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Title: Engineering Local Coordination Environments of Atomically Dispersed and Heteroatom-Coordinated Single Metal Site Electrocatalysts for Clean Energy-Conversion

Journal Article · · Advanced Energy Materials
 [1];  [2];  [1];  [2];  [1]; ORCiD logo [2]
  1. Faculty of Chemical Engineering Yunnan Provincial Key Laboratory of Energy Saving in Phosphorus Chemical Engineering and New Phosphorus Materials The Higher Educational Key Laboratory for Phosphorus Chemical Engineering of Yunnan Province Kunming University of Science and Technology Kunming 650500 China
  2. Department of Chemical and Biological Engineering University at Buffalo The State University of New York Buffalo NY 14260 USA

Not provided.

Research Organization:
Giner, Inc., Newton, MA (United States); Carnegie Mellon Univ., Pittsburgh, PA (United States); Indiana Univ., Bloomington, IN (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
DOE Contract Number:
EE0008075; EE0008076; EE0008417
OSTI ID:
1799420
Journal Information:
Advanced Energy Materials, Vol. 10, Issue 11; ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English

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Rational Design of Fe–N/C Hybrid for Enhanced Nitrogen Reduction Electrocatalysis under Ambient Conditions in Aqueous Solution journal November 2018
Fabricating Single‐Atom Catalysts from Chelating Metal in Open Frameworks journal February 2019
Identification of binuclear Co2N5 active sites for oxygen reduction reaction with more than one magnitude higher activity than single atom CoN4 site journal April 2018
Ionic Exchange of Metal–Organic Frameworks to Access Single Nickel Sites for Efficient Electroreduction of CO 2 journal June 2017
Active Salt/Silica-Templated 2D Mesoporous FeCo-N x -Carbon as Bifunctional Oxygen Electrodes for Zinc-Air Batteries journal January 2018
Unveiling Active Sites of CO 2 Reduction on Nitrogen-Coordinated and Atomically Dispersed Iron and Cobalt Catalysts journal March 2018
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Fe Isolated Single Atoms on S, N Codoped Carbon by Copolymer Pyrolysis Strategy for Highly Efficient Oxygen Reduction Reaction journal May 2018
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Direct transformation of bulk copper into copper single sites via emitting and trapping of atoms journal October 2018
Unraveling the high-activity nature of Fe–N–C electrocatalysts for the oxygen reduction reaction: the extraordinary synergy between Fe–N 4 and Fe 4 N journal January 2019
Surface Immobilization of Transition Metal Ions on Nitrogen-Doped Graphene Realizing High-Efficient and Selective CO 2 Reduction journal March 2018
Polydopamine-Inspired, Dual Heteroatom-Doped Carbon Nanotubes for Highly Efficient Overall Water Splitting journal December 2016
Atomically dispersed nickel–nitrogen–sulfur species anchored on porous carbon nanosheets for efficient water oxidation journal March 2019
Carbon Monoxide as a Promoter of Atomically Dispersed Platinum Catalyst in Electrochemical Hydrogen Evolution Reaction journal October 2018
Unveiling the high-activity origin of single-atom iron catalysts for oxygen reduction reaction journal June 2018
Manganese acting as a high-performance heterogeneous electrocatalyst in carbon dioxide reduction journal July 2019
Morphology Control of Carbon-Free Spinel NiCo 2 O 4 Catalysts for Enhanced Bifunctional Oxygen Reduction and Evolution in Alkaline Media journal December 2017
Highly active metallic nickel sites confined in N-doped carbon nanotubes toward significantly enhanced activity of CO2 electroreduction journal September 2019
Silica-Templated Covalent Organic Framework-Derived Fe–N-Doped Mesoporous Carbon as Oxygen Reduction Electrocatalyst journal April 2019
Highly Efficient CO 2 Electroreduction on ZnN 4 -based Single-Atom Catalyst journal August 2018
Pt alloy nanoparticles decorated on large-size nitrogen-doped graphene tubes for highly stable oxygen-reduction catalysts journal January 2018
Atomic Fe Dispersed on N-Doped Carbon Hollow Nanospheres for High-Efficiency Electrocatalytic Oxygen Reduction journal December 2018
A universal principle for a rational design of single-atom electrocatalysts journal April 2018
Tailoring FeN 4 Sites with Edge Enrichment for Boosted Oxygen Reduction Performance in Proton Exchange Membrane Fuel Cell journal January 2019
High-performance fuel cell cathodes exclusively containing atomically dispersed iron active sites journal January 2019
Single-Site Active Iron-Based Bifunctional Oxygen Catalyst for a Compressible and Rechargeable Zinc–Air Battery journal January 2018
Selective CO 2 Reduction to CO in Water using Earth-Abundant Metal and Nitrogen-Doped Carbon Electrocatalysts journal May 2018
Graphene Defects Trap Atomic Ni Species for Hydrogen and Oxygen Evolution Reactions journal February 2018
