Effect of the Co-cation on Cu Speciation in Cu-Exchanged Mordenite and ZSM-5 Catalysts for the Oxidation of Methane to Methanol

Brezicki, G; Zheng, J.; Paolucci, C.; Schlögl, R.; Davis, R.

doi:10.1021/acscatal.1c00543

Effect of the Co-cation on Cu Speciation in Cu-Exchanged Mordenite and ZSM-5 Catalysts for the Oxidation of Methane to Methanol

Journal Article · 01 January 2022 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.1c00543· OSTI ID:1808971

Brezicki, G; Zheng, J.; Paolucci, C.; Schlögl, R.; Davis, R.

Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: ~OTHER

DOE Contract Number:: SC0012704

OSTI ID:: 1808971

Report Number(s):: BNL-221866-2021-JACI

Journal Information:: ACS Catalysis, Vol. 11, Issue 9

Country of Publication:: United States

Language:: English

References (89)

Natural Gas From Shale Bursts Onto the Scene Kerr, R. A. Science, Vol. 328, Issue 5986, p. 1624-1626 https://doi.org/10.1126/science.328.5986.1624	journal	June 2010
Postextraction Separation, On-Board Storage, and Catalytic Conversion of Methane in Natural Gas: A Review Saha, Dipendu; Grappe, Hippolyte A.; Chakraborty, Amlan Chemical Reviews, Vol. 116, Issue 19 https://doi.org/10.1021/acs.chemrev.5b00745	journal	August 2016
Direct Conversion of Methane to Value-Added Chemicals over Heterogeneous Catalysts: Challenges and Prospects Schwach, Pierre; Pan, Xiulian; Bao, Xinhe Chemical Reviews, Vol. 117, Issue 13 https://doi.org/10.1021/acs.chemrev.6b00715	journal	March 2017
Direct conversion of methane to fuels and chemicals Holmen, Anders Catalysis Today, Vol. 142, Issue 1-2, p. 2-8 https://doi.org/10.1016/j.cattod.2009.01.004	journal	April 2009
Methane activation: the past and future Tang, Pei; Zhu, Qingjun; Wu, Zhaoxuan Energy Environ. Sci., Vol. 7, Issue 8 https://doi.org/10.1039/C4EE00604F	journal	January 2014
Electrification and Decarbonization of the Chemical Industry Schiffer, Zachary J.; Manthiram, Karthish Joule, Vol. 1, Issue 1 https://doi.org/10.1016/j.joule.2017.07.008	journal	September 2017
Designing Catalysts for Functionalization of Unactivated C–H Bonds Based on the CH Activation Reaction Hashiguchi, Brian G.; Bischof, Steven M.; Konnick, Michael M. Accounts of Chemical Research, Vol. 45, Issue 6 https://doi.org/10.1021/ar200250r	journal	January 2012
Unconventional Chemistry for Unconventional Natural Gas McFarland, E. Science, Vol. 338, Issue 6105 https://doi.org/10.1126/science.1226840	journal	October 2012
Catalytic conversion of methane to more useful chemicals and fuels: a challenge for the 21st century Lunsford, Jack H. Catalysis Today, Vol. 63, Issue 2-4, p. 165-174 https://doi.org/10.1016/S0920-5861(00)00456-9	journal	December 2000
Direct conversion of methane into oxygenates Otsuka, Kiyoshi; Wang, Ye Applied Catalysis A: General, Vol. 222, Issue 1-2, p. 145-161 https://doi.org/10.1016/S0926-860X(01)00837-7	journal	December 2001
Direct methane conversion routes to chemicals and fuels Alvarez-Galvan, M. C.; Mota, N.; Ojeda, M. Catalysis Today, Vol. 171, Issue 1, p. 15-23 https://doi.org/10.1016/j.cattod.2011.02.028	journal	August 2011
Methane Activation by Heterogeneous Catalysis Horn, Raimund; Schlögl, Robert Catalysis Letters, Vol. 145, Issue 1 https://doi.org/10.1007/s10562-014-1417-z	journal	November 2014
