Adsorption cooling system using metal organic frameworks

Baumann, Theodore F.; Satcher, Jr., Joe H.; Farmer, Joseph C.

Adsorption cooling system using metal organic frameworks

Patent · 09 November 2020

OSTI ID:1771608

Baumann, Theodore F.; Satcher, Jr., Joe H.; Farmer, Joseph C.

An adsorptive cooling system includes: a first highly adsorptive structure positioned to receive thermal energy from a thermal energy source, including: a first substrate; and a first metal-organic framework (MOF) coupled to the first substrate and adapted for adsorbing and desorbing a refrigerant under predetermined thermodynamic conditions; a second highly adsorptive structure positioned to receive thermal energy from the thermal energy source including: a second substrate; and a second MOF coupled to the second substrate and adapted for adsorbing and desorbing a refrigerant under predetermined thermodynamic conditions; a cooling unit; and a circulation system adapted for circulating refrigerant from the first highly adsorptive structure and the second highly adsorptive structure to the cooling unit to provide cooling from the thermal energy source and to return the refrigerant to at least one of the first highly adsorptive structure and the second highly adsorptive structure.

View Patent

Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC52-07NA27344

Assignee:: Lawrence Livermore National Security, LLC (Livermore, CA)

Patent Number(s):: 10,830,504

Application Number:: 13/457,331

OSTI ID:: 1771608

Country of Publication:: United States

Language:: English

References (31)

