angewandte Chemie International Edition, Vol. 53, Issue 44 https://doi.org/10.1002/anie.201407030	journal	September 2014
A Consistent Reaction Scheme for the Selective Catalytic Reduction of Nitrogen Oxides with Ammonia Janssens, Ton V. W.; Falsig, Hanne; Lundegaard, Lars F. ACS Catalysis, Vol. 5, Issue 5 https://doi.org/10.1021/cs501673g	journal	March 2015
Transient Kinetic Analysis of Low-Temperature NH ₃ -SCR over Cu-CHA Catalysts Reveals a Quadratic Dependence of Cu Reduction Rates on Cu ^II Gramigni, Federica; Nasello, Nicole Daniela; Usberti, Nicola ACS Catalysis, Vol. 11, Issue 8 https://doi.org/10.1021/acscatal.0c05362	journal	April 2021
Selective Catalytic Reduction over Cu/SSZ-13: Linking Homo- and Heterogeneous Catalysis Gao, Feng; Mei, Donghai; Wang, Yilin Journal of the American Chemical Society, Vol. 139, Issue 13 https://doi.org/10.1021/jacs.7b01128	journal	March 2017
Activation of oxygen on (NH3Cu NH3)+ in NH3-SCR over Cu-CHA Chen, Lin; Falsig, Hanne; Janssens, Ton V. W. Journal of Catalysis, Vol. 358 https://doi.org/10.1016/j.jcat.2017.12.009	journal	February 2018
A Complete Multisite Reaction Mechanism for Low-Temperature NH ₃ -SCR over Cu-CHA Chen, Lin; Janssens, Ton V. W.; Vennestrøm, Peter N. R. ACS Catalysis, Vol. 10, Issue 10 https://doi.org/10.1021/acscatal.0c00440	journal	April 2020
Effects of dioxygen pressure on rates of NOx selective catalytic reduction with NH3 on Cu-CHA zeolites Jones, Casey B.; Khurana, Ishant; Krishna, Siddarth H. Journal of Catalysis, Vol. 389 https://doi.org/10.1016/j.jcat.2020.05.022	journal	September 2020
N ₂ O Formation and Mitigation in Diesel Aftertreatment Systems Kamasamudram, Krishna; Henry, Cary; Currier, Neal SAE International Journal of Engines, Vol. 5, Issue 2 https://doi.org/10.4271/2012-01-1085	journal	January 2012
Brief Investigation of SCR High Temperature N ₂ O Production Bartley, Gordon J.; Sharp, Christopher A. SAE International Journal of Engines, Vol. 5, Issue 2 https://doi.org/10.4271/2012-01-1082	journal	January 2012
Effects of copper loading on NH3-SCR and NO oxidation over Cu impregnated CHA zeolite Akter, Nusnin; Chen, Xianyin; Parise, John Korean Journal of Chemical Engineering, Vol. 35, Issue 1 https://doi.org/10.1007/s11814-017-0268-x	journal	November 2017
New insights into Cu/SSZ-13 SCR catalyst acidity. Part I: Nature of acidic sites probed by NH3 titration Luo, Jinyong; Gao, Feng; Kamasamudram, Krishna Journal of Catalysis, Vol. 348 https://doi.org/10.1016/j.jcat.2017.02.025	journal	April 2017
Impact of Hydrothermal Aging on the Formation and Decomposition of Ammonium Nitrate on a Cu/zeolite SCR Catalyst Ottinger, Nathan; Xi, Yuanzhou; Keturakis, Christopher SAE International Journal of Engines, Vol. 10, Issue 4 https://doi.org/10.4271/2017-01-0946	journal	February 2017
A comparative study of N2O formation during the selective catalytic reduction of NOx with NH3 on zeolite supported Cu catalysts Chen, Hai-Ying; Wei, Zhehao; Kollar, Marton Journal of Catalysis, Vol. 329 https://doi.org/10.1016/j.jcat.2015.06.016	journal	September 2015
