Scalable Synthesis of Multivalent Macromonomers for ROMP

Nguyen, H; Gallagher, N.; Vohidov, F.; Jiang, Y.; Kawamoto, K.; Zhang, H.; Park, J.; Huang, Z.; Ottaviani, M.; Rajca, A.; Johnson, J.

doi:10.1021/acsmacrolett.8b00201

Scalable Synthesis of Multivalent Macromonomers for ROMP

Journal Article · 01 January 2022 · ACS Macro Letters

DOI:https://doi.org/10.1021/acsmacrolett.8b00201· OSTI ID:1808977

Nguyen, H; Gallagher, N.; Vohidov, F.; Jiang, Y.; Kawamoto, K.; Zhang, H.; Park, J.; Huang, Z.; Ottaviani, M.; Rajca, A.; Johnson, J.

Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: ~OTHER

DOE Contract Number:: SC0012704

OSTI ID:: 1808977

Report Number(s):: BNL-221872-2021-JACI

Journal Information:: ACS Macro Letters, Vol. 7, Issue 4

Country of Publication:: United States

Language:: English

References (42)

The Convergence of Synthetic Organic and Polymer Chemistries Hawker, C. J. Science, Vol. 309, Issue 5738 https://doi.org/10.1126/science.1109778	journal	August 2005
Nanostructured functional materials prepared by atom transfer radical polymerization Matyjaszewski, Krzysztof; Tsarevsky, Nicolay V. Nature Chemistry, Vol. 1, Issue 4 https://doi.org/10.1038/nchem.257	journal	June 2009
Applications of Orthogonal “Click” Chemistries in the Synthesis of Functional Soft Materials Iha, Rhiannon K.; Wooley, Karen L.; Nyström, Andreas M. Chemical Reviews, Vol. 109, Issue 11 https://doi.org/10.1021/cr900138t	journal	November 2009
Organocatalytic Ring-Opening Polymerization Kamber, Nahrain E.; Jeong, Wonhee; Waymouth, Robert M. Chemical Reviews, Vol. 107, Issue 12 https://doi.org/10.1021/cr068415b	journal	December 2007
Molecular Bottlebrushes: New Opportunities in Nanomaterials Fabrication Rzayev, Javid ACS Macro Letters, Vol. 1, Issue 9 https://doi.org/10.1021/mz300402x	journal	September 2012
Cylindrical molecular brushes: Synthesis, characterization, and properties Sheiko, Sergei S.; Sumerlin, Brent S.; Matyjaszewski, Krzysztof Progress in Polymer Science, Vol. 33, Issue 7 https://doi.org/10.1016/j.progpolymsci.2008.05.001	journal	July 2008
Stimuli-responsive molecular brushes Lee, Hyung-il; Pietrasik, Joanna; Sheiko, Sergei S. Progress in Polymer Science, Vol. 35, Issue 1-2 https://doi.org/10.1016/j.progpolymsci.2009.11.002	journal	January 2010
Structure, function, self-assembly, and applications of bottlebrush copolymers Verduzco, Rafael; Li, Xianyu; Pesek, Stacy L. Chemical Society Reviews, Vol. 44, Issue 8 https://doi.org/10.1039/C4CS00329B	journal	January 2015
Efficient Synthesis of Narrowly Dispersed Brush Copolymers and Study of Their Assemblies: The Importance of Side Chain Arrangement Xia, Yan; Olsen, Bradley D.; Kornfield, Julia A. Journal of the American Chemical Society, Vol. 131, Issue 51, p. 18525-18532 https://doi.org/10.1021/ja908379q	journal	December 2009
Efficient Synthesis of Narrowly Dispersed Brush Polymers via Living Ring-Opening Metathesis Polymerization of Macromonomers Xia, Yan; Kornfield, Julia A.; Grubbs, Robert H. Macromolecules, Vol. 42, Issue 11, p. 3761-3766 https://doi.org/10.1021/ma900280c	journal	June 2009
One-Pot Tandem Synthesis of a Core−Shell Brush Copolymer from Small Molecule Reactants by Ring-Opening Metathesis and Reversible Addition−Fragmentation Chain Transfer (Co)polymerizations Cheng, Chong; Khoshdel, Ezat; Wooley, Karen L. Macromolecules, Vol. 40, Issue 7 https://doi.org/10.1021/ma0627525	journal	March 2007
Facile syntheses of cylindrical molecular brushes by a sequential RAFT and ROMP “grafting-through” methodology Li, Zhou; Zhang, Ke; Ma, Jun Journal of Polymer Science Part A: Polymer Chemistry, Vol. 47, Issue 20 https://doi.org/10.1002/pola.23626	journal	October 2009
Synthesis of Hetero-Grafted Amphiphilic Diblock Molecular Brushes and Their Self-Assembly in Aqueous Medium Li, Zhou; Ma, Jun; Cheng, Chong Macromolecules, Vol. 43, Issue 3 https://doi.org/10.1021/ma902513n	journal	February 2010
Importance of Macromonomer Quality in the Ring-Opening Metathesis Polymerization of Macromonomers Teo, Yew Chin; Xia, Yan Macromolecules, Vol. 48, Issue 16 https://doi.org/10.1021/acs.macromol.5b01176	journal	August 2015
