Mesoscale Interrogation Reveals Mechanistic Origins of Lithium Filaments along Grain Boundaries in I

Vishnugopi, Bairav S.; Dixit, Marm B.; Hao, Feng; Shyam, Badri; Cook, John B.; Hatzell, Kelsey B.; Mukherjee, Partha P.

doi:10.1002/aenm.202102825

Title: Mesoscale Interrogation Reveals Mechanistic Origins of Lithium Filaments along Grain Boundaries in I

Journal Article · 01 January 2022 · Adv. Eng. Mater.

DOI:https://doi.org/10.1002/aenm.202102825· OSTI ID:1847705

Vishnugopi, Bairav S.; Dixit, Marm B.; Hao, Feng; Shyam, Badri; Cook, John B.; Hatzell, Kelsey B.; Mukherjee, Partha P.

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: DOE - Office Of Science; National Science Foundation (NSF)

OSTI ID:: 1847705

Journal Information:: Adv. Eng. Mater., Vol. 12, Issue (3)

Country of Publication:: United States

Language:: ENGLISH

References (71)

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review Cheng, Xin-Bing; Zhang, Rui; Zhao, Chen-Zi Chemical Reviews, Vol. 117, Issue 15 https://doi.org/10.1021/acs.chemrev.7b00115	journal	July 2017
Promise and reality of post-lithium-ion batteries with high energy densities Choi, Jang Wook; Aurbach, Doron Nature Reviews Materials, Vol. 1, Issue 4 https://doi.org/10.1038/natrevmats.2016.13	journal	March 2016
Lithium metal anodes for rechargeable batteries Xu, Wu; Wang, Jiulin; Ding, Fei Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE40795K	journal	January 2014
Reviving Lithium-Metal Anodes for Next-Generation High-Energy Batteries Guo, Yanpeng; Li, Huiqiao; Zhai, Tianyou Advanced Materials, Vol. 29, Issue 29 https://doi.org/10.1002/adma.201700007	journal	June 2017
Dendrite-free lithium metal anodes: stable solid electrolyte interphases for high-efficiency batteries Cheng, Xin-Bing; Zhang, Qiang Journal of Materials Chemistry A, Vol. 3, Issue 14 https://doi.org/10.1039/C5TA00689A	journal	January 2015
Quantifying the promise of lithium–air batteries for electric vehicles Gallagher, Kevin G.; Goebel, Steven; Greszler, Thomas Energy & Environmental Science, Vol. 7, Issue 5 https://doi.org/10.1039/c3ee43870h	journal	January 2014
Electrochemical in situ investigations of SEI and dendrite formation on the lithium metal anode Bieker, Georg; Winter, Martin; Bieker, Peter Physical Chemistry Chemical Physics, Vol. 17, Issue 14 https://doi.org/10.1039/C4CP05865H	journal	January 2015
Reviving the lithium metal anode for high-energy batteries Lin, Dingchang; Liu, Yayuan; Cui, Yi Nature Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1038/nnano.2017.16	journal	March 2017
Dead lithium: mass transport effects on voltage, capacity, and failure of lithium metal anodes Chen, Kuan-Hung; Wood, Kevin N.; Kazyak, Eric Journal of Materials Chemistry A, Vol. 5, Issue 23 https://doi.org/10.1039/C7TA00371D	journal	January 2017
Microscopic observations of the formation, growth and shrinkage of lithium moss during electrodeposition and dissolution Steiger, Jens; Kramer, Dominik; Mönig, Reiner Electrochimica Acta, Vol. 136 https://doi.org/10.1016/j.electacta.2014.05.120	journal	August 2014
