Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Non-intuitive Trends in Flory-Huggins Interaction Parameters in Polyether-Based Polymers

Journal Article · · Macromolecules

Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
~OTHER
DOE Contract Number:
SC0012704
OSTI ID:
1812366
Report Number(s):
BNL-221942-2021-JACI
Journal Information:
Macromolecules, Journal Name: Macromolecules Journal Issue: 14 Vol. 54; ISSN 0024-9297
Country of Publication:
United States
Language:
English

References (68)

Sequential thiol-ene/thiol-ene and thiol-ene/thiol-yne reactions as a route to well-defined mono and bis end-functionalized poly( N -isopropylacrylamide): Thiol-Ene/Thiol-Ene and Thiol-Ene/Thiol-Yne Reactions journal June 2009
Self-Consistent Field Theory and Its Applications book December 2005
Morphological Behavior of Polystyrene -block- Polylactide/Polystyrene -block- Poly(ethylene oxide) Blends journal August 2008
Flory-Huggins parameter χ, from binary mixtures of Lennard-Jones particles to block copolymer melts journal February 2014
Anomalous mixing behavior of polyisobutylene/polypropylene blends: Molecular dynamics simulation study journal May 2004
Structure of PS−PEO Diblock Copolymers in Solution and the Bulk State Probed Using Dynamic Light-Scattering and Small-Angle Neutron-Scattering and Dynamic Mechanical Measurements journal July 1997
Quantifying phase behavior in partially miscible polystyrene/poly(styrene-co-4-bromostyrene) blends journal December 2001
Scaling Relations and Coronal Dimensions in Aqueous Block Polyelectrolyte Micelles journal August 1995
Investigation of polymer-solvent interactions in poly(styrene sulfonate) thin films journal July 2017
Polymerization of Ethylene Oxide, Propylene Oxide, and Other Alkylene Oxides: Synthesis, Novel Polymer Architectures, and Bioconjugation journal December 2015
Entropic Corrections to the Flory-Huggins Theory of Polymer Blends: Architectural and Conformational Effects journal April 1994
Block Copolymer Thermodynamics: Theory and Experiment journal October 1990
From molecular models to system analysis for lithium battery electrolytes journal August 2002
Self-Healing Supramolecular Block Copolymers journal September 2012
Effect of Molecular Weight on the Mechanical and Electrical Properties of Block Copolymer Electrolytes journal June 2007
Study of phase-separation dynamics by use of cell dynamical systems. I. Modeling journal July 1988
Concentration profile for a polymer-polymer interface. 1. Identical chemical composition and molecular weight journal July 1989
Influence of Conformational Asymmetry on Polymer−Polymer Interactions:  An Entropic or Enthalpic Effect? journal September 2002
Predicting Solubility of Small Molecules in Macromolecular Compounds for Nanomedicine Application from Atomistic Simulations journal March 2020
Polymer Properties book December 2009
Prediction of thermodynamic properties of polymer solutions by a group-contribution method journal November 1986
Multifunctional Poly(ethylene glycol)s journal July 2011
Synthesis and characterization of sulfonated poly(ether ether ketone) for proton exchange membranes journal February 2004
Predicting the solubility of mixtures of sugars and their replacers using the Flory–Huggins theory journal January 2017
Simulations of shear-induced morphological transitions in block copolymers journal January 2013
Click-Chemie: diverse chemische Funktionalität mit einer Handvoll guter Reaktionen journal June 2001
Small-Angle X-Ray Scattering from Bulk Block Polymers in Disordered State. Estimation of χ-Values from Accidental Thermal Fluctuations journal June 1985
Poly(ethylene oxide)-based electrolytes for lithium-ion batteries journal January 2015
Polymer Therapeutics: Concepts and Applications journal February 2006
Synthesis and Characterization of Network Single Ion Conductors Based on Comb-Branched Polyepoxide Ethers and Lithium Bis(allylmalonato)borate journal January 2006
Theory of Microphase Separation in Block Copolymers journal November 1980
