Pyridine-d5 as a 2H NMR probe for investigation of macrostructure and pore shapes in a layered Sn(iv) phosphonate–phosphate material

Bakhmutov, Vladimir I.; Elliott, Douglas W.; Wylie, Gregory P.; Clearfield, Abraham; Contreras-Ramirez, Aida; Zhou, Hong-Cai

doi:10.1039/c9cc09254d

Title: Pyridine-d₅ as a ²H NMR probe for investigation of macrostructure and pore shapes in a layered Sn(iv) phosphonate–phosphate material

Journal Article · Fri Feb 21 00:00:00 EST 2020 · ChemComm

DOI:https://doi.org/10.1039/c9cc09254d· OSTI ID:1801184

^[1]; Elliott, Douglas W. ^[1]; Wylie, Gregory P. ^[1]; Clearfield, Abraham ^[1];

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Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry
Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry. Dept. of Materials Science and Engineering

Isotropic and anisotropic motions and molecular states of pyridine-d₅, adsorbed on the surface within the pores of a layered Sn(IV) phosphonate–phosphate material (1) have been characterized thermodynamically and kinetically by solid-state NMR. The data obtained provide formulation of macrostructure and shapes of pores in 1.

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Research Organization:: Texas A & M Univ., College Station, TX (United States)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE), Nuclear Energy University Program (NEUP); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: NE0000746; SC0017864

OSTI ID:: 1801184

Alternate ID(s):: OSTI ID: 1602078

Journal Information:: ChemComm, Vol. 56, Issue 25; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 1 work

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Title: Pyridine-d5 as a 2H NMR probe for investigation of macrostructure and pore shapes in a layered Sn(iv) phosphonate–phosphate material

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Title: Pyridine-d₅ as a ²H NMR probe for investigation of macrostructure and pore shapes in a layered Sn(iv) phosphonate–phosphate material