Operando analysis of the molten Li|LLZO interface: Understanding how the physical properties of Li affect the critical current density

Kinzer, Bryan; Davis, Andrew L.; Krauskopf, Thorben; Hartmann, Hannah; LePage, William S.; Kazyak, Eric; Janek, Jürgen; Dasgupta, Neil P.; Sakamoto, Jeff

doi:10.1016/j.matt.2021.04.016

Operando analysis of the molten Li|LLZO interface: Understanding how the physical properties of Li affect the critical current density

Journal Article · 01 June 2021 · Matter (Online)

DOI:https://doi.org/10.1016/j.matt.2021.04.016· OSTI ID:1848223

; ; Krauskopf, Thorben; Hartmann, Hannah; ; Kazyak, Eric; Janek, Jürgen; Dasgupta, Neil P.;

Not provided.

Research Organization:: Univ. of Michigan, Ann Arbor, MI (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

DOE Contract Number:: AR0000653

OSTI ID:: 1848223

Journal Information:: Matter (Online), Vol. 4, Issue 6; ISSN 2590-2385

Publisher:: Cell Press/Elsevier

Country of Publication:: United States

Language:: English

References (53)

Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries Albertus, Paul; Babinec, Susan; Litzelman, Scott Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0047-2	journal	December 2017
Benchmarking the performance of all-solid-state lithium batteries Randau, Simon; Weber, Dominik A.; Kötz, Olaf Nature Energy, Vol. 5, Issue 3 https://doi.org/10.1038/s41560-020-0565-1	journal	March 2020
Challenges Facing Lithium Batteries and Electrical Double-Layer Capacitors Choi, Nam-Soon; Chen, Zonghai; Freunberger, Stefan A. Angewandte Chemie International Edition, Vol. 51, Issue 40 https://doi.org/10.1002/anie.201201429	journal	September 2012
Fundamentals of inorganic solid-state electrolytes for batteries Famprikis, Theodosios; Canepa, Pieremanuele; Dawson, James A. Nature Materials, Vol. 18, Issue 12 https://doi.org/10.1038/s41563-019-0431-3	journal	August 2019
Lithium Metal Anodes: Toward an Improved Understanding of Coupled Morphological, Electrochemical, and Mechanical Behavior Wood, Kevin N.; Noked, Malachi; Dasgupta, Neil P. ACS Energy Letters, Vol. 2, Issue 3 https://doi.org/10.1021/acsenergylett.6b00650	journal	February 2017
High-Efficiency Lithium-Metal Anode Enabled by Liquefied Gas Electrolytes Yang, Yangyuchen; Davies, Daniel M.; Yin, Yijie Joule, Vol. 3, Issue 8 https://doi.org/10.1016/j.joule.2019.06.008	journal	August 2019
Recent progress in liquid electrolytes for lithium metal batteries Ue, Makoto; Uosaki, Kohei Current Opinion in Electrochemistry, Vol. 17 https://doi.org/10.1016/j.coelec.2019.05.001	journal	October 2019
Challenges in Lithium Metal Anodes for Solid-State Batteries Hatzell, Kelsey B.; Chen, Xi Chelsea; Cobb, Corie L. ACS Energy Letters, Vol. 5, Issue 3 https://doi.org/10.1021/acsenergylett.9b02668	journal	February 2020
Li ₇ La ₃ Zr ₂ O ₁₂ Interface Modification for Li Dendrite Prevention Tsai, Chih-Long; Roddatis, Vladimir; Chandran, C. Vinod ACS Applied Materials & Interfaces, Vol. 8, Issue 16 https://doi.org/10.1021/acsami.6b00831	journal	April 2016
Demonstration of high current densities and extended cycling in the garnet Li7La3Zr2O12 solid electrolyte Taylor, Nathan J.; Stangeland-Molo, Sandra; Haslam, Catherine G. Journal of Power Sources, Vol. 396 https://doi.org/10.1016/j.jpowsour.2018.06.055	journal	August 2018
