Nonflammable Nonaqueous Electrolytes for Lithium Batteries

Jia, Hao; Xu, Wu

doi:10.1016/j.coelec.2021.100781

Nonflammable Nonaqueous Electrolytes for Lithium Batteries

Journal Article · 01 December 2021 · Current Opinion in Electrochemistry

DOI:https://doi.org/10.1016/j.coelec.2021.100781· OSTI ID:1819878

Jia, Hao ^[1]; ^[1]

BATTELLE (PACIFIC NW LAB)

As the energy density of state-of-the-art lithium (Li)-ion batteries (LIBs) increases, the safety concern of LIBs using liquid electrolytes is drawing increasing attention. Flammability of electrolytes is a critical link of the overall safety performance of LIBs and Li metal batteries. For this reason, intensive efforts have been devoted to suppressing the flammability of liquid electrolytes. In this short review, the common approaches to reduce the flammability of the liquid electrolytes will be summarized. The advantages and limitations of these approaches will also be discussed.

Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1819878

Report Number(s):: PNNL-SA-161413

Journal Information:: Current Opinion in Electrochemistry, Vol. 30

Country of Publication:: United States

Language:: English

References (42)

Best Practice: Performance and Cost Evaluation of Lithium Ion Battery Active Materials with Special Emphasis on Energy Efficiency Meister, Paul; Jia, Haiping; Li, Jie Chemistry of Materials, Vol. 28, Issue 20 https://doi.org/10.1021/acs.chemmater.6b02895	journal	October 2016
Before Li Ion Batteries Winter, Martin; Barnett, Brian; Xu, Kang Chemical Reviews, Vol. 118, Issue 23 https://doi.org/10.1021/acs.chemrev.8b00422	journal	November 2018
Concept of reliability and safety assessment of lithium-ion batteries in electric vehicles: Basics, progress, and challenges Gandoman, Foad H.; Jaguemont, Joris; Goutam, Shovon Applied Energy, Vol. 251 https://doi.org/10.1016/j.apenergy.2019.113343	journal	October 2019
Ror2 signaling regulates Golgi structure and transport through IFT20 for tumor invasiveness Nishita, Michiru; Park, Seung-Yeol; Nishio, Tadashi Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-016-0028-x	journal	January 2017
Progress of enhancing the safety of lithium ion battery from the electrolyte aspect Wang, Qingsong; Jiang, Lihua; Yu, Yan Nano Energy, Vol. 55 https://doi.org/10.1016/j.nanoen.2018.10.035	journal	January 2019
Dimethyl methylphosphonate (DMMP) as an efficient flame retardant additive for the lithium-ion battery electrolytes Xiang, H. F.; Xu, H. Y.; Wang, Z. Z. Journal of Power Sources, Vol. 173, Issue 1 https://doi.org/10.1016/j.jpowsour.2007.05.001	journal	November 2007
Comparative study of trimethyl phosphite and trimethyl phosphate as electrolyte additives in lithium ion batteries Yao, X. L.; Xie, S.; Chen, C. H. Journal of Power Sources, Vol. 144, Issue 1 https://doi.org/10.1016/j.jpowsour.2004.11.042	journal	June 2005
Towards a Safe Lithium-Sulfur Battery with a Flame-Inhibiting Electrolyte and a Sulfur-Based Composite Cathode Wang, Jiulin; Lin, Fengjiao; Jia, Hao Angewandte Chemie International Edition, Vol. 53, Issue 38 https://doi.org/10.1002/anie.201405157	journal	July 2014
TPPi as a flame retardant for rechargeable lithium batteries with sulfur composite cathodes Jia, Hao; Wang, Jiulin; Lin, Fengjiao Chem. Commun., Vol. 50, Issue 53 https://doi.org/10.1039/C4CC01151A	journal	January 2014
Flame-retardant additives for lithium-ion batteries Hyung, Yoo E.; Vissers, Donald R.; Amine, Khalil Journal of Power Sources, Vol. 119-121 https://doi.org/10.1016/S0378-7753(03)00225-8	journal	June 2003
Phosphorus additives for improving high voltage stability and safety of lithium ion batteries von Aspern, Natascha; Röser, Stephan; Rezaei Rad, Babak Journal of Fluorine Chemistry, Vol. 198 https://doi.org/10.1016/j.jfluchem.2017.02.005	journal	June 2017
