Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Contrasting Bonding Extremes in Two [Ge[subscript 6]][superscript n;#8722;] Complexes: A Wadian Poly

Journal Article · · Inorg. Chem.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
DOE - Office Of Science; U.S. OFFICE OF NAVAL RESEARCH
OSTI ID:
1824690
Journal Information:
Inorg. Chem., Vol. 60, Issue (19)
Country of Publication:
United States
Language:
ENGLISH

References (97)

Recent advances in structural chemistry of Group 14 Zintl ions March 2019
Zintl-Ionen, Käfigverbindungen und intermetalloide Cluster der Elemente der 14. und 15. Gruppe March 2011
Zintl Ions, Cage Compounds, and Intermetalloid Clusters of Group 14 and Group 15 Elements March 2011
Chemistry of Deltahedral Zintl Ions November 2006
Intermetalloid and Heterometallic Clusters Combining p-Block (Semi)Metals with d- or f-Block Metals May 2019
Interpenetrating As20 Fullerene and Ni12 Icosahedra in the Onion-Skin [As@Ni12@As20]3- Ion May 2003
[(Ni-Ni-Ni)@(Ge9)2]4−: A Linear Triatomic Nickel Filament Enclosed in a Dimer of Nine-Atom Germanium Clusters June 2005
[(Ni-Ni-Ni)@(Ge9)2]4−: A Linear Triatomic Nickel Filament Enclosed in a Dimer of Nine-Atom Germanium Clusters June 2005
Symmetry Reduction upon Size Mismatch: The Non-Icosahedral Intermetalloid Cluster [Co@Ge 12 ] 3−: Symmetry Reduction upon Size Mismatch: The Non-Icosahedral Intermetalloid Cluster [Co@Ge 12 ] 3− October 2018
[Co 2 @Ge 16 ] 4− : Localized versus Delocalized Bonding in Two Isomeric Intermetalloid Clusters December 2017
Structure and bonding in a bimetallic endohedral cage, [Co 2 @Ge 16 ] z− September 2015
[(Pd−Pd)@Ge 18 ] 4- :  A Palladium Dimer Inside the Largest Single-Cage Deltahedron June 2005
[Au3Ge18]5−—A Gold–Germanium Cluster with Remarkable Au–Au Interactions February 2007
[Au3Ge18]5− – ein Gold-Germanium-Cluster mit bemerkenswerten Au-Au-Wechselwirkungen February 2007
[Au3Ge45]9− – ein binäres Cluster-Anion mit einer {Ge45}-Einheit July 2007
[Au3Ge45]9−—A Binary Anion Containing a {Ge45} Cluster July 2007
Synthesis and Isolation of [Fe@Ge 10 ] 3− : A Pentagonal Prismatic Zintl Ion Cage Encapsulating an Interstitial Iron Atom March 2009
[Co@Ge 10 ] 3− : An Intermetalloid Cluster with Archimedean Pentagonal Prismatic Structure March 2009
[Co@Ge 10 ] 3− : An Intermetalloid Cluster with Archimedean Pentagonal Prismatic Structure March 2009
Synthesis and Characterization of [Ru@Ge 12 ] 3– : An Endohedral 3-Connected Cluster January 2014
Oxidative Coupling of Deltahedral [Ge 9 ] 4 - Zintl Ions September 1999
“n-Doping” of Deltahedral Zintl Ions May 2011
Low Dimensional Arrangements of the Zintl Ion [Ge9-Ge9]6— and Chemical Bonding in [Ge6]2—, [Ge9-Ge9]6—, and∞1{[Ge9]}2— January 2003
First Synthesis of Group-14 Polyanions by Extraction of a Binary Alloy with dmf and a Novel Conformation of the (Ge9−Ge9)6− Dimer: Crystal Structures of [K6(Ge9−Ge9)](dmf)12, [Rb6(Ge9−Ge9)](dmf)12 and [K2.5Cs3.5(Ge9−Ge9)](dmf)12. August 2006
An Unprecedented1∞[Ge9]2− Polymer: A Link between Molecular Zintl Clusters and Solid-State Phases January 2000
An Unprecedented1∞[Ge9]2− Polymer: A Link between Molecular Zintl Clusters and Solid-State Phases January 2000
The Controlled Oxidative Coupling of Ge94? Zintl Anions to a Linear Trimer [Ge9=Ge9=Ge9]6? May 2005
[Ge9Ge9Ge9Ge9]8-:  A Linear Tetramer of Nine-Atom Germanium Clusters, a Nanorod August 2003
On the Oxidation of [Ge 9 ] 4− – Crystal Structures and Raman Spectroscopic Investigation of Linked Ge 9 Clusters January 2021
Retention of the Zn−Zn bond in [Ge 9 Zn−ZnGe 9 ] 6− and Formation of [(Ge 9 Zn)−(Ge 9 )−(ZnGe 9 )] 8− and Polymeric 1∞ [−(Ge 9 Zn) 2− −]1 January 2017
Retention of the Zn−Zn bond in [Ge 9 Zn−ZnGe 9 ] 6− and Formation of [(Ge 9 Zn)−(Ge 9 )−(ZnGe 9 )] 8− and Polymeric 1∞ [−(Ge 9 Zn) 2− −]1 January 2017