Selective Oxidation of Methane by the Bis(μ-oxo)dicopper Core Stabilized on ZSM-5 and Mordenite Zeolites Groothaert, Marijke H.; Smeets, Pieter J.; Sels, Bert F. Journal of the American Chemical Society, Vol. 127, Issue 5 https://doi.org/10.1021/ja047158u	journal	February 2005
Cu based zeolites: A UV–vis study of the active site in the selective methane oxidation at low temperatures Smeets, Pieter J.; Groothaert, Marijke H.; Schoonheydt, Robert A. Catalysis Today, Vol. 110, Issue 3-4 https://doi.org/10.1016/j.cattod.2005.09.028	journal	December 2005
Cu-ZSM-5 Zeolites for the Formation of Methanol from Methane and Oxygen: Probing the Active Sites and Spectator Species Beznis, Nadzeya V.; Weckhuysen, Bert M.; Bitter, Johannes H. Catalysis Letters, Vol. 138, Issue 1-2 https://doi.org/10.1007/s10562-010-0380-6	journal	June 2010
A [Cu ₂ O] ²⁺ core in Cu-ZSM-5, the active site in the oxidation of methane to methanol Woertink, Julia S.; Smeets, Pieter J.; Groothaert, Marijke H. Proceedings of the National Academy of Sciences, Vol. 106, Issue 45 https://doi.org/10.1073/pnas.0910461106	journal	October 2009
Spectroscopic Definition of the Copper Active Sites in Mordenite: Selective Methane Oxidation Vanelderen, Pieter; Snyder, Benjamin E. R.; Tsai, Ming-Li Journal of the American Chemical Society, Vol. 137, Issue 19 https://doi.org/10.1021/jacs.5b02817	journal	May 2015
Single-site trinuclear copper oxygen clusters in mordenite for selective conversion of methane to methanol Grundner, Sebastian; Markovits, Monica A. C.; Li, Guanna Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8546	journal	June 2015
Effect of Location and Distribution of Al Sites in ZSM-5 on the Formation of Cu-Oxo Clusters Active for Direct Conversion of Methane to Methanol Markovits, Monica A. C.; Jentys, Andreas; Tromp, Moniek Topics in Catalysis, Vol. 59, Issue 17-18 https://doi.org/10.1007/s11244-016-0676-x	journal	August 2016
Stability and reactivity of copper oxo-clusters in ZSM-5 zeolite for selective methane oxidation to methanol Li, Guanna; Vassilev, Peter; Sanchez-Sanchez, Maricruz Journal of Catalysis, Vol. 338 https://doi.org/10.1016/j.jcat.2016.03.014	journal	June 2016
The Nuclearity of the Active Site for Methane to Methanol Conversion in Cu-Mordenite: A Quantitative Assessment Pappas, Dimitrios K.; Martini, Andrea; Dyballa, Michael Journal of the American Chemical Society, Vol. 140, Issue 45 https://doi.org/10.1021/jacs.8b08071	journal	October 2018
Evolution of active sites during selective oxidation of methane to methanol over Cu-CHA and Cu-MOR zeolites as monitored by operando XAS Borfecchia, Elisa; Pappas, Dimitrios K.; Dyballa, Michael Catalysis Today, Vol. 333 https://doi.org/10.1016/j.cattod.2018.07.028	journal	August 2019
Isothermal Cyclic Conversion of Methane into Methanol over Copper-Exchanged Zeolite at Low Temperature Tomkins, Patrick; Mansouri, Ali; Bozbag, Selmi E. Angewandte Chemie International Edition, Vol. 55, Issue 18 https://doi.org/10.1002/anie.201511065	journal	March 2016
Insights into the Speciation of Cu in the Cu-H-Mordenite Catalyst for the Oxidation of Methane to Methanol Brezicki, Gordon; Kammert, James D.; Gunnoe, T. Brent ACS Catalysis, Vol. 9, Issue 6 https://doi.org/10.1021/acscatal.9b00852	journal	April 2019
Importance of Methane Chemical Potential for Its Conversion to Methanol on Cu‐Exchanged Mordenite Zheng, Jian; Lee, Insu; Khramenkova, Elena Chemistry – A European Journal, Vol. 26, Issue 34 https://doi.org/10.1002/chem.202000772	journal	May 2020
