Recent advances in structural chemistry of Group 14 Zintl ions
|
|
March 2019 |
Zintl-Ionen, Käfigverbindungen und intermetalloide Cluster der Elemente der 14. und 15. Gruppe
|
|
March 2011 |
Zintl Ions, Cage Compounds, and Intermetalloid Clusters of Group 14 and Group 15 Elements
|
|
March 2011 |
Chemistry of Deltahedral Zintl Ions
|
|
November 2006 |
Intermetalloid and Heterometallic Clusters Combining p-Block (Semi)Metals with d- or f-Block Metals
|
|
May 2019 |
Interpenetrating As20 Fullerene and Ni12 Icosahedra in the Onion-Skin [As@Ni12@As20]3- Ion
|
|
May 2003 |
[(Ni-Ni-Ni)@(Ge9)2]4−: A Linear Triatomic Nickel Filament Enclosed in a Dimer of Nine-Atom Germanium Clusters
|
|
June 2005 |
[(Ni-Ni-Ni)@(Ge9)2]4−: A Linear Triatomic Nickel Filament Enclosed in a Dimer of Nine-Atom Germanium Clusters
|
|
June 2005 |
Symmetry Reduction upon Size Mismatch: The Non-Icosahedral Intermetalloid Cluster [Co@Ge 12 ] 3−: Symmetry Reduction upon Size Mismatch: The Non-Icosahedral Intermetalloid Cluster [Co@Ge 12 ] 3−
|
|
October 2018 |
[Co 2 @Ge 16 ] 4− : Localized versus Delocalized Bonding in Two Isomeric Intermetalloid Clusters
|
|
December 2017 |
Structure and bonding in a bimetallic endohedral cage, [Co 2 @Ge 16 ] z−
|
|
September 2015 |
[(Pd−Pd)@Ge 18 ] 4- : A Palladium Dimer Inside the Largest Single-Cage Deltahedron
|
|
June 2005 |
[Au3Ge18]5−—A Gold–Germanium Cluster with Remarkable Au–Au Interactions
|
|
February 2007 |
[Au3Ge18]5− – ein Gold-Germanium-Cluster mit bemerkenswerten Au-Au-Wechselwirkungen
|
|
February 2007 |
[Au3Ge45]9− – ein binäres Cluster-Anion mit einer {Ge45}-Einheit
|
|
July 2007 |
[Au3Ge45]9−—A Binary Anion Containing a {Ge45} Cluster
|
|
July 2007 |
Synthesis and Isolation of [Fe@Ge 10 ] 3− : A Pentagonal Prismatic Zintl Ion Cage Encapsulating an Interstitial Iron Atom
|
|
March 2009 |
[Co@Ge 10 ] 3− : An Intermetalloid Cluster with Archimedean Pentagonal Prismatic Structure
|
|
March 2009 |
[Co@Ge 10 ] 3− : An Intermetalloid Cluster with Archimedean Pentagonal Prismatic Structure
|
|
March 2009 |
Synthesis and Characterization of [Ru@Ge 12 ] 3– : An Endohedral 3-Connected Cluster
|
|
January 2014 |
Oxidative Coupling of Deltahedral [Ge 9 ] 4 - Zintl Ions
|
|
September 1999 |
“n-Doping” of Deltahedral Zintl Ions
|
|
May 2011 |
Low Dimensional Arrangements of the Zintl Ion [Ge9-Ge9]6— and Chemical Bonding in [Ge6]2—, [Ge9-Ge9]6—, and∞1{[Ge9]}2—
|
|
January 2003 |
First Synthesis of Group-14 Polyanions by Extraction of a Binary Alloy with dmf and a Novel Conformation of the (Ge9−Ge9)6− Dimer: Crystal Structures of [K6(Ge9−Ge9)](dmf)12, [Rb6(Ge9−Ge9)](dmf)12 and [K2.5Cs3.5(Ge9−Ge9)](dmf)12.
|
|
August 2006 |
An Unprecedented1∞[Ge9]2− Polymer: A Link between Molecular Zintl Clusters and Solid-State Phases
|
|
January 2000 |
An Unprecedented1∞[Ge9]2− Polymer: A Link between Molecular Zintl Clusters and Solid-State Phases
|
|
January 2000 |
The Controlled Oxidative Coupling of Ge94? Zintl Anions to a Linear Trimer [Ge9=Ge9=Ge9]6?