High-energy long-cycling all-solid-state lithium metal batteries enabled by silver–carbon composite anodes Lee, Yong-Gun; Fujiki, Satoshi; Jung, Changhoon Nature Energy, Vol. 5, Issue 4 https://doi.org/10.1038/s41560-020-0575-z	journal	March 2020
Intergranular Li metal propagation through polycrystalline Li6.25Al0.25La3Zr2O12 ceramic electrolyte Cheng, Eric Jianfeng; Sharafi, Asma; Sakamoto, Jeff Electrochimica Acta, Vol. 223 https://doi.org/10.1016/j.electacta.2016.12.018	journal	January 2017
Effect of Pore Connectivity on Li Dendrite Propagation within LLZO Electrolytes Observed with Synchrotron X-ray Tomography Shen, Fengyu; Dixit, Marm B.; Xiao, Xianghui ACS Energy Letters, Vol. 3, Issue 4 https://doi.org/10.1021/acsenergylett.8b00249	journal	March 2018
Study of the Mechanisms of Internal Short Circuit in a Li/Li Cell by Synchrotron X-ray Phase Contrast Tomography Sun, Fu; Moroni, Riko; Dong, Kang ACS Energy Letters, Vol. 2, Issue 1 https://doi.org/10.1021/acsenergylett.6b00589	journal	December 2016
Mechanism of Lithium Metal Penetration through Inorganic Solid Electrolytes Porz, Lukas; Swamy, Tushar; Sheldon, Brian W. Advanced Energy Materials, Vol. 7, Issue 20 https://doi.org/10.1002/aenm.201701003	journal	July 2017
Li Penetration in Ceramic Solid Electrolytes: Operando Microscopy Analysis of Morphology, Propagation, and Reversibility Kazyak, Eric; Garcia-Mendez, Regina; LePage, William S. Matter, Vol. 2, Issue 4 https://doi.org/10.1016/j.matt.2020.02.008	journal	April 2020
Temperature dependent flux balance of the Li/Li7La3Zr2O12 interface Wang, Michael; Wolfenstine, Jeffrey B.; Sakamoto, Jeff Electrochimica Acta, Vol. 296 https://doi.org/10.1016/j.electacta.2018.11.034	journal	February 2019
The chemical and electrochemical stability of beta-alumina Ansell, R. 0. Journal of Materials Science, Vol. 21, Issue 2 https://doi.org/10.1007/BF01145497	journal	February 1986
Physicochemical Concepts of the Lithium Metal Anode in Solid-State Batteries Krauskopf, Thorben; Richter, Felix H.; Zeier, Wolfgang G. Chemical Reviews, Vol. 120, Issue 15 https://doi.org/10.1021/acs.chemrev.0c00431	journal	July 2020
An Analysis of Solid-State Electrodeposition-Induced Metal Plastic Flow and Predictions of Stress States in Solid Ionic Conductor Defects Barroso-Luque, Luis; Tu, Qingsong; Ceder, Gerbrand Journal of The Electrochemical Society, Vol. 167, Issue 2 https://doi.org/10.1149/1945-7111/ab6c5b	journal	January 2020
Failure modes of Na-beta alumina De Jonghe, Lutgard C.; Feldman, L.; Buechele, A. Solid State Ionics, Vol. 5 https://doi.org/10.1016/0167-2738(81)90244-7	journal	October 1981
Initiation of mode I degradation in sodium-beta alumina electrolytes Feldman, L. A.; De Jonghe, Lutgard C. Journal of Materials Science, Vol. 17, Issue 2 https://doi.org/10.1007/BF00591486	journal	February 1982
The breakdown of β-alumina ceramic electrolyte Armstrong, R. D.; Dickinson, T.; Turner, J. Electrochimica Acta, Vol. 19, Issue 5 https://doi.org/10.1016/0013-4686(74)85065-6	journal	May 1974
High electronic conductivity as the origin of lithium dendrite formation within solid electrolytes Han, Fudong; Westover, Andrew S.; Yue, Jie Nature Energy, Vol. 4, Issue 3 https://doi.org/10.1038/s41560-018-0312-z	journal	January 2019
Slow degradation and electron conduction in sodium/beta-aluminas De Jonghe, Lutgard C.; Feldman, Leslie; Beuchele, Andrew Journal of Materials Science, Vol. 16, Issue 3 https://doi.org/10.1007/BF02402796	journal	March 1981
