Nanoporous Iridium Nanosheets for Polymer Electrolyte Membrane Electrolysis

Chatterjee, Swarnendu; Peng, Xiong; Intikhab, Saad; Zeng, Guosong; Kariuki, Nancy N.; Myers, Deborah J.; Danilovic, Nemanja; Snyder, Joshua

doi:10.1002/aenm.202101438

Nanoporous Iridium Nanosheets for Polymer Electrolyte Membrane Electrolysis

Journal Article · 01 September 2021 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.202101438· OSTI ID:1846378

Chatterjee, Swarnendu; Peng, Xiong; Intikhab, Saad; Zeng, Guosong; Kariuki, Nancy N.; Myers, Deborah J.; Danilovic, Nemanja; Snyder, Joshua

The growth of the hydrogen economy is predicated on advancements in electrochemical energy technologies, with water electrolysis as a key component to the technological portfolio. Much of the focus on anode catalyst development for polymer electrolyte membrane water electrolyzers (PEMWE) is centered on activity as controlled by compositional and morphological impacts on reactant/intermediate/product adsorption. However, the effectiveness of this strategy is found to be limited upon integration of these materials into PEMWE membrane electrode assemblies (MEA). Regardless of catalyst activity, the combination of electrode inhomogeneity, ionomer integration, and high density of oxide-oxide interfaces yields significant performance losses associated with poor catalytic electrode conductivity. Here many of these limitations are addressed through the development of a unique catalyst morphology composed of nanoporous Ir nanosheets (npIr(x)-NS) that exhibit high catalytic activity for the anodic oxygen evolution reaction and superior electrode electronic conductivity in comparison to a commercial IrO2 nanoparticle catalyst. The utility of the npIr(x)-NS is demonstrated through incorporation into PEMWE MEAs where their performance exceeds that of commercial catalyst coated membranes at loadings as low as 0.06 mg(Ir) cm(-2) while exhibiting a negligible loss in performance following 50 000 accelerated stress test cycles.

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF) - Directorate for Mathematical and Physical Sciences Division of Materials Research (MPS-DMR); USDOE Office of Energy Efficiency and Renewable Energy (EERE) - Office of Fuel Cell Technologies (FCTO); USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1846378

Journal Information:: Advanced Energy Materials, Vol. 11, Issue 34

Country of Publication:: United States

Language:: English

References (51)

