Enhanced visible-light-assisted peroxymonosulfate activation on cobalt-doped mesoporous iron oxide for orange II degradation

Achola, Laura A.; Ghebrehiwet, Aaron; Macharia, John; Kerns, Peter; He, Junkai; Fee, Jared; Tinson, Chelsey; Shi, Jianhang; March, Seth; Jain, Menka; Suib, Steven L.

doi:10.1016/j.apcatb.2019.118332

Title: Enhanced visible-light-assisted peroxymonosulfate activation on cobalt-doped mesoporous iron oxide for orange II degradation

Journal Article · Wed Apr 01 00:00:00 EDT 2020 · Applied Catalysis B: Environmental

DOI:https://doi.org/10.1016/j.apcatb.2019.118332· OSTI ID:1800623

Achola, Laura A. ^[1]; Ghebrehiwet, Aaron ^[1]; Macharia, John ^[1]; Kerns, Peter ^[1]; He, Junkai ^[1]; Fee, Jared ^[1]; Tinson, Chelsey ^[1]; Shi, Jianhang ^[1]; March, Seth ^[1]; Jain, Menka ^[1];

^[1]

Univ. of Connecticut, Storrs, CT (United States)

Sulfate radical-based advanced oxidation processes (SR-AOP) attracted a lot of attention due to their capability and adaptability in wastewater treatment. Although heterogeneous cobalt-based catalysts have been extensively studied and have emerged superior for peroxymonosulfate (PMS) activation, leaching of cobalt is still a major concern. Herein, we report a photo-assisted PMS activation approach using cobalt doped mesoporous iron oxide with exceptional activity and stability up to 7 cycles with very low cobalt leaching (0.5 ppm). The highest activity was obtained by 1 mol % cobalt doped mesoporous iron oxide. Orange II dye was completely degraded by the reactive oxygen species (ROS) generated under visible light irradiation within 1 min. ROS were evaluated using two distinct techniques (Fluorescence probes and Electron Paramagnetic Resonance (EPR). ROS quenching experiments were also used to highlight the dominant pathway. This study correlates the structural and electronic changes induced with cobalt doping to the exceptional activity.

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Research Organization:: Univ. of Connecticut, Storrs, CT (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: FG02-86ER13622

OSTI ID:: 1800623

Journal Information:: Applied Catalysis B: Environmental, Vol. 263, Issue C; ISSN 0926-3373

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Chemistry
Engineering
Cobalt-doped iron oxide
Mesoporous material
Peroxymonosulfate activation
Reactive oxygen species
Visible-light-assisted

Title: Enhanced visible-light-assisted peroxymonosulfate activation on cobalt-doped mesoporous iron oxide for orange II degradation

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