Cu Loading Dependence of Fast NH3-SCR on Cu/SSZ-13 Cui, Yanran; Gao, Feng Emission Control Science and Technology, Vol. 5, Issue 2 https://doi.org/10.1007/s40825-019-00117-2	journal	March 2019
Inhibitory effect of NO2 on the selective catalytic reduction of NOx with NH3 over one-pot-synthesized Cu–SSZ-13 catalyst Xie, Lijuan; Liu, Fudong; Liu, Kuo Catalysis Science & Technology, Vol. 4, Issue 4 https://doi.org/10.1039/c3cy00924f	journal	January 2014
The Impact of Ammonium Nitrate Species on Low Temperature NOx Conversion Over Cu/CHA SCR Catalyst Luo, Jinyong; Tang, Yadan; Joshi, Saurabh SAE International Journal of Engines, Vol. 10, Issue 4 https://doi.org/10.4271/2017-01-0953	journal	February 2017
A comparative study of the NH3-SCR reactions over a Cu-zeolite and a Fe-zeolite catalyst Colombo, Massimo; Nova, Isabella; Tronconi, Enrico Catalysis Today, Vol. 151, Issue 3-4 https://doi.org/10.1016/j.cattod.2010.01.010	journal	June 2010
N ₂ O Formation Pathways over Zeolite-Supported Cu and Fe Catalysts in NH ₃ -SCR Zhang, Dong; Yang, Ralph T. Energy & Fuels, Vol. 32, Issue 2 https://doi.org/10.1021/acs.energyfuels.7b03405	journal	January 2018
Dynamics of low temperature N2O formation under SCR reaction conditions over a Cu-SSZ-13 catalyst Xi, Yuanzhou; Ottinger, Nathan A.; Keturakis, Christopher J. Applied Catalysis B: Environmental, Vol. 294 https://doi.org/10.1016/j.apcatb.2021.120245	journal	October 2021
The Role of H ⁺ - and Cu ⁺ -Sites for N ₂ O Formation during NH ₃ -SCR over Cu-CHA Feng, Yingxin; Janssens, Ton V. W.; Vennestrøm, Peter N. R. The Journal of Physical Chemistry C, Vol. 125, Issue 8 https://doi.org/10.1021/acs.jpcc.0c11008	journal	February 2021
Effects of NO ₂ Addition on the NH ₃ -SCR over Small-Pore Cu–SSZ-13 Zeolites with Varying Cu Loadings Shan, Yulong; Shi, Xiaoyan; He, Guangzhi The Journal of Physical Chemistry C, Vol. 122, Issue 45 https://doi.org/10.1021/acs.jpcc.8b05930	journal	October 2018
The Effect of Copper Loading on the Selective Catalytic Reduction of Nitric Oxide by Ammonia Over Cu-SSZ-13 Kwak, Ja Hun; Tran, Diana; Szanyi, Janos Catalysis Letters, Vol. 142, Issue 3 https://doi.org/10.1007/s10562-012-0771-y	journal	February 2012
Experimental and Computational Interrogation of Fast SCR Mechanism and Active Sites on H-Form SSZ-13 Li, Sichi; Zheng, Yang; Gao, Feng ACS Catalysis, Vol. 7, Issue 8 https://doi.org/10.1021/acscatal.7b01319	journal	July 2017
Theoretical Study on the NO _x Selective Catalytic Reduction on Single-Cu Sites and Brønsted Acid Sites in Cu-SSZ-13 Goncalves, Tiago J.; Plessow, Philipp N.; Studt, Felix The Journal of Physical Chemistry C, Vol. 125, Issue 23 https://doi.org/10.1021/acs.jpcc.1c01066	journal	June 2021
Effect of Transition Metal Ion Properties on the Catalytic Functions and Sulfation Behavior of Zeolite-Based SCR Catalysts Kumar, Ashok; Kamasamudram, Krishna; Currier, Neal SAE International Journal of Engines, Vol. 10, Issue 4 https://doi.org/10.4271/2017-01-0939	journal	February 2017