Hydrogen at Scale (H ₂ @Scale): Key to a Clean, Economic, and Sustainable Energy System Pivovar, Bryan; Rustagi, Neha; Satyapal, Sunita The Electrochemical Society Interface, Vol. 27, Issue 1 https://doi.org/10.1149/2.F04181if	journal	January 2018
Perspectives on Low-Temperature Electrolysis and Potential for Renewable Hydrogen at Scale Ayers, Katherine; Danilovic, Nemanja; Ouimet, Ryan Annual Review of Chemical and Biomolecular Engineering, Vol. 10, Issue 1 https://doi.org/10.1146/annurev-chembioeng-060718-030241	journal	June 2019
Pathway to Complete Energy Sector Decarbonization with Available Iridium Resources using Ultralow Loaded Water Electrolyzers Taie, Zachary; Peng, Xiong; Kulkarni, Devashish ACS Applied Materials & Interfaces, Vol. 12, Issue 47 https://doi.org/10.1021/acsami.0c15687	journal	November 2020
Activity–Stability Trends for the Oxygen Evolution Reaction on Monometallic Oxides in Acidic Environments Danilovic, Nemanja; Subbaraman, Ramachandran; Chang, Kee-Chul The Journal of Physical Chemistry Letters, Vol. 5, Issue 14 https://doi.org/10.1021/jz501061n	journal	July 2014
Degradation of iridium oxides via oxygen evolution from the lattice: correlating atomic scale structure with reaction mechanisms Kasian, Olga; Geiger, Simon; Li, Tong Energy & Environmental Science, Vol. 12, Issue 12 https://doi.org/10.1039/C9EE01872G	journal	January 2019
A highly active and stable IrO _x /SrIrO ₃ catalyst for the oxygen evolution reaction Seitz, Linsey C.; Dickens, Colin F.; Nishio, Kazunori Science, Vol. 353, Issue 6303 https://doi.org/10.1126/science.aaf5050	journal	September 2016
Iridium-based double perovskites for efficient water oxidation in acid media Diaz-Morales, Oscar; Raaijman, Stefan; Kortlever, Ruud Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12363	journal	August 2016
Balancing activity, stability and conductivity of nanoporous core-shell iridium/iridium oxide oxygen evolution catalysts Kim, Yong-Tae; Lopes, Pietro Papa; Park, Shin-Ae Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01734-7	journal	November 2017
Activity and Durability of Iridium Nanoparticles in the Oxygen Evolution Reaction Alia, Shaun M.; Rasimick, Brian; Ngo, Chilan Journal of The Electrochemical Society, Vol. 163, Issue 11 https://doi.org/10.1149/2.0151611jes	journal	January 2016
Measurement of the Protonic and Electronic Conductivities of PEM Water Electrolyzer Electrodes Mandal, Manas; Moore, Michael; Secanell, Marc ACS Applied Materials & Interfaces, Vol. 12, Issue 44 https://doi.org/10.1021/acsami.0c12111	journal	October 2020
Supported Oxygen Evolution Catalysts by Design: Toward Lower Precious Metal Loading and Improved Conductivity in Proton Exchange Membrane Water Electrolyzers Regmi, Yagya N.; Tzanetopoulos, Eden; Zeng, Guosong ACS Catalysis, Vol. 10, Issue 21 https://doi.org/10.1021/acscatal.0c03098	journal	October 2020
Efficient and Stable Low Iridium Loaded Anodes for PEM Water Electrolysis Made Possible by Nanofiber Interlayers Hegge, Friedemann; Lombeck, Florian; Cruz Ortiz, Edgar ACS Applied Energy Materials, Vol. 3, Issue 9 https://doi.org/10.1021/acsaem.0c00735	journal	August 2020
Iridium-Based Nanowires as Highly Active, Oxygen Evolution Reaction Electrocatalysts Alia, Shaun M.; Shulda, Sarah; Ngo, Chilan ACS Catalysis, Vol. 8, Issue 3 https://doi.org/10.1021/acscatal.7b03787	journal	January 2018
Hierarchically Structured Porous Transport Layers for Polymer Electrolyte Water Electrolysis Schuler, Tobias; Ciccone, Joseph M.; Krentscher, Bernd Advanced Energy Materials, Vol. 10, Issue 2 https://doi.org/10.1002/aenm.201903216	journal	November 2019
Polymer Electrolyte Water Electrolysis: Correlating Performance and Porous Transport Layer Structure: Part II. Electrochemical Performance Analysis Schuler, Tobias; Schmidt, Thomas J.; Büchi, Felix N. Journal of The Electrochemical Society, Vol. 166, Issue 10 https://doi.org/10.1149/2.1241908jes	journal	January 2019
Highly Active, Durable Dispersed Iridium Nanocatalysts for PEM Water Electrolyzers Zhao, Shuai; Stocks, Allison; Rasimick, Brian Journal of The Electrochemical Society, Vol. 165, Issue 2 https://doi.org/10.1149/2.0981802jes	journal	January 2018
