Electrochemical Utilization of Iron IV in the Li 1.3 Fe 0.4 Nb 0.3 O 2 Disordered Rocksalt Cathode

Lebens‐Higgins, Z; Chung, H.; Zuba, M.; Wu, J.; Rana, J.; Mejia, C.; Wang, L.; Du, Y.; Yang, W.; Meng, Y.; Piper, L.; Temprano, I.; Jones, M.; Grey, C.

doi:10.1002/batt.202000318

Electrochemical Utilization of Iron IV in the Li 1.3 Fe 0.4 Nb 0.3 O 2 Disordered Rocksalt Cathode

Journal Article · 01 January 2022 · Batteries & Supercaps

DOI:https://doi.org/10.1002/batt.202000318· OSTI ID:1783978

Lebens‐Higgins, Z; Chung, H.; Zuba, M.; Wu, J.; Rana, J.; Mejia, C.; Wang, L.; Du, Y.; Yang, W.; Meng, Y.; Piper, L.; Temprano, I.; Jones, M.; Grey, C.

Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: ~OTHER

DOE Contract Number:: SC0012704

OSTI ID:: 1783978

Report Number(s):: BNL-221509-2021-JACI

Journal Information:: Batteries & Supercaps, Vol. 4, Issue 5

Country of Publication:: United States

Language:: English

References (40)