The origin of N2O formation in the selective catalytic reduction of NOx by NH3 in O2 rich atmosphere on Cu-faujasite catalysts Delahay, Gerard; Coq, Bernard; Kieger, Stephane Catalysis Today, Vol. 54, Issue 4 https://doi.org/10.1016/S0920-5861(99)00206-0	journal	December 1999
The chemistry of the NO/NO2–NH3 “fast” SCR reaction over Fe-ZSM5 investigated by transient reaction analysis Grossale, A.; Nova, I.; Tronconi, E. Journal of Catalysis, Vol. 256, Issue 2 https://doi.org/10.1016/j.jcat.2008.03.027	journal	June 2008
Effect of Oxygen Concentration in NH₃-SCR Reaction over Fe- and Cu-loaded Beta Zeolites Takamitsu, Yasuyuki; Ito, Yuuki; Ogawa, Hiroshi Journal of the Japan Petroleum Institute, Vol. 55, Issue 1 https://doi.org/10.1627/jpi.55.57	journal	January 2012
Effect of zeolite topology on NH3-SCR activity and stability of Cu-exchanged zeolites Tarach, Karolina A.; Jabłońska, Magdalena; Pyra, Kamila Applied Catalysis B: Environmental, Vol. 284 https://doi.org/10.1016/j.apcatb.2020.119752	journal	May 2021
Experimental Investigation on N ₂ O Formation during the Selective Catalytic Reduction of NOx with NH ₃ over Cu-SSZ-13 Liu, Biao; Yao, Dongwei; Wu, Feng Industrial & Engineering Chemistry Research, Vol. 58, Issue 45 https://doi.org/10.1021/acs.iecr.9b03294	journal	October 2019
Formation and Reactions of NH ₄ NO ₃ during Transient and Steady-State NH ₃ -SCR of NO _x over H-AFX Zeolites: Spectroscopic and Theoretical Studies Kubota, Hiroe; Liu, Chong; Toyao, Takashi ACS Catalysis, Vol. 10, Issue 3 https://doi.org/10.1021/acscatal.9b05151	journal	January 2020
Reduction of nitric oxide with methane on Pd/Co/H-ZSM-5 catalysts: cooperative effects of Pd and Co Ogura, Masaru; Sugiura, Yukihiro; Hayashi, Masayoshi Catalysis Letters, Vol. 42, Issue 3-4 https://doi.org/10.1007/BF00810686	journal	January 1996
Structure–Activity Relationship of Different Cu–Zeolite Catalysts for NH3–SCR Ruggeri, M. P.; Nova, I.; Tronconi, E. Topics in Catalysis, Vol. 59, Issue 10-12 https://doi.org/10.1007/s11244-016-0562-6	journal	May 2016
Evolution Mechanism of N2O for the Selective Catalytic Reduction of NOx by NH3 Over Cu-SSZ-13 Assisted Fe-BEA Catalysts Wang, Pan; Jin, Miaomiao; Yu, Dan Catalysis Letters, Vol. 151, Issue 11 https://doi.org/10.1007/s10562-021-03588-7	journal	March 2021
Synthesis of zeolite UZM-35 and catalytic properties of copper-exchanged UZM-35 for ammonia selective catalytic reduction Lee, Jeong Hwan; Kim, Young Jin; Ryu, Taekyung Applied Catalysis B: Environmental, Vol. 200 https://doi.org/10.1016/j.apcatb.2016.07.040	journal	January 2017
Source of N and O in N2O formation during selective catalytic reduction of NO with NH3 over MnO /TiO2 Wang, Denghui; Yao, Qi; Hui, Shien Fuel, Vol. 251 https://doi.org/10.1016/j.fuel.2019.04.035	journal	September 2019
High Temperature SCR Over Cu-SSZ-13 and Cu-SSZ-13 + Fe-SSZ-13: Activity of Cu2+ and [CuOH]1+ Sites and the Apparent Promoting Effect of Adding Fe into Cu-SSZ-13 Catalyst González, Juan M.; Villa, Aída L. Catalysis Letters, Vol. 151, Issue 10 https://doi.org/10.1007/s10562-021-03550-7	journal	February 2021
Copper Coordination in Cu-SSZ-13 and Cu-SSZ-16 Investigated by Variable-Temperature XRD Fickel, Dustin W.; Lobo, Raul F. The Journal of Physical Chemistry C, Vol. 114, Issue 3 https://doi.org/10.1021/jp9105025	journal	December 2009
