Exsolution of nanoparticles on A-site-deficient lanthanum ferrite perovskites: its effect on co-elec

Kim, Jaesung; Ferree, Matthew; Gunduz, Seval; Millet, Jean-Marc M.; Aouine, Mimoun; Co, Anne C.; Ozkan, Umit S.

doi:10.1039/D1TA07389C

Exsolution of nanoparticles on A-site-deficient lanthanum ferrite perovskites: its effect on co-elec

Journal Article · 01 January 2022 · J. Mater. Chem. A

DOI:https://doi.org/10.1039/D1TA07389C· OSTI ID:1847703

Kim, Jaesung; Ferree, Matthew; Gunduz, Seval; Millet, Jean-Marc M.; Aouine, Mimoun; Co, Anne C.; Ozkan, Umit S.

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: DOE - Office Of Science; DOE - BASIC ENERGY SCIENCES

OSTI ID:: 1847703

Journal Information:: J. Mater. Chem. A, Vol. 10, Issue (5)

Country of Publication:: United States

Language:: ENGLISH

References (73)

Sustainable hydrocarbon fuels by recycling CO 2 and H 2 O with renewable or nuclear energy Graves, Christopher; Ebbesen, Sune D.; Mogensen, Mogens Renewable and Sustainable Energy Reviews, Vol. 15, Issue 1 https://doi.org/10.1016/j.rser.2010.07.014	journal	January 2011
Production of synthesis gas (H2 and CO) by high-temperature Co-electrolysis of H2O and CO2 Alenazey, Feraih; Alyousef, Yousef; Almisned, Omar International Journal of Hydrogen Energy, Vol. 40, Issue 32 https://doi.org/10.1016/j.ijhydene.2015.06.034	journal	August 2015
Nickel Impregnated Cerium-Doped Strontium Titanate Fuel Electrode: Direct Carbon Dioxide Electrolysis and Co-Electrolysis Cumming, Denis J.; Thompson, Alison R.; Rothman, Rachael H. Journal of The Electrochemical Society, Vol. 163, Issue 11 https://doi.org/10.1149/2.0081611jes	journal	January 2016
In-situ nano-alloying Pd-Ni for economical control of syngas production from high-temperature thermo-electrochemical reduction of steam/CO2 Kim, Si-Won; Park, Mansoo; Kim, Hyoungchul Applied Catalysis B: Environmental, Vol. 200 https://doi.org/10.1016/j.apcatb.2016.07.008	journal	January 2017
A nanostructured ceramic fuel electrode for efficient CO ₂ /H ₂ O electrolysis without safe gas Li, Yihang; Li, Pan; Hu, Bobing Journal of Materials Chemistry A, Vol. 4, Issue 23 https://doi.org/10.1039/C6TA02830F	journal	January 2016
Coke formation during high-temperature CO2 electrolysis over AFeO3 (A = La/Sr) cathode: Effect of A-site metal segregation Deka, Dhruba J.; Kim, Jaesung; Gunduz, Seval Applied Catalysis B: Environmental, Vol. 283 https://doi.org/10.1016/j.apcatb.2020.119642	journal	April 2021
Surface Chemistry of Perovskite-Type Electrodes During High Temperature CO ₂ Electrolysis Investigated by Operando Photoelectron Spectroscopy Opitz, Alexander K.; Nenning, Andreas; Rameshan, Christoph ACS Applied Materials & Interfaces, Vol. 9, Issue 41 https://doi.org/10.1021/acsami.7b10673	journal	October 2017
Highly Efficient CO ₂ Electrolysis on Cathodes with Exsolved Alkaline Earth Oxide Nanostructures Ye, Lingting; Pan, Changchang; Zhang, Minyi ACS Applied Materials & Interfaces, Vol. 9, Issue 30 https://doi.org/10.1021/acsami.7b07039	journal	July 2017
Future cost and performance of water electrolysis: An expert elicitation study Schmidt, O.; Gambhir, A.; Staffell, I. International Journal of Hydrogen Energy, Vol. 42, Issue 52 https://doi.org/10.1016/j.ijhydene.2017.10.045	journal	December 2017