Lithium Electrode Morphology during Cycling in Lithium Cells Yoshimatsu, Isamu Journal of The Electrochemical Society, Vol. 135, Issue 10 https://doi.org/10.1149/1.2095351	journal	January 1988
Dendrites and Pits: Untangling the Complex Behavior of Lithium Metal Anodes through Operando Video Microscopy Wood, Kevin N.; Kazyak, Eric; Chadwick, Alexander F. ACS Central Science, Vol. 2, Issue 11 https://doi.org/10.1021/acscentsci.6b00260	journal	October 2016
Challenges in Lithium Metal Anodes for Solid-State Batteries Hatzell, Kelsey B.; Chen, Xi Chelsea; Cobb, Corie L. ACS Energy Letters, Vol. 5, Issue 3 https://doi.org/10.1021/acsenergylett.9b02668	journal	February 2020
Physicochemical Concepts of the Lithium Metal Anode in Solid-State Batteries Krauskopf, Thorben; Richter, Felix H.; Zeier, Wolfgang G. Chemical Reviews, Vol. 120, Issue 15 https://doi.org/10.1021/acs.chemrev.0c00431	journal	July 2020
High-power all-solid-state batteries using sulfide superionic conductors Kato, Yuki; Hori, Satoshi; Saito, Toshiya Nature Energy, Vol. 1, Issue 4 https://doi.org/10.1038/nenergy.2016.30	journal	March 2016
High sodium ion conductivity of glass–ceramic electrolytes with cubic Na3PS4 Hayashi, Akitoshi; Noi, Kousuke; Tanibata, Naoto Journal of Power Sources, Vol. 258 https://doi.org/10.1016/j.jpowsour.2014.02.054	journal	July 2014
Transition of lithium growth mechanisms in liquid electrolytes Bai, Peng; Li, Ju; Brushett, Fikile R. Energy & Environmental Science, Vol. 9, Issue 10 https://doi.org/10.1039/C6EE01674J	journal	January 2016
Electrochemical aspects of the generation of ramified metallic electrodeposits Chazalviel, J. -N. Physical Review A, Vol. 42, Issue 12 https://doi.org/10.1103/PhysRevA.42.7355	journal	December 1990
Chemo-Mechanical Challenges in Solid-State Batteries Lewis, John A.; Tippens, Jared; Cortes, Francisco Javier Quintero Trends in Chemistry, Vol. 1, Issue 9 https://doi.org/10.1016/j.trechm.2019.06.013	journal	December 2019
A solid future for battery development Janek, Jürgen; Zeier, Wolfgang G. Nature Energy, Vol. 1, Issue 9 https://doi.org/10.1038/nenergy.2016.141	journal	September 2016
Direct observation of lithium dendrites inside garnet-type lithium-ion solid electrolyte Ren, Yaoyu; Shen, Yang; Lin, Yuanhua Electrochemistry Communications, Vol. 57 https://doi.org/10.1016/j.elecom.2015.05.001	journal	August 2015
Intergranular Li metal propagation through polycrystalline Li6.25Al0.25La3Zr2O12 ceramic electrolyte Cheng, Eric Jianfeng; Sharafi, Asma; Sakamoto, Jeff Electrochimica Acta, Vol. 223 https://doi.org/10.1016/j.electacta.2016.12.018	journal	January 2017
Characterizing the Li–Li7La3Zr2O12 interface stability and kinetics as a function of temperature and current density Sharafi, Asma; Meyer, Harry M.; Nanda, Jagjit Journal of Power Sources, Vol. 302 https://doi.org/10.1016/j.jpowsour.2015.10.053	journal	January 2016
Effect of Surface Microstructure on Electrochemical Performance of Garnet Solid Electrolytes Cheng, Lei; Chen, Wei; Kunz, Martin ACS Applied Materials & Interfaces, Vol. 7, Issue 3 https://doi.org/10.1021/am508111r	journal	January 2015