On the Nature of Bridging Metal Atoms in Intermetalloid Clusters: Synthesis and Structure of the Metal-Atom-Bridged Zintl Clusters [Sn(Ge 9 ) 2 ] 4− and [Zn(Ge 9 ) 2 )] 6− August 2016
${{\hfill\ 1\atop \hfill \infty }}$[HgGe 9 ] 2��� ��� Ein durch Heteroatome kovalent verkn��pftes Polymer mit Zintl-Ionen als Bausteinen September 2002
${{\hfill\ 1\atop \hfill \infty }}$[HgGe 9 ] 2��� ���A Polymer with Zintl Ions as Building Blocks Covalently Linked by Heteroatoms September 2002
Synthesis and Crystal Structure of [K([2.2]crypt)]2[HgGe9](dmf) October 2007
[Hg3(Ge9)4]10−: a nanometric molecular rod precursor to polymeric mercury-linked cluster chains January 2008
[Ge8(Mo(CO)3)2]4−: an unprecedented 20-electron empty ten-vertex Zintl cluster January 2014
The Elusive closo -Ge 10 2− Zintl Ion: Finally “Captured” as a Ligand in the Complex [Ge 10 Mn(CO) 4 ] 3− July 2010
Synthesis and characterization of pristine closo-[Ge 10 ] 2− January 2016
Studies on the Reactivity of [Ge9]4− towards [Fe(cot)(CO)3]: Synthesis and Characterization of [Ge8Fe(CO)3]3− and of the Anionic Organometallic Species [Fe(cot)(CO)3]− August 2010
{Ge 9 [Si(SiMe 3 ) 3 ] 2 } 2− : a starting point for mixed substituted metalloid germanium clusters January 2016
Rational Synthesis of [Ge 9 {Si(SiMe 3 ) 3 } 3 ] from Its Parent Zintl Ion Ge 9 4– January 2012
[Ge 9 {M(CO) 5 } 3 ] 4− : electrophilic addition of M(CO) 5 and [E 9 ] 4− Zintl anions (M = Cr, Mo, W) January 2017
Syntheses, Crystal Structures, and Density Functional Theory Calculations of the c loso -[1-M(CO) 34 -E 9 )] 4 - (E = Sn, Pb; M = Mo, W) Cluster Anions and Solution NMR Spectroscopic Characterization of [1-M(CO) 34 -Sn 9 )] 4 - (M = Cr, Mo, W) January 2002
Thecloso-[Sn9M(CO)3]4− Zintl Ion Clusters where M=Cr, Mo, W: Two Structural Isomers and Their Dynamic Behavior December 2001
Crystal Structures of [K(2.2.2-crypt)]4[Pb9Mo(CO)3] — Isolation of the Novel Isomers [(η5-Pb9)Mo(CO)3]4- beside [(η4-Pb9)Mo(CO)3]4- September 2005
Closo-[CrPb 9 (CO) 3 ] 4– : a 100 year history of the nonaplumbide tetra-anion January 1990
A Highly Distorted Open-Shell Endohedral Zintl Cluster: [Mn@Pb 12 ] 3– September 2011
[NbAs8]3-, ein neuartiger Komplextyp und eine unerwartete eindimensionale Kettenstruktur:∞1[b{NbAs8}]2- April 1986
[NbAs8]3−, a Novel Type of Complex and an Unexpected One-Dimensional Chain Structure:∞1[Rb{NbAs8}]2− April 1986
Gas Phase, Solution, and Solid State Alkali Ion Binding by the [NbE 8 ] 3 - (E = As, Sb) Complexes:  Synthesis, Structure, and Spectroscopy June 2004
A Carbon-Free Sandwich Complex [(P5)2Ti]2- February 2002
On the Formation of Intermetalloid Clusters: Titanocene(III)diammin as a Versatile Reactant Toward Nonastannide Zintl Clusters October 2014
[V@Ge 8 As 4 ] 3− and [Nb@Ge 8 As 6 ] 3− : encapsulation of electron-poor transition metal atoms January 2015
Understanding of multimetallic cluster growth January 2016
All-Metal Antiaromaticity in Sb 4 -Type Lanthanocene Anions April 2016
All-Metal Antiaromaticity in Sb 4 -Type Lanthanocene Anions April 2016
Substantial π-aromaticity in the anionic heavy-metal cluster [Th@Bi12]4− December 2020
[(η-C6H5Me)NbSn6Nb(η-C6H5Me)]2−: ein Komplex mit einem metallstabilisierten cyclohexananalogen Sn612−-Zintl-Ion June 2001
The [(-C6H5Me)NbSn6Nb(-C6H5Me)]2 Ion: A Complex Containing a Metal-Stabilized Sn612 Cyclohexane-Like Zintl Ion June 2001
On the reaction of GeCl 2 ·dioxane with KFeCp(CO) 2 : isolation and characterization of novel bimetallic clusters January 2019
Ge6Me12 and Ge6H12 Cyclohexagermanes: Conformer Equilibria Studied by Raman Spectroscopy and Quantum Chemical Calculations November 2007
A luminescent and dichroic hexagermane January 2013
Reduktion des Systems NbX5/AIX3 mit Aluminium in Gegenwart aromatischer Kohlenwasserstoffe: Ein Zugang zu metallorganischen Niob(II)-, Niob(I)- und Niob(0)-Komplexen January 1991