|
|
May 2005 |
[Ge9Ge9Ge9Ge9]8-: A Linear Tetramer of Nine-Atom Germanium Clusters, a Nanorod
|
|
August 2003 |
On the Oxidation of [Ge 9 ] 4− – Crystal Structures and Raman Spectroscopic Investigation of Linked Ge 9 Clusters
|
|
January 2021 |
Retention of the Zn−Zn bond in [Ge 9 Zn−ZnGe 9 ] 6− and Formation of [(Ge 9 Zn)−(Ge 9 )−(ZnGe 9 )] 8− and Polymeric 1∞ [−(Ge 9 Zn) 2− −]1
|
|
January 2017 |
Retention of the Zn−Zn bond in [Ge 9 Zn−ZnGe 9 ] 6− and Formation of [(Ge 9 Zn)−(Ge 9 )−(ZnGe 9 )] 8− and Polymeric 1∞ [−(Ge 9 Zn) 2− −]1
|
|
January 2017 |
On the Nature of Bridging Metal Atoms in Intermetalloid Clusters: Synthesis and Structure of the Metal-Atom-Bridged Zintl Clusters [Sn(Ge 9 ) 2 ] 4− and [Zn(Ge 9 ) 2 )] 6−
|
|
August 2016 |
${{\hfill\ 1\atop \hfill \infty }}$[HgGe 9 ] 2��� ��� Ein durch Heteroatome kovalent verkn��pftes Polymer mit Zintl-Ionen als Bausteinen
|
|
September 2002 |
${{\hfill\ 1\atop \hfill \infty }}$[HgGe 9 ] 2��� ���A Polymer with Zintl Ions as Building Blocks Covalently Linked by Heteroatoms
|
|
September 2002 |
Synthesis and Crystal Structure of [K([2.2]crypt)]2[HgGe9](dmf)
|
|
October 2007 |
[Hg3(Ge9)4]10−: a nanometric molecular rod precursor to polymeric mercury-linked cluster chains
|
|
January 2008 |
[Ge8(Mo(CO)3)2]4−: an unprecedented 20-electron empty ten-vertex Zintl cluster
|
|
January 2014 |
The Elusive closo -Ge 10 2− Zintl Ion: Finally “Captured” as a Ligand in the Complex [Ge 10 Mn(CO) 4 ] 3−
|
|
July 2010 |
Synthesis and characterization of pristine closo-[Ge 10 ] 2−
|
|
January 2016 |
Studies on the Reactivity of [Ge9]4− towards [Fe(cot)(CO)3]: Synthesis and Characterization of [Ge8Fe(CO)3]3− and of the Anionic Organometallic Species [Fe(cot)(CO)3]−
|
|
August 2010 |
{Ge 9 [Si(SiMe 3 ) 3 ] 2 } 2− : a starting point for mixed substituted metalloid germanium clusters
|
|
January 2016 |
Rational Synthesis of [Ge 9 {Si(SiMe 3 ) 3 } 3 ] − from Its Parent Zintl Ion Ge 9 4–
|
|
January 2012 |
[Ge 9 {M(CO) 5 } 3 ] 4− : electrophilic addition of M(CO) 5 and [E 9 ] 4− Zintl anions (M = Cr, Mo, W)
|
|
January 2017 |
Syntheses, Crystal Structures, and Density Functional Theory Calculations of the c loso -[1-M(CO) 3 (η 4 -E 9 )] 4 - (E = Sn, Pb; M = Mo, W) Cluster Anions and Solution NMR Spectroscopic Characterization of [1-M(CO) 3 (η 4 -Sn 9 )] 4 - (M = Cr, Mo, W) †
|
|
January 2002 |
Thecloso-[Sn9M(CO)3]4− Zintl Ion Clusters where M=Cr, Mo, W: Two Structural Isomers and Their Dynamic Behavior
|
|
December 2001 |
Crystal Structures of [K(2.2.2-crypt)]4[Pb9Mo(CO)3] — Isolation of the Novel Isomers [(η5-Pb9)Mo(CO)3]4- beside [(η4-Pb9)Mo(CO)3]4-
|
|
September 2005 |
Closo-[CrPb 9 (CO) 3 ] 4– : a 100 year history of the nonaplumbide tetra-anion
|
|
January 1990 |
A Highly Distorted Open-Shell Endohedral Zintl Cluster: [Mn@Pb 12 ] 3–
