Polyethylene Hydrogenolysis at Mild Conditions over Ruthenium on Tungstated Zirconia

Wang, C; Xie, T.; Kots, P.; Vance, B.; Yu, K.; Kumar, P.; Fu, J.; Liu, S.; Tsilomelekis, G.; Stach, E.; Zheng, W.; Vlachos, D.

doi:10.1021/jacsau.1c00200

Polyethylene Hydrogenolysis at Mild Conditions over Ruthenium on Tungstated Zirconia

Journal Article · 01 January 2022 · JACS Au

DOI:https://doi.org/10.1021/jacsau.1c00200· OSTI ID:1823006

Wang, C; Xie, T.; Kots, P.; Vance, B.; Yu, K.; Kumar, P.; Fu, J.; Liu, S.; Tsilomelekis, G.; Stach, E.; Zheng, W.; Vlachos, D.

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: ~OTHER

DOE Contract Number:: SC0012704

OSTI ID:: 1823006

Report Number(s):: BNL-222195-2021-JACI

Journal Information:: JACS Au, Vol. 1, Issue 9

Country of Publication:: United States

Language:: English

References (70)

Production, use, and fate of all plastics ever made Geyer, Roland; Jambeck, Jenna R.; Law, Kara Lavender Science Advances, Vol. 3, Issue 7 https://doi.org/10.1126/sciadv.1700782	journal	July 2017
Catalytic Alkane Metathesis by Tandem Alkane Dehydrogenation-Olefin Metathesis Goldman, Alan S.; Roy, Amy H.; Huang, Zheng Science, Vol. 312, Issue 5771, p. 257-261 https://doi.org/10.1126/science.1123787	journal	April 2006
Tandem Heterogeneous Catalysis for Polyethylene Depolymerization via an Olefin-Intermediate Process Ellis, Lucas D.; Orski, Sara V.; Kenlaw, Grace A. ACS Sustainable Chemistry & Engineering, Vol. 9, Issue 2 https://doi.org/10.1021/acssuschemeng.0c07612	journal	January 2021
Trash to Treasure: Microwave-Assisted Conversion of Polyethylene to Functional Chemicals Bäckström, Eva; Odelius, Karin; Hakkarainen, Minna Industrial & Engineering Chemistry Research, Vol. 56, Issue 50 https://doi.org/10.1021/acs.iecr.7b04091	journal	December 2017
Upcycling Single-Use Polyethylene into High-Quality Liquid Products Celik, Gokhan; Kennedy, Robert M.; Hackler, Ryan A. ACS Central Science, Vol. 5, Issue 11 https://doi.org/10.1021/acscentsci.9b00722	journal	September 2019
Developing Advanced Catalysts for the Conversion of Polyolefinic Waste Plastics into Fuels and Chemicals Serrano, D. P.; Aguado, J.; Escola, J. M. ACS Catalysis, Vol. 2, Issue 9 https://doi.org/10.1021/cs3003403	journal	August 2012
The Use of Heterogeneous Catalysis in the Chemical Valorization of Plastic Waste Mark, Lesli O.; Cendejas, Melissa C.; Hermans, Ive ChemSusChem, Vol. 13, Issue 22 https://doi.org/10.1002/cssc.202001905	journal	October 2020
Investigation of the Catalytic Pyrolysis of High-Density Polyethylene over a HZSM-5 Catalyst in a Laboratory Fluidized-Bed Reactor Sharratt, P. N.; Lin, Y. -H.; Garforth, A. A. Industrial & Engineering Chemistry Research, Vol. 36, Issue 12 https://doi.org/10.1021/ie970348b	journal	December 1997
Single Pot Catalyst Strategy to Branched Products via Adhesive Isomerization and Hydrocracking of Polyethylene over Platinum Tungstated Zirconia Vance, Brandon C.; Kots, Pavel A.; Wang, Cong Applied Catalysis B: Environmental https://doi.org/10.1016/j.apcatb.2021.120483	journal	June 2021
The Chemistry and Kinetics of Polyethylene Pyrolysis: A Process to Produce Fuels and Chemicals Zhao, Dongting; Wang, Xianhua; Miller, James B. ChemSusChem, Vol. 13, Issue 7 https://doi.org/10.1002/cssc.201903434	journal	February 2020