Towards a smart energy network: The roles of fuel/electrolysis cells and technological perspectives Zhang, Xiongwen; Chan, Siew Hwa; Ho, Hiang Kwee International Journal of Hydrogen Energy, Vol. 40, Issue 21 https://doi.org/10.1016/j.ijhydene.2015.03.133	journal	June 2015
Recent advances in high temperature electrolysis using solid oxide fuel cells: A review Laguna-Bercero, M. A. Journal of Power Sources, Vol. 203 https://doi.org/10.1016/j.jpowsour.2011.12.019	journal	April 2012
Highly active oxide cathode of La(Sr)Fe(Mn)O3 for intermediate temperature CO2 and CO2-H2O co-electrolysis using LSGM electrolyte Ishihara, Tatsumi; Wang, Shijing; Wu, Kuan-Ting Solid State Ionics, Vol. 299 https://doi.org/10.1016/j.ssi.2016.09.013	journal	January 2017
Sulfur Tolerant LSCM-based Composite Cathode for High Temperature Electrolysis/Co-electrolysis of H ₂ O and CO ₂ Lim, C. K.; Liu, Q.; Zhou, J. Fuel Cells, Vol. 17, Issue 4 https://doi.org/10.1002/fuce.201600189	journal	May 2017
Dependence of Syngas Composition on Microstructure of La _0.8 Sr _0.2 Cr _0.5 Mn _0.5 O _3–δ Based Cathode for CO ₂ and H ₂ O Co-Electrolysis Maide, Martin; Lillmaa, Kadi; Nurk, Gunnar ECS Transactions, Vol. 78, Issue 1 https://doi.org/10.1149/07801.3275ecst	journal	May 2017
Co-electrolysis of steam and CO ₂ in full-ceramic symmetrical SOECs: a strategy for avoiding the use of hydrogen as a safe gas Torrell, M.; García-Rodríguez, S.; Morata, A. Faraday Discussions, Vol. 182 https://doi.org/10.1039/C5FD00018A	journal	January 2015
(La,Sr)(Cr,Mn)O3/GDC cathode for high temperature steam electrolysis and steam-carbon dioxide co-electrolysis Yue, Xiangling; Irvine, John T. S. Solid State Ionics, Vol. 225 https://doi.org/10.1016/j.ssi.2012.06.015	journal	October 2012
An emerging platform for electrocatalysis: perovskite exsolution Huang, Keke Science Bulletin, Vol. 61, Issue 23 https://doi.org/10.1007/s11434-016-1194-8	journal	December 2016
In Situ Observation of Nanoparticle Exsolution from Perovskite Oxides: From Atomic Scale Mechanistic Insight to Nanostructure Tailoring Neagu, Dragos; Kyriakou, Vasileios; Roiban, Ioan-Lucian ACS Nano, Vol. 13, Issue 11 https://doi.org/10.1021/acsnano.9b05652	journal	October 2019
In situ growth of nanoparticles through control of non-stoichiometry Neagu, Dragos; Tsekouras, George; Miller, David N. Nature Chemistry, Vol. 5, Issue 11 https://doi.org/10.1038/nchem.1773	journal	October 2013
A-site deficient perovskite: the parent for in situ exsolution of highly active, regenerable nano-particles as SOFC anodes Sun, Yifei; Li, Jianhui; Zeng, Yimin Journal of Materials Chemistry A, Vol. 3, Issue 20 https://doi.org/10.1039/C5TA01733E	journal	January 2015
Exsolved Nickel Nanoparticles Acting as Oxygen Storage Reservoirs and Active Sites for Redox CH 4 Conversion Otto, Svenja-K.; Kousi, Kalliopi; Neagu, Dragos ACS Applied Energy Materials, Vol. 2, Issue 10 https://doi.org/10.1021/acsaem.9b01267	journal	September 2019
Cation-swapped homogeneous nanoparticles in perovskite oxides for high power density Joo, Sangwook; Kwon, Ohhun; Kim, Kyeounghak Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08624-0	journal	February 2019