Contact between Garnet-Type Solid Electrolyte and Lithium Metal Anode: Influence on Charge Transfer Resistance and Short Circuit Prevention Basappa, Rajendra Hongahally; Ito, Tomoko; Yamada, Hirotoshi Journal of The Electrochemical Society, Vol. 164, Issue 4 https://doi.org/10.1149/2.0841704jes	journal	January 2017
Lithium Mechanics: Roles of Strain Rate and Temperature and Implications for Lithium Metal Batteries LePage, William S.; Chen, Yuxin; Kazyak, Eric Journal of The Electrochemical Society, Vol. 166, Issue 2 https://doi.org/10.1149/2.0221902jes	journal	January 2019
The Impact of Elastic Deformation on Deposition Kinetics at Lithium/Polymer Interfaces Monroe, Charles; Newman, John Journal of The Electrochemical Society, Vol. 152, Issue 2 https://doi.org/10.1149/1.1850854	journal	January 2005
The Effect of Interfacial Deformation on Electrodeposition Kinetics Monroe, Charles; Newman, John Journal of The Electrochemical Society, Vol. 151, Issue 6 https://doi.org/10.1149/1.1710893	journal	January 2004
Effect of Pore Connectivity on Li Dendrite Propagation within LLZO Electrolytes Observed with Synchrotron X-ray Tomography Shen, Fengyu; Dixit, Marm B.; Xiao, Xianghui ACS Energy Letters, Vol. 3, Issue 4 https://doi.org/10.1021/acsenergylett.8b00249	journal	March 2018
Tortuosity Effects in Garnet-Type Li ₇ La ₃ Zr ₂ O ₁₂ Solid Electrolytes Dixit, Marm B.; Regala, Matthew; Shen, Fengyu ACS Applied Materials & Interfaces, Vol. 11, Issue 2 https://doi.org/10.1021/acsami.8b16536	journal	December 2018
Mechanical Stress Induced Current Focusing and Fracture in Grain Boundaries Barai, Pallab; Higa, Kenneth; Ngo, Anh T. Journal of The Electrochemical Society, Vol. 166, Issue 10 https://doi.org/10.1149/2.0321910jes	journal	January 2019
Modulating Nanoinhomogeneity at Electrode–Solid Electrolyte Interfaces for Dendrite‐Proof Solid‐State Batteries and Long‐Life Memristors Lu, Ziheng; Yang, Ziwei; Li, Cheng Advanced Energy Materials, Vol. 11, Issue 16 https://doi.org/10.1002/aenm.202003811	journal	March 2021
The Role of Local Inhomogeneities on Dendrite Growth in LLZO-Based Solid Electrolytes Barai, Pallab; Ngo, Anh T.; Narayanan, Badri Journal of The Electrochemical Society, Vol. 167, Issue 10 https://doi.org/10.1149/1945-7111/ab9b08	journal	June 2020
Mechanism of Lithium Metal Penetration through Inorganic Solid Electrolytes Porz, Lukas; Swamy, Tushar; Sheldon, Brian W. Advanced Energy Materials, Vol. 7, Issue 20 https://doi.org/10.1002/aenm.201701003	journal	July 2017
Lithium-Metal Growth Kinetics on LLZO Garnet-Type Solid Electrolytes Krauskopf, Thorben; Dippel, Rabea; Hartmann, Hannah Joule, Vol. 3, Issue 8 https://doi.org/10.1016/j.joule.2019.06.013	journal	August 2019
Molar Volume Mismatch: A Malefactor for Irregular Metallic Electrodeposition with Solid Electrolytes Mistry, Aashutosh; Mukherjee, Partha P. Journal of The Electrochemical Society, Vol. 167, Issue 8 https://doi.org/10.1149/1945-7111/ab8ecd	journal	May 2020
Microstructure and Pressure-Driven Electrodeposition Stability in Solid-State Batteries Verma, Ankit; Kawakami, Hiroki; Wada, Hiroyuki Cell Reports Physical Science, Vol. 2, Issue 1 https://doi.org/10.1016/j.xcrp.2020.100301	journal	January 2021