Composite zeolite beta catalysts for catalytic hydrocracking of plastic waste to liquid fuels Munir, Dureem; Amer, Hassaan; Aslam, Rabya Materials for Renewable and Sustainable Energy, Vol. 9, Issue 2 https://doi.org/10.1007/s40243-020-00169-3	journal	April 2020
Catalytic Conversion of Polyolefins into Liquid Fuels over MCM-41: Comparison with ZSM-5 and Amorphous SiO ₂ −Al ₂ O ₃ Aguado, J.; Sotelo, J. L.; Serrano, D. P. Energy & Fuels, Vol. 11, Issue 6 https://doi.org/10.1021/ef970055v	journal	November 1997
Catalytic activity of zeolitic and mesostructured catalysts in the cracking of pure and waste polyolefins Aguado, J.; Serrano, D. P.; Miguel, G. San Journal of Analytical and Applied Pyrolysis, Vol. 78, Issue 1 https://doi.org/10.1016/j.jaap.2006.06.004	journal	January 2007
Molecular Redistribution and Molecular Averaging: Disproportionation of Paraffins via Bifunctional Catalysis Chen, C. Y.; O’Rear, D. J.; Leung, P. Topics in Catalysis, Vol. 55, Issue 19-20 https://doi.org/10.1007/s11244-012-9910-3	journal	October 2012
Pd-modified beta zeolite for modulated hydro-cracking of low-density polyethylene into a paraffinic-rich hydrocarbon fuel Pyra, Kamila; Tarach, Karolina A.; Śrębowata, Anna Applied Catalysis B: Environmental, Vol. 277 https://doi.org/10.1016/j.apcatb.2020.119070	journal	November 2020
Plastic waste to fuels by hydrocracking at mild conditions Liu, Sibao; Kots, Pavel A.; Vance, Brandon C. Science Advances, Vol. 7, Issue 17 https://doi.org/10.1126/sciadv.abf8283	journal	April 2021
Hydrocracking of virgin and post-consumer polymers Jumah, Abdulrahman bin; Tedstone, Aleksander A.; Garforth, Arthur A. Microporous and Mesoporous Materials, Vol. 315 https://doi.org/10.1016/j.micromeso.2021.110912	journal	February 2021
Catalyzing the Hydrocracking of Low Density Polyethylene Bin Jumah, Abdulrahman; Anbumuthu, Vanithasri; Tedstone, Aleksander A. Industrial & Engineering Chemistry Research, Vol. 58, Issue 45 https://doi.org/10.1021/acs.iecr.9b04263	journal	October 2019
Polyethylene catalytic hydrocracking by PtHZSM-5, PtHY, and PtHMCM-41 Hesse, Nathan D.; White, Robert L. Journal of Applied Polymer Science, Vol. 92, Issue 2 https://doi.org/10.1002/app.20083	journal	January 2004
Low-temperature catalytic upgrading of waste polyolefinic plastics into liquid fuels and waxes Nakaji, Yosuke; Tamura, Masazumi; Miyaoka, Shuhei Applied Catalysis B: Environmental, Vol. 285 https://doi.org/10.1016/j.apcatb.2020.119805	journal	May 2021
Conversion of Polyolefin Waste to Liquid Alkanes with Ru-Based Catalysts under Mild Conditions Rorrer, Julie E.; Beckham, Gregg T.; Román-Leshkov, Yuriy JACS Au, Vol. 1, Issue 1 https://doi.org/10.1021/jacsau.0c00041	journal	December 2020
Polyethylene upcycling to long-chain alkylaromatics by tandem hydrogenolysis/aromatization Zhang, Fan; Zeng, Manhao; Yappert, Ryan D. Science, Vol. 370, Issue 6515 https://doi.org/10.1126/science.abc5441	journal	October 2020
Catalytic Hydrogenolysis of Polyolefins into Alkanes Sánchez-Rivera, Kevin L.; Huber, George W. ACS Central Science, Vol. 7, Issue 1 https://doi.org/10.1021/acscentsci.0c01637	journal	December 2020
