skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Vapor- and liquid-phase adsorption of alcohol and water in silicalite-1 synthesized in fluoride media

Journal Article · · AIChE Journal
DOI:https://doi.org/10.1002/aic.16868· OSTI ID:1799260
ORCiD logo [1]; ORCiD logo [2];  [3];  [2];  [3]; ORCiD logo [4]; ORCiD logo [1]
  1. Department of Chemical Engineering and Materials Science University of Minnesota Minneapolis MN; Department of Chemistry and Chemical Theory Center University of Minnesota Minneapolis MN
  2. Department of Chemical Engineering and Materials Science University of Minnesota Minneapolis MN
  3. Facility for Adsorbent Characterization and Testing, Material Measurement Laboratory National Institute of Standards and Technology Gaithersburg MD
  4. Department of Chemical Engineering and Materials Science University of Minnesota Minneapolis MN; Department of Chemical and Biomolecular Engineering Johns Hopkins University Baltimore MD; Department of Research and Exploratory Development, Applied Physics Laboratory Johns Hopkins University Laurel MD

Not provided.

Research Organization:
Univ. of Wisconsin, Madison, WI (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
DOE Contract Number:
EE0006878
OSTI ID:
1799260
Journal Information:
AIChE Journal, Vol. 66, Issue 4; ISSN 0001-1541
Publisher:
American Institute of Chemical Engineers
Country of Publication:
United States
Language:
English

References (66)

