Enhanced delivery of engineered Fe-Mn binary oxides in heterogeneous porous media for efficient arsenic stabilization

Yan, Xiulan; Fei, Yang; Yang, Xiao; Liang, Tao; Zhong, Lirong

doi:10.1016/j.jhazmat.2021.127371

Title: Enhanced delivery of engineered Fe-Mn binary oxides in heterogeneous porous media for efficient arsenic stabilization

Journal Article · 15 February 2022 · Journal of Hazardous Materials

DOI:https://doi.org/10.1016/j.jhazmat.2021.127371· OSTI ID:1829443

Yan, Xiulan ^[1]; Fei, Yang ^[2]; Yang, Xiao ^[2]; Liang, Tao ^[2]; Zhong, Lirong ^[3]

Institute of Geographic Sciences and Natural Resources Research, Chinese Academy of Science
Chinese Academy of Sciences
BATTELLE (PACIFIC NW LAB)

Heterogeneity in sediment and aquifer is universal, resulting in preferential flows of injected materials in the high permeability regions and forming flow by-passed zones in the low permeability regions during in-situ subsurface remediation. This adverse effect can considerably delay the completion of remedial operations and significantly increase the cost. Column experiments were designed and conducted to study the transport of starch- and starch-xanthan gum modified Fe-Mn binary oxide particles (SFM and SXFM) in saturated heterogeneous porous media and to reveal the particles’ arsenic (As) stabilization performance. Fine-in-Coarse (FIC) and Coarse-in-Fine (CIF) patterns of heterogeneous packings were set up in the columns. Testing results demonstrated that starch-xanthan gum dual treatment on Fe-Mn binary oxides successfully improved the particles’ migration capability in heterogeneous porous media and their distribution uniformity attributed to the profound shear thinning behavior of xanthan gum solution. The addition of xanthan gum to the system increased the viscosity and shear thinning property of SXFM suspension, making it a better candidate for delivery. Both SFM and SXFM stabilized As in heterogeneously packed sediment collected from a contaminated site, with SXFM showing better stabilization performance than SFM. The stabilization effects of SXFM were 90.7-97.0%, compared to 82.0-95.2% of SFM.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1829443

Report Number(s):: PNNL-SA-163806

Journal Information:: Journal of Hazardous Materials, Vol. 424, Issue Part A

Country of Publication:: United States

Language:: English

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