Growth Kinetics of Individual Co Particles Ex-solved on SrTi _0.75 Co _0.25 O _3-δ Polycrystalline Perovskite Thin Films Jo, Yong-Ryun; Koo, Bonjae; Seo, Min-Ji Journal of the American Chemical Society, Vol. 141, Issue 16 https://doi.org/10.1021/jacs.9b01882	journal	April 2019
Enhancing Perovskite Electrocatalysis of Solid Oxide Cells Through Controlled Exsolution of Nanoparticles Hua, Bin; Li, Meng; Sun, Yi-Fei ChemSusChem, Vol. 10, Issue 17 https://doi.org/10.1002/cssc.201700936	journal	August 2017
Perovskites: Replacement of Ca by Ni in a Perovskite Titanate to Yield a Novel Perovskite Exsolution Architecture for Oxygen‐Evolution Reactions (Adv. Energy Mater. 10/2020) Lee, Jin Goo; Myung, Jae‐Ha; Naden, Aaron B. Advanced Energy Materials, Vol. 10, Issue 10 https://doi.org/10.1002/aenm.202070044	journal	March 2020
Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution Neagu, Dragos; Oh, Tae-Sik; Miller, David N. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9120	journal	September 2015
Nanoscale and nano-structured electrodes of solid oxide fuel cells by infiltration: Advances and challenges Jiang, San Ping International Journal of Hydrogen Energy, Vol. 37, Issue 1 https://doi.org/10.1016/j.ijhydene.2011.09.067	journal	January 2012
Nanostructured Double Perovskite Cathode With Low Sintering Temperature For Intermediate Temperature Solid Oxide Fuel Cells Kim, Seona; Jun, Areum; Kwon, Ohhun ChemSusChem, Vol. 8, Issue 18 https://doi.org/10.1002/cssc.201500509	journal	July 2015
Switching on electrocatalytic activity in solid oxide cells Myung, Jae-ha; Neagu, Dragos; Miller, David N. Nature, Vol. 537, Issue 7621 https://doi.org/10.1038/nature19090	journal	August 2016
Co-electrolysis of H2O and CO2 on exsolved Ni nanoparticles for efficient syngas generation at controllable H2/CO ratios Kyriakou, V.; Neagu, D.; Papaioannou, E. I. Applied Catalysis B: Environmental, Vol. 258 https://doi.org/10.1016/j.apcatb.2019.117950	journal	December 2019
Ni-Substituted Sr(Ti,Fe)O3 SOFC Anodes: Achieving High Performance via Metal Alloy Nanoparticle Exsolution Zhu, Tenglong; Troiani, Horacio E.; Mogni, Liliana V. Joule, Vol. 2, Issue 3 https://doi.org/10.1016/j.joule.2018.02.006	journal	March 2018
CO2 dry reforming of CH4 with Sr and Ni co-doped LaCrO3 perovskite catalysts Wei, Tong; Jia, Lichao; Luo, Jing-Li Applied Surface Science, Vol. 506 https://doi.org/10.1016/j.apsusc.2019.144699	journal	March 2020
Evolution of Exsolved Nanoparticles on a Perovskite Oxide Surface during a Redox Process Lai, Ke-Yu; Manthiram, Arumugam Chemistry of Materials, Vol. 30, Issue 8 https://doi.org/10.1021/acs.chemmater.8b01029	journal	March 2018
Exsolved Fe–Ni nano-particles from Sr ₂ Fe _1.3 Ni _0.2 Mo _0.5 O ₆ perovskite oxide as a cathode for solid oxide steam electrolysis cells Wang, Y.; Liu, T.; Li, M. Journal of Materials Chemistry A, Vol. 4, Issue 37 https://doi.org/10.1039/C6TA06078A	journal	January 2016
Robust redox-reversible perovskite type steam electrolyser electrode decorated with in situ exsolved metallic nanoparticles Liu, Tong; Zhao, Yiqian; Zhang, Xiaoyu Journal of Materials Chemistry A, Vol. 8, Issue 2 https://doi.org/10.1039/C9TA06309A	journal	January 2020