Pathways of Methane Transformation over Copper‐Exchanged Mordenite as Revealed by In Situ NMR and IR Spectroscopy Sushkevich, Vitaly L.; Verel, René; Bokhoven, Jeroen A. Angewandte Chemie, Vol. 132, Issue 2 https://doi.org/10.1002/ange.201912668	journal	November 2019
The Effect of the Active-Site Structure on the Activity of Copper Mordenite in the Aerobic and Anaerobic Conversion of Methane into Methanol Sushkevich, Vitaly L.; Palagin, Dennis; van Bokhoven, Jeroen A. Angewandte Chemie International Edition, Vol. 57, Issue 29 https://doi.org/10.1002/anie.201802922	journal	June 2018
Monocopper Active Site for Partial Methane Oxidation in Cu-Exchanged 8MR Zeolites Kulkarni, Ambarish R.; Zhao, Zhi-Jian; Siahrostami, Samira ACS Catalysis, Vol. 6, Issue 10 https://doi.org/10.1021/acscatal.6b01895	journal	September 2016
Particulate methane monooxygenase contains only mononuclear copper centers Ross, Matthew O.; MacMillan, Fraser; Wang, Jingzhou Science, Vol. 364, Issue 6440 https://doi.org/10.1126/science.aav2572	journal	May 2019
Alkane Oxidation: Methane Monooxygenases, Related Enzymes, and Their Biomimetics Wang, Vincent C. -C.; Maji, Suman; Chen, Peter P. -Y. Chemical Reviews, Vol. 117, Issue 13 https://doi.org/10.1021/acs.chemrev.6b00624	journal	February 2017
A tale of two methane monooxygenases Ross, Matthew O.; Rosenzweig, Amy C. JBIC Journal of Biological Inorganic Chemistry, Vol. 22, Issue 2-3 https://doi.org/10.1007/s00775-016-1419-y	journal	November 2016
Copper Active Sites in Biology Solomon, Edward I.; Heppner, David E.; Johnston, Esther M. Chemical Reviews, Vol. 114, Issue 7 https://doi.org/10.1021/cr400327t	journal	January 2014
Oxidation of methane by a biological dicopper centre Balasubramanian, Ramakrishnan; Smith, Stephen M.; Rawat, Swati Nature, Vol. 465, Issue 7294 https://doi.org/10.1038/nature08992	journal	April 2010
Controlled Oxidation of Hydrocarbons by the Membrane-Bound Methane Monooxygenase: The Case for a Tricopper Cluster Chan, Sunney I.; Yu, Steve S. -F. Accounts of Chemical Research, Vol. 41, Issue 8 https://doi.org/10.1021/ar700277n	journal	August 2008
Zeolite Surface Methoxy Groups as Key Intermediates in the Stepwise Conversion of Methane to Methanol Dyballa, Michael; Thorshaug, Knut; Pappas, Dimitrios K. ChemCatChem, Vol. 11, Issue 20 https://doi.org/10.1002/cctc.201901315	journal	September 2019
High-throughput operando -ready X-ray absorption spectroscopy flow reactor cell for powder samples Kammert, James D.; Brezicki, Gordon; Acevedo-Esteves, Raul Review of Scientific Instruments, Vol. 91, Issue 1 https://doi.org/10.1063/1.5124301	journal	January 2020
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Accurate and simple analytic representation of the electron-gas correlation energy Perdew, John P.; Wang, Yue Physical Review B, Vol. 45, Issue 23, p. 13244-13249 https://doi.org/10.1103/PhysRevB.45.13244	journal	June 1992
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Reaction Conditions of Methane-to-Methanol Conversion Affect the Structure of Active Copper Sites Alayon, Evalyn Mae C.; Nachtegaal, Maarten; Bodi, Andras ACS Catalysis, Vol. 4, Issue 1 https://doi.org/10.1021/cs400713c	journal	December 2013