Lithium Metal Penetration Induced by Electrodeposition through Solid Electrolytes: Example in Single-Crystal Li ₆ La ₃ ZrTaO ₁₂ Garnet Swamy, Tushar; Park, Richard; Sheldon, Brian W. Journal of The Electrochemical Society, Vol. 165, Issue 16 https://doi.org/10.1149/2.1391814jes	journal	January 2018
Grain Boundary Softening: A Potential Mechanism for Lithium Metal Penetration through Stiff Solid Electrolytes Yu, Seungho; Siegel, Donald J. ACS Applied Materials & Interfaces, Vol. 10, Issue 44 https://doi.org/10.1021/acsami.8b17223	journal	October 2018
Revealing the Short‐Circuiting Mechanism of Garnet‐Based Solid‐State Electrolyte Song, Yongli; Yang, Luyi; Zhao, Wenguang Advanced Energy Materials, Vol. 9, Issue 21 https://doi.org/10.1002/aenm.201900671	journal	April 2019
High electronic conductivity as the origin of lithium dendrite formation within solid electrolytes Han, Fudong; Westover, Andrew S.; Yue, Jie Nature Energy, Vol. 4, Issue 3 https://doi.org/10.1038/s41560-018-0312-z	journal	January 2019
Interphase Morphology between a Solid-State Electrolyte and Lithium Controls Cell Failure Lewis, John A.; Cortes, Francisco Javier Quintero; Boebinger, Matthew G. ACS Energy Letters, Vol. 4, Issue 2 https://doi.org/10.1021/acsenergylett.9b00093	journal	January 2019
Visualizing Chemomechanical Degradation of a Solid-State Battery Electrolyte Tippens, Jared; Miers, John C.; Afshar, Arman ACS Energy Letters, Vol. 4, Issue 6 https://doi.org/10.1021/acsenergylett.9b00816	journal	May 2019
Linking void and interphase evolution to electrochemistry in solid-state batteries using operando X-ray tomography Lewis, John A.; Cortes, Francisco Javier Quintero; Liu, Yuhgene Nature Materials, Vol. 20, Issue 4 https://doi.org/10.1038/s41563-020-00903-2	journal	January 2021
Temperature dependent flux balance of the Li/Li7La3Zr2O12 interface Wang, Michael; Wolfenstine, Jeffrey B.; Sakamoto, Jeff Electrochimica Acta, Vol. 296 https://doi.org/10.1016/j.electacta.2018.11.034	journal	February 2019
Diffusion Limitation of Lithium Metal and Li–Mg Alloy Anodes on LLZO Type Solid Electrolytes as a Function of Temperature and Pressure Krauskopf, Thorben; Mogwitz, Boris; Rosenbach, Carolin Advanced Energy Materials, Vol. 9, Issue 44 https://doi.org/10.1002/aenm.201902568	journal	October 2019
Critical stripping current leads to dendrite formation on plating in lithium anode solid electrolyte cells Kasemchainan, Jitti; Zekoll, Stefanie; Spencer Jolly, Dominic Nature Materials, Vol. 18, Issue 10 https://doi.org/10.1038/s41563-019-0438-9	journal	July 2019
Characterizing the Li-Solid-Electrolyte Interface Dynamics as a Function of Stack Pressure and Current Density Wang, Michael J.; Choudhury, Rishav; Sakamoto, Jeff Joule, Vol. 3, Issue 9 https://doi.org/10.1016/j.joule.2019.06.017	journal	September 2019
Toward a Fundamental Understanding of the Lithium Metal Anode in Solid-State Batteries—An Electrochemo-Mechanical Study on the Garnet-Type Solid Electrolyte Li _6.25 Al _0.25 La ₃ Zr ₂ O ₁₂ Krauskopf, Thorben; Hartmann, Hannah; Zeier, Wolfgang G. ACS Applied Materials & Interfaces, Vol. 11, Issue 15 https://doi.org/10.1021/acsami.9b02537	journal	March 2019