Surface Chemistry Mechanism of Ultra-Low Interfacial Resistance in the Solid-State Electrolyte Li ₇ La ₃ Zr ₂ O ₁₂ Sharafi, Asma; Kazyak, Eric; Davis, Andrew L. Chemistry of Materials, Vol. 29, Issue 18 https://doi.org/10.1021/acs.chemmater.7b03002	journal	September 2017
Sodium/Na β″ Alumina Interface: Effect of Pressure on Voids Spencer Jolly, Dominic; Ning, Ziyang; Darnbrough, James E. ACS Applied Materials & Interfaces, Vol. 12, Issue 1 https://doi.org/10.1021/acsami.9b17786	journal	December 2019
Lithium Mechanics: Roles of Strain Rate and Temperature and Implications for Lithium Metal Batteries LePage, William S.; Chen, Yuxin; Kazyak, Eric Journal of The Electrochemical Society, Vol. 166, Issue 2 https://doi.org/10.1149/2.0221902jes	journal	January 2019
Critical stripping current leads to dendrite formation on plating in lithium anode solid electrolyte cells Kasemchainan, Jitti; Zekoll, Stefanie; Spencer Jolly, Dominic Nature Materials, Vol. 18, Issue 10 https://doi.org/10.1038/s41563-019-0438-9	journal	July 2019
Elastic, plastic, and creep mechanical properties of lithium metal Masias, Alvaro; Felten, Nando; Garcia-Mendez, Regina Journal of Materials Science, Vol. 54, Issue 3 https://doi.org/10.1007/s10853-018-2971-3	journal	October 2018
Analysis of elastic, plastic, and creep properties of sodium metal and implications for solid-state batteries Wang, Michael J.; Chang, Jiun-Yeu; Wolfenstine, Jeffrey B. Materialia, Vol. 12 https://doi.org/10.1016/j.mtla.2020.100792	journal	August 2020
Toward a Fundamental Understanding of the Lithium Metal Anode in Solid-State Batteries—An Electrochemo-Mechanical Study on the Garnet-Type Solid Electrolyte Li _6.25 Al _0.25 La ₃ Zr ₂ O ₁₂ Krauskopf, Thorben; Hartmann, Hannah; Zeier, Wolfgang G. ACS Applied Materials & Interfaces, Vol. 11, Issue 15 https://doi.org/10.1021/acsami.9b02537	journal	March 2019
Dead lithium: mass transport effects on voltage, capacity, and failure of lithium metal anodes Chen, Kuan-Hung; Wood, Kevin N.; Kazyak, Eric Journal of Materials Chemistry A, Vol. 5, Issue 23 https://doi.org/10.1039/C7TA00371D	journal	January 2017
An intermediate temperature garnet-type solid electrolyte-based molten lithium battery for grid energy storage Jin, Yang; Liu, Kai; Lang, Jialiang Nature Energy, Vol. 3, Issue 9 https://doi.org/10.1038/s41560-018-0198-9	journal	July 2018
Characterizing the Li-Solid-Electrolyte Interface Dynamics as a Function of Stack Pressure and Current Density Wang, Michael J.; Choudhury, Rishav; Sakamoto, Jeff Joule, Vol. 3, Issue 9 https://doi.org/10.1016/j.joule.2019.06.017	journal	September 2019
High-Energy-Density Solid-Electrolyte-Based Liquid Li-S and Li-Se Batteries Jin, Yang; Liu, Kai; Lang, Jialiang Joule, Vol. 4, Issue 1 https://doi.org/10.1016/j.joule.2019.09.003	journal	January 2020
A molten battery consisting of Li metal anode, AlCl3-LiCl cathode and solid electrolyte Lang, Jialiang; Liu, Kai; Jin, Yang Energy Storage Materials, Vol. 24 https://doi.org/10.1016/j.ensm.2019.07.027	journal	January 2020
Lithium Metal Penetration Induced by Electrodeposition through Solid Electrolytes: Example in Single-Crystal Li ₆ La ₃ ZrTaO ₁₂ Garnet Swamy, Tushar; Park, Richard; Sheldon, Brian W. Journal of The Electrochemical Society, Vol. 165, Issue 16 https://doi.org/10.1149/2.1391814jes	journal	January 2018