Structural investigations of La _0.6 Sr _0.4 FeO _3−δ under reducing conditions: kinetic and thermodynamic limitations for phase transformations and iron exsolution phenomena Götsch, Thomas; Schlicker, Lukas; Bekheet, Maged F. RSC Advances, Vol. 8, Issue 6 https://doi.org/10.1039/C7RA12309D	journal	January 2018
Production of syngas with controllable H2/CO ratio by high temperature co-electrolysis of CO2 and H2O over Ni and Co- doped lanthanum strontium ferrite perovskite cathodes Deka, Dhruba J.; Gunduz, Seval; Fitzgerald, Taylor Applied Catalysis B: Environmental, Vol. 248 https://doi.org/10.1016/j.apcatb.2019.02.045	journal	July 2019
In situ preparation of a La _1.2 Sr _0.8 Mn _0.4 Fe _0.6 O ₄ Ruddlesden–Popper phase with exsolved Fe nanoparticles as an anode for SOFCs Chung, Yong Sik; Kim, Taewook; Shin, Tae Ho Journal of Materials Chemistry A, Vol. 5, Issue 14 https://doi.org/10.1039/C6TA09692A	journal	January 2017
An X-ray study of the trimetallic LaxSm1−xFeO3 orthoferrites Sangaletti, Luigi; Depero, Laura E.; Allieri, Brigida Journal of the European Ceramic Society, Vol. 21, Issue 6 https://doi.org/10.1016/S0955-2219(00)00267-3	journal	June 2001
The Scherrer equation versus the 'Debye-Scherrer equation' Holzwarth, Uwe; Gibson, Neil Nature Nanotechnology, Vol. 6, Issue 9 https://doi.org/10.1038/nnano.2011.145	journal	August 2011
Praseodymium and gadolinium doped ceria as a cathode material for low temperature solid oxide fuel cells Chockalingam, Rajalekshmi; Ganguli, Ashok Kumar; Basu, Suddhasatwa Journal of Power Sources, Vol. 250 https://doi.org/10.1016/j.jpowsour.2013.10.105	journal	March 2014
La/Sr-based perovskites as soot oxidation catalysts for Gasoline Particulate Filters Hernández, W. Y.; Tsampas, M. N.; Zhao, C. Catalysis Today, Vol. 258 https://doi.org/10.1016/j.cattod.2014.12.021	journal	December 2015
Catalytic effects in oxygen permeation through mixed-conductive LSCF perovskite membranes Teraoka, Y. Solid State Ionics, Vol. 152-153 https://doi.org/10.1016/S0167-2738(02)00409-5	journal	December 2002
Catalytic combustion of toluene over a Sr and Fe substituted LaCoO3 perovskite Li, Ning; Boréave, Antoinette; Deloume, Jean-Pierre Solid State Ionics, Vol. 179, Issue 27-32 https://doi.org/10.1016/j.ssi.2008.01.060	journal	September 2008
Methane and propane combustion over lanthanum transition-metal perovskites: role of oxygen mobility Alifanti, M.; Kirchnerova, J.; Delmon, B. Applied Catalysis A: General, Vol. 262, Issue 2 https://doi.org/10.1016/j.apcata.2003.11.024	journal	May 2004
The Effect of Fe in Perovskite Catalysts for Steam CO ₂ Reforming of Methane Yang, Eun-Hyeok; Noh, Young-Su; Lim, Sung Soo Journal of Nanoscience and Nanotechnology, Vol. 16, Issue 2 https://doi.org/10.1166/jnn.2016.12004	journal	February 2016
Investigation of hetero-phases grown via in-situ exsolution on a Ni-doped (La,Sr)FeO3 cathode and the resultant activity enhancement in CO2 reduction Deka, Dhruba J.; Kim, Jaesung; Gunduz, Seval Applied Catalysis B: Environmental, Vol. 286 https://doi.org/10.1016/j.apcatb.2021.119917	journal	June 2021
Ruddlesden-Popper phase A2BO4 oxides: Recent studies on structure, electrical, dielectric, and optical properties Nirala, Gurudeo; Yadav, Dharmendra; Upadhyay, Shail Journal of Advanced Ceramics, Vol. 9, Issue 2 https://doi.org/10.1007/s40145-020-0365-x	journal	March 2020