Bottlebrush Polymer Synthesis by Ring-Opening Metathesis Polymerization: The Significance of the Anchor Group Radzinski, Scott C.; Foster, Jeffrey C.; Chapleski, Robert C. Journal of the American Chemical Society, Vol. 138, Issue 22 https://doi.org/10.1021/jacs.5b13317	journal	May 2016
Providing Oligonucleotides with Steric Selectivity by Brush-Polymer-Assisted Compaction Lu, Xueguang; Tran, Thanh-Huyen; Jia, Fei Journal of the American Chemical Society, Vol. 137, Issue 39 https://doi.org/10.1021/jacs.5b08069	journal	September 2015
Effective Antisense Gene Regulation via Noncationic, Polyethylene Glycol Brushes Lu, Xueguang; Jia, Fei; Tan, Xuyu Journal of the American Chemical Society, Vol. 138, Issue 29 https://doi.org/10.1021/jacs.6b05787	journal	July 2016
Depth-Profiling the Nuclease Stability and the Gene Silencing Efficacy of Brush-Architectured Poly(ethylene glycol)–DNA Conjugates Jia, Fei; Lu, Xueguang; Wang, Dali Journal of the American Chemical Society, Vol. 139, Issue 31 https://doi.org/10.1021/jacs.7b05064	journal	July 2017
Rapid self-assembly of brush block copolymers to photonic crystals Sveinbjornsson, B. R.; Weitekamp, R. A.; Miyake, G. M. Proceedings of the National Academy of Sciences, Vol. 109, Issue 36, p. 14332-14336 https://doi.org/10.1073/pnas.1213055109	journal	August 2012
Precisely Tunable Photonic Crystals From Rapidly Self-Assembling Brush Block Copolymer Blends Miyake, Garret M.; Piunova, Victoria A.; Weitekamp, Raymond A. Angewandte Chemie International Edition, Vol. 51, Issue 45, p. 11246-11248 https://doi.org/10.1002/anie.201205743	journal	September 2012
Using an RNAi Signature Assay To Guide the Design of Three-Drug-Conjugated Nanoparticles with Validated Mechanisms, In Vivo Efficacy, and Low Toxicity Barnes, Jonathan C.; Bruno, Peter M.; Nguyen, Hung V. -T. Journal of the American Chemical Society, Vol. 138, Issue 38 https://doi.org/10.1021/jacs.6b06321	journal	September 2016
Graft-through Synthesis and Assembly of Janus Bottlebrush Polymers from A- Branch -B Diblock Macromonomers Kawamoto, Ken; Zhong, Mingjiang; Gadelrab, Karim R. Journal of the American Chemical Society, Vol. 138, Issue 36 https://doi.org/10.1021/jacs.6b07670	journal	September 2016
Crosslinking-induced morphology change of latex nanoparticles: A study of RAFT-mediated polymerization in aqueous dispersed media using amphiphilic double-brush copolymers as reactive surfactants Li, Yukun; Christian-Tabak, Leela; Fuan, Vivien Li Fong Journal of Polymer Science Part A: Polymer Chemistry, Vol. 52, Issue 22 https://doi.org/10.1002/pola.27387	journal	September 2014
pH-Sensitive brush polymer-drug conjugates by ring-opening metathesis copolymerization Zou, Jiong; Jafr, Goran; Themistou, Efrosyni Chemical Communications, Vol. 47, Issue 15 https://doi.org/10.1039/c0cc05531j	journal	January 2011
Tapered Bottlebrush Polymers: Cone-Shaped Nanostructures by Sequential Addition of Macromonomers Radzinski, Scott C.; Foster, Jeffrey C.; Scannelli, Samantha J. ACS Macro Letters, Vol. 6, Issue 10 https://doi.org/10.1021/acsmacrolett.7b00724	journal	October 2017
Interplay between Molecular Packing, Drug Loading, and Core Cross-Linking in Bottlebrush Copolymer Micelles Unsal, Hande; Onbulak, Sebla; Calik, Filiz Macromolecules, Vol. 50, Issue 4 https://doi.org/10.1021/acs.macromol.6b02182	journal	February 2017
Synthesis and one-dimensional assembly of cylindrical polymer nanoparticles prepared from tricomponent bottlebrush copolymers Onbulak, Sebla; Rzayev, Javid Journal of Polymer Science Part A: Polymer Chemistry, Vol. 55, Issue 23 https://doi.org/10.1002/pola.28771	journal	September 2017
Drug-Loaded, Bivalent-Bottle-Brush Polymers by Graft-through ROMP Johnson, Jeremiah A.; Lu, Ying Y.; Burts, Alan O. Macromolecules, Vol. 43, Issue 24 https://doi.org/10.1021/ma1021506	journal	December 2010
Well-Defined Amphiphilic Double-Brush Copolymers and Their Performance as Emulsion Surfactants Li, Yukun; Zou, Jiong; Das, Biswa P. Macromolecules, Vol. 45, Issue 11 https://doi.org/10.1021/ma300565j	journal	May 2012