Electrochemical performance evaluations and safety investigations of pentafluoro(phenoxy)cyclotriphosphazene as a flame retardant electrolyte additive for application in lithium ion battery systems using a newly designed apparatus for improved self-extinguishing time measurements Dagger, Tim; Lürenbaum, Constantin; Schappacher, Falko M. Journal of Power Sources, Vol. 342 https://doi.org/10.1016/j.jpowsour.2016.12.007	journal	February 2017
An electrochemically compatible and flame-retardant electrolyte additive for safe lithium ion batteries Wu, Bingbin; Pei, Feng; Wu, Yue Journal of Power Sources, Vol. 227 https://doi.org/10.1016/j.jpowsour.2012.11.018	journal	April 2013
Phosphorus-based Flame Retardancy Mechanisms—Old Hat or a Starting Point for Future Development? Schartel, Bernhard Materials, Vol. 3, Issue 10 https://doi.org/10.3390/ma3104710	journal	September 2010
A novel flame‐retardant electrolyte additive for safer lithium‐ion batteries Yan, Peng; Zhu, Yucheng; Pan, Xuhai International Journal of Energy Research, Vol. 45, Issue 2 https://doi.org/10.1002/er.5972	journal	September 2020
Stable and Safe Lithium Metal Batteries with Ni-Rich Cathodes Enabled by a High Efficiency Flame Retardant Additive Li, Yuan; An, Yongling; Tian, Yuan Journal of The Electrochemical Society, Vol. 166, Issue 13 https://doi.org/10.1149/2.0081913jes	journal	January 2019
Non-flammable Inorganic Liquid Electrolyte Lithium-Ion Batteries Ramar, Vishwanathan; Pszolla, Christian; Rapp, Manfred Journal of The Electrochemical Society, Vol. 167, Issue 7 https://doi.org/10.1149/1945-7111/ab7119	journal	January 2020
Room Temperature Ionic Liquid-based Electrolytes as an Alternative to Carbonate-based Electrolytes Yim, Taeeun; Kwon, Mi-Sook; Mun, Junyoung Israel Journal of Chemistry, Vol. 55, Issue 5 https://doi.org/10.1002/ijch.201400181	journal	March 2015
Are room temperature ionic liquids able to improve the safety of supercapacitors organic electrolytes without degrading the performances? Abdallah, Thamra; Lemordant, Daniel; Claude-Montigny, Bénédicte Journal of Power Sources, Vol. 201 https://doi.org/10.1016/j.jpowsour.2011.10.115	journal	March 2012
Room temperature ionic liquid (RTIL)-based electrolyte cocktails for safe, high working potential Li-based polymer batteries Nair, Jijeesh Ravi; Colò, Francesca; Kazzazi, Arefeh Journal of Power Sources, Vol. 412 https://doi.org/10.1016/j.jpowsour.2018.11.061	journal	February 2019
Advances and issues in developing salt-concentrated battery electrolytes Yamada, Yuki; Wang, Jianhui; Ko, Seongjae Nature Energy https://doi.org/10.1038/s41560-019-0336-z	journal	March 2019
Recent Progress in Understanding Solid Electrolyte Interphase on Lithium Metal Anodes Wu, Haiping; Jia, Hao; Wang, Chongmin Advanced Energy Materials, Vol. 11, Issue 5 https://doi.org/10.1002/aenm.202003092	journal	December 2020
Optimized Nonflammable Concentrated Electrolytes by Introducing a Low-Dielectric Diluent Takada, Koji; Yamada, Yuki; Yamada, Atsuo ACS Applied Materials & Interfaces, Vol. 11, Issue 39 https://doi.org/10.1021/acsami.9b12709	journal	September 2019
Nonflammable Electrolytes for Lithium Ion Batteries Enabled by Ultraconformal Passivation Interphases Cao, Xia; Xu, Yaobin; Zhang, Linchao ACS Energy Letters, Vol. 4, Issue 10 https://doi.org/10.1021/acsenergylett.9b01926	journal	September 2019
Highly Reversible Lithium-Metal Anode and Lithium–Sulfur Batteries Enabled by an Intrinsic Safe Electrolyte Chen, Jiahang; Yang, Huijun; Zhang, Xuan ACS Applied Materials & Interfaces, Vol. 11, Issue 36 https://doi.org/10.1021/acsami.9b09215	journal	August 2019
High-Efficiency Lithium Metal Batteries with Fire-Retardant Electrolytes Chen, Shuru; Zheng, Jianming; Yu, Lu Joule, Vol. 2, Issue 8 https://doi.org/10.1016/j.joule.2018.05.002	journal	August 2018
High‐Performance Silicon Anodes Enabled By Nonflammable Localized High‐Concentration Electrolytes Jia, Haiping; Zou, Lianfeng; Gao, Peiyuan Advanced Energy Materials, Vol. 9, Issue 31 https://doi.org/10.1002/aenm.201900784	journal	July 2019
Stable Li Metal Anode with “Ion–Solvent-Coordinated” Nonflammable Electrolyte for Safe Li Metal Batteries Xiao, Lifen; Zeng, Ziqi; Liu, Xingwei ACS Energy Letters, Vol. 4, Issue 2 https://doi.org/10.1021/acsenergylett.8b02527	journal	January 2019
