Evaluating the microstructure and origin of nonmetallic inclusions in as-cast U-10 Mo fuel

Kautz, Elizabeth J.; Shahrezaei, Sina; Athon, Matthew T.; Frank, Michael A.; Schemer-Kohrn, Alan L.; Soulami, Ayoub; Lavender, Curt A.; Joshi, Vineet V.; Devaraj, Arun

doi:10.1016/j.jnucmat.2021.152949

Evaluating the microstructure and origin of nonmetallic inclusions in as-cast U-10 Mo fuel

Journal Article · 01 October 2021 · Journal of Nuclear Materials

DOI:https://doi.org/10.1016/j.jnucmat.2021.152949· OSTI ID:1808549

Kautz, Elizabeth J. ^[1]; Shahrezaei, Sina ^[1]; Athon, Matthew T. ^[1]; Frank, Michael A. ^[1]; Schemer-Kohrn, Alan L. ^[1]; ^[1]; Lavender, Curt A. ^[1]; ^[1]; ^[1]

BATTELLE (PACIFIC NW LAB)

Low enriched uranium alloyed with 10 wt% molybdenum (U-10Mo) has been identified as a promising alternative to highly enriched uranium oxide dispersion fuels for use in high performance research and test reactors. Manufacturing U-10Mo alloy fuel involves several complex thermomechanical processing steps and understanding the microstructure and its evolution throughout the various fabrication steps is critical to enable the deployment of a reliable fuel production capability. Nonmetallic inclusions are often found in U castings and may affect subsequent fuel processing steps and microstructure evolution. Yet the origin of these inclusions is not well established. To elucidate the origin and formation mechanisms, nonmetallic inclusions in U-10Mo castings were characterized on sub-nanometer to millimeter scales. Inclusion distribution, morphology, size, and composition were characterized. Inclusions were estimated to comprise ~ 0.4 % of the fuel (by area), were identified at both grain boundaries and grain interiors, and were found to have varying morphologies (e.g., core-shell, elongated, nanoscale). All inclusions were either uranium carbides or oxides, or a combination of the two (i.e., dual-phase inclusions). Analysis of inclusions via atom probe tomography (APT) revealed that carbides and oxides were hypostoichiometric, with minor amounts of additional impurity elements present (e.g., Si, H). All inclusions analyzed were found to be enriched to ~20 at. % 235U, indicating that the inclusions formed during the downblending of HEU metal with depleted uranium via the casting process.

Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1808549

Report Number(s):: PNNL-SA-158125

Journal Information:: Journal of Nuclear Materials, Vol. 554

Country of Publication:: United States

Language:: English

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casting
metallic nuclear fuel
U-10Mo
uranium-molybdenum
low-enriched uranium
LEU
atom probe tomography

Evaluating the microstructure and origin of nonmetallic inclusions in as-cast U-10 Mo fuel

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