|
|
September 2011 |
[NbAs8]3-, ein neuartiger Komplextyp und eine unerwartete eindimensionale Kettenstruktur:∞1[b{NbAs8}]2-
|
|
April 1986 |
[NbAs8]3−, a Novel Type of Complex and an Unexpected One-Dimensional Chain Structure:∞1[Rb{NbAs8}]2−
|
|
April 1986 |
Gas Phase, Solution, and Solid State Alkali Ion Binding by the [NbE 8 ] 3 - (E = As, Sb) Complexes: Synthesis, Structure, and Spectroscopy
|
|
June 2004 |
A Carbon-Free Sandwich Complex [(P5)2Ti]2-
|
|
February 2002 |
On the Formation of Intermetalloid Clusters: Titanocene(III)diammin as a Versatile Reactant Toward Nonastannide Zintl Clusters
|
|
October 2014 |
[V@Ge 8 As 4 ] 3− and [Nb@Ge 8 As 6 ] 3− : encapsulation of electron-poor transition metal atoms
|
|
January 2015 |
Understanding of multimetallic cluster growth
|
|
January 2016 |
All-Metal Antiaromaticity in Sb 4 -Type Lanthanocene Anions
|
|
April 2016 |
All-Metal Antiaromaticity in Sb 4 -Type Lanthanocene Anions
|
|
April 2016 |
Substantial π-aromaticity in the anionic heavy-metal cluster [Th@Bi12]4−
|
|
December 2020 |
[(η-C6H5Me)NbSn6Nb(η-C6H5Me)]2−: ein Komplex mit einem metallstabilisierten cyclohexananalogen Sn612−-Zintl-Ion
|
|
June 2001 |
The [(-C6H5Me)NbSn6Nb(-C6H5Me)]2 Ion: A Complex Containing a Metal-Stabilized Sn612 Cyclohexane-Like Zintl Ion
|
|
June 2001 |
On the reaction of GeCl 2 ·dioxane with KFeCp(CO) 2 : isolation and characterization of novel bimetallic clusters
|
|
January 2019 |
Ge6Me12 and Ge6H12 Cyclohexagermanes: Conformer Equilibria Studied by Raman Spectroscopy and Quantum Chemical Calculations
|
|
November 2007 |
A luminescent and dichroic hexagermane
|
|
January 2013 |
Reduktion des Systems NbX5/AIX3 mit Aluminium in Gegenwart aromatischer Kohlenwasserstoffe: Ein Zugang zu metallorganischen Niob(II)-, Niob(I)- und Niob(0)-Komplexen
|
|
January 1991 |
The Reduction of the NbX5/AlX3 System with Aluminum in the Presence of Aromatic Hydrocarbons: An Approach to Niobium(II), Niobium(I), and Niobium(0) Organometallics
|
|
January 1991 |
A short history of SHELX
|
|
December 2007 |
Crystal structure refinement with SHELXL
|
|
January 2015 |
OLEX2 : a complete structure solution, refinement and analysis program
|
|
January 2009 |
Density-functional exchange-energy approximation with correct asymptotic behavior
|
|
September 1988 |
The determination of molecular structures by density functional theory. The evaluation of analytical energy gradients by numerical integration
|
|
January 1988 |
COSMO: a new approach to dielectric screening in solvents with explicit expressions for the screening energy and its gradient
|
|
January 1993 |
Relativistic total energy using regular approximations
|
|
December 1994 |
The Induced Magnetic Field
|
|
August 2011 |
What is aromaticity?