Determination of the electronic and geometric structure of Cu sites during methane conversion over Cu-MOR with X-ray absorption spectroscopy Alayon, Evalyn Mae C.; Nachtegaal, Maarten; Kleymenov, Evgeny Microporous and Mesoporous Materials, Vol. 166 https://doi.org/10.1016/j.micromeso.2012.04.054	journal	January 2013
Oxygen Precursor to the Reactive Intermediate in Methanol Synthesis by Cu-ZSM-5 Smeets, Pieter J.; Hadt, Ryan G.; Woertink, Julia S. Journal of the American Chemical Society, Vol. 132, Issue 42 https://doi.org/10.1021/ja106283u	journal	October 2010
Formation of [Cu ₂ O ₂ ] ²⁺ and [Cu ₂ O] ²⁺ toward C–H Bond Activation in Cu-SSZ-13 and Cu-SSZ-39 Ipek, Bahar; Wulfers, Matthew J.; Kim, Hacksung ACS Catalysis, Vol. 7, Issue 7 https://doi.org/10.1021/acscatal.6b03005	journal	May 2017
UV–Vis and Photoluminescence Spectroscopy to Understand the Coordination of Cu Cations in the Zeolite SSZ-13 Göltl, Florian; Conrad, Sabrina; Wolf, Patrick Chemistry of Materials, Vol. 31, Issue 23 https://doi.org/10.1021/acs.chemmater.9b01439	journal	November 2019
Dynamic CuII/CuI speciation in Cu-CHA catalysts by in situ Diffuse Reflectance UV–vis-NIR spectroscopy Negri, Chiara; Signorile, Matteo; Porcaro, Natale G. Applied Catalysis A: General, Vol. 578 https://doi.org/10.1016/j.apcata.2019.03.018	journal	May 2019
Consequences of exchange-site heterogeneity and dynamics on the UV-visible spectrum of Cu-exchanged SSZ-13 Li, Hui; Paolucci, Christopher; Khurana, Ishant Chemical Science, Vol. 10, Issue 8 https://doi.org/10.1039/C8SC05056B	journal	January 2019
Conversion of methane to methanol on copper-containing small-pore zeolites and zeotypes Wulfers, M. J.; Teketel, S.; Ipek, B. Chemical Communications, Vol. 51, Issue 21 https://doi.org/10.1039/C4CC09645B	journal	January 2015
Distinct activation of Cu-MOR for direct oxidation of methane to methanol Kim, Younhwa; Kim, Tae Yong; Lee, Hyunjoo Chemical Communications, Vol. 53, Issue 29 https://doi.org/10.1039/C7CC00467B	journal	January 2017
Solid-State Ion-Exchanged Cu/Mordenite Catalysts for the Direct Conversion of Methane to Methanol Le, Ha V.; Parishan, Samira; Sagaltchik, Anton ACS Catalysis, Vol. 7, Issue 2 https://doi.org/10.1021/acscatal.6b02372	journal	January 2017
Characterization of Cu-exchanged SSZ-13: a comparative FTIR, UV-Vis, and EPR study with Cu-ZSM-5 and Cu-β with similar Si/Al and Cu/Al ratios Giordanino, Filippo; Vennestrøm, Peter N. R.; Lundegaard, Lars F. Dalton Transactions, Vol. 42, Issue 35 https://doi.org/10.1039/c3dt50732g	journal	January 2013
Synthesis of single-site copper catalysts for methane partial oxidation Grundner, S.; Luo, W.; Sanchez-Sanchez, M. Chemical Communications, Vol. 52, Issue 12 https://doi.org/10.1039/C5CC08371K	journal	January 2016
Comparative Study of Diverse Copper Zeolites for the Conversion of Methane into Methanol Park, Min Bum; Ahn, Sang Hyun; Mansouri, Ali ChemCatChem, Vol. 9, Issue 19 https://doi.org/10.1002/cctc.201700768	journal	August 2017
Strategies for the Direct Catalytic Valorization of Methane Using Heterogeneous Catalysis: Challenges and Opportunities Olivos-Suarez, Alma I.; Szécsényi, Àgnes; Hensen, Emiel J. M. ACS Catalysis, Vol. 6, Issue 5 https://doi.org/10.1021/acscatal.6b00428	journal	April 2016
