Tosylamidation of cyclohexane by a cytochrome P-450 model
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January 1982 |
Nitrene transfer reactions mediated by metallo-porphyrin complexes
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January 2009 |
Selective functionalisation of saturated C–H bonds with metalloporphyrin catalysts
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January 2011 |
Transition Metal-Catalyzed C–H Amination: Scope, Mechanism, and Applications
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January 2017 |
Metalloporphyrin Catalyzed C–H Amination
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March 2019 |
Intramolecular C(sp3)–H amination
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January 2013 |
Manganese-Catalyzed C–H Activation
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May 2016 |
Intramolecular nitrene carbon-hydrogen insertions mediated by transition-metal complexes as nitrogen analogs of cytochrome P-450 reactions
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October 1983 |
The hydroxylation and amidation of equilenin acetate catalyzed by chloro[5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato]manganese(iii)
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January 2000 |
Amidation of Saturated C−H Bonds Catalyzed by Electron-Deficient Ruthenium and Manganese Porphyrins. A Highly Catalytic Nitrogen Atom Transfer Process
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June 2000 |
Metalloporphyrin-Mediated Asymmetric Nitrogen-Atom Transfer to Hydrocarbons: Aziridination of Alkenes and Amidation of Saturated C−H Bonds Catalyzed by Chiral Ruthenium and Manganese Porphyrins
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April 2002 |
Allylic amination of alkenes by tosyliminoiodobenzene: manganese porphyrins as suitable catalysts
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January 1988 |
Iron- and manganese-porphyrin catalysed aziridination of alkenes by tosyl- and acyl-iminoiodobenzene
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January 1984 |
Tetraalkylammonium N-chloro-p-toluenesulfonamide as aminating agent of olefins
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October 1997 |
Iron(III) Porphyrin Catalyzed Aziridination of Alkenes with Bromamine-T as Nitrene Source
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May 2004 |
Antagonistic metal-directed inductions in catalytic asymmetric aziridination by manganese and iron tetramethylchiroporphyrins
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January 1999 |
Manganese-catalysed benzylic C(sp3)–H amination for late-stage functionalization
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April 2018 |
A manganese catalyst for highly reactive yet chemoselective intramolecular C(sp3)–H amination
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October 2015 |
Mechanism and Chemoselectivity of Mn-Catalyzed Intramolecular Nitrene Transfer Reaction: C–H Amination vs. C=C Aziridination
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March 2020 |
DFT Mechanistic Account for the Site Selectivity of Electron-Rich C(sp 3 )–H Bond in the Manganese-Catalyzed Aminations
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January 2020 |
Mechanism Insight into the Csp 3 –H Amination Catalyzed by the Metal Phthalocyanine
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December 2018 |
Activation and transfer of nitrogen from a nitridomanganese(V) porphyrin complex. Aza analog of epoxidation
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April 1983 |
The Elusive Terminal Imido of Manganese(V)
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October 2002 |
An Isolable, Nonreducible High-Valent Manganese(V) Imido Corrolazine Complex
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October 2006 |
Generation and Reactivity of a One‐Electron‐Oxidized Manganese(V) Imido Complex with a Tetraamido Macrocyclic Ligand
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August 2019 |
Nitrogen atom activation: the influence of porphyrin ring structure on the kinetics of the reaction of trifluoroacetic anhydride with nitrido manganese(V) porphyrins
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September 1988 |
Laser Flash Photolysis Formation and Direct Kinetic Studies of Manganese(V)-Oxo Porphyrin Intermediates
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September 2003 |
Laser Flash Photolysis Generation and Kinetic Studies of Porphyrin−Manganese−Oxo Intermediates. Rate Constants for Oxidations Effected by Porphyrin−Mn V −Oxo Species and Apparent Disproportionation Equilibrium Constants for Porphyrin−Mn IV −Oxo Species
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May 2005 |
Laser flash photolysis production of metal-oxo derivatives and direct kinetic studies of their oxidation reactions
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September 2006 |