|
|
January 1996 |
Magnetic criteria for aromaticity
|
|
April 1975 |
Magnetic criteria of aromaticity
|
|
January 2015 |
A Combined Charge and Energy Decomposition Scheme for Bond Analysis
|
|
March 2009 |
Bond Orbitals from Chemical Valence Theory
|
|
March 2008 |
Building a Bridge between Coordination Compounds and Clusters: Bonding Analysis of the Icosahedral Molecules [M(ER) 12 ] (M = Cr, Mo, W; E = Zn, Cd, Hg)
|
|
August 2011 |
Surprising Acid/Base and Ion-Sequestration Chemistry of Sn 9 4– : HSn 9 3– , Ni@HSn 9 3– , and the Sn 9 3– Ion Revisited
|
|
May 2012 |
The [Sn 9 Pt 2 (PPh 3 )] 2 - and [Sn 9 Ni 2 (CO)] 3 - Complexes: Two Markedly Different Sn 9 M 2 L Transition Metal Zintl Ion Clusters and Their Dynamic Behavior
|
|
April 2002 |
Organotransition-Metal Metallacarboranes. 36. A Remarkably Stable Transition-Metal-Benzyne Complex: Synthesis and Structure of Cp(PMe3)(.eta.2-C6H4)Ta(Et2C2B4H4)
|
|
January 1995 |
Organotransition-Metal Metallacarboranes. 38. C2B3 and C2B4 Carborane Ligands as Cyclopentadienyl Analogs: Early Transition Metal Complexes
|
|
June 1995 |
Small Carborane Ligands as Tailorable Cp Surrogates. Halogenation, Alkylation, and Arylation at Metal and Cage Positions on CpX 2 M(Et 2 C 2 B 4 H 4 ) Complexes (M = Ta, Nb) 1
|
|
May 2000 |
Mononuclear metallacarboranes of groups 6–10 metals: Analogues of metallocenes
|
|
June 2006 |
Titanium and Zirconium Et 2 C 2 B 4 H 4 −Metal−Phosphine Complexes: Synthesis, Characterization, and Ethylene Polymerization Activity 1
|
|
October 2000 |
Synthesis and Characterization of the First Niobocene Germyl Complexes and Reactivity of Triphenylsilyl-, Triphenylgermyl-, and Triphenylstannylniobocene Derivatives. X-ray Molecular Structures of d 0 Nb(η 5 -C 5 H 4 SiMe 3 ) 2 (H) 2 (EPh 3 ) (E = Ge, Sn)
|
|
March 1998 |
Bis(germyl)-Substituted Niobocenes
|
|
April 2003 |
Crystal structure of the zerovalent niobium complex Nb (η-C6H5Me)2
|
|
March 1996 |
Syntheses and Structures of Asymmetric Bis(silyl) Niobocene Hydrides
|
|
December 2006 |
Exchange Coupling in Niobocene Trihydrides, Nb(C 5 H 3 RR‘) 2 H 3 , and Their Adducts with Copper Triad Cations, [{Nb(C 5 H 3 RR‘) 2 H 3 } 2 M] + (R = R‘ = H; R = H, R‘= SiMe 3 ; R = R‘ = SiMe 3 ; M = Cu, Ag, Au)
|
|
January 1996 |
Cluster Growth and Fragmentation in the Highly Fluxional Platinum Derivatives of Sn 9 4 - : Synthesis, Characterization, and Solution Dynamics of Pt 2 @Sn 17 4 - and Pt@Sn 9 H 3 -
|
|
April 2007 |
A new double bond metathesis reaction: conversion of an niobium:niobium and an nitrogen:nitrogen bond into two niobium:nitrogen bonds
|
|
August 1984 |
New niobium complexes with alkynes. 2. Tetranuclear compounds with niobium-niobium bonds, an unprecedented type of tetracarbon ligand, and oxygen in a rectangular environment
|
|
February 1990 |
A New Type of Divalent Niobium Compound: The First Nb−Nb Triple Bond in a Tetragonal Lantern Environment
|
|
August 1997 |
Über den Gitterbau von NaTl und seine Beziehung zu den Strukturen vom Typus des β-Messings: 4. Mitteilung über Metalle und Legierungen
|
|
February 1932 |
Bond Multiplicity in Transition-Metal Complexes: Applications of Two-Electron Valence Indices
|
|
August 2008 |