High-Performance Anode Material Sr ₂ FeMo _0.65 Ni _0.35 O _6−δ with In Situ Exsolved Nanoparticle Catalyst Du, Zhihong; Zhao, Hailei; Yi, Sha ACS Nano, Vol. 10, Issue 9 https://doi.org/10.1021/acsnano.6b03979	journal	August 2016
Thermal Stability of an in Situ Exsolved Metallic Nanoparticle Structured Perovskite Type Hydrogen Electrode for Solid Oxide Cells Zhang, Tianhang; Zhao, Yiqian; Zhang, Xiaoyu ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 21 https://doi.org/10.1021/acssuschemeng.9b04350	journal	September 2019
Reversible Segregation of Ni in LaFe _0.8 Ni _0.2 O _{3± δ} During Coke Removal Steiger, Patrick; Nachtegaal, Maarten; Kröcher, Oliver ChemCatChem, Vol. 10, Issue 19 https://doi.org/10.1002/cctc.201800603	journal	August 2018
Structural Reversibility and Nickel Particle stability in Lanthanum Iron Nickel Perovskite-Type Catalysts Steiger, Patrick; Delmelle, Renaud; Foppiano, Debora ChemSusChem, Vol. 10, Issue 11 https://doi.org/10.1002/cssc.201700358	journal	May 2017
Use of XPS in the determination of chemical environment and oxidation state of iron and sulfur samples: constitution of a data basis in binding energies for Fe and S reference compounds and applications to the evidence of surface species of an oxidized pyrite in a carbonate medium Descostes, M.; Mercier, F.; Thromat, N. Applied Surface Science, Vol. 165, Issue 4 https://doi.org/10.1016/S0169-4332(00)00443-8	journal	October 2000
Three-dimensionally ordered macroporous La0.6Sr0.4FeO3−δ: High-efficiency catalysts for the oxidative removal of toluene Zhao, Zhenxuan; Dai, Hongxing; Deng, Jiguang Microporous and Mesoporous Materials, Vol. 163 https://doi.org/10.1016/j.micromeso.2012.07.006	journal	November 2012
Effects of Oxygen Mobility in La–Fe-Based Perovskites on the Catalytic Activity and Selectivity of Methane Oxidation Chang, Hui; Bjørgum, Erlend; Mihai, Oana ACS Catalysis, Vol. 10, Issue 6 https://doi.org/10.1021/acscatal.9b05154	journal	January 2020
Ambient Pressure XPS Study of Mixed Conducting Perovskite-Type SOFC Cathode and Anode Materials under Well-Defined Electrochemical Polarization Nenning, Andreas; Opitz, Alexander K.; Rameshan, Christoph The Journal of Physical Chemistry C, Vol. 120, Issue 3 https://doi.org/10.1021/acs.jpcc.5b08596	journal	January 2016
Redox activity of surface oxygen anions in oxygen-deficient perovskite oxides during electrochemical reactions Mueller, David N.; Machala, Michael L.; Bluhm, Hendrik Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7097	journal	January 2015
An efficient and robust lanthanum strontium cobalt ferrite catalyst as a bifunctional oxygen electrode for reversible solid oxide cells Kim, Doyeub; Park, Jin Wan; Chae, Munseok S. Journal of Materials Chemistry A, Vol. 9, Issue 9 https://doi.org/10.1039/D0TA11233J	journal	January 2021
Manganese–lanthanum oxides modified with silver for the catalytic combustion of methane Machocki, Andrzej; Ioannides, Theophilos; Stasinska, Beata Journal of Catalysis, Vol. 227, Issue 2 https://doi.org/10.1016/j.jcat.2004.07.022	journal	October 2004