Non-flammable electrolytes with high salt-to-solvent ratios for Li-ion and Li-metal batteries Zeng, Ziqi; Murugesan, Vijayakumar; Han, Kee Sung Nature Energy, Vol. 3, Issue 8 https://doi.org/10.1038/s41560-018-0196-y	journal	July 2018
Fluorine and Lithium: Ideal Partners for High‐Performance Rechargeable Battery Electrolytes Aspern, N.; Röschenthaler, G. ‐V.; Winter, M. Angewandte Chemie International Edition, Vol. 58, Issue 45 https://doi.org/10.1002/anie.201901381	journal	November 2019
Influence of the Fluorination Degree of Organophosphates on Flammability and Electrochemical Performance in Lithium Ion Batteries: Studies on Fluorinated Compounds Deriving from Triethyl Phosphate Murmann, Patrick; Mönnighoff, Xaver; von Aspern, Natascha Journal of The Electrochemical Society, Vol. 163, Issue 5 https://doi.org/10.1149/2.1031605jes	journal	January 2016
Non-flammable organic liquid electrolyte for high-safety and high-energy density Li-ion batteries Pham, Hieu Quang; Lee, Hee-Yeol; Hwang, Eui-Hyung Journal of Power Sources, Vol. 404 https://doi.org/10.1016/j.jpowsour.2018.09.075	journal	November 2018
Roles of Nonflammable Organic Liquid Electrolyte in Stabilizing the Interface of the LiNi _0.8 Co _0.1 Mn _0.1 O ₂ Cathode at 4.5 V and Improving the Battery Performance Pham, Hieu Quang; Thi Tran, Yen Hai; Han, Jisoo The Journal of Physical Chemistry C, Vol. 124, Issue 1 https://doi.org/10.1021/acs.jpcc.9b09960	journal	December 2019
Electrospun cellulose polymer nanofiber membrane with flame resistance properties for lithium-ion batteries Chen, Yue; Qiu, Linlin; Ma, Xiangyu Carbohydrate Polymers, Vol. 234 https://doi.org/10.1016/j.carbpol.2020.115907	journal	April 2020
Inherently flame-retardant solid polymer electrolyte for safety-enhanced lithium metal battery Li, Hongping; Yang, Jun; Chen, Suli Chemical Engineering Journal, Vol. 410 https://doi.org/10.1016/j.cej.2021.128415	journal	April 2021
Novel flame retardant rigid spirocyclic biphosphate based copolymer gel electrolytes for sodium ion batteries with excellent high-temperature performance Zheng, Jinyun; Yang, Yiwan; Li, Wenjie Journal of Materials Chemistry A, Vol. 8, Issue 43 https://doi.org/10.1039/D0TA09490K	journal	January 2020
Intrinsically Safe Gel Polymer Electrolyte Comprising Flame-Retarding Polymer Matrix for Lithium Ion Battery Application Jia, Hao; Onishi, Hitoshi; Wagner, Ralf ACS Applied Materials & Interfaces, Vol. 10, Issue 49 https://doi.org/10.1021/acsami.8b15505	journal	November 2018
Non-flammable polyphosphonate electrolytes Dixon, Brian G.; Morris, R. Scott; Dallek, Steven Journal of Power Sources, Vol. 138, Issue 1-2, p. 274-276 https://doi.org/10.1016/j.jpowsour.2004.06.016	journal	November 2004
Strong Chemical Interaction between Lithium Polysulfides and Flame‐Retardant Polyphosphazene for Lithium–Sulfur Batteries with Enhanced Safety and Electrochemical Performance Chen, Peng; Wu, Zhen; Guo, Tong Advanced Materials, Vol. 33, Issue 9 https://doi.org/10.1002/adma.202007549	journal	January 2021
A flame retarding separator with improved thermal stability for safe lithium-ion batteries Woo, Jung-Je; Nam, Sang Hoon; Seo, Seok-Jun Electrochemistry Communications, Vol. 35 https://doi.org/10.1016/j.elecom.2013.08.005	journal	October 2013
Neoteric Polyimide Nanofiber Encapsulated by the TiO ₂ Armor As the Tough, Highly Wettable, and Flame-Retardant Separator for Advanced Lithium-Ion Batteries Dong, Guoqing; Liu, Bingxue; Kong, Lushi ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 21 https://doi.org/10.1021/acssuschemeng.9b03525	journal	September 2019
A robust flame retardant fluorinated polyimide nanofiber separator for high-temperature lithium–sulfur batteries Luo, Xiang; Lu, Xianbo; Chen, Xiaodong Journal of Materials Chemistry A, Vol. 8, Issue 29 https://doi.org/10.1039/D0TA00439A	journal	January 2020

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