Effect of Calcination Temperature on the Morphological and Electrochemical Characteristics of Supported Iridium Hydroxyoxide Electrocatalysts for the PEM Electrolyzer Anode Karimi, Fatemeh; Bazylak, Aimy; Peppley, Brant A. Journal of The Electrochemical Society, Vol. 164, Issue 4 https://doi.org/10.1149/2.0111706jes	journal	January 2017
3D nanoporous iridium-based alloy microwires for efficient oxygen evolution in acidic media Zhao, Yang; Luo, Min; Chu, Shufen Nano Energy, Vol. 59 https://doi.org/10.1016/j.nanoen.2019.02.020	journal	May 2019
Noble Metal-Free Nanoporous High-Entropy Alloys as Highly Efficient Electrocatalysts for Oxygen Evolution Reaction Qiu, Hua-Jun; Fang, Gang; Gao, Jiaojiao ACS Materials Letters, Vol. 1, Issue 5 https://doi.org/10.1021/acsmaterialslett.9b00414	journal	September 2019
Monolithic nanoporous Ni Fe alloy by dealloying laser processed Ni Fe Al as electrocatalyst toward oxygen evolution reaction Cui, Xiaodan; Zhang, Boliang; Zeng, Congyuan International Journal of Hydrogen Energy, Vol. 43, Issue 32 https://doi.org/10.1016/j.ijhydene.2018.06.109	journal	August 2018
Nanoporous multimetallic Ir alloys as efficient and stable electrocatalysts for acidic oxygen evolution reactions Chatterjee, Swarnendu; Intikhab, Saad; Profitt, Lauren Journal of Catalysis, Vol. 393 https://doi.org/10.1016/j.jcat.2020.11.038	journal	January 2021
Ductile-brittle transition in random porous Au Li, Rong; Sieradzki, K. Physical Review Letters, Vol. 68, Issue 8 https://doi.org/10.1103/PhysRevLett.68.1168	journal	February 1992
Microscopic failure behavior of nanoporous gold Biener, Juergen; Hodge, Andrea M.; Hamza, Alex V. Applied Physics Letters, Vol. 87, Issue 12 https://doi.org/10.1063/1.2051791	journal	September 2005
Ultra-small-angle X-ray scattering at the Advanced Photon Source Ilavsky, Jan; Jemian, Pete R.; Allen, Andrew J. Journal of Applied Crystallography, Vol. 42, Issue 3 https://doi.org/10.1107/S0021889809008802	journal	April 2009
Nika : software for two-dimensional data reduction Ilavsky, Jan Journal of Applied Crystallography, Vol. 45, Issue 2 https://doi.org/10.1107/S0021889812004037	journal	March 2012
Irena : tool suite for modeling and analysis of small-angle scattering Ilavsky, Jan; Jemian, Peter R. Journal of Applied Crystallography, Vol. 42, Issue 2 https://doi.org/10.1107/S0021889809002222	journal	February 2009
Characterization of 9Cr-1MoVNb steel by anomalous small-angle X-ray scattering Jemian, P. R.; Weertman, J. R.; Long, G. G. Acta Metallurgica et Materialia, Vol. 39, Issue 11 https://doi.org/10.1016/0956-7151(91)90062-6	journal	November 1991
Standard Electrode Potentials and Temperature Coefficients in Water at 298.15 K Bratsch, Steven G. Journal of Physical and Chemical Reference Data, Vol. 18, Issue 1 https://doi.org/10.1063/1.555839	journal	January 1989
Role of electron pathway in dimensionally increasing water splitting reaction sites in liquid electrolytes Yang, Gaoqiang; Yu, Shule; Li, Yifan Electrochimica Acta, Vol. 362 https://doi.org/10.1016/j.electacta.2020.137113	journal	December 2020
In situ investigation on ultrafast oxygen evolution reactions of water splitting in proton exchange membrane electrolyzer cells Mo, Jingke; Kang, Zhenye; Yang, Gaoqiang Journal of Materials Chemistry A, Vol. 5, Issue 35 https://doi.org/10.1039/C7TA05681H	journal	January 2017
An Atomistic Description of Dealloying Erlebacher, Jonah Journal of The Electrochemical Society, Vol. 151, Issue 10 https://doi.org/10.1149/1.1784820	journal	January 2004
Evolution of nanoporosity in dealloying Erlebacher, Jonah; Aziz, Michael J.; Karma, Alain Nature, Vol. 410, Issue 6827, p. 450-453 https://doi.org/10.1038/35068529	journal	March 2001
The Dealloying Critical Potential Sieradzki, K.; Dimitrov, N.; Movrin, D. Journal of The Electrochemical Society, Vol. 149, Issue 8 https://doi.org/10.1149/1.1492288	journal	January 2002
Atomic origins of the high catalytic activity of nanoporous gold Fujita, Takeshi; Guan, Pengfei; McKenna, Keith Nature Materials, Vol. 11, Issue 9 https://doi.org/10.1038/nmat3391	journal	August 2012
Using Surface Segregation To Design Stable Ru-Ir Oxides for the Oxygen Evolution Reaction in Acidic Environments Danilovic, Nemanja; Subbaraman, Ramachandran; Chang, Kee Chul Angewandte Chemie International Edition, Vol. 53, Issue 51 https://doi.org/10.1002/anie.201406455	journal	October 2014