Surface properties and catalytic performance of La1−Sr CrO3 perovskite-type oxides for CO and C3H6 combustion Rida, K.; Benabbas, A.; Bouremmad, F. Catalysis Communications, Vol. 7, Issue 12 https://doi.org/10.1016/j.catcom.2006.04.011	journal	December 2006
Surface strontium enrichment on highly active perovskites for oxygen electrocatalysis in solid oxide fuel cells Crumlin, Ethan J.; Mutoro, Eva; Liu, Zhi Energy & Environmental Science, Vol. 5, Issue 3 https://doi.org/10.1039/c2ee03397f	journal	January 2012
Infrared spectrometric studies of the surface basicity of metal oxides and zeolites using adsorbed probe molecules Lavalley, J. C. Catalysis Today, Vol. 27, Issue 3-4 https://doi.org/10.1016/0920-5861(95)00161-1	journal	February 1996
CO2 and H2O Electrolysis Using Solid Oxide Electrolyzer Cell (SOEC) with La and Cl- doped Strontium Titanate Cathode Dogu, Doruk; Gunduz, Seval; Meyer, Katja E. Catalysis Letters, Vol. 149, Issue 7 https://doi.org/10.1007/s10562-019-02786-8	journal	April 2019
Enhancing CO2 electrolysis through synergistic control of non-stoichiometry and doping to tune cathode surface structures Ye, Lingting; Zhang, Minyi; Huang, Ping Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14785	journal	March 2017
Role of Adsorbed Water on Charge Carrier Dynamics in Photoexcited TiO ₂ Litke, Anton; Su, Yaqiong; Tranca, Ionut The Journal of Physical Chemistry C, Vol. 121, Issue 13 https://doi.org/10.1021/acs.jpcc.7b00472	journal	March 2017
Vibrational spectroscopy of water at the vapor/water interface Du, Q.; Superfine, R.; Freysz, E. Physical Review Letters, Vol. 70, Issue 15 https://doi.org/10.1103/PhysRevLett.70.2313	journal	April 1993
Infrared Studies of the Surface Hydroxyl Groups on Titanium Dioxide, and of the Chemisorption of Carbon Monoxide and Carbon Dioxide Yates, D. J. C. The Journal of Physical Chemistry, Vol. 65, Issue 5 https://doi.org/10.1021/j100823a011	journal	May 1961
Infiltrated mesoporous oxygen electrodes for high temperature co-electrolysis of H ₂ O and CO ₂ in solid oxide electrolysis cells Hernández, E.; Baiutti, F.; Morata, A. Journal of Materials Chemistry A, Vol. 6, Issue 20 https://doi.org/10.1039/C8TA01045E	journal	January 2018
Temperature-induced changes in the synthesis gas composition in a high-temperature H2O and CO2 co-electrolysis system Deka, Dhruba J.; Kim, Jaesung; Gunduz, Seval Applied Catalysis A: General, Vol. 602 https://doi.org/10.1016/j.apcata.2020.117697	journal	July 2020
High temperature solid oxide H2O/CO2 co-electrolysis for syngas production Wang, Yao; Liu, Tong; Lei, Libin Fuel Processing Technology, Vol. 161 https://doi.org/10.1016/j.fuproc.2016.08.009	journal	June 2017
Validation of the Crystallography Open Database using the Crystallographic Information Framework Vaitkus, Antanas; Merkys, Andrius; Gražulis, Saulius Journal of Applied Crystallography, Vol. 54, Issue 2 https://doi.org/10.1107/S1600576720016532	journal	February 2021
GSAS-II : the genesis of a modern open-source all purpose crystallography software package Toby, Brian H.; Von Dreele, Robert B. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813003531	journal	March 2013
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005

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