Preparation of LiFeO[sub 2] with Alpha-NaFeO[sub 2]-Type Structure Using a Mixed-Alkaline Hydrothermal Method Ado, Kazuaki Journal of The Electrochemical Society, Vol. 144, Issue 7 https://doi.org/10.1149/1.1837791	journal	January 1997
Intrinsic instability of Fe4+ in electrochemically oxidized ramsdellite and orthorhombic Li1−xHxFeO2 Bordet-Le Guenne, L.; Deniard, P.; Lecerf, A. Journal of Materials Chemistry, Vol. 9, Issue 5 https://doi.org/10.1039/a809947b	journal	January 1999
First Principles Study on Factors Determining Battery Voltages of LiMO ₂ ( M = Ti - Ni ) Koyama, Yukinori; Tanaka, Isao; Kim, Yang-Soo Japanese Journal of Applied Physics, Vol. 38, Issue Part 1, No. 8 https://doi.org/10.1143/JJAP.38.4804	journal	August 1999
Highly electroactive nanosized α-LiFeO2 Morales, Julián; Santos-Peña, Jesús Electrochemistry Communications, Vol. 9, Issue 8 https://doi.org/10.1016/j.elecom.2007.06.013	journal	August 2007
Insights into the electrochemical activity of nanosized α-LiFeO2 Morales, J.; Santos-Peña, J.; Trócoli, R. Electrochimica Acta, Vol. 53, Issue 22 https://doi.org/10.1016/j.electacta.2008.04.057	journal	September 2008
Structure and electrode reactions of layered rocksalt LiFeO2 nanoparticles for lithium battery cathode Hirayama, Masaaki; Tomita, Hiroki; Kubota, Kei Journal of Power Sources, Vol. 196, Issue 16 https://doi.org/10.1016/j.jpowsour.2010.10.009	journal	August 2011
Structural properties and electrochemistry of α-LiFeO2 Abdel-Ghany, A. E.; Mauger, A.; Groult, H. Journal of Power Sources, Vol. 197 https://doi.org/10.1016/j.jpowsour.2011.09.054	journal	January 2012
Low temperature synthesis of Fe2O3 and LiFeO2 as cathode materials for lithium-ion batteries Li, Keyan; Chen, Hao; Shua, Fenfen Electrochimica Acta, Vol. 136 https://doi.org/10.1016/j.electacta.2014.05.068	journal	August 2014
Understanding electrochemical potentials of cathode materials in rechargeable batteries Liu, Chaofeng; Neale, Zachary G.; Cao, Guozhong Materials Today, Vol. 19, Issue 2 https://doi.org/10.1016/j.mattod.2015.10.009	journal	March 2016
Role of Electronic Structure in the Susceptibility of Metastable Transition-Metal Oxide Structures to Transformation Reed, John; Ceder, Gerbrand Chemical Reviews, Vol. 104, Issue 10 https://doi.org/10.1021/cr020733x	journal	October 2004
A first principles investigation of new cathode materials for advanced lithium batteries Jeon, Young-Ah; Kim, Sung-Kwan; Kim, Yang-Soo Journal of Electroceramics, Vol. 17, Issue 2-4 https://doi.org/10.1007/s10832-006-7674-5	journal	December 2006
Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries Assat, Gaurav; Tarascon, Jean-Marie Nature Energy, Vol. 3, Issue 5 https://doi.org/10.1038/s41560-018-0097-0	journal	April 2018
Origin of stabilization and destabilization in solid-state redox reaction of oxide ions for lithium-ion batteries Yabuuchi, Naoaki; Nakayama, Masanobu; Takeuchi, Mitsue Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13814	journal	December 2016
Identifying the Chemical Origin of Oxygen Redox Activity in Li-Rich Anti-Fluorite Lithium Iron Oxide by Experimental and Theoretical X-ray Absorption Spectroscopy Li, Liang; Lee, Eungje; Freeland, John W. The Journal of Physical Chemistry Letters, Vol. 10, Issue 4 https://doi.org/10.1021/acs.jpclett.8b03271	journal	January 2019
Enabling the high capacity of lithium-rich anti-fluorite lithium iron oxide by simultaneous anionic and cationic redox Zhan, Chun; Yao, Zhenpeng; Lu, Jun Nature Energy, Vol. 2, Issue 12 https://doi.org/10.1038/s41560-017-0043-6	journal	December 2017
A high pressure pathway toward boron-based nanostructured solids Grosjean, Rémi; Le Godec, Yann; Delacroix, Simon Dalton Transactions, Vol. 47, Issue 23 https://doi.org/10.1039/C8DT00932E	journal	January 2018
Electrochemical properties and Mössbauer effect of anti-fluorite type compound, LiFeO Hirano, A.; Matsumura, T.; Ueda, M. Solid State Ionics, Vol. 176, Issue 37-38 https://doi.org/10.1016/j.ssi.2005.08.013	journal	November 2005
Novel Complex Stacking of Fully-Ordered Transition Metal Layers in Li ₄ FeSbO ₆ Materials McCalla, Eric; Abakumov, Artem; Rousse, Gwenaelle Chemistry of Materials, Vol. 27, Issue 5 https://doi.org/10.1021/cm504500a	journal	February 2015
Cation-Disordered Lithium-Excess Li–Fe–Ti Oxide Cathode Materials for Enhanced Li-Ion Storage Yang, Meng; Jin, Junyang; Shen, Yinlin ACS Applied Materials & Interfaces, Vol. 11, Issue 47 https://doi.org/10.1021/acsami.9b14137	journal	November 2019
Identifying the anionic redox activity in cation-disordered Li _1.25 Nb _0.25 Fe _0.50 O ₂ /C oxide cathodes for Li-ion batteries Luo, Mingzeng; Zheng, Shiyao; Wu, Jue Journal of Materials Chemistry A, Vol. 8, Issue 10 https://doi.org/10.1039/C9TA11739C	journal	January 2020
Characterization of Disordered Li _{(1+ x )} Ti _{2 x} Fe _{(1–3 x )} O ₂ as Positive Electrode Materials in Li-Ion Batteries Using Percolation Theory Glazier, Stephen L.; Li, Jing; Zhou, Jigang Chemistry of Materials, Vol. 27, Issue 22 https://doi.org/10.1021/acs.chemmater.5b03530	journal	November 2015