Direct observation of noble metal nanoparticles transforming to thermally stable single atoms journal July 2018
Identification of champion transition metals centers in metal and nitrogen-codoped carbon catalysts for CO2 reduction journal June 2018
Structural Advantage Induced by Sulfur to Boost the Catalytic Performance of FeNC Catalyst towards the Oxygen Reduction Reaction journal July 2018
Energy storage for electricity generation and related processes: Technologies appraisal and grid scale applications journal October 2018
Isolated Diatomic Ni-Fe Metal-Nitrogen Sites for Synergistic Electroreduction of CO 2 journal April 2019
Single-Atom Electrocatalysts journal October 2017
Self-Adjusting Activity Induced by Intrinsic Reaction Intermediate in Fe–N–C Single-Atom Catalysts journal August 2019
Unravelling the electrochemical mechanisms for nitrogen fixation on single transition metal atoms embedded in defective graphitic carbon nitride journal January 2018
Atomic Fe-N x Coupled Open-Mesoporous Carbon Nanofibers for Efficient and Bioadaptable Oxygen Electrode in Mg-Air Batteries journal August 2018
Bifunctional Perovskite Oxide Catalysts for Oxygen Reduction and Evolution in Alkaline Media journal September 2015
Regulation of Coordination Number over Single Co Sites: Triggering the Efficient Electroreduction of CO 2 journal January 2018
Edge-Site Engineering of Atomically Dispersed Fe–N 4 by Selective C–N Bond Cleavage for Enhanced Oxygen Reduction Reaction Activities journal August 2018
Metal-organic framework-derived nitrogen-doped highly disordered carbon for electrochemical ammonia synthesis using N2 and H2O in alkaline electrolytes journal June 2018
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Nitrogen-Coordinated Single Cobalt Atom Catalysts for Oxygen Reduction in Proton Exchange Membrane Fuel Cells journal January 2018
Ruthenium Ion-Complexed Graphitic Carbon Nitride Nanosheets Supported on Reduced Graphene Oxide as High-Performance Catalysts for Electrochemical Hydrogen Evolution journal December 2017
Understanding heterogeneous electrocatalytic carbon dioxide reduction through operando techniques journal December 2018
Electrochemical Reduction of CO 2 Catalyzed by Fe-N-C Materials: A Structure–Selectivity Study journal January 2017
A Review of Electrocatalytic Reduction of Dinitrogen to Ammonia under Ambient Conditions journal May 2018
Unraveling Mechanistic Reaction Pathways of the Electrochemical CO 2 Reduction on Fe–N–C Single-Site Catalysts journal June 2019
Experimental Observation of Redox-Induced Fe–N Switching Behavior as a Determinant Role for Oxygen Reduction Activity journal October 2015
Understanding Active Sites in Pyrolyzed Fe–N–C Catalysts for Fuel Cell Cathodes by Bridging Density Functional Theory Calculations and 57 Fe Mössbauer Spectroscopy journal September 2019
S-Doping of an Fe/N/C ORR Catalyst for Polymer Electrolyte Membrane Fuel Cells with High Power Density journal July 2015
Iron‐Free Cathode Catalysts for Proton‐Exchange‐Membrane Fuel Cells: Cobalt Catalysts and the Peroxide Mitigation Approach journal December 2018
Coordination of Atomic Co–Pt Coupling Species at Carbon Defects as Active Sites for Oxygen Reduction Reaction journal July 2018
Ultrathin two-dimensional materials for photo- and electrocatalytic hydrogen evolution journal September 2018
Synergistic effect of an atomically dual-metal doped catalyst for highly efficient oxygen evolution journal January 2018
From the Sabatier principle to a predictive theory of transition-metal heterogeneous catalysis journal August 2015
PGM‐Free Cathode Catalysts for PEM Fuel Cells: A Mini‐Review on Stability Challenges journal December 2018
Modulating the Electronic Structure of Single‐Atom Catalysts on 2D Nanomaterials for Enhanced Electrocatalytic Performance journal March 2019
Identification of single-atom active sites in carbon-based cobalt catalysts during electrocatalytic hydrogen evolution journal December 2018
Suppression of Hydrogen Evolution Reaction in Electrochemical N 2 Reduction Using Single-Atom Catalysts: A Computational Guideline journal July 2018
Iced photochemical reduction to synthesize atomically dispersed metals by suppressing nanocrystal growth journal November 2017
Identification of FeN 4 as an Efficient Active Site for Electrochemical N 2 Reduction journal June 2019
High-Loading Cobalt Oxide Coupled with Nitrogen-Doped Graphene for Oxygen Reduction in Anion-Exchange-Membrane Alkaline Fuel Cells journal April 2013
Carbon-Supported Single Atom Catalysts for Electrochemical Energy Conversion and Storage journal August 2018
Achieving a Record-High Yield Rate of 120.9 μgNH3  mgcat.−1  h−1 for N 2 Electrochemical Reduction over Ru Single-Atom Catalysts journal August 2018
Mn- and N- doped carbon as promising catalysts for oxygen reduction reaction: Theoretical prediction and experimental validation journal April 2019
