Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

High-pressure phase transformation of carbonate malachite Cu2(CO3)(OH)2 driven by [CuO6] regularization and [CO3] rotation

Journal Article · · Geoscience Frontiers

Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
~OTHER
DOE Contract Number:
SC0012704
OSTI ID:
1783462
Report Number(s):
BNL-221410-2021-JACI
Journal Information:
Geoscience Frontiers, Vol. 12, Issue 2
Country of Publication:
United States
Language:
English

References (36)

H2O storage capacity of olivine at 5–8GPa and consequences for dehydration partial melting of the upper mantle journal September 2012
CaCO3 phase diagram studied with Raman spectroscopy at pressures up to 50 GPa and high temperatures and DFT modeling journal August 2018
Carbonates from the lower part of transition zone or even the lower mantle journal August 2007
Stability of iron-bearing carbonates in the deep Earth’s interior journal July 2017
Melting in the Earth's deep upper mantle caused by carbon dioxide journal March 2006
Deep global cycling of carbon constrained by the solidus of anhydrous, carbonated eclogite under upper mantle conditions journal October 2004
Raman spectroscopic study of azurite and malachite at 298 and 77 K journal January 2002
Compressibility of carbonophosphate bradleyite Na3Mg(CO3)(PO4) by X-ray diffraction and Raman spectroscopy journal September 2014
The crystal chemistry and the compressibility of silicate-carbonate minerals: Spurrite, galuskinite and tilleyite journal September 2015
Compressibility of a natural smithsonite ZnCO 3 up to 50 GPa journal January 2014
Aragonite-II and CaCO 3 -VII: New High-Pressure, High-Temperature Polymorphs of CaCO 3 journal October 2017
The infra-red spectra of azurite and malachite journal December 1968
Thermodynamic constraints on carbonate stability and carbon volatility during subduction journal August 2019
Two-dimensional detector software: From real detector to idealised image or two-theta scan journal January 1996
High pressure, high resolution synchrotron x-ray powder diffraction with a position-sensitive detector journal May 1992
Carbonatitic Inclusions in deep Mantle Diamond from Juina, Brazil: new Minerals in the Carbonate-Halide Association journal October 2013
Ultralow viscosity of carbonate melts at high pressures journal October 2014
Spin gap in malachite Cu 2 (OH) 2 CO 3 and its evolution under pressure journal December 2013
Iron-rich carbonates stabilized by magnetic entropy at lower mantle conditions journal February 2020
Vibrational and elastic properties of ferromagnesite across the electronic spin-pairing transition of iron journal March 2012
High-pressure compressibility and vibrational properties of (Ca,Mn)CO 3 journal December 2016
First direct evidence of sedimentary carbonate recycling in subduction-related xenoliths journal June 2015
Calibration of the ruby pressure gauge to 800 kbar under quasi-hydrostatic conditions journal January 1986
Phase transition at high pressure in Cu 2 CO 3 (OH) 2 related to the reduction of the Jahn–Teller effect journal May 2012
Evidence for the existence of a PbCO 3 -II phase from high pressure X-ray measurements journal April 2010
Novel high-pressure structures of MgCO3, CaCO3 and CO2 and their role in Earth's lower mantle journal August 2008
Mantle-wide sequestration of carbon in silicates and the structure of magnesite II journal January 2008
Structures and stability of calcium and magnesium carbonates at mantle pressures journal March 2015
O–H Stretching Frequencies in Very Short and Possibly Symmetrical Hydrogen Bonds journal September 1952
Seismic evidence for silicate melt atop the 410-km mantle discontinuity journal June 1994
Hydrogen bonding in basic copper salts: a spectroscopic study of malachite, Cu2(OH)2CO3, and brochantite, Cu4(OH)6SO4 journal May 1993
Infrared study of some synthetic phases of malachite (Cu2(OH)2CO3)–hydrozincite (Zn5(OH)6(CO3)2) series journal July 2002
Peridotite–CO2–H2O, and carbonatitic liquids in the upper asthenosphere journal March 1977
Diamond from the Dabie Shan Metamorphic Rocks and Its Implication for Tectonic Setting journal April 1992
Oceanic crust in the mid-mantle beneath west-central Pacific subduction zones: evidence from S to P converted waveforms journal August 2015
Comparative compressibilities of calcite-structure carbonates; deviations from empirical relations journal June 1999