Oxygen reduction in nanoporous metal–ionic liquid composite electrocatalysts Snyder, J.; Fujita, T.; Chen, M. W. Nature Materials, Vol. 9, Issue 11 https://doi.org/10.1038/nmat2878	journal	October 2010
Correlation between the Melting Point of a Nanosolid and the Cohesive Energy of a Surface Atom Sun, Chang Q.; Wang, Y.; Tay, B. K. The Journal of Physical Chemistry B, Vol. 106, Issue 41 https://doi.org/10.1021/jp025868l	journal	September 2002
The influence of chloride on the initial anodic dissolution of Cu3Au(111) Renner, F. U.; Stierle, A.; Dosch, H. Electrochemistry Communications, Vol. 9, Issue 7 https://doi.org/10.1016/j.elecom.2007.03.001	journal	July 2007
The influence of halides on the initial selective dissolution of Cu3Au (1 1 1) Ankah, Genesis N.; Pareek, Aparna; Cherevko, Serhiy Electrochimica Acta, Vol. 85 https://doi.org/10.1016/j.electacta.2012.08.059	journal	December 2012
Influence of anion species on electrochemical dealloying of single-phase Al2Au alloy in sodium halide solutions Zhang, Zhonghua; Zhang, Chi; Sun, Junzhe RSC Advances, Vol. 2, Issue 10 https://doi.org/10.1039/c2ra20087b	journal	January 2012
Stabilized Nanoporous Metals by Dealloying Ternary Alloy Precursors Snyder, Josh; Asanithi, Piyapong; Dalton, Alan B. Advanced Materials, Vol. 20, Issue 24, p. 4883-4886 https://doi.org/10.1002/adma.200702760	journal	December 2008
Dealloying Silver/Gold Alloys in Neutral Silver Nitrate Solution: Porosity Evolution, Surface Composition, and Surface Oxides Snyder, J.; Livi, K.; Erlebacher, J. Journal of The Electrochemical Society, Vol. 155, Issue 8, p. C464-C473 https://doi.org/10.1149/1.2940319	journal	January 2008
Hierarchical electrode design of highly efficient and stable unitized regenerative fuel cells (URFCs) for long-term energy storage Peng, Xiong; Taie, Zachary; Liu, Jiangjin Energy & Environmental Science, Vol. 13, Issue 12 https://doi.org/10.1039/D0EE03244A	journal	January 2020
On the Micro-, Meso-, and Macroporous Structures of Polymer Electrolyte Membrane Fuel Cell Catalyst Layers Soboleva, Tatyana; Zhao, Xinsheng; Malek, Kourosh ACS Applied Materials & Interfaces, Vol. 2, Issue 2 https://doi.org/10.1021/am900600y	journal	January 2010
Iridium Oxygen Evolution Activity and Durability Baselines in Rotating Disk Electrode Half-Cells Alia, Shaun M.; Anderson, Grace C. Journal of The Electrochemical Society, Vol. 166, Issue 4 https://doi.org/10.1149/2.0731904jes	journal	January 2019
A low temperature unitized regenerative fuel cell realizing 60% round trip efficiency and 10 000 cycles of durability for energy storage applications Regmi, Yagya N.; Peng, Xiong; Fornaciari, Julie C. Energy & Environmental Science, Vol. 13, Issue 7 https://doi.org/10.1039/C9EE03626A	journal	January 2020
Initial approaches in benchmarking and round robin testing for proton exchange membrane water electrolyzers Bender, G.; Carmo, M.; Smolinka, T. International Journal of Hydrogen Energy, Vol. 44, Issue 18 https://doi.org/10.1016/j.ijhydene.2019.02.074	journal	April 2019
Electrolyzer Durability at Low Catalyst Loading and with Dynamic Operation Alia, Shaun M.; Stariha, Sarah; Borup, Rod L. Journal of The Electrochemical Society, Vol. 166, Issue 15 https://doi.org/10.1149/2.0231915jes	journal	January 2019
Impact of Intermittent Operation on Lifetime and Performance of a PEM Water Electrolyzer Weiß, A.; Siebel, A.; Bernt, M. Journal of The Electrochemical Society, Vol. 166, Issue 8 https://doi.org/10.1149/2.0421908jes	journal	January 2019
Initiation and Inhibition of Dealloying of Single Crystalline Cu ₃ Au (111) Surfaces Pareek, Aparna; Borodin, Sergiy; Bashir, Asif Journal of the American Chemical Society, Vol. 133, Issue 45 https://doi.org/10.1021/ja2054644	journal	October 2011
IrO ₂ -Based Disperse-Phase Electrocatalysts: A Complementary Study by Means of the Cavity-Microelectrode and Ex-Situ X-ray Absorption Spectroscopy Minguzzi, Alessandro; Locatelli, Cristina; Cappelletti, Giuseppe The Journal of Physical Chemistry A, Vol. 116, Issue 25 https://doi.org/10.1021/jp212310v	journal	March 2012

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