skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Network-Forming Liquids from Metal-Bis(acetamide) Frameworks with Low Melting Temperatures

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.0c11718· OSTI ID:1785247

Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
~OTHER
DOE Contract Number:
SC0012704
OSTI ID:
1785247
Report Number(s):
BNL-221573-2021-JACI
Journal Information:
Journal of the American Chemical Society, Vol. 143, Issue 7
Country of Publication:
United States
Language:
English

References (75)

Relationship between structure, entropy, and mobility in network-forming ionic melts journal March 2009
Transport Properties of Tetrahedral, Network-Forming Ionic Melts journal November 2009
Network Topology and the Fragility of Tetrahedral Glass-Forming Liquids journal October 2009
Polyamorphism and density anomalies in network‐forming fluids: Zeroth‐ and first‐order approximations journal July 1996
Liquid-Liquid Immiscibility in Pure Fluids: Polyamorphism in Simulations of a Network-Forming Fluid journal November 1996
Polymorphic Phase Transitions in Liquids and Glasses journal January 1997
Structure and dynamics in network-forming materials journal October 2016
Reticular synthesis and the design of new materials journal June 2003
Functional Porous Coordination Polymers journal April 2004
Hybrid porous solids past, present, future journal January 2008
Introduction to Reticular Chemistry journal January 2019
Liquid metal–organic frameworks journal October 2017
Liquid, glass and amorphous solid states of coordination polymers and metal–organic frameworks journal September 2018
Melting of Zeolitic Imidazolate Frameworks with Different Topologies: Insight from First-Principles Molecular Dynamics journal March 2018
A New Dimension for Coordination Polymers and Metal–Organic Frameworks: Towards Functional Glasses and Liquids journal February 2020
Development of a Cambridge Structural Database Subset: A Collection of Metal–Organic Frameworks for Past, Present, and Future journal March 2017
Hybrid glasses from strong and fragile metal-organic framework liquids journal August 2015
Reversible Solid-to-Liquid Phase Transition of Coordination Polymer Crystals journal January 2015
Melt-Quenched Glasses of Metal–Organic Frameworks journal March 2016
Metal-organic framework glasses with permanent accessible porosity journal November 2018
Meltable Mixed-Linker Zeolitic Imidazolate Frameworks and Their Microporous Glasses: From Melting Point Engineering to Selective Hydrocarbon Sorption journal July 2019
Crystal Structures and Melting Behaviors of 2D and 3D Anionic Coordination Polymers Containing Organometallic Ionic Liquid Components journal June 2019
Crystal melting and glass formation in copper thiocyanate based coordination polymers journal January 2019
Pressure promoted low-temperature melting of metal–organic frameworks journal March 2019
Stable melt formation of 2D nitrile-based coordination polymer and hierarchical crystal–glass structuring journal January 2020
Halogenated Metal–Organic Framework Glasses and Liquids journal January 2020
Crystal melting and vitrification behaviors of a three-dimensional nitrile-based metal–organic framework journal January 2021
Flux melting of metal–organic frameworks journal January 2019
Amorphous Metal–Organic Frameworks journal April 2014
Glass Formation of a Coordination Polymer Crystal for Enhanced Proton Conductivity and Material Flexibility journal April 2016
Nanoporous Transparent MOF Glasses with Accessible Internal Surface journal August 2016
A metal-organic framework with ultrahigh glass-forming ability journal March 2018
Glass-phase coordination polymer displaying proton conductivity and guest-accessible porosity journal January 2019
Ionic liquids. Green solvents for the future journal January 2000
Exploring an Anti-Crystal Engineering Approach to the Preparation of Pharmaceutically Active Ionic Liquids journal February 2009
Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2 journal May 2011
Organised chaos: entropy in hybrid inorganic–organic systems and other materials journal January 2016
Estimation of Entropy of Melting from Molecular Structure:  A Non-Group Contribution Method journal January 1996
Entropy–enthalpy compensation in the fusion of organic molecules: implications for Walden’s rule and molecular freedom in the liquid state journal November 1999
Molecular Symmetry, Rotational Entropy, and Elevated Melting Points journal December 1999
Formation of Polymeric Network Arrays by Complexes of Manganese(II) or Cobalt(II) with Alkane Chain Linked Bis(amide) Ligands of Biological Relevance journal May 1999
Influence of the Counteranion on the Formation of Polymeric Networks by Metal Complexes of Hexamethylenebis(acetamide) journal January 2001
Aggregation of two different coordination polymers by reacting zinc nitrate and cadmium chloride with N,N′-ethylenebisacetamide journal September 2011
Metal-ligand bond lengths and strengths: are they correlated? A detailed CSD analysis journal July 2013
A fundamental view of enthalpy–entropy compensation journal January 2014
637. The stability of transition-metal complexes journal January 1953
Water exchange on metal ions: experiments and simulations journal June 1999
Metal–Organic Phase-Change Materials for Thermal Energy Storage journal November 2020
Enthalpy/Entropy Compensation as a Competition between Dynamics and Bonding:  The Relevance to Melting of Crystals and Biological Aggregates journal January 2001
Melting behaviour in the n-alkanol family. Enthalpy–entropy compensation journal January 2004
The Hydrogen Bond in the Solid State journal January 2002
Configurational Entropy Revisited journal September 2007
Relation between the transport coefficients and the internal entropy of simple systems journal June 1977
Entropy, diffusivity, and structural order in liquids with waterlike anomalies journal November 2006
Water and water-like liquids: relationships between structure, entropy and mobility journal January 2013
Amphidynamic Character of Crystalline MOF-5: Rotational Dynamics of Terephthalate Phenylenes in a Free-Volume, Sterically Unhindered Environment
  • Gould, Stephanie L.; Tranchemontagne, David; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 130, Issue 11, p. 3246-3247 https://doi.org/10.1021/ja077122c
journal March 2008
PDFgetX3 : a rapid and highly automatable program for processing powder diffraction data into total scattering pair distribution functions journal March 2013
Rigidity Percolation book January 1985
Constraint theory, vector percolation and glass formation journal February 1985
Molecular dynamics study of screening in ionic fluids journal July 2000
On the Structure and Dynamics of Ionic Liquids journal February 2004
Extended-range order, interstitial voids and the first sharp diffraction peak of network glasses journal March 1995
Topological versus chemical ordering in network glasses at intermediate and extended length scales journal May 2005
Melt-Quenched Hybrid Glasses from Metal-Organic Frameworks journal January 2017
Metal-organic framework and inorganic glass composites journal November 2020
Inorganic glasses, glass-forming liquids and amorphizing solids journal January 2007
Under what conditions can a glass be formed? journal September 1969
Role of Viscosity in Influencing the Glass-Forming Ability of Organic Molecules from the Undercooled Melt State journal July 2011
Evaluation of the activation energy of viscous flow for a binary mixture in order to estimate the thermodiffusion coefficient journal January 2011
Long-Lived Structures in Fragile Glass-Forming Liquids journal September 1995
Little evidence for dynamic divergences in ultraviscous molecular liquids journal July 2008
Viscosity of glass-forming systems journal December 2016
Liquid landscape journal June 1998
Supercooled liquids and the glass transition journal March 2001
From 50 Years Ago, the Birth of Modern Liquid-State Science journal May 2017