Confirmation of Isolated Cu ²⁺ Ions in SSZ-13 Zeolite as Active Sites in NH ₃ -Selective Catalytic Reduction Deka, Upakul; Juhin, Amélie; Eilertsen, Einar A. The Journal of Physical Chemistry C, Vol. 116, Issue 7 https://doi.org/10.1021/jp212450d	journal	February 2012
A comparison of hydrothermal aging effects on NH3-SCR of NO over Cu-SSZ-13 and Cu-SAPO-34 catalysts Wang, Di; Jangjou, Yasser; Liu, Yong Applied Catalysis B: Environmental, Vol. 165 https://doi.org/10.1016/j.apcatb.2014.10.020	journal	April 2015
Fundamental principles of laboratory fixed bed reactor design Hickman, Daniel A.; Degenstein, John C.; Ribeiro, Fabio H. Current Opinion in Chemical Engineering, Vol. 13 https://doi.org/10.1016/j.coche.2016.07.002	journal	August 2016
Consequences of product inhibition in the quantification of kinetic parameters Harris, James W.; Verma, Anuj A.; Arvay, Jeremy W. Journal of Catalysis, Vol. 389 https://doi.org/10.1016/j.jcat.2020.06.014	journal	September 2020
The State of the Art in Selective Catalytic Reduction of NO _x by Ammonia Using Metal‐Exchanged Zeolite Catalysts Brandenberger, Sandro; Kröcher, Oliver; Tissler, Arno Catalysis Reviews, Vol. 50, Issue 4 https://doi.org/10.1080/01614940802480122	journal	December 2008
EPR Study of Copper-Exchanged Zeolites: Effects of Correlated g - and A -Strain, Si/Al Ratio, and Parent Zeolite Carl, Patrick J.; Larsen, Sarah C. The Journal of Physical Chemistry B, Vol. 104, Issue 28 https://doi.org/10.1021/jp000015j	journal	July 2000
Selective Catalytic Reduction of NO _x with NH ₃ over a Cu-SSZ-13 Catalyst Prepared by a Solid-State Ion-Exchange Method Wang, Di; Gao, Feng; Peden, Charles H. F. ChemCatChem, Vol. 6, Issue 6 https://doi.org/10.1002/cctc.201402010	journal	April 2014
Controlling Dynamic Structural Transformation of Atomically Dispersed CuO _x Species and Influence on Their Catalytic Performances Liu, Annai; Liu, Lichen; Cao, Yuan ACS Catalysis, Vol. 9, Issue 11 https://doi.org/10.1021/acscatal.9b02773	journal	September 2019
Role of Hydrated Cu Ion Complexes and Aluminum Distribution in the Framework on the Cu Ion Siting in ZSM-5 Dědeček, Jiří; Wichterlová, Blanka The Journal of Physical Chemistry B, Vol. 101, Issue 49 https://doi.org/10.1021/jp971776y	journal	December 1997
Effects of Si/Al ratio on Cu/SSZ-13 NH3-SCR catalysts: Implications for the active Cu species and the roles of Brønsted acidity Gao, Feng; Washton, Nancy M.; Wang, Yilin Journal of Catalysis, Vol. 331 https://doi.org/10.1016/j.jcat.2015.08.004	journal	November 2015
NO oxidation: A probe reaction on Cu-SSZ-13 Verma, Anuj A.; Bates, Shane A.; Anggara, Trunojoyo Journal of Catalysis, Vol. 312 https://doi.org/10.1016/j.jcat.2014.01.017	journal	April 2014
Structure–activity relationships in NH3-SCR over Cu-SSZ-13 as probed by reaction kinetics and EPR studies Gao, Feng; Walter, Eric D.; Karp, Eric M. Journal of Catalysis, Vol. 300 https://doi.org/10.1016/j.jcat.2012.12.020	journal	April 2013