A density functional theory study of C–H bond activation of methane on a bridge site of M–O–M-ZSM-5 Clusters (M=Au, Ag, Fe and Cu) Kurnaz, Emine; Fellah, Mehmet Ferdi; Onal, Isik Microporous and Mesoporous Materials, Vol. 138, Issue 1-3 https://doi.org/10.1016/j.micromeso.2010.09.028	journal	February 2011
Copper–Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity Elwell, Courtney E.; Gagnon, Nicole L.; Neisen, Benjamin D. Chemical Reviews, Vol. 117, Issue 3 https://doi.org/10.1021/acs.chemrev.6b00636	journal	January 2017
EXAFS wavelet transform analysis of Cu-MOR zeolites for the direct methane to methanol conversion Martini, Andrea; Signorile, Matteo; Negri, Chiara Physical Chemistry Chemical Physics, Vol. 22, Issue 34 https://doi.org/10.1039/D0CP01257B	journal	January 2020
Wavelet analysis of a Cu-oxo zeolite EXAFS simulated spectrum Martini, Andrea; Pankin, Ilia A.; Marsicano, Anna Radiation Physics and Chemistry, Vol. 175 https://doi.org/10.1016/j.radphyschem.2019.05.023	journal	October 2020
Identifying Cu-oxo species in Cu-zeolites by XAS: A theoretical survey by DFT-assisted XANES simulation and EXAFS wavelet transform Pankin, Ilia A.; Martini, Andrea; Lomachenko, Kirill A. Catalysis Today, Vol. 345 https://doi.org/10.1016/j.cattod.2019.09.032	journal	April 2020
Methane to Acetic Acid over Cu-Exchanged Zeolites: Mechanistic Insights from a Site-Specific Carbonylation Reaction Narsimhan, Karthik; Michaelis, Vladimir K.; Mathies, Guinevere Journal of the American Chemical Society, Vol. 137, Issue 5 https://doi.org/10.1021/ja5106927	journal	January 2015
Copper(I) and Copper(II) Coordination Structure under Hydrothermal Conditions at 325 °C: An X-ray Absorption Fine Structure and Molecular Dynamics Study Fulton, John L.; Hoffmann, Markus M.; Darab, John G. The Journal of Physical Chemistry A, Vol. 104, Issue 49 https://doi.org/10.1021/jp001949a	journal	December 2000
Bis(μ-oxo) versus mono(μ-oxo)dicopper cores in a zeolite for converting methane to methanol: an in situ XAS and DFT investigation Alayon, Evalyn Mae C.; Nachtegaal, Maarten; Bodi, Andras Physical Chemistry Chemical Physics, Vol. 17, Issue 12 https://doi.org/10.1039/C4CP03226H	journal	January 2015
Bis(μ-oxo)dicopper in Cu-ZSM-5 and Its Role in the Decomposition of NO: A Combined in Situ XAFS, UV−Vis−Near-IR, and Kinetic Study Groothaert, Marijke H.; van Bokhoven, Jeroen A.; Battiston, Andrea A. Journal of the American Chemical Society, Vol. 125, Issue 25 https://doi.org/10.1021/ja029684w	journal	June 2003
Methane to Methanol: Structure–Activity Relationships for Cu-CHA Pappas, Dimitrios K.; Borfecchia, Elisa; Dyballa, Michael Journal of the American Chemical Society, Vol. 139, Issue 42 https://doi.org/10.1021/jacs.7b06472	journal	October 2017
Formation of Active Cu-oxo Clusters for Methane Oxidation in Cu-Exchanged Mordenite Ikuno, Takaaki; Grundner, Sebastian; Jentys, Andreas The Journal of Physical Chemistry C, Vol. 123, Issue 14 https://doi.org/10.1021/acs.jpcc.8b10293	journal	March 2019
Revisiting the nature of Cu sites in the activated Cu-SSZ-13 catalyst for SCR reaction Borfecchia, E.; Lomachenko, K. A.; Giordanino, F. Chemical Science, Vol. 6, Issue 1 https://doi.org/10.1039/C4SC02907K	journal	January 2015
Coordination chemistry and reactivity of copper in zeolites Vanelderen, Pieter; Vancauwenbergh, Julie; Sels, Bert F. Coordination Chemistry Reviews, Vol. 257, Issue 2 https://doi.org/10.1016/j.ccr.2012.07.008	journal	January 2013