Synchrotron Imaging of Pore Formation in Li Metal Solid-State Batteries Aided by Machine Learning Dixit, Marm B.; Verma, Ankit; Zaman, Wahid ACS Applied Energy Materials, Vol. 3, Issue 10 https://doi.org/10.1021/acsaem.0c02053	journal	September 2020
Li Penetration in Ceramic Solid Electrolytes: Operando Microscopy Analysis of Morphology, Propagation, and Reversibility Kazyak, Eric; Garcia-Mendez, Regina; LePage, William S. Matter, Vol. 2, Issue 4 https://doi.org/10.1016/j.matt.2020.02.008	journal	April 2020
Coupled crack propagation and dendrite growth in solid electrolyte of all-solid-state battery Yuan, Chunhao; Gao, Xiang; Jia, Yikai Nano Energy, Vol. 86 https://doi.org/10.1016/j.nanoen.2021.106057	journal	August 2021
Atomic-Scale Influence of Grain Boundaries on Li-Ion Conduction in Solid Electrolytes for All-Solid-State Batteries Dawson, James A.; Canepa, Pieremanuele; Famprikis, Theodosios Journal of the American Chemical Society, Vol. 140, Issue 1 https://doi.org/10.1021/jacs.7b10593	journal	December 2017
Resolving the Grain Boundary and Lattice Impedance of Hot-Pressed Li ₇ La ₃ Zr ₂ O ₁₂ Garnet Electrolytes Tenhaeff, Wyatt E.; Rangasamy, Ezhiyl; Wang, Yangyang ChemElectroChem, Vol. 1, Issue 2 https://doi.org/10.1002/celc.201300022	journal	July 2013
Grain Boundary Contributions to Li-Ion Transport in the Solid Electrolyte Li ₇ La ₃ Zr ₂ O ₁₂ (LLZO) Yu, Seungho; Siegel, Donald J. Chemistry of Materials, Vol. 29, Issue 22 https://doi.org/10.1021/acs.chemmater.7b02805	journal	November 2017
Origin of the low grain boundary conductivity in lithium ion conducting perovskites: Li _3x La _0.67−x TiO ₃ Wu, Jian-Fang; Guo, Xin Physical Chemistry Chemical Physics, Vol. 19, Issue 8 https://doi.org/10.1039/C6CP07757A	journal	January 2017
A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries Seino, Yoshikatsu; Ota, Tsuyoshi; Takada, Kazunori Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE41655K	journal	January 2014
Frequency factors and isotope effects in solid state rate processes Vineyard, George H. Journal of Physics and Chemistry of Solids, Vol. 3, Issue 1-2 https://doi.org/10.1016/0022-3697(57)90059-8	journal	January 1957
Introduction to the Kinetic Monte Carlo Method Voter, Arthur F. Radiation Effects in Solids https://doi.org/10.1007/978-1-4020-5295-8_1	book	January 2007
Surface diffusion manifestation in electrodeposition of metal anodes Vishnugopi, Bairav S.; Hao, Feng; Verma, Ankit Physical Chemistry Chemical Physics, Vol. 22, Issue 20 https://doi.org/10.1039/D0CP01352H	journal	January 2020
Double-Edged Effect of Temperature on Lithium Dendrites Vishnugopi, Bairav Sabarish; Hao, Feng; Verma, Ankit ACS Applied Materials & Interfaces, Vol. 12, Issue 21 https://doi.org/10.1021/acsami.0c04355	journal	May 2020
Co-Electrodeposition Mechanism in Rechargeable Metal Batteries Vishnugopi, Bairav S.; Hao, Feng; Verma, Ankit ACS Energy Letters, Vol. 6, Issue 6 https://doi.org/10.1021/acsenergylett.1c00677	journal	May 2021