Nature of active sites in Cu-LTA NH3-SCR catalysts: A comparative study with Cu-SSZ-13 Ryu, Taekyung; Kim, Hyojun; Hong, Suk Bong Applied Catalysis B: Environmental, Vol. 245 https://doi.org/10.1016/j.apcatb.2019.01.006	journal	May 2019
Improvement of low-temperature hydrothermal stability of Cu/SAPO-34 catalysts by Cu 2+ species Wang, Jun; Fan, Dequan; Yu, Tie Journal of Catalysis, Vol. 322 https://doi.org/10.1016/j.jcat.2014.11.010	journal	February 2015
The nature of ‘overexchanged’ copper and platinum on zeolites Schreier, Marc; Teren, Sarah; Belcher, Latonia Nanotechnology, Vol. 16, Issue 7 https://doi.org/10.1088/0957-4484/16/7/036	journal	June 2005
Role of Temperature and pH in Cu(OH) ₂ Solubility Hidmi, Loay; Edwards, Marc Environmental Science & Technology, Vol. 33, Issue 15 https://doi.org/10.1021/es981121q	journal	August 1999
Characterization of Cu-exchanged SSZ-13: a comparative FTIR, UV-Vis, and EPR study with Cu-ZSM-5 and Cu-β with similar Si/Al and Cu/Al ratios Giordanino, Filippo; Vennestrøm, Peter N. R.; Lundegaard, Lars F. Dalton Transactions, Vol. 42, Issue 35 https://doi.org/10.1039/c3dt50732g	journal	January 2013
Simple Template-Free Solution Route for the Controlled Synthesis of Cu(OH) ₂ and CuO Nanostructures Lu, Conghua; Qi, Limin; Yang, Jinhu The Journal of Physical Chemistry B, Vol. 108, Issue 46 https://doi.org/10.1021/jp046772p	journal	November 2004
Synthesis of Different Cu(OH) ₂ and CuO (Nanowires, Rectangles, Seed-, Belt-, and Sheetlike) Nanostructures by Simple Wet Chemical Route Singh, Dinesh Pratap; Ojha, Animesh Kumar; Srivastava, Onkar Nath The Journal of Physical Chemistry C, Vol. 113, Issue 9 https://doi.org/10.1021/jp804832g	journal	February 2009
The Scherrer Formula for X-Ray Particle Size Determination Patterson, A. L. Physical Review, Vol. 56, Issue 10 https://doi.org/10.1103/PhysRev.56.978	journal	November 1939
Structural Interconversion between Agglomerated Palladium Domains and Mononuclear Pd(II) Cations in Chabazite Zeolites Lardinois, Trevor M.; Bates, Jason S.; Lippie, Harrison H. Chemistry of Materials, Vol. 33, Issue 5 https://doi.org/10.1021/acs.chemmater.0c04465	journal	February 2021
Metal Loading Affects the Proton Transport Properties and the Reaction Monitoring Performance of Fe-ZSM-5 and Cu-ZSM-5 in NH ₃ -SCR Chen, Peirong; Moos, Ralf; Simon, Ulrich The Journal of Physical Chemistry C, Vol. 120, Issue 44 https://doi.org/10.1021/acs.jpcc.6b07353	journal	October 2016
Mobility of NH3-Solvated CuII Ions in Cu-SSZ-13 and Cu-ZSM-5 NH3-SCR Catalysts: A Comparative Impedance Spectroscopy Study Rizzotto, Valentina; Chen, Peirong; Simon, Ulrich Catalysts, Vol. 8, Issue 4 https://doi.org/10.3390/catal8040162	journal	April 2018
Low temperature catalytic NO oxidation over microporous materials Loiland, Jason A.; Lobo, Raul F. Journal of Catalysis, Vol. 311 https://doi.org/10.1016/j.jcat.2013.12.013	journal	March 2014

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Influence of ZCuOH, Z ₂ Cu, and Extraframework Cu _x O _y Species in Cu-SSZ-13 on N ₂ O Formation during the Selective Catalytic Reduction of NO _x with NH ₃