Laser Flash Photolysis Generation of High-Valent Transition Metal−Oxo Species: Insights from Kinetic Studies in Real Time
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March 2008 |
Photochemical reduction of nitrate and nitrite by manganese and iron porphyrins
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March 1991 |
Metalloporphyrin photochemistry with matrix isolation
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July 1991 |
Formation and kinetic studies of manganese(IV)-oxo porphyrins: Oxygen atom transfer mechanism of sulfide oxidations
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March 2020 |
Laser Flash Photolysis Generation and Kinetic Studies of Corrole-Manganese(v)-Oxo Intermediates
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September 2005 |
Visible light-induced formation of corrole-manganese(V)-oxo complexes: Observation of multiple oxidation pathways
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October 2016 |
Visible-light photolysis of corrole-manganese(IV) nitrites to generate corrole-manganese(V)-oxo complexes
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August 2017 |
Photochemical generation of manganese(IV)-oxo porphyrins by visible light photolysis of dimanganese(III) μ-oxo bis-porphyrins
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September 2016 |
Characterization of a Reactive Rh 2 Nitrenoid by Crystalline Matrix Isolation
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September 2019 |
In Crystallo Snapshots of Rh 2 -Catalyzed C–H Amination
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November 2020 |
Characterization of Porphyrin-Co(III)-‘Nitrene Radical’ Species Relevant in Catalytic Nitrene Transfer Reactions
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April 2015 |
Bis(sulfonylimide)ruthenium(VI) Porphyrins: X-ray Crystal Structure and Mechanism of CH Bond Amination by Density Functional Theory Calculations
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July 2013 |
[Fe(F20TPP)Cl] catalyzed intramolecular C–N bond formation for alkaloid synthesis using aryl azides as nitrogen source
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January 2010 |
Observation of a Photogenerated Rh 2 Nitrenoid Intermediate in C–H Amination
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July 2018 |
Crystal and molecular structure of chloramine-T trihydrate. Absence of a sodium-nitrogen interaction in the oxidant. N-chloro-N-sodiotoluene-p-sulfonamide
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October 1986 |
Nitrogen Radicals as Synthesis Intermediates. N-Halamide Rearrangements and Additions to Unsaturated Hydrocarbons
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January 1971 |
Remote C–H Functionalization via Selective Hydrogen Atom Transfer
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February 2018 |
Cyclization of N-Halogenated Amines (The Hofmann-Löffler Reaction).
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February 1963 |
Recent progress in the generation and use of nitrogen-centred radicals
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January 2008 |
Manganese porphyrin complexes
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January 1972 |
Synthesis and spectroscopic studies of manganese porphyrin-thiolate complexes
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January 1997 |
Generation and dissociation of oxygen- and chloride-bridged iron(III) and manganese(III) tetraphenylporphyrin dimer ions in the gas phase
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January 2009 |
High-Frequency and -Field Electron Paramagnetic Resonance of High-Spin Manganese(III) in Porphyrinic Complexes
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December 1999 |
High-frequency and -field electron paramagnetic resonance of high-spin manganese(III) in tetrapyrrole complexes
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April 2002 |
Manganese tetraphenylporphyrin bromide and iodide. Studies of structures and magnetic properties
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July 2020 |
High-field (high-frequency) EPR spectroscopy and structural characterization of a novel manganese(iii) corrole
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January 2000 |
Synthesis, Characterization, and Physicochemical Properties of Manganese(III) and Manganese(V)−Oxo Corrolazines
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June 2005 |
Advanced Paramagnetic Resonance Studies on Manganese and Iron Corroles with a Formal d 4 Electron Count
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January 2020 |
High-Frequency and Field EPR Investigation of (8,12-Diethyl-2,3,7,13,17,18-hexamethylcorrolato)manganese(III)
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August 2001 |
Is the Axial Zero-Field Splitting Parameter of Tetragonally Elongated High-Spin Manganese(III) Complexes Always Negative?
