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Electron-Rich Ruthenium Single-Atom Alloy for Aqueous Levulinic Acid Hydrogenation

Journal Article · · ACS Catal.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
DOE - Office Of Science; FOREIGN
OSTI ID:
1831263
Journal Information:
ACS Catal., Vol. 11, Issue (19)
Country of Publication:
United States
Language:
ENGLISH

References (98)

Bimetallic catalysts for upgrading of biomass to fuels and chemicals journal January 2012
Catalytic Conversion of Carbohydrates to Initial Platform Chemicals: Chemistry and Sustainability journal November 2017
Production of Liquid Alkanes by Aqueous-Phase Processing of Biomass-Derived Carbohydrates journal June 2005
Cu–ZrO2 nanocomposite catalyst for selective hydrogenation of levulinic acid and its ester to γ-valerolactone journal January 2012
Role of water in metal catalyst performance for ketone hydrogenation: a joint experimental and theoretical study on levulinic acid conversion into gamma-valerolactone journal January 2014
High-yield production of levulinic acid from cellulose and its upgrading to γ-valerolactone journal January 2014
Transformations of biomass-derived platform molecules: from high added-value chemicals to fuels via aqueous-phase processing journal January 2011
Gamma-valerolactone, a sustainable platform molecule derived from lignocellulosic biomass journal January 2013
A sustainable process for the production of γ-valerolactone by hydrogenation of biomass-derived levulinic acid journal January 2012
Theoretical Investigation of the Hydrodeoxygenation of Levulinic Acid to γ-Valerolactone over Ru(0001) journal December 2016
Recent Advances in Ruthenium-Catalyzed Hydrogenation Reactions of Renewable Biomass-Derived Levulinic Acid in Aqueous Media journal April 2020
Why Is Ruthenium an Efficient Catalyst for the Aqueous-Phase Hydrogenation of Biosourced Carbonyl Compounds? journal June 2015
Improved catalytic activity and stability for hydrogenation of levulinic acid by Ru/N-doped hierarchically porous carbon journal April 2018
Double-active sites cooperatively catalyzed transfer hydrogenation of ethyl levulinate over a ruthenium-based catalyst journal December 2017
Electron-Rich Ruthenium on Nitrogen-Doped Carbons Promoting Levulinic Acid Hydrogenation to γ-Valerolactone: Effect of Metal–Support Interaction journal September 2019
Graphene-Modified Ru Nanocatalyst for Low-Temperature Hydrogenation of Carbonyl Groups journal November 2015
Enhanced adsorption properties of bimetallic RuCo catalyst for the hydrodeoxygenation of phenolic compounds and raw lignin-oil journal December 2020
Complete Aqueous Hydrogenation of 5-Hydroxymethylfurfural at Room Temperature over Bimetallic RuPd/Graphene Catalyst journal May 2019
Site-Dependent Activity and Selectivity of H 2 O 2 Formation from H 2 and O 2 over Au-Based Catalysts journal June 2019
Alkali ions secure hydrides for catalytic hydrogenation journal July 2020
Pt Single Atoms Embedded in the Surface of Ni Nanocrystals as Highly Active Catalysts for Selective Hydrogenation of Nitro Compounds journal May 2018
CO 2 Hydrogenation to Formate Catalyzed by Ru Coordinated with a N,P-Containing Polymer journal July 2020
Ru 1 Co n Single-Atom Alloy for Enhancing Fischer–Tropsch Synthesis journal January 2021
Defect Chemistry in Heterogeneous Catalysis: Recognition, Understanding, and Utilization journal September 2020
Activating and optimizing MoS2 basal planes for hydrogen evolution through the formation of strained sulphur vacancies journal November 2015
Ag Alloyed Pd Single-Atom Catalysts for Efficient Selective Hydrogenation of Acetylene to Ethylene in Excess Ethylene journal May 2015
Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles journal April 2018
Theoretical Understandings of Graphene-based Metal Single-Atom Catalysts: Stability and Catalytic Performance journal October 2020
Single‐Atom Catalysts: A Sustainable Pathway for the Advanced Catalytic Applications journal February 2021
Single‐Atom Catalysts journal April 2021
Notched-Polyoxometalate Strategy to Fabricate Atomically Dispersed Ru Catalysts for Biomass Conversion journal February 2021
Carbon-Based Single-Atom Catalysts for Advanced Applications journal January 2020
Carbon Nitride‐Based Ruthenium Single Atom Photocatalyst for CO 2 Reduction to Methanol journal March 2021