Local Spin Density Functional Theory Study of Copper Ion-Exchanged ZSM-5 Trout, Bernhardt L.; Chakraborty, Arup K.; Bell, Alexis T. The Journal of Physical Chemistry, Vol. 100, Issue 10 https://doi.org/10.1021/jp9524744	journal	January 1996
Electron Paramagnetic Resonance Studies of Copper Ion-Exchanged ZSM-5 Larsen, Sarah C.; Aylor, Adam; Bell, Alexis T. The Journal of Physical Chemistry, Vol. 98, Issue 44 https://doi.org/10.1021/j100095a039	journal	November 1994
Autoreduction of Copper in Zeolites: Role of Topology, Si/Al Ratio, and Copper Loading Sushkevich, Vitaly L.; Smirnov, Andrei V.; van Bokhoven, Jeroen A. The Journal of Physical Chemistry C, Vol. 123, Issue 15 https://doi.org/10.1021/acs.jpcc.9b00986	journal	March 2019
On the role of strength and location of Brønsted acid sites for ethylamine synthesis on mordenite catalysts Veefkind, Victor A.; Smidt, Martin L.; Lercher, Johannes A. Applied Catalysis A: General, Vol. 194-195 https://doi.org/10.1016/S0926-860X(99)00378-6	journal	March 2000
Effects of Si/Al ratio on Cu/SSZ-13 NH3-SCR catalysts: Implications for the active Cu species and the roles of Brønsted acidity Gao, Feng; Washton, Nancy M.; Wang, Yilin Journal of Catalysis, Vol. 331 https://doi.org/10.1016/j.jcat.2015.08.004	journal	November 2015
The Stability of Copper Oxo Species in Zeolite Frameworks Vilella, Laia; Studt, Felix European Journal of Inorganic Chemistry, Vol. 2016, Issue 10 https://doi.org/10.1002/ejic.201501270	journal	March 2016
Theoretical Insights into the Selective Oxidation of Methane to Methanol in Copper-Exchanged Mordenite Zhao, Zhi-Jian; Kulkarni, Ambarish; Vilella, Laia ACS Catalysis, Vol. 6, Issue 6 https://doi.org/10.1021/acscatal.6b00440	journal	May 2016
Dioxygen Activation on Cu-MOR Zeolite: Theoretical Insights into the Formation of Cu ₂ O and Cu ₃ O ₃ Active Species Mahyuddin, M. Haris; Tanaka, Takahiro; Staykov, Aleksandar Inorganic Chemistry, Vol. 57, Issue 16 https://doi.org/10.1021/acs.inorgchem.8b01329	journal	April 2018
First-Principles Study of Oxidation State and Coordination of Cu-Dimers in Cu-SSZ-13 during Methane-to-Methanol Reaction Conditions Engedahl, Unni; Grönbeck, Henrik; Hellman, Anders The Journal of Physical Chemistry C, Vol. 123, Issue 43 https://doi.org/10.1021/acs.jpcc.9b07954	journal	October 2019
[Cu ₂ O] ²⁺ Active Site Formation in Cu–ZSM-5: Geometric and Electronic Structure Requirements for N ₂ O Activation Tsai, Ming-Li; Hadt, Ryan G.; Vanelderen, Pieter Journal of the American Chemical Society, Vol. 136, Issue 9 https://doi.org/10.1021/ja4113808	journal	February 2014
Methane Activation on H-ZSM-5 Zeolite with Low Copper Loading. The Nature of Active Sites and Intermediates Identified with the Combination of Spectroscopic Methods Gabrienko, Anton A.; Yashnik, Svetlana A.; Kolganov, Alexander A. Inorganic Chemistry, Vol. 59, Issue 3 https://doi.org/10.1021/acs.inorgchem.9b03462	journal	January 2020
Selective anaerobic oxidation of methane enables direct synthesis of methanol Sushkevich, Vitaly L.; Palagin, Dennis; Ranocchiari, Marco Science, Vol. 356, Issue 6337 https://doi.org/10.1126/science.aam9035	journal	May 2017
Mechanistic Insights on the Direct Conversion of Methane into Methanol over Cu/Na–ZSM-5 Zeolite: Evidence from EPR and Solid-State NMR Wu, Jian-Feng; Gao, Xu-Dong; Wu, Long-Min ACS Catalysis, Vol. 9, Issue 9 https://doi.org/10.1021/acscatal.9b02898	journal	August 2019