Catalytic upcycling of high-density polyethylene via a processive mechanism Tennakoon, Akalanka; Wu, Xun; Paterson, Alexander L. Nature Catalysis, Vol. 3, Issue 11 https://doi.org/10.1038/s41929-020-00519-4	journal	October 2020
Deconstruction of high-density polyethylene into liquid hydrocarbon fuels and lubricants by hydrogenolysis over Ru catalyst Jia, Chuhua; Xie, Shaoqu; Zhang, Wanli Chem Catalysis, Vol. 1, Issue 2 https://doi.org/10.1016/j.checat.2021.04.002	journal	July 2021
Catalytic hydrocracking of synthetic polymers into grid-compatible gas streams Lee, Wei-Tse; Bobbink, Felix D.; van Muyden, Antoine P. Cell Reports Physical Science, Vol. 2, Issue 2 https://doi.org/10.1016/j.xcrp.2021.100332	journal	February 2021
Oxidation Behavior and Kinetics of Eight C ₂₀ –C ₅₄ n -Alkanes by High Pressure Differential Scanning Calorimetry (HP-DSC) Yuan, Chengdong; Emelianov, Dmitrii A.; Varfolomeev, Mikhail A. Energy & Fuels, Vol. 32, Issue 7 https://doi.org/10.1021/acs.energyfuels.8b01401	journal	June 2018
The Determination of The Homologous Purity of Higher Normal Alkanes up to Dohectane with Capillary Gas Chromatography Urabe, Yoshiko; Takamizawa, Kanichiro Polymer Journal, Vol. 26, Issue 3 https://doi.org/10.1295/polymj.26.283	journal	March 1994
Drawing behavior and mechanical properties of ultra-high molecular weight polyethylene blends with a linear polyethylene wax Shen, Lihua; Severn, John; Bastiaansen, Cees W. M. Polymer, Vol. 153 https://doi.org/10.1016/j.polymer.2018.01.083	journal	September 2018
CRC Handbook of Chemistry and Physics Haynes, William M. CRC Press https://doi.org/10.1201/b17118	book	June 2014
The relationship between the degree of branching and glass transition temperature of branched polyethylene: experiment and simulation Luo, Xiang; Xie, Shijie; Liu, Jun Polym. Chem., Vol. 5, Issue 4 https://doi.org/10.1039/C3PY00896G	journal	January 2014
Nanoparticle size evaluation of catalysts by EXAFS: Advantages and limitations Marinkovic, Nebojsa; Sasaki, Kotaro; Adzic, Radoslav Zastita materijala, Vol. 57, Issue 1 https://doi.org/10.5937/ZasMat1601101M	journal	January 2016
Synthesis of Mo and Ru solid-solution alloy NPs and their hydrogen evolution reaction activity Okazoe, Shinya; Kusada, Kohei; Wu, Dongshuang Chemical Communications, Vol. 56, Issue 92 https://doi.org/10.1039/D0CC05958G	journal	January 2020
Nonstoichiometric Tungsten Oxide Based on Hexagonal WO ₃ Solonin, Yu. M.; Khyzhun, O. Yu.; Graivoronskaya, E. A. Crystal Growth & Design, Vol. 1, Issue 6 https://doi.org/10.1021/cg015545z	journal	November 2001
Low temperature synthesis of nanocrystalline WO3 films by sol–gel process Djaoued, Y.; Priya, S.; Balaji, S. Journal of Non-Crystalline Solids, Vol. 354, Issue 2-9 https://doi.org/10.1016/j.jnoncrysol.2007.07.090	journal	January 2008
Identification of active Zr–WOx clusters on a ZrO2 support for solid acid catalysts Zhou, Wu; Ross-Medgaarden, Elizabeth I.; Knowles, William V. Nature Chemistry, Vol. 1, Issue 9 https://doi.org/10.1038/nchem.433	journal	November 2009
A Study of Tetrahydrofurfuryl Alcohol to 1,5-Pentanediol Over Pt–WOx/C Wang, Cong; Lee, Jennifer D.; Ji, Yichen Catalysis Letters, Vol. 148, Issue 4 https://doi.org/10.1007/s10562-018-2323-6	journal	February 2018