Nonuniform Ionic and Electronic Transport of Ceramic and Polymer/Ceramic Hybrid Electrolyte by Nanometer‐Scale Operando Imaging for Solid‐State Battery Jiang, Chun‐Sheng; Dunlap, Nathan; Li, Yejing Advanced Energy Materials, Vol. 10, Issue 21 https://doi.org/10.1002/aenm.202000219	journal	April 2020
Elastic Properties of the Solid Electrolyte Li ₇ La ₃ Zr ₂ O ₁₂ (LLZO) Yu, Seungho; Schmidt, Robert D.; Garcia-Mendez, Regina Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b03854	journal	December 2015
Elastic, plastic, and creep mechanical properties of lithium metal Masias, Alvaro; Felten, Nando; Garcia-Mendez, Regina Journal of Materials Science, Vol. 54, Issue 3 https://doi.org/10.1007/s10853-018-2971-3	journal	October 2018
3D Imaging of Lithium Protrusions in Solid‐State Lithium Batteries using X‐Ray Computed Tomography Hao, Shuai; Bailey, Josh J.; Iacoviello, Francesco Advanced Functional Materials, Vol. 31, Issue 10 https://doi.org/10.1002/adfm.202007564	journal	December 2020
Enhancement Effects of Co Doping on Interfacial Properties of Sn Electrode−Collector: A First-Principles Study Zhang, Panpan; Wang, Yan; Lei, Weixin ACS Applied Materials & Interfaces, Vol. 11, Issue 27 https://doi.org/10.1021/acsami.9b01418	journal	June 2019
Energetics Dictates Deposition at Metal/Solid Electrolyte Interfaces Tewari, Deepti; Mukherjee, Partha P. The Journal of Physical Chemistry C, Vol. 125, Issue 4 https://doi.org/10.1021/acs.jpcc.0c05873	journal	August 2020
Challenges and Opportunities for Fast Charging of Solid-State Lithium Metal Batteries Vishnugopi, Bairav S.; Kazyak, Eric; Lewis, John A. ACS Energy Letters, Vol. 6, Issue 10 https://doi.org/10.1021/acsenergylett.1c01352	journal	September 2021
Blocking lithium dendrite growth in solid-state batteries with an ultrathin amorphous Li-La-Zr-O solid electrolyte Sastre, Jordi; Futscher, Moritz H.; Pompizi, Lea Communications Materials, Vol. 2, Issue 1 https://doi.org/10.1038/s43246-021-00177-4	journal	July 2021
A chemo-mechanical damage model at large deformation: numerical and experimental studies on polycrystalline energy materials Bai, Yang; Santos, David A.; Rezaei, Shahed International Journal of Solids and Structures, Vol. 228 https://doi.org/10.1016/j.ijsolstr.2021.111099	journal	October 2021

Similar Records

Mesoscale Interrogation Reveals Mechanistic Origins of Lithium Filaments along Grain Boundaries in I

Journal Article · 2022 · Adv. Eng. Mater. · OSTI ID:1847705

Vishnugopi, Bairav S.; Dixit, Marm B.; Hao, Feng; +4 more

Mesoscale Interrogation Reveals Mechanistic Origins of Lithium Filaments along Grain Boundaries in Inorganic Solid Electrolytes

Journal Article · 2021 · Advanced Energy Materials · OSTI ID:1847705

Vishnugopi, Bairav S.; Dixit, Marm B.; Hao, Feng; +4 more

Origin of fast oxide ion diffusion along grain boundaries in Sr-doped LaMnO ₃

Journal Article · 2018 · Physical Chemistry Chemical Physics. PCCP · OSTI ID:1847705

Polfus, Jonathan M.; Yildiz, Bilge; Tuller, Harry L.

Title: Mesoscale Interrogation Reveals Mechanistic Origins of Lithium Filaments along Grain Boundaries in I

Citation Formats

References (71)

Similar Records

Related Subjects