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Title: Elucidation of the Active Phase and Deactivation Mechanisms of Chromium Nitride in the Electrochemical Nitrogen Reduction Reaction

Abstract

Not provided.

Authors:
 [1]; ORCiD logo [1];  [1];  [1]; ; ;  [2]; ORCiD logo [1]; ORCiD logo [1]
  1. Center for Catalytic Science and Technology, Department of Chemical and Biomolecular Engineering, University of Delaware, 150 Academy Street, Newark, Delaware 19718, United States
  2. Department of Chemical Engineering, Columbia University, New York, New York 10027, United States
Publication Date:
Research Org.:
Univ. of Delaware, Newark, DE (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1803032
DOE Contract Number:  
SC0016537
Resource Type:
Journal Article
Journal Name:
Journal of Physical Chemistry. C
Additional Journal Information:
Journal Volume: 123; Journal Issue: 39; Journal ID: ISSN 1932-7447
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
Chemistry; Science & Technology - Other Topics; Materials Science

Citation Formats

Nash, Jared, Yang, Xuan, Anibal, Jacob, Dunwell, Marco, Yao, Siyu, Attenkofer, Klaus, Chen, Jingguang G., Yan, Yushan, and Xu, Bingjun. Elucidation of the Active Phase and Deactivation Mechanisms of Chromium Nitride in the Electrochemical Nitrogen Reduction Reaction. United States: N. p., 2019. Web. doi:10.1021/acs.jpcc.9b05436.
Nash, Jared, Yang, Xuan, Anibal, Jacob, Dunwell, Marco, Yao, Siyu, Attenkofer, Klaus, Chen, Jingguang G., Yan, Yushan, & Xu, Bingjun. Elucidation of the Active Phase and Deactivation Mechanisms of Chromium Nitride in the Electrochemical Nitrogen Reduction Reaction. United States. https://doi.org/10.1021/acs.jpcc.9b05436
Nash, Jared, Yang, Xuan, Anibal, Jacob, Dunwell, Marco, Yao, Siyu, Attenkofer, Klaus, Chen, Jingguang G., Yan, Yushan, and Xu, Bingjun. 2019. "Elucidation of the Active Phase and Deactivation Mechanisms of Chromium Nitride in the Electrochemical Nitrogen Reduction Reaction". United States. https://doi.org/10.1021/acs.jpcc.9b05436.
@article{osti_1803032,
title = {Elucidation of the Active Phase and Deactivation Mechanisms of Chromium Nitride in the Electrochemical Nitrogen Reduction Reaction},
author = {Nash, Jared and Yang, Xuan and Anibal, Jacob and Dunwell, Marco and Yao, Siyu and Attenkofer, Klaus and Chen, Jingguang G. and Yan, Yushan and Xu, Bingjun},
abstractNote = {Not provided.},
doi = {10.1021/acs.jpcc.9b05436},
url = {https://www.osti.gov/biblio/1803032}, journal = {Journal of Physical Chemistry. C},
issn = {1932-7447},
number = 39,
volume = 123,
place = {United States},
year = {Tue Sep 03 00:00:00 EDT 2019},
month = {Tue Sep 03 00:00:00 EDT 2019}
}

Works referenced in this record:

How a century of ammonia synthesis changed the world
journal, September 2008


Ammonia synthesis: The bellwether reaction in heterogeneous catalysis
journal, September 1994


Catalytic Synthesis of Ammonia—A “Never-Ending Story”?
journal, May 2003


Electrochemical Synthesis of Ammonia in Solid Electrolyte Cells
journal, January 2014


Mechanistic Insights into Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride Nanoparticles
journal, September 2018


Electrochemical Ammonia Synthesis and Ammonia Fuel Cells
journal, December 2018


Electrochemical Synthesis of Ammonia: A Low Pressure, Low Temperature Approach
journal, January 2015


Ammonia synthesis from N 2 and H 2 O using a lithium cycling electrification strategy at atmospheric pressure
journal, January 2017