Single-Atomic Ruthenium Catalytic Sites on Nitrogen-Doped Graphene for Oxygen Reduction Reaction in Acidic Medium journal June 2017
Dynamic oxygen adsorption on single-atomic Ruthenium catalyst with high performance for acidic oxygen evolution reaction journal October 2019
Engineering the electronic structure of single atom Ru sites via compressive strain boosts acidic water oxidation electrocatalysis journal March 2019
Accelerating water dissociation kinetics by isolating cobalt atoms into ruthenium lattice journal November 2018
Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts journal April 2010
Nitrogen Fixation by Ru Single-Atom Electrocatalytic Reduction journal January 2019
Single-Atom Catalysts across the Periodic Table journal October 2020
Catalysis to discriminate single atoms from subnanometric ruthenium particles in ultra-high loading catalysts journal January 2020
Tackling CO Poisoning with Single-Atom Alloy Catalysts journal May 2016
Ruthenium‐Based Single‐Atom Alloy with High Electrocatalytic Activity for Hydrogen Evolution journal April 2019
H 2 Activation and Spillover on Catalytically Relevant Pt–Cu Single Atom Alloys journal August 2015
Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limit journal October 2015
RuCo NPs supported on MIL-96(Al) as highly active catalysts for the hydrolysis of ammonia borane journal February 2017
Ab initio molecular dynamics for open-shell transition metals journal November 1993
Projector augmented-wave method journal December 1994
Generalized Gradient Approximation Made Simple journal October 1996
Force reversed method for locating transition states journal February 2012
Enhancement of Antibacterial Activity of Capped Silver Nanoparticles in Combination with Antibiotics, on Model Gram-Negative and Gram-Positive Bacteria journal January 2013
Transient Bimodal Particle Size Distributions during Pt Sintering on Alumina and Silica journal January 2015
Cobalt nanoparticles encapsulated in porous nitrogen-doped carbon: Oxygen activation and efficient catalytic removal of formaldehyde at room temperature journal December 2019
Atomically Dispersed Ru Catalyst for Low-Temperature Nitrogen Activation to Ammonia via an Associative Mechanism journal July 2020
Deciphering the Nature of Ru Sites in Reductively Exsolved Oxides with Electronic and Geometric Metal–Support Interactions journal November 2020
Dandelion-like cobalt oxide microsphere-supported RuCo bimetallic catalyst for highly efficient hydrogenolysis of 5-hydroxymethylfurfural journal December 2018
Single cobalt sites in mesoporous N-doped carbon matrix for selective catalytic hydrogenation of nitroarenes journal January 2018
Integrating MXene nanosheets with cobalt-tipped carbon nanotubes for an efficient oxygen reduction reaction journal January 2019
Implanting Isolated Ru Atoms into Edge‐Rich Carbon Matrix for Efficient Electrocatalytic Hydrogen Evolution journal May 2020
Achieving a Record-High Yield Rate of 120.9 μgNH3  mgcat.−1  h−1 for N 2 Electrochemical Reduction over Ru Single-Atom Catalysts journal August 2018
Exploring the ruthenium catalysed synthesis of γ-valerolactone in alcohols and utilisation of mild solvent-free reaction conditions journal January 2012
An Efficient and Reusable Embedded Ru Catalyst for the Hydrogenolysis of Levulinic Acid to γ-Valerolactone journal March 2017
Ru nanoparticles deposited on ultrathin TiO2 nanosheets as highly active catalyst for levulinic acid hydrogenation to γ-valerolactone journal December 2019
Ru/CeO2 catalyst with optimized CeO2 morphology and surface facet for efficient hydrogenation of ethyl levulinate to γ-valerolactone journal September 2020
New route toward building active ruthenium nanoparticles on ordered mesoporous carbons with extremely high stability journal April 2014
Hydrogenation of levulinic acid to γ-valerolactone over bifunctional Ru/(AlO)(ZrO) catalyst: Effective control of Lewis acidity and surface synergy journal September 2020
Hydrogenation of Levulinic Acid to γ-Valerolactone in Water Using Millimeter Sized Supported Ru Catalysts in a Packed Bed Reactor journal May 2016
Alkali promotion of alumina-supported ruthenium catalysts for hydrogenation of levulinic acid to γ-valerolactone journal March 2017
Rational nanoparticle synthesis to determine the effects of size, support, and K dopant on Ru activity for levulinic acid hydrogenation to γ-valerolactone journal June 2015