Nature of Catalytically Active Sites in the Supported WO ₃ /ZrO ₂ Solid Acid System: A Current Perspective Zhou, Wu; Soultanidis, Nikolaos; Xu, Hui ACS Catalysis, Vol. 7, Issue 3 https://doi.org/10.1021/acscatal.6b03697	journal	February 2017
A Characterization Study of Reactive Sites in ALD-Synthesized WOx/ZrO2 Catalysts Wang, Cong; Mao, Xinyu; Lee, Jennifer Catalysts, Vol. 8, Issue 7 https://doi.org/10.3390/catal8070292	journal	July 2018
Metal-Catalyzed C–C Bond Cleavage in Alkanes: Effects of Methyl Substitution on Transition-State Structures and Stability Flaherty, David W.; Hibbitts, David D.; Iglesia, Enrique Journal of the American Chemical Society, Vol. 136, Issue 27 https://doi.org/10.1021/ja5037429	journal	June 2014
H-D Exchange of Simple Aromatics as a Measure of Brønsted-Acid Site Strengths in Solids Wang, Cong; Li, Sha; Mao, Xinyu Catalysis Letters, Vol. 148, Issue 11 https://doi.org/10.1007/s10562-018-2563-5	journal	September 2018
Hydrogenolysis of n-heptane over unsupported metals Carter, J. Journal of Catalysis, Vol. 20, Issue 2 https://doi.org/10.1016/0021-9517(71)90083-2	journal	February 1971
Catalytic Production of Branched Small Alkanes from Biohydrocarbons Oya, Shin-ichi; Kanno, Daisuke; Watanabe, Hideo ChemSusChem, Vol. 8, Issue 15 https://doi.org/10.1002/cssc.201500375	journal	June 2015
Regioselectivity and Reaction Mechanism of Ru-Catalyzed Hydrogenolysis of Squalane and Model Alkanes Nakagawa, Yoshinao; Oya, Shin-ichi; Kanno, Daisuke ChemSusChem, Vol. 10, Issue 1 https://doi.org/10.1002/cssc.201601204	journal	November 2016
Hydrogen Spillover. Facts and Fiction Prins, R. Chemical Reviews, Vol. 112, Issue 5 https://doi.org/10.1021/cr200346z	journal	February 2012
Mechanistic Study of the Direct Hydrodeoxygenation of m -Cresol over WO _x -Decorated Pt/C Catalysts Wang, Cong; Mironenko, Alexander V.; Raizada, Abhishek ACS Catalysis, Vol. 8, Issue 9 https://doi.org/10.1021/acscatal.8b01746	journal	July 2018
Heterogeneous catalytic hydrogenation of CO ₂ by metal oxides: defect engineering – perfecting imperfection Jia, Jia; Qian, Chenxi; Dong, Yuchan Chemical Society Reviews, Vol. 46, Issue 15 https://doi.org/10.1039/C7CS00026J	journal	January 2017
Selective Hydrogenolysis of Glycerol to 1,3-Propanediol: Manipulating the Frustrated Lewis Pairs by Introducing Gold to Pt/WO _x Zhao, Xiaochen; Wang, Jia; Yang, Man ChemSusChem, Vol. 10, Issue 5 https://doi.org/10.1002/cssc.201601503	journal	December 2016
Role of Hydrogen Spillover in Methanol Synthesis over Cu/ZrO2 Jung, Kwang-Deog; Bell, Alexis T. Journal of Catalysis, Vol. 193, Issue 2 https://doi.org/10.1006/jcat.2000.2881	journal	July 2000
Resolving ruthenium: XPS studies of common ruthenium materials Morgan, David J. Surface and Interface Analysis, Vol. 47, Issue 11 https://doi.org/10.1002/sia.5852	journal	September 2015
Catalytic and structural properties of ruthenium bimetallic catalysts: Preparation and characterization Coq, Bernard; Crabb, Eleanor; Warawdekar, Mayukh Journal of Molecular Catalysis, Vol. 92, Issue 1 https://doi.org/10.1016/0304-5102(94)85006-2	journal	August 1994
Structural Determination of Bulk and Surface Tungsten Oxides with UV−vis Diffuse Reflectance Spectroscopy and Raman Spectroscopy Ross-Medgaarden, Elizabeth I.; Wachs, Israel E. The Journal of Physical Chemistry C, Vol. 111, Issue 41 https://doi.org/10.1021/jp074219c	journal	September 2007