Methane-to-Methanol: Activity Descriptors in Copper-Exchanged Zeolites for the Rational Design of Materials Sushkevich, Vitaly L.; van Bokhoven, Jeroen A. ACS Catalysis, Vol. 9, Issue 7 https://doi.org/10.1021/acscatal.9b01534	journal	May 2019
Cu-Erionite Zeolite Achieves High Yield in Direct Oxidation of Methane to Methanol by Isothermal Chemical Looping Zhu, Jie; Sushkevich, Vitaly L.; Knorpp, Amy J. Chemistry of Materials, Vol. 32, Issue 4 https://doi.org/10.1021/acs.chemmater.9b04223	journal	January 2020
Roles of Zeolite Confinement and Cu–O–Cu Angle on the Direct Conversion of Methane to Methanol by [Cu ₂ (μ-O)] ²⁺ -Exchanged AEI, CHA, AFX, and MFI Zeolites Mahyuddin, M. Haris; Staykov, Aleksandar; Shiota, Yoshihito ACS Catalysis, Vol. 7, Issue 6 https://doi.org/10.1021/acscatal.7b00588	journal	April 2017
Theoretical Overview of Methane Hydroxylation by Copper–Oxygen Species in Enzymatic and Zeolitic Catalysts Mahyuddin, M. Haris; Shiota, Yoshihito; Staykov, Aleksandar Accounts of Chemical Research, Vol. 51, Issue 10 https://doi.org/10.1021/acs.accounts.8b00236	journal	September 2018
Methane Partial Oxidation over [Cu ₂ (μ-O)] ²⁺ and [Cu ₃ (μ-O) ₃ ] ²⁺ Active Species in Large-Pore Zeolites Mahyuddin, M. Haris; Tanaka, Takahiro; Shiota, Yoshihito ACS Catalysis, Vol. 8, Issue 2 https://doi.org/10.1021/acscatal.7b03389	journal	January 2018
Modeling C–H Bond Activation and Oxidations of Alkanes over Cu–MOR Using First-Principles Methods Xu, Jiayi; Liu, Bin The Journal of Physical Chemistry C, Vol. 123, Issue 16 https://doi.org/10.1021/acs.jpcc.9b00194	journal	April 2019
Nature of the Surface Intermediates Formed from Methane on Cu-ZSM-5 Zeolite: A Combined Solid-State Nuclear Magnetic Resonance and Density Functional Theory Study Kolganov, Alexander A.; Gabrienko, Anton A.; Yashnik, Svetlana A. The Journal of Physical Chemistry C, Vol. 124, Issue 11 https://doi.org/10.1021/acs.jpcc.0c00311	journal	February 2020
Effects of single and double active sites of Cu oxide clusters over the MFI zeolite for direct conversion of methane to methanol: DFT calculations Nunthakitgoson, Watinee; Thivasasith, Anawat; Maihom, Thana Physical Chemistry Chemical Physics, Vol. 23, Issue 3 https://doi.org/10.1039/D0CP05435F	journal	January 2021

Similar Records

Insights into the Speciation of Cu in the Cu-H-Mordenite Catalyst for the Oxidation of Methane to Methanol

Journal Article · 2020 · ACS Catalysis · OSTI ID:1688557

Brezicki, G; Kammert, J.; Gunnoe, B.; +2 more

Effects of Zeolite Structure And Composition on the Synthesis of Dimethyl Carbonate By Oxidative Carbonylation of Methanol on Cu-Exchanged Y, ZSM-5, And Mordenite

Journal Article · 2009 · J. Cat. 251:443,2007 · OSTI ID:953914

Zhang, Y; Briggs, D N; Smit, E de; +1 more

Total oxidation of methane on transition metal cations stabilized in a matrix of ZSM-5 type zeolites: III. A Co/ZSM-5 system

Journal Article · 1994 · Kinetics and Catalysis · OSTI ID:62475

Goryashchenko, S S; Alimov, M A; Fedorovskaya, E A; +2 more

Related Subjects

99 GENERAL AND MISCELLANEOUS

Effect of the Co-cation on Cu Speciation in Cu-Exchanged Mordenite and ZSM-5 Catalysts for the Oxidation of Methane to Methanol

Citation Formats

References (89)

Similar Records

Related Subjects