Facile Fabrication of Composition-Tuned Ru–Ni Bimetallics in Ordered Mesoporous Carbon for Levulinic Acid Hydrogenation journal April 2014
Acid-Functionalized Mesoporous Carbon: An Efficient Support for Ruthenium-Catalyzed γ-Valerolactone Production journal June 2015
Novel aqueous-phase hydrogenation reaction of the key biorefinery platform chemical levulinic acid into γ-valerolactone employing highly active, selective and stable water-soluble ruthenium catalysts modified with nitrogen-containing ligands journal December 2018
ZrO 2 Is Preferred over TiO 2 as Support for the Ru-Catalyzed Hydrogenation of Levulinic Acid to γ-Valerolactone journal July 2016
Highly Selective Hydrogenation of Levulinic Acid to γ-Valerolactone Over Ru/ZrO2 Catalysts journal May 2017
Hydrogenation of biomass-derived levulinic acid to γ-valerolactone catalyzed by mesoporous supported dendrimer-derived Ru and Pt catalysts: An alternative method for the production of renewable biofuels journal January 2018
Hydrogenation of levulinic acid to γ-valerolactone using ruthenium nanoparticles journal March 2013
RuSn bimetallic catalysts for selective hydrogenation of levulinic acid to γ-valerolactone journal May 2012
Novel synthesis of Ru/OMS catalyst by solvent-free method: Selective hydrogenation of levulinic acid to γ-valerolactone in aqueous medium and kinetic modelling journal February 2018
UiO-66 derived Ru/ZrO 2 @C as a highly stable catalyst for hydrogenation of levulinic acid to γ-valerolactone journal January 2017
Magnetic Co/Al2O3 catalyst derived from hydrotalcite for hydrogenation of levulinic acid to γ-valerolactone journal September 2015
An investigation on the influence of support type for Ni catalysed vapour phase hydrogenation of aqueous levulinic acid to γ-valerolactone journal January 2016
Heterostructured Ni/NiO composite as a robust catalyst for the hydrogenation of levulinic acid to γ-valerolactone journal November 2017
Identification of the catalytically active component of Cu–Zr–O catalyst for the hydrogenation of levulinic acid to γ-valerolactone journal January 2017
Hydrogenation of levulinic acid to γ-valerolactone by Ni and MoO x co-loaded carbon catalysts journal January 2014
Highly efficient conversion of biomass-derived levulinic acid into γ-valerolactone over Ni/MgO catalyst journal January 2015
Co encapsulated N-doped carbon nanotubes as robust catalyst for valorization of levulinic acid in aqueous media journal January 2021
Promotion effects of PrPO 4 for the hydrogenation transformation of biomass-derived compounds over Pr–Ni–P composites journal January 2021
Highly active and stable Co nanoparticles embedded in nitrogen-doped mesoporous carbon nanofibers for aqueous-phase levulinic acid hydrogenation journal August 2021
In situ -generated Co embedded in N-doped carbon hybrids as robust catalysts for the upgrading of levulinic acid in aqueous phase journal January 2020
Ultra-selective desulfurization of 4, 6-dimethyldibenzothiophene via carbon-sulfur bond cleavage with the bimetal single atom on N-rGO journal November 2020
Significant Promotion of Surface Oxygen Vacancies on Bimetallic CoNi Nanocatalysts for Hydrodeoxygenation of Biomass-derived Vanillin to Produce Methylcyclohexanol journal March 2020
Enhanced activity of Ru-Ir nanoparticles over SiC for hydrogenation of levulinic acid at room-temperature journal March 2021
Lean NO x reduction by CO at low temperature over bimetallic IrRu/Al 2 O 3 catalysts with different Ir : Ru ratios journal January 2020
Trimetallic Cu–Ni–Zn/H-ZSM-5 Catalyst for the One-Pot Conversion of Levulinic Acid to High-Yield 1,4-Pentanediol under Mild Conditions in an Aqueous Medium journal February 2021
Hydrogenation and hydrodeoxygenation of aromatic lignin monomers over Cu/C, Ni/C, Pd/C, Pt/C, Rh/C and Ru/C catalysts: Mechanisms, reaction micro-kinetic modelling and quantitative structure-activity relationships journal March 2019
Ru–Ni/Al 2 O 3 bimetallic catalysts with high catalytic activity for N -propylcarbazole hydrogenation journal January 2020
Analysis of Kinetics and Reaction Pathways in the Aqueous-Phase Hydrogenation of Levulinic Acid To Form γ-Valerolactone over Ru/C journal March 2014
MoO x -Decorated Co-Based Catalysts toward the Hydrodeoxygenation Reaction of Biomass-Derived Platform Molecules journal July 2021