Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

The Effect of Temperature on the Stability and Cerium Oxidation State of CeTi2O6 in Inert and Oxidizing Atmospheres

Journal Article · · Inorganic Chemistry

Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
~OTHER
DOE Contract Number:
SC0012704
OSTI ID:
1783973
Report Number(s):
BNL-221504-2021-JACI
Journal Information:
Inorganic Chemistry, Vol. 59, Issue 23
Country of Publication:
United States
Language:
English

References (30)

Advanced Ceramics and Glass-Ceramics for Immobilisation of ILW and HLW journal January 2012
The formation of stoichiometric uranium brannerite (UTi2O6) glass-ceramic composites from the component oxides in a one-pot synthesis journal December 2020
Ceramic matrices for plutonium disposition journal November 2007
Chemistry, microstructure, and alpha decay damage of natural brannerite journal January 2012
Chemical and microstructural characterisation studies on natural and heat treated brannerite samples journal December 2012
Brannerite, a new uranium mineral journal February 1920
Recrystallisation of amorphous natural brannerite through annealing: The effect of radiation damage on the chemical durability of brannerite journal May 2006
Geochemical fingerprints of brannerite (UTi 2 O 6 ): an integrated study journal February 2020
Solubility of actinide surrogates in nuclear glasses journal January 2003
Feasibility Limits in Using Cerium as a Surrogate for Plutonium Incorporation in Zircon, Zirconia and Pyrochlore journal January 2000
Crystal structure and non-stoichiometry of cerium brannerite: Ce0.975Ti2O5.95 journal August 2012
Novel Chemical Synthesis and Characterization of CeTi 2 O 6 Brannerite journal June 2014
How temperature influences the stoichiometry of CeTi2O6 journal June 2012
Assessing the oxidation states and structural stability of the Ce analogue of brannerite journal July 2017
CeTi 2 O 6 —A Promising Oxide for Solar Thermochemical Hydrogen Production journal April 2020
Whole powder pattern decomposition methods and applications: A retrospection journal December 2005
Ab-initio structure determination of LiSbWO6 by X-ray powder diffraction journal March 1988
TOPAS and TOPAS-Academic : an optimization program integrating computer algebra and crystallographic objects written in C++ journal February 2018
NIST HAXPES at NSLS and NSLS-II journal July 2018
High resolution x‐ray absorption spectroscopy with absolute energy calibration for the determination of absorption edge energies journal March 1996
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT journal June 2005
ATHENA and ARTEMIS Interactive Graphical Data Analysisusing IFEFFIT journal January 2005
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides journal September 1976
The Effect of A-Site Cation on the Formation of Brannerite (ATi2O6, A = U, Th, Ce) Ceramic Phases in a Glass-Ceramic Composite System journal January 2020
Uranium brannerite with Tb(III)/Dy(III) ions: Phase formation, structures, and crystallizations in glass journal June 2019
Structural and spectroscopic investigations on the crystallization of uranium brannerite phases in glass journal May 2018
Enthalpies of formation of U-, Th-, Ce-brannerite: implications for plutonium immobilization journal August 2003
Thermochemistry of rare-earth orthophosphates journal September 2001
Structural changes in equimolar ceria–hafnia materials under solar thermochemical looping conditions: cation ordering, formation and stability of the pyrochlore structure journal January 2017
The HADES Facility for High Activity Decommissioning Engineering & Science: part of the UK National Nuclear User Facility journal April 2020