Characterizing the Li–Li7La3Zr2O12 interface stability and kinetics as a function of temperature and current density Sharafi, Asma; Meyer, Harry M.; Nanda, Jagjit Journal of Power Sources, Vol. 302 https://doi.org/10.1016/j.jpowsour.2015.10.053	journal	January 2016
Sodium Penetration in Rapid Ion Conductors Virkar, Anil V.; Viswanathan, L. Journal of the American Ceramic Society, Vol. 62, Issue 9-10 https://doi.org/10.1111/j.1151-2916.1979.tb19123.x	journal	September 1979
The Electronic Conductivity of Single Crystalline Ga‐Stabilized Cubic Li ₇ La ₃ Zr ₂ O ₁₂ : A Technologically Relevant Parameter for All‐Solid‐State Batteries Philipp, Martin; Gadermaier, Bernhard; Posch, Patrick Advanced Materials Interfaces https://doi.org/10.1002/admi.202000450	journal	June 2020
A novel temperature-dependent yield stress model for ceramic materials under indentation Li, Chaojuan; Wang, Ruzhuan; Wang, Xiaorong Ceramics International, Vol. 46, Issue 7 https://doi.org/10.1016/j.ceramint.2019.12.109	journal	May 2020
The Fast Charge Transfer Kinetics of the Lithium Metal Anode on the Garnet‐Type Solid Electrolyte Li _6.25 Al _0.25 La ₃ Zr ₂ O ₁₂ Krauskopf, Thorben; Mogwitz, Boris; Hartmann, Hannah Advanced Energy Materials, Vol. 10, Issue 27 https://doi.org/10.1002/aenm.202000945	journal	June 2020
Mechanical failure of garnet electrolytes during Li electrodeposition observed by in-operando microscopy Manalastas, William; Rikarte, Jokin; Chater, Richard J. Journal of Power Sources, Vol. 412 https://doi.org/10.1016/j.jpowsour.2018.11.041	journal	February 2019
Lithium-Metal Growth Kinetics on LLZO Garnet-Type Solid Electrolytes Krauskopf, Thorben; Dippel, Rabea; Hartmann, Hannah Joule, Vol. 3, Issue 8 https://doi.org/10.1016/j.joule.2019.06.013	journal	August 2019
Fundamental Problems in Viscoplasticity Perzyna, Piotr Advances in Applied Mechanics https://doi.org/10.1016/S0065-2156(08)70009-7	book	May 1966
An Elastic-Viscoplastic Model for Lithium Anand, Lallit; Narayan, Sooraj Journal of The Electrochemical Society, Vol. 166, Issue 6 https://doi.org/10.1149/2.0861906jes	journal	January 2019
Self‐Diffusion Coefficient of Liquid Lithium Murday, J. S.; Cotts, R. M. The Journal of Chemical Physics, Vol. 48, Issue 11 https://doi.org/10.1063/1.1668160	journal	June 1968
Molecular Transport in Liquids and Glasses Cohen, Morrel H.; Turnbull, David The Journal of Chemical Physics, Vol. 31, Issue 5 https://doi.org/10.1063/1.1730566	journal	November 1959
Isotope Inter-Diffusion and Self-Diffusion in Solid Lithium Metal Lodding, A.; Mundy, J. N.; Ott, A. physica status solidi (b), Vol. 38, Issue 2 https://doi.org/10.1002/pssb.19700380206	journal	January 1970
Dendritic cracking in solid electrolytes driven by lithium insertion Klinsmann, Markus; Hildebrand, Felix E.; Ganser, Markus Journal of Power Sources, Vol. 442 https://doi.org/10.1016/j.jpowsour.2019.227226	journal	December 2019
Modeling of lithium electrodeposition at the lithium/ceramic electrolyte interface: The role of interfacial resistance and surface defects Bucci, Giovanna; Christensen, Jake Journal of Power Sources, Vol. 441 https://doi.org/10.1016/j.jpowsour.2019.227186	journal	November 2019
Correlating the effect of dopant type (Al, Ga, Ta) on the mechanical and electrical properties of hot-pressed Li-garnet electrolyte Han, Gigap; Kinzer, Bryan; Garcia-Mendez, Regina Journal of the European Ceramic Society, Vol. 40, Issue 5 https://doi.org/10.1016/j.jeurceramsoc.2019.12.054	journal	May 2020

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