Lithium deintercalation in LiFePO4 nanoparticles via a domino-cascade model Delmas, C.; Maccario, M.; Croguennec, L. Nature Materials, Vol. 7, Issue 8 https://doi.org/10.1038/nmat2230	journal	July 2008
Enabling multi-electron reaction of ε-VOPO ₄ to reach theoretical capacity for lithium-ion batteries Siu, Carrie; Seymour, Ieuan D.; Britto, Sylvia Chemical Communications, Vol. 54, Issue 56 https://doi.org/10.1039/C8CC02386G	journal	January 2018
Surface aging at olivine LiFePO ₄ : a direct visual observation of iron dissolution and the protection role of nano-carbon coating Wang, Jiajun; Yang, Jinli; Tang, Yongji J. Mater. Chem. A, Vol. 1, Issue 5 https://doi.org/10.1039/C2TA00521B	journal	January 2013
High-temperature storage and cycling of C-LiFePO4/graphite Li-ion cells Amine, K.; Liu, J.; Belharouak, I. Electrochemistry Communications, Vol. 7, Issue 7 https://doi.org/10.1016/j.elecom.2005.04.018	journal	July 2005
P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries Yabuuchi, Naoaki; Kajiyama, Masataka; Iwatate, Junichi Nature Materials, Vol. 11, Issue 6 https://doi.org/10.1038/nmat3309	journal	April 2012
Evolution of the Electrode–Electrolyte Interface of LiNi _0.8 Co _0.15 Al _0.05 O ₂ Electrodes Due to Electrochemical and Thermal Stress Lebens-Higgins, Zachary W.; Sallis, Shawn; Faenza, Nicholas V. Chemistry of Materials, Vol. 30, Issue 3 https://doi.org/10.1021/acs.chemmater.7b04782	journal	January 2018
The iron L edges: Fe 2p X-ray absorption and electron energy loss spectroscopy Miedema, Piter S.; de Groot, Frank M. F. Journal of Electron Spectroscopy and Related Phenomena, Vol. 187 https://doi.org/10.1016/j.elspec.2013.03.005	journal	April 2013
Valence Band Structure and X-ray Spectra of Oxygen-Deficient Ferrites SrFeO _x Galakhov, V. R.; Kurmaev, E. Z.; Kuepper, K. The Journal of Physical Chemistry C, Vol. 114, Issue 11 https://doi.org/10.1021/jp909091s	journal	March 2010
Synthesis, characterisation and corrosion behaviour of simulant Chernobyl nuclear meltdown materials Barlow, Sean T.; Bailey, Daniel J.; Fisher, Adam J. npj Materials Degradation, Vol. 4, Issue 1 https://doi.org/10.1038/s41529-020-0108-z	journal	January 2020
Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides Gent, William E.; Lim, Kipil; Liang, Yufeng Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-02041-x	journal	December 2017
Dissociate lattice oxygen redox reactions from capacity and voltage drops of battery electrodes Wu, Jinpeng; Zhuo, Zengqing; Rong, Xiaohui Science Advances, Vol. 6, Issue 6 https://doi.org/10.1126/sciadv.aaw3871	journal	February 2020
Distinction between Intrinsic and X-ray-Induced Oxidized Oxygen States in Li-Rich 3d Layered Oxides and LiAlO ₂ Lebens-Higgins, Zachary W.; Vinckeviciute, Julija; Wu, Jinpeng The Journal of Physical Chemistry C, Vol. 123, Issue 21 https://doi.org/10.1021/acs.jpcc.9b01298	journal	May 2019
Origin of High Capacity and Poor Cycling Stability of Li-Rich Layered Oxides: A Long-Duration in Situ Synchrotron Powder Diffraction Study Kleiner, Karin; Strehle, Benjamin; Baker, Annabelle R. Chemistry of Materials, Vol. 30, Issue 11 https://doi.org/10.1021/acs.chemmater.8b00163	journal	May 2018
Quantifying the Capacity Contributions during Activation of Li ₂ MnO ₃ Rana, Jatinkumar; Papp, Joseph K.; Lebens-Higgins, Zachary ACS Energy Letters, Vol. 5, Issue 2 https://doi.org/10.1021/acsenergylett.9b02799	journal	January 2020
Electrochemical Oxidation of Lithium Carbonate Generates Singlet Oxygen Mahne, Nika; Renfrew, Sara E.; McCloskey, Bryan D. Angewandte Chemie International Edition, Vol. 57, Issue 19 https://doi.org/10.1002/anie.201802277	journal	April 2018
Elektrochemische Oxidation von Lithiumcarbonat generiert Singulett‐Sauerstoff Mahne, Nika; Renfrew, Sara E.; McCloskey, Bryan D. Angewandte Chemie, Vol. 130, Issue 19 https://doi.org/10.1002/ange.201802277	journal	April 2018
High-Capacity P2-Type Na _x Li _0.25 Mn _0.75 O ₂ Cathode Enabled by Anionic Oxygen Redox Chen, Xiaoli; Li, Ning; Kedzie, Elyse Journal of The Electrochemical Society, Vol. 166, Issue 16 https://doi.org/10.1149/2.0611916jes	journal	January 2019
Superstructure control of first-cycle voltage hysteresis in oxygen-redox cathodes House, Robert A.; Maitra, Urmimala; Pérez-Osorio, Miguel A. Nature, Vol. 577, Issue 7791 https://doi.org/10.1038/s41586-019-1854-3	journal	December 2019
Low temperature synthesis and electrochemical characteristics of LiFeO2 cathodes Sakurai, Yoji; Arai, Hajime; Okada, Shigeto Journal of Power Sources, Vol. 68, Issue 2 https://doi.org/10.1016/S0378-7753(96)02579-7	journal	October 1997

Similar Records

Electrochemical Utilization of Iron IV in the Li_1.3Fe_0.4Nb_0.3O₂ Disordered Rocksalt Cathode

Journal Article · 2021 · Batteries & Supercaps · OSTI ID:1826554

Lebens‐Higgins, Zachary; Chung, Hyeseung; Temprano, Israel; +11 more

Related Subjects

99 GENERAL AND MISCELLANEOUS

Electrochemical Utilization of Iron IV in the Li 1.3 Fe 0.4 Nb 0.3 O 2 Disordered Rocksalt Cathode

Citation Formats

References (40)

Similar Records

Related Subjects