Selective cyclodehydration of diols on zeolites journal November 1993
TraPPE-zeo: Transferable Potentials for Phase Equilibria Force Field for All-Silica Zeolites journal November 2013
ACS Virtual Issue on Multicomponent Systems: Absorption, Adsorption, and Diffusion journal September 2018
Evaluation of Zeolites in Production of Tetrahydrofuran from 1,4-Butanediol:  Performance Tests and Kinetic Investigations journal January 2007
Transferable Potentials for Phase Equilibria. 6. United-Atom Description for Ethers, Glycols, Ketones, and Aldehydes journal November 2004
Effects of Zeolite Membrane Structure on the Separation of 1,3-Propanediol from Glycerol and Glucose by Pervaporation journal May 2001
Thermodynamics of mixed-gas adsorption journal January 1965
Elucidating structure–properties relations for the design of highly selective carbon-based HMF sorbents journal January 2014
Insights into Supramolecular Sites Responsible for Complete Separation of Biomass-Derived Phenolics and Glucose in Metal–Organic Framework NU-1000 journal April 2017
Selective adsorption of HMF on porous carbons from fructose/DMSO mixtures journal August 2012
Adsorption of the Compounds Encountered in Monosaccharide Dehydration in Zeolite Beta journal May 2013
Amino cyclization of terminal (α,ω)-diols over modified ZSM-5 catalysts journal September 2002
Predicting Multicomponent Phase Equilibria and Free Energies of Transfer for Alkanes by Molecular Simulation journal September 1997
Adsorption of Liquid Mixtures on Silicalite-1 Zeolite:  A Density-Bottle Method journal August 2005
Recovery of HMF from aqueous solution by zeolitic imidazolate frameworks journal March 2015
Length exclusion in the adsorption of chain molecules on chabazite type zeolites journal January 2007
Novel Configurational-Bias Monte Carlo Method for Branched Molecules. Transferable Potentials for Phase Equilibria. 2. United-Atom Description of Branched Alkanes journal May 1999
Adsorption of fermentation inhibitors from lignocellulosic biomass hydrolyzates for improved ethanol yield and value-added product recovery journal June 2009
Adsorption of 1,2-Dichloropropane from Aqueous Solution onto Activated Carbon journal May 2008
Nonequilibrium Aspects of Adsorption from a Dilute Aqueous Solution of 1-Propanol onto Activated Carbon:  Interrelation between the Sorbent “Concentration” Effect and Metastability journal February 1999
The Dehydration of Fructose Towards 5-Hydroxymethylfurfural Using Activated Carbon as Adsorbent journal January 1992
Adsorption equilibria of bio-based butanol solutions using zeolite journal December 2009
Hydrogen Bonding Effects in Adsorption of Water−Alcohol Mixtures in Zeolites and the Consequences for the Characteristics of the Maxwell−Stefan Diffusivities journal July 2010
Direct determination of phase coexistence properties of fluids by Monte Carlo simulation in a new ensemble journal July 1987
Adsorption of congo red onto activated carbons having different surface properties: studies of kinetics and adsorption equilibrium journal January 2012
Viscosity and Density of Water + Ethyl Acetate + Ethanol Mixtures at 298.15 and 318.15 K and Atmospheric Pressure journal July 2007
Applying the wave theory to fixed-bed dynamics of Metal-Organic Frameworks exhibiting stepped adsorption isotherms: Water/ethanol separation on ZIF-8 journal September 2017
Ethanol, Acetic Acid, and Water Adsorption from Binary and Ternary Liquid Mixtures on High-Silica Zeolites journal April 2006
On the location and disorder of the tetrapropylammonium (TPA) ion in zeolite ZSM-5 with improved framework accuracy journal April 1987
Accurate Characterization of the Pore Volume in Microporous Crystalline Materials journal July 2017
Packing Effects in the Liquid-Phase Adsorption of C 5 - C 22 n -Alkanes on ZSM-5 journal October 2003
Separation of isomaltose from high sugar concentrated enzyme reaction mixture by dealuminated β-zeolite journal August 2004
Chemicals from Biomass: Combining Ring-Opening Tautomerization and Hydrogenation Reactions to Produce 1,5-Pentanediol from Furfural journal March 2017
Evaluation of Experimental Methods for the Study of Liquid-Phase Adsorption of Alkane/Alkene Mixtures on Y Zeolites journal July 2005
MFI zeolite as adsorbent for selective recovery of hydrocarbons from ABE fermentation broths journal September 2013
Densities, Viscosities, Refractive Indices, and Excess Properties of Aqueous 1,2-Etanediol, 1,3-Propanediol, 1,4-Butanediol, and 1,5-Pentanediol Binary Mixtures journal November 2016
A β-naphthol-modified hyper-cross-linked resin for adsorption of p- aminobenzoic acid from aqueous solutions journal February 2014
Zeolites as alcohol adsorbents from aqueous solutions journal January 2006
Adsorption of Biomass-Derived Polyols onto Metal–Organic Frameworks from Aqueous Solutions journal August 2018
Adsorption of benzene mixtures on silicalite-1 and NaX zeolites journal November 2006
Single- and multicomponent sorption/diffusion of hydrocarbons from their iso-octane solution in H-ZSM-5 zeolite journal January 1989
Adsorption from solution of nonelectrolytes by microporous crystalline solids: Ethanol—water/silicalite system journal July 1988
Separation of 1,3-Propanediol from Aqueous Solutions Using Pervaporation through an X-type Zeolite Membrane journal April 2001
Computer simulations in the Gibbs ensemble journal November 1989
Adsorption of alcohols from aqueous solution by ZSM-5 journal February 1984
Adsorption and Separation of C1−C8 Alcohols on SAPO-34 journal April 2011
Probing the Relationship between Silicalite-1 Defects and Polyol Adsorption Properties journal May 2013
Phase equilibria by simulation in the Gibbs ensemble: Alternative derivation, generalization and application to mixture and membrane equilibria journal March 1988
Molecular Competition Effects in Liquid-Phase Adsorption of Long-Chain n-Alkane Mixtures in ZSM-5 Zeolite Pores journal June 2003
Understanding the unique sorption of alkane- α , ω -diols in silicalite-1 journal August 2018
Adsorption of Hydrocarbon Chloro-Derivatives onto DTO Commercial Activated Carbon from Multi-Component Aqueous Solutions journal October 2003
Separation of 1,3-propanediol from glycerol and glucose using a ZSM-5 zeolite membrane journal September 2001
The Effect of Local Defects on Water Adsorption in Silicalite-1 Zeolite:  A Joint Experimental and Molecular Simulation Study journal September 2007
Synthesis of MEL type zeolite with different kinds of morphology for the recovery of 1-butanol from aqueous solution journal July 2011
Adsorption of HMF from Water/DMSO Solutions onto Hydrophobic Zeolites: Experiment and Simulation journal September 2013
Selective Liquid Phase Adsorption of 5-Hydroxymethylfurfural on Nanoporous Hyper-Cross-Linked Polymers journal August 2014
Conversion of Furfural to 1,5-Pentanediol: Process Synthesis and Analysis journal May 2017
Monte Carlo Calculations for Alcohols and Their Mixtures with Alkanes. Transferable Potentials for Phase Equilibria. 5. United-Atom Description of Primary, Secondary, and Tertiary Alcohols journal April 2001
A study of packing induced selectivity effects in the liquid phase adsorption of alkane/alkene mixtures on NaY journal July 2005
Adsorptive Separation of 1-Butanol from Aqueous Solutions Using MFI- and FER-Type Zeolite Frameworks: A Monte Carlo Study journal February 2016
Nonuniform Chain-Length-Dependent Diffusion of Short 1-Alcohols in SAPO-34 in Liquid Phase journal May 2013
Removal of the Fermentation Inhibitor, Furfural, Using Activated Carbon in Cellulosic-Ethanol Production journal December 2011
Partial Molar Volumes and Partial Molar Isentropic Compressions of Selected Alkane-α,ω-diols at Infinite Dilution in Water at Temperatures T = (278 to 318) K and Atmospheric Pressure journal May 2013
Concentration of alcohols by adsorption on silicalite journal January 1981
Adsorption of Water and Butanol in Silicalite-1 Film Studied with in Situ Attenuated Total Reflectance–Fourier Transform Infrared Spectroscopy journal April 2015
Multicomponent Adsorption of Alcohols onto Silicalite-1 from Aqueous Solution: Isotherms, Structural Analysis, and Assessment of Ideal Adsorbed Solution Theory journal October 2012