Catalytic Mechanisms and Design Principles for Single‐Atom Catalysts in Highly Efficient CO 2 Conversion journal October 2019
Enhanced oxygen reduction with single-atomic-site iron catalysts for a zinc-air battery and hydrogen-air fuel cell journal December 2018
UIO-66-NH 2 -Derived Mesoporous Carbon Catalyst Co-Doped with Fe/N/S as Highly Efficient Cathode Catalyst for PEMFCs journal December 2018
High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt journal April 2011
Distinguished Zn,Co-Nx-C-Sy active sites confined in dentric carbon for highly efficient oxygen reduction reaction and flexible Zn-air Batteries journal April 2019
Single-atom catalysts for CO 2 electroreduction with significant activity and selectivity improvements journal January 2017
Activity origin and catalyst design principles for electrocatalytic hydrogen evolution on heteroatom-doped graphene journal September 2016
Recent Progress in the Theoretical Investigation of Electrocatalytic Reduction of CO 2 journal April 2018
Coordinatively unsaturated nickel–nitrogen sites towards selective and high-rate CO 2 electroreduction journal January 2018
Metal-Organic Framework-Derived Bamboo-like Nitrogen-Doped Graphene Tubes as an Active Matrix for Hybrid Oxygen-Reduction Electrocatalysts journal November 2014
Electrochemical CO 2 Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design journal December 2018
Single-Atom to Single-Atom Grafting of Pt 1 onto FeN 4 Center: Pt 1 @FeNC Multifunctional Electrocatalyst with Significantly Enhanced Properties journal September 2017
Identification of catalytic sites for oxygen reduction and oxygen evolution in N-doped graphene materials: Development of highly efficient metal-free bifunctional electrocatalyst journal April 2016
Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials journal August 2015
Rational Design of Single Molybdenum Atoms Anchored on N-Doped Carbon for Effective Hydrogen Evolution Reaction journal November 2017
Insight into the role of Ni–Fe dual sites in the oxygen evolution reaction based on atomically metal-doped polymeric carbon nitride journal January 2019
Unsaturated edge-anchored Ni single atoms on porous microwave exfoliated graphene oxide for electrochemical CO2 journal April 2019
Achievements, challenges and perspectives on cathode catalysts in proton exchange membrane fuel cells for transportation journal July 2019
Highly selective and active CO2 reduction electrocatalysts based on cobalt phthalocyanine/carbon nanotube hybrid structures journal March 2017
Charge Polarization from Atomic Metals on Adjacent Graphitic Layers for Enhancing the Hydrogen Evolution Reaction journal June 2019
Single Atomic Iron Catalysts for Oxygen Reduction in Acidic Media: Particle Size Control and Thermal Activation journal September 2017
Role of Local Carbon Structure Surrounding FeN 4 Sites in Boosting the Catalytic Activity for Oxygen Reduction journal May 2017
Recent progress in single-atom electrocatalysts: concept, synthesis, and applications in clean energy conversion journal January 2018
Activity Descriptor Identification for Oxygen Reduction on Nonprecious Electrocatalysts: Linking Surface Science to Coordination Chemistry journal October 2013
Highly active atomically dispersed CoN 4 fuel cell cathode catalysts derived from surfactant-assisted MOFs: carbon-shell confinement strategy journal January 2019
Atomically Dispersed Iron-Nitrogen Species as Electrocatalysts for Bifunctional Oxygen Evolution and Reduction Reactions journal December 2016
The Solid-Phase Synthesis of an Fe-N-C Electrocatalyst for High-Power Proton-Exchange Membrane Fuel Cells journal January 2018
Nitrogen Fixation by Ru Single-Atom Electrocatalytic Reduction journal January 2019
Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction journal February 2018
Understanding the activity and selectivity of single atom catalysts for hydrogen and oxygen evolution via ab initial study journal January 2018
Defect‐Based Single‐Atom Electrocatalysts journal December 2018
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode journal November 2004
Current challenge and perspective of PGM-free cathode catalysts for PEM fuel cells journal June 2017
Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst journal August 2017
Combining theory and experiment in electrocatalysis: Insights into materials design journal January 2017
Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts journal August 2016
Engineering nanostructures of PGM-free oxygen-reduction catalysts using metal-organic frameworks journal January 2017
Cooperative Spin Transition of Monodispersed FeN 3 Sites within Graphene Induced by CO Adsorption journal October 2018
Single Co Atoms Anchored in Porous N-Doped Carbon for Efficient Zinc−Air Battery Cathodes journal August 2018