Facile Synthesis and Visualization of Janus Double-Brush Copolymers Li, Yukun; Themistou, Efrosyni; Zou, Jiong ACS Macro Letters, Vol. 1, Issue 1 https://doi.org/10.1021/mz200013e	journal	November 2011
“Brush-First” Method for the Parallel Synthesis of Photocleavable, Nitroxide-Labeled Poly(ethylene glycol) Star Polymers Liu, Jenny; Burts, Alan O.; Li, Yongjun Journal of the American Chemical Society, Vol. 134, Issue 39 https://doi.org/10.1021/ja3067176	journal	September 2012
Brush-first and Click: Efficient Synthesis of Nanoparticles that Degrade and Release Doxorubicin in Response to Light Burts, Alan O.; Liao, Longyan; Lu, Ying Y. Photochemistry and Photobiology, Vol. 90, Issue 2 https://doi.org/10.1111/php.12182	journal	November 2013
Brush-First Synthesis of Core-Photodegradable Miktoarm Star Polymers via ROMP: Towards Photoresponsive Self-Assemblies Burts, Alan O.; Gao, Angela X.; Johnson, Jeremiah A. Macromolecular Rapid Communications, Vol. 35, Issue 2 https://doi.org/10.1002/marc.201300618	journal	November 2013
A Convergent Synthetic Platform for Single-Nanoparticle Combination Cancer Therapy: Ratiometric Loading and Controlled Release of Cisplatin, Doxorubicin, and Camptothecin Liao, Longyan; Liu, Jenny; Dreaden, Erik C. Journal of the American Chemical Society, Vol. 136, Issue 16 https://doi.org/10.1021/ja502011g	journal	April 2014
Synthesis of Acid-Labile PEG and PEG-Doxorubicin-Conjugate Nanoparticles via Brush-First ROMP Gao, Angela X.; Liao, Longyan; Johnson, Jeremiah A. ACS Macro Letters, Vol. 3, Issue 9 https://doi.org/10.1021/mz5004097	journal	August 2014
Redox-responsive branched-bottlebrush polymers for in vivo MRI and fluorescence imaging Sowers, Molly A.; McCombs, Jessica R.; Wang, Ying Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6460	journal	November 2014
Nitroxide-Based Macromolecular Contrast Agents with Unprecedented Transverse Relaxivity and Stability for Magnetic Resonance Imaging of Tumors Nguyen, Hung V. -T.; Chen, Qixian; Paletta, Joseph T. ACS Central Science, Vol. 3, Issue 7 https://doi.org/10.1021/acscentsci.7b00253	journal	July 2017
Cyclic β-Peptoids Roy, Olivier; Faure, Sophie; Thery, Vincent Organic Letters, Vol. 10, Issue 5 https://doi.org/10.1021/ol7030763	journal	February 2008
Synthesis and Cell Adhesive Properties of Linear and Cyclic RGD Functionalized Polynorbornene Thin Films Patel, Paresma R.; Kiser, Rosemary Conrad; Lu, Ying Y. Biomacromolecules, Vol. 13, Issue 8 https://doi.org/10.1021/bm300795y	journal	July 2012
Self-Assembly of Symmetric Brush Diblock Copolymers Gu, Weiyin; Huh, June; Hong, Sung Woo ACS Nano, Vol. 7, Issue 3 https://doi.org/10.1021/nn305867d	journal	February 2013
Improving Brush Polymer Infrared One-Dimensional Photonic Crystals via Linear Polymer Additives Macfarlane, Robert J.; Kim, Bongkeun; Lee, Byeongdu Journal of the American Chemical Society, Vol. 136, Issue 50 https://doi.org/10.1021/ja5093562	journal	December 2014
Effects of Grafting Density on Block Polymer Self-Assembly: From Linear to Bottlebrush Lin, Tzu-Pin; Chang, Alice B.; Luo, Shao-Xiong ACS Nano, Vol. 11, Issue 11 https://doi.org/10.1021/acsnano.7b06664	journal	September 2017

Similar Records

Scalable Synthesis of Multivalent Macromonomers for ROMP

Journal Article · 2018 · ACS Macro Letters · OSTI ID:1436783

Nguyen, Hung V. -T.; Gallagher, Nolan M.; Vohidov, Farrukh; +8 more

Graft-through Synthesis and Assembly of Janus Bottlebrush Polymers from A- Branch -B Diblock Macromonomers

Journal Article · 2016 · Journal of the American Chemical Society · OSTI ID:1346236

Kawamoto, Ken; Zhong, Mingjiang; Gadelrab, Karim R.; +4 more

ROMP-CT/NMP Synthesis of Multiblock Copolymers Containing Linear Poly(ethylene) Segments

Journal Article · 2014 · Macromolecules · OSTI ID:1123952

Banik, Steven M.; Monnot, Beau L.; Weber, Ryan L.; +1 more

Related Subjects

99 GENERAL AND MISCELLANEOUS

Scalable Synthesis of Multivalent Macromonomers for ROMP

Citation Formats

References (42)

Similar Records

Related Subjects