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July 2002 |
Bond Dissociation Energies of Organic Molecules
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April 2003 |
Handbook of Bond Dissociation Energies in Organic Compounds
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December 2002 |
Photoirradiated and .gamma.-ray-irradiated reactions of manganese(III, IV, V) tetraphenylporphyrins in 2-methyltetrahydrofuran. Reactions of azidomanganese(III) porphyrin
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April 1987 |
Constrained complexes of manganese(II) tetraphenylporphyrin in rigid solution
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April 1982 |
Origin of the Zero-Field Splitting in Mononuclear Octahedral Dihalide Mn II Complexes: An Investigation by Multifrequency High-Field Electron Paramagnetic Resonance and Density Functional Theory
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June 2007 |
Synthesis, characterization, and ground electronic state of the unstable monomeric manganese(IV) porphyrin complexes diazido- and bis(isocyanato)(5,10,15,20-tetraphenylporphinato)manganese(IV). Crystal and molecular structure of the bis(isocyanato) complex
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December 1983 |
The E.P.R. of Ground State Triplet Nitrenes
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August 1962 |
Spectroscopy and Kinetics of Triplet 4-Methylbenzenesulfonylnitrene
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January 1996 |
Photochemical formation of oxochromium(IV) tetraphenylporphyrin from nitritochromium(III) tetraphenylporphyrin in benzene
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March 1992 |
Laser Flash Photolysis Studies of Nitritomanganese(III) Tetraphenylporphyrin. Reactions of O 2 , NO, and Pyridine with Manganese(II) Tetraphenylporphyrin
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April 1998 |
Complexes with Nitrogen-Centered Radical Ligands: Classification, Spectroscopic Features, Reactivity, and Catalytic Applications
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November 2013 |
Komplexe mit Stickstoffradikalliganden: Einteilung, spektroskopische Eigenschaften, Reaktivität und katalytische Anwendungen
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November 2013 |
Principles of structure, bonding, and reactivity for metal nitrosyl complexes
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September 1974 |
Hydrogen abstraction from amines: formation of aminyl vs. .alpha.-aminoalkyl radicals
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April 1983 |
Visible-Light-Mediated Synthesis of Amidyl Radicals: Transition-Metal-Free Hydroamination and N -Arylation Reactions
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June 2016 |
Photochemical Generation of Nitrogen-Centered Amidyl, Hydrazonyl, and Imidyl Radicals: Methodology Developments and Catalytic Applications
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July 2017 |
An Iodine-Catalyzed Hofmann-Löffler Reaction
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May 2015 |
Eine Iod-katalysierte Hofmann-Löffler-Reaktion
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May 2015 |
Efficient C–H Amination Catalysis Using Nickel-Dipyrrin Complexes
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May 2020 |
Catalytic C–H Amination Mediated by Dipyrrin Cobalt Imidos
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April 2019 |
High-Spin Iron Imido Complexes Competent for C–H Bond Amination
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August 2017 |
Catalytic C−H Bond Amination from High-Spin Iron Imido Complexes
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April 2011 |
Aziridination of Alkenes and Amidation of Alkanes by Bis(tosylimido)ruthenium(VI) Porphyrins. A Mechanistic Study
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October 1999 |
Copper-Nitrene Complexes in Catalytic CH Amination
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December 2008 |
Copper-Nitrene Complexes in Catalytic CH Amination
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December 2008 |
Inter- and Intramolecular Experimental and Calculated Equilibrium Isotope Effects for (silox) 2 ( t Bu 3 SiND)TiR + RH (silox = t Bu 3 SiO): Inferred Kinetic Isotope Effects for RH/D Addition to Transient (silox) 2 TiNSi t Bu 3
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August 2000 |
Large Isotope Effects in Organometallic Chemistry
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September 2021 |
Oxomanganese(IV) porphyrins identified by resonance Raman and infrared spectroscopy. Weak bonds and the stability of the half-filled t2g subshell
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June 1988 |
Structural characterization of a complex of Manganese(V) nitrido[tetrakis(p-methoxyphenyl)porphinato] manganese(V)
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December 1982 |
Characterization of a Dinuclear MnVO Complex and Its Efficient Evolution of O2 in the Presence of Water
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January 2004 |
Characterization of a Dinuclear MnVO Complex and Its Efficient Evolution of O2 in the Presence of Water
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January 2004 |