New insights into the nature of the acidic catalytic active sites present in ZrO2-supported tungsten oxide catalysts Rossmedgaarden, E.; Knowles, W.; Kim, T. Journal of Catalysis, Vol. 256, Issue 1 https://doi.org/10.1016/j.jcat.2008.03.003	journal	May 2008
Multiwavelength Raman Spectroscopic Characterization of Alumina-Supported Molybdenum Oxide Prepared by Vapor Deposition Drake, Tasha L.; Stair, Peter C. Topics in Catalysis, Vol. 60, Issue 19-20 https://doi.org/10.1007/s11244-017-0842-9	journal	November 2017
Hydrogen Adsorption on Ru/ZrO ₂ Studied by FT-IR Ishikawa, Hiroyuki; Kondo, Junko N.; Domen, Kazunari The Journal of Physical Chemistry B, Vol. 103, Issue 16 https://doi.org/10.1021/jp9842852	journal	April 1999
Infrared and Raman spectroscopies of rf sputtered tungsten oxide films Daniel, M. F.; Desbat, B.; Lassegues, J. C. Journal of Solid State Chemistry, Vol. 73, Issue 1 https://doi.org/10.1016/0022-4596(88)90062-X	journal	March 1988
Infrared and Raman study of WO₃ tungsten trioxides and WO₃, xH₂O tungsten trioxide tydrates Daniel, M. F.; Desbat, B.; Lassegues, J. C. Journal of Solid State Chemistry, Vol. 67, Issue 2, p. 235-247 https://doi.org/10.1016/0022-4596(87)90359-8	journal	April 1987
Anwendung von kinetischen Methoden f�r die Untersuchung der Struktur und der Reaktionen der Bildung von hochmolekularen Aquowolframaten Spitzin, Vikt. I.; Kabanow, V. J. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 322, Issue 5-6 https://doi.org/10.1002/zaac.19633220505	journal	June 1963
Fischer-Tropsch synthesis on cobalt and ruthenium. Metal dispersion and support effects on reaction rate and selectivity Iglesia, E. Journal of Catalysis, Vol. 137, Issue 1 https://doi.org/10.1016/0021-9517(92)90150-G	journal	September 1992
The kinetics of H2 adsorption on supported ruthenium catalysts Lin, Hsin-Yu; Chen, Yu-Wen Thermochimica Acta, Vol. 419, Issue 1-2 https://doi.org/10.1016/j.tca.2004.03.007	journal	September 2004
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Ab initiomolecular dynamics for liquid metals Kresse, G.; Hafner, J. Physical Review B, Vol. 47, Issue 1, p. 558-561 https://doi.org/10.1103/PhysRevB.47.558	journal	January 1993
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu Grimme, Stefan; Antony, Jens; Ehrlich, Stephan The Journal of Chemical Physics, Vol. 132, Issue 15 https://doi.org/10.1063/1.3382344	journal	April 2010
Effect of the damping function in dispersion corrected density functional theory Grimme, Stefan; Ehrlich, Stephan; Goerigk, Lars Journal of Computational Chemistry, Vol. 32, Issue 7 https://doi.org/10.1002/jcc.21759	journal	March 2011
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
The structure of the p(√3 × √3)R30° bilayer of D2O on Ru(001) Held, G.; Menzel, D. Surface Science, Vol. 316, Issue 1-2 https://doi.org/10.1016/0039-6028(94)91131-2	journal	September 1994
Crystal structure and paramagnetic behaviour of Salje, Ekhard K. H.; Rehmann, Stephan; Pobell, Frank Journal of Physics: Condensed Matter, Vol. 9, Issue 31 https://doi.org/10.1088/0953-8984/9/31/010	journal	August 1997
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/PhysRevB.13.5188	journal	June 1976

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