Ammonia Synthesis at Atmospheric Pressure
journal, October 1998


Preparation of double-doped BaCeO 3 and its application in the synthesis of ammonia at atmospheric pressure
journal, January 2007


Protonic conduction in Ca2+-doped La2M2O7 (M=Ce, Zr) with its application to ammonia synthesis electrochemically
journal, August 2005


Electrochemical synthesis of ammonia at atmospheric pressure and low temperature in a solid polymer electrolyte cell
journal, January 2000


Ammonia as a Suitable Fuel for Fuel Cells
journal, August 2014


Direct Ammonia Alkaline Anion-Exchange Membrane Fuel Cells
journal, January 2010


Synthesis of ammonia directly from air and water at ambient temperature and pressure
journal, January 2013


Electrochemical Nitrogen Reduction Reaction on Noble Metal Catalysts in Proton and Hydroxide Exchange Membrane Electrolyzers
journal, January 2017


Ammonia Electrosynthesis with High Selectivity under Ambient Conditions via a Li + Incorporation Strategy
journal, July 2017


Ammonia synthesis at low temperatures
journal, March 2000


A theoretical evaluation of possible transition metal electro-catalysts for N 2 reduction
journal, January 2012


The Challenge of Electrochemical Ammonia Synthesis: A New Perspective on the Role of Nitrogen Scaling Relations
journal, June 2015


High-performance artificial nitrogen fixation at ambient conditions using a metal-free electrocatalyst
journal, August 2018


Electrochemical Synthesis of Ammonia from Water and Nitrogen in Ethylenediamine under Ambient Temperature and Pressure
journal, January 2016


Electro-synthesis of ammonia from nitrogen at ambient temperature and pressure in ionic liquids
journal, January 2017


Electroreduction of N 2 to Ammonia at Ambient Conditions on Mononitrides of Zr, Nb, Cr, and V: A DFT Guide for Experiments
journal, December 2015


Highly efficient electrochemical ammonia synthesis via nitrogen reduction reactions on a VN nanowire array under ambient conditions
journal, January 2018


Efficient Electrochemical N 2 Reduction to NH 3 on MoN Nanosheets Array under Ambient Conditions
journal, July 2018


Metal Nitride and Metal Carbide Nanoparticles by a Soft Urea Pathway
journal, November 2009


Recent advances in metal nitrides as high-performance electrode materials for energy storage devices
journal, January 2015


Correlating hydrogen oxidation and evolution activity on platinum at different pH with measured hydrogen binding energy
journal, January 2015


Experimental Methods for Quantifying the Activity of Platinum Electrocatalysts for the Oxygen Reduction Reaction
journal, August 2010


Exchange current density of the hydrogen oxidation reaction on Pt/C in polymer solid base electrolyte
journal, December 2015


Hydrogen Oxidation and Evolution Reaction Kinetics on Carbon Supported Pt, Ir, Rh, and Pd Electrocatalysts in Acidic Media
journal, November 2014


Manipulating Water in High-Performance Hydroxide Exchange Membrane Fuel Cells through Asymmetric Humidification and Wetproofing
journal, January 2015


A study on corrosion resistance characteristics of PVD Cr-N coated steels by electrochemical method
journal, February 2002


X-ray photoelectron spectroscopy studies of high-dose nitrogen ion implanted-chromium: a possibility of a standard material for chemical state analysis
journal, January 1989


XPS investigations of chromium nitride thin films
journal, October 2005


XPS study of the supported CrO3/SiO2 system: Elimination of the oxide-support contribution from the Cr 2p band
journal, January 1993


Comparison of surface oxidation of titanium nitride and chromium nitride films studied by x-ray absorption and photoelectron spectroscopy
journal, September 1997


LEEIXS and XPS studies of reactive unbalanced magnetron sputtered chromium oxynitride thin films with air
journal, February 2004


Low-energy implantation and sputtering of TiO2 by nitrogen and argon and the electrochemical reoxidation
journal, September 1991


Surface characterisation of plasma-nitrided titanium: an XPS study
journal, April 1995


XPS studies with ammonia synthesis catalysts
journal, July 1979