The Reduction of the NbX5/AlX3 System with Aluminum in the Presence of Aromatic Hydrocarbons: An Approach to Niobium(II), Niobium(I), and Niobium(0) Organometallics January 1991
A short history of SHELX December 2007
Crystal structure refinement with SHELXL January 2015
OLEX2 : a complete structure solution, refinement and analysis program January 2009
Density-functional exchange-energy approximation with correct asymptotic behavior September 1988
The determination of molecular structures by density functional theory. The evaluation of analytical energy gradients by numerical integration January 1988
COSMO: a new approach to dielectric screening in solvents with explicit expressions for the screening energy and its gradient January 1993
Relativistic total energy using regular approximations December 1994
The Induced Magnetic Field August 2011
What is aromaticity? January 1996
Magnetic criteria for aromaticity April 1975
Magnetic criteria of aromaticity January 2015
A Combined Charge and Energy Decomposition Scheme for Bond Analysis March 2009
Bond Orbitals from Chemical Valence Theory March 2008
Building a Bridge between Coordination Compounds and Clusters: Bonding Analysis of the Icosahedral Molecules [M(ER) 12 ] (M = Cr, Mo, W; E = Zn, Cd, Hg) August 2011
Surprising Acid/Base and Ion-Sequestration Chemistry of Sn 9 4– : HSn 9 3– , Ni@HSn 9 3– , and the Sn 9 3– Ion Revisited May 2012
The [Sn 9 Pt 2 (PPh 3 )] 2 - and [Sn 9 Ni 2 (CO)] 3 - Complexes:  Two Markedly Different Sn 9 M 2 L Transition Metal Zintl Ion Clusters and Their Dynamic Behavior April 2002
Organotransition-Metal Metallacarboranes. 36. A Remarkably Stable Transition-Metal-Benzyne Complex: Synthesis and Structure of Cp(PMe3)(.eta.2-C6H4)Ta(Et2C2B4H4) January 1995
Organotransition-Metal Metallacarboranes. 38. C2B3 and C2B4 Carborane Ligands as Cyclopentadienyl Analogs: Early Transition Metal Complexes June 1995
Small Carborane Ligands as Tailorable Cp Surrogates. Halogenation, Alkylation, and Arylation at Metal and Cage Positions on CpX 2 M(Et 2 C 2 B 4 H 4 ) Complexes (M = Ta, Nb) 1 May 2000
Mononuclear metallacarboranes of groups 6–10 metals: Analogues of metallocenes June 2006
Titanium and Zirconium Et 2 C 2 B 4 H 4 −Metal−Phosphine Complexes:  Synthesis, Characterization, and Ethylene Polymerization Activity 1 October 2000
Synthesis and Characterization of the First Niobocene Germyl Complexes and Reactivity of Triphenylsilyl-, Triphenylgermyl-, and Triphenylstannylniobocene Derivatives. X-ray Molecular Structures of d 0 Nb(η 5 -C 5 H 4 SiMe 3 ) 2 (H) 2 (EPh 3 ) (E = Ge, Sn) March 1998
Bis(germyl)-Substituted Niobocenes April 2003
Crystal structure of the zerovalent niobium complex Nb (η-C6H5Me)2 March 1996
Syntheses and Structures of Asymmetric Bis(silyl) Niobocene Hydrides December 2006
Exchange Coupling in Niobocene Trihydrides, Nb(C 5 H 3 RR‘) 2 H 3 , and Their Adducts with Copper Triad Cations, [{Nb(C 5 H 3 RR‘) 2 H 3 } 2 M] + (R = R‘ = H; R = H, R‘= SiMe 3 ; R = R‘ = SiMe 3 ; M = Cu, Ag, Au) January 1996
Cluster Growth and Fragmentation in the Highly Fluxional Platinum Derivatives of Sn 9 4 - :  Synthesis, Characterization, and Solution Dynamics of Pt 2 @Sn 17 4 - and Pt@Sn 9 H 3 - April 2007
A new double bond metathesis reaction: conversion of an niobium:niobium and an nitrogen:nitrogen bond into two niobium:nitrogen bonds August 1984
New niobium complexes with alkynes. 2. Tetranuclear compounds with niobium-niobium bonds, an unprecedented type of tetracarbon ligand, and oxygen in a rectangular environment February 1990
A New Type of Divalent Niobium Compound:  The First Nb−Nb Triple Bond in a Tetragonal Lantern Environment August 1997
Über den Gitterbau von NaTl und seine Beziehung zu den Strukturen vom Typus des β-Messings: 4. Mitteilung über Metalle und Legierungen February 1932
Bond Multiplicity in Transition-Metal Complexes: Applications of Two-Electron Valence Indices August 2008