Theoretical and Practical Approaches for Prediction of Drug–Polymer Miscibility and Solubility journal August 2006
Small angle X-ray scattering from block copolymer/homopolymer mixtures journal February 1993
Pathways toward Electric Field Induced Alignment of Block Copolymers journal October 2002
Block Copolymer Templating Syntheses of Mesoporous Metal Oxides with Large Ordering Lengths and Semicrystalline Framework journal October 1999
Phase Equilibria in Polymer—Solvent Systems 1,2 journal October 1952
Predicting the phase behavior of ABAC tetrablock terpolymers: Sensitivity to Flory–Huggins interaction parameters journal October 2018
Collective and Single-Chain Correlations in Disordered Melts of Symmetric Diblock Copolymers: Quantitative Comparison of Simulations and Theory journal January 2014
Molecular dynamics simulations of athermal polymer blends: Finite system size considerations journal July 1995
Prediction of Phase Behaviors of Polymer–Solvent Mixtures from the COSMO-SAC Activity Coefficient Model journal September 2013
Predicting the Flory-Huggins χ Parameter for Polymers with Stiffness Mismatch from Molecular Dynamics Simulations journal June 2016
Dynamic simulation of diblock copolymer microphase separation journal May 1998
Dissipative particle dynamics: Bridging the gap between atomistic and mesoscopic simulation journal September 1997
Anticorrosive coatings: a review journal January 2009
Poly(allyl glycidyl ether)- block -poly(ethylene oxide): A novel promising polymeric intermediate for the preparation of micellar drug delivery systems: Micellar Drug Delivery Systems journal November 2004
Facile Synthesis of Ordered Mesoporous Alumina and Alumina-Supported Metal Oxides with Tailored Adsorption and Framework Properties journal March 2011
Renormalized one-loop theory of correlations in disordered diblock copolymers journal August 2011
Poly(allyl glycidyl ether)-A versatile and functional polyether platform journal August 2011
Synthesis of Novel Poly(ethylene glycol) Derivatives Having Pendant Amino Groups and Aggregating Behavior of Its Mixture with Fatty Acid in Water journal January 1996
Stable and Unstable Phases of a Linear Multiblock Copolymer Melt journal November 1994
Fluctuation effects in a symmetric diblock copolymer near the order–disorder transition journal May 1990
Phase Separation and Viscoelastic Behavior of Semicompatible Polymer Blends: Poly(vinylidene fluoride)/Poly(methyl methacrylate) System journal March 1981
Scattering functions for disordered two-component polymer systems including block polymers journal February 1987
Advanced functional polymer membranes journal March 2006
The power of thiol-ene chemistry journal February 2010
Predicting Flory-Huggins χ from Simulations journal July 2017
Structure and Thermomechanical Properties of Polyurethane Block Copolymers with Shape Memory Effect journal July 2001
Poly(ethylene glycol- co -allyl glycidyl ether)s: A PEG-Based Modular Synthetic Platform for Multiple Bioconjugation journal March 2011
Safety assessment on polyethylene glycols (PEGs) and their derivatives as used in cosmetic products journal October 2005
Renormalization of the one-loop theory of fluctuations in polymer blends and diblock copolymer melts journal December 2007
Modeling and Simulations of Polymers: A Roadmap journal January 2019
Allyl Glycidyl Ether-Based Polymer Electrolytes for Room Temperature Lithium Batteries journal November 2013
Temperature dependence of the interaction parameter of polystyrene and poly(methyl methacrylate) journal May 1990
Role of intramolecular energy on polyolefin miscibility: Isotactic polypropylene/polyethylene blends journal January 2003
Block copolymer based composition and morphology control in nanostructured hybrid materials for energy conversion and storage: solar cells, batteries, and fuel cells journal January 2011
Self-Consistent Field Theory for Melts of Low-Molecular-Weight Diblock Copolymer journal October 2012
Interdiffusion of polymers across interfaces journal December 1996
Conformational Asymmetry and Polymer-Polymer Thermodynamics journal July 1994