Fuel Gas Storage and Separations by Metal−Organic Frameworks: Simulated Adsorption Isotherms for H ₂ and CH ₄ and Their Equimolar Mixture Gallo, Marco; Glossman-Mitnik, Daniel The Journal of Physical Chemistry C, Vol. 113, Issue 16 https://doi.org/10.1021/jp809539w	journal	March 2009
Performance limitations of adsorption cycles for solar cooling Critoph, R. E. Solar Energy, Vol. 41, Issue 1 https://doi.org/10.1016/0038-092X(88)90111-9	journal	January 1988
MOFs as Adsorbents for Low Temperature Heating and Cooling Applications Henninger, Stefan K.; Habib, Hesham A.; Janiak, Christoph Journal of the American Chemical Society, Vol. 131, Issue 8 https://doi.org/10.1021/ja808444z	journal	March 2009
CO ₂ Adsorption-Based Separation by Metal Organic Framework (Cu-BTC) versus Zeolite (13X) Liang, Zhijian; Marshall, Marc; Chaffee, Alan L. Energy & Fuels, Vol. 23, Issue 5 https://doi.org/10.1021/ef800938e	journal	May 2009
Testing the Accuracy of Correlations for Multicomponent Mass Transport of Adsorbed Gases in Metal−Organic Frameworks: Diffusion of H ₂ /CH ₄ Mixtures in CuBTC Keskin, Seda; Liu, Jinchen; Johnson, J. Karl Langmuir, Vol. 24, Issue 15 https://doi.org/10.1021/la800486f	journal	July 2008
Comparative Molecular Simulation Study of CO ₂ /N ₂ and CH ₄ /N ₂ Separation in Zeolites and Metal−Organic Frameworks Liu, Bei; Smit, Berend Langmuir, Vol. 25, Issue 10 https://doi.org/10.1021/la900823d	journal	May 2009
Adsorption Dynamics of Gases and Vapors on the Nanoporous Metal Organic Framework Material Ni ₂ (4,4‘-Bipyridine) ₃ (NO ₃ ) ₄ : Guest Modification of Host Sorption Behavior Fletcher, Ashleigh J.; Cussen, Edmund J.; Prior, Timothy J. Journal of the American Chemical Society, Vol. 123, Issue 41 https://doi.org/10.1021/ja0109895	journal	October 2001
On the Nature of the Adsorbed Hydrogen Phase in Microporous Metal−Organic Frameworks at Supercritical Temperatures Poirier, Eric; Dailly, Anne Langmuir, Vol. 25, Issue 20 https://doi.org/10.1021/la901680p	journal	September 2009
Structural diversity and chemical trends in hybrid inorganic–organic framework materials Cheetham, Anthony K.; Rao, C. N. R.; Feller, Russell K. Chem. Commun., Issue 46 https://doi.org/10.1039/B610264F	journal	January 2006
Amine functionalised metal organic frameworks (MOFs) as adsorbents for carbon dioxide Arstad, Bjørnar; Fjellvåg, Helmer; Kongshaug, Kjell Ove Adsorption, Vol. 14, Issue 6 https://doi.org/10.1007/s10450-008-9137-6	journal	July 2008
Adsorptive machines with advanced cycles for heat pumping or cooling applications Pons, M.; Poyelle, F. International Journal of Refrigeration, Vol. 22, Issue 1 https://doi.org/10.1016/S0140-7007(97)00042-X	journal	January 1999
Method for Analyzing Structural Changes of Flexible Metal−Organic Frameworks Induced by Adsorbates Dubbeldam, D.; Krishna, R.; Snurr, R. Q. The Journal of Physical Chemistry C, Vol. 113, Issue 44 https://doi.org/10.1021/jp906635f	journal	October 2009
Adsorption and Separation of Noble Gases by IRMOF-1: Grand Canonical Monte Carlo Simulations Greathouse, Jeffery A.; Kinnibrugh, Tiffany L.; Allendorf, Mark D. Industrial & Engineering Chemistry Research, Vol. 48, Issue 7 https://doi.org/10.1021/ie801294n	journal	April 2009
Solid sorption heat powered cycles for cooling and heat pumping applications Meunier, F. Applied Thermal Engineering, Vol. 18, Issue 9-10 https://doi.org/10.1016/S1359-4311(97)00122-1	journal	September 1998
Development of Hydrogen Storage Material with a Single Nanopore Structure [単一構造を持つ細孔を使った水素吸蔵体の開発] Sato, Sota Journal of Synthetic Organic Chemistry, Japan, Vol. 66, Issue 8 https://doi.org/10.5059/yukigoseikyokaishi.66.806	journal	January 2008
Study of the fundamentals of adsorption systems Teng, Y.; Wang, R. Z.; Wu, J. Y. Applied Thermal Engineering, Vol. 17, Issue 4 https://doi.org/10.1016/S1359-4311(96)00039-7	journal	April 1997
Comparative Molecular Simulation Study of Methane Adsorption in Metal−Organic Frameworks Wang, Sanyue Energy & Fuels, Vol. 21, Issue 2 https://doi.org/10.1021/ef060578f	journal	March 2007
Ab Initio Study of Hydrogen Adsorption in MOF-5 Sillar, Kaido; Hofmann, Alexander; Sauer, Joachim Journal of the American Chemical Society, Vol. 131, Issue 11 https://doi.org/10.1021/ja8099079	journal	March 2009
Adsorption of CO ₂ -Containing Gas Mixtures over Amine-Bearing Pore-Expanded MCM-41 Silica: Application for Gas Purification Belmabkhout, Youssef; Serna-Guerrero, Rodrigo; Sayari, Abdelhamid Industrial & Engineering Chemistry Research, Vol. 49, Issue 1 https://doi.org/10.1021/ie900837t	journal	January 2010
Discrimination of Small Gas Molecules through Adsorption: Reverse Selectivity for Hydrogen in a Flexible Metal−Organic Framework Chun, Hyungphil; Seo, Jinwoo Inorganic Chemistry, Vol. 48, Issue 21 https://doi.org/10.1021/ic901456k	journal	October 2009
Hydrogen storage in metal–organic frameworks Collins, David J.; Zhou, Hong-Cai Journal of Materials Chemistry, Vol. 17, Issue 30 https://doi.org/10.1039/b702858j	journal	January 2007
Gas Adsorption Properties of the Chromium-Based Metal Organic Framework MIL-101 Chowdhury, Pradip; Bikkina, Chaitanya; Gumma, Sasidhar The Journal of Physical Chemistry C, Vol. 113, Issue 16, p. 6616-6621 https://doi.org/10.1021/jp811418r	journal	March 2009
Molecular Simulation of CO2/H2 Mixture Separation in Metal-organic Frameworks: Effect of Catenation and Electrostatic Interactions Yang, Qingyuan; Xu, Qing; Liu, Bei Chinese Journal of Chemical Engineering, Vol. 17, Issue 5 https://doi.org/10.1016/S1004-9541(08)60277-3	journal	October 2009
High Uptakes of CO ₂ and CH ₄ in Mesoporous MetalOrganic Frameworks MIL-100 and MIL-101 Llewellyn, Philip L.; Bourrelly, Sandrine; Serre, Christian Langmuir, Vol. 24, Issue 14 https://doi.org/10.1021/la800227x	journal	July 2008
Stepwise and hysteretic sorption of N ₂ , O ₂ , CO ₂ , and H ₂ gases in a porous metal–organic framework [Zn2(BPnDC)2(bpy)] Park, Hye Jeong; Suh, Myunghyun Paik Chem. Commun., Vol. 46, Issue 4 https://doi.org/10.1039/B913067E	journal	January 2010
Molecular Simulations for Adsorptive Separation of CO ₂ /CH ₄ Mixture in Metal-Exposed, Catenated, and Charged Metal−Organic Frameworks Babarao, Ravichandar; Jiang, Jianwen; Sandler, Stanley I. Langmuir, Vol. 25, Issue 9 https://doi.org/10.1021/la803074g	journal	December 2008
Reticular synthesis and the design of new materials Yaghi, Omar M.; O'Keeffe, Michael; Ockwig, Nathan W. Nature, Vol. 423, Issue 6941, p. 705-714 https://doi.org/10.1038/nature01650	journal	June 2003
Single Crystal X-ray Diffraction Studies of Carbon Dioxide and Fuel-Related Gases Adsorbed on the Small Pore Scandium Terephthalate Metal Organic Framework, Sc ₂ (O ₂ CC ₆ H ₄ CO ₂ ) ₃ Miller, Stuart R.; Wright, Paul A.; Devic, Thomas Langmuir, Vol. 25, Issue 6 https://doi.org/10.1021/la803788u	journal	March 2009
Thermodynamics of Adsorption Cycles: A Theoretical Study Luo, L.; Feidt, M. Heat Transfer Engineering, Vol. 13, Issue 4 https://doi.org/10.1080/01457639208939785	journal	January 1992
Screening of Metal−Organic Frameworks for Carbon Dioxide Capture from Flue Gas Using a Combined Experimental and Modeling Approach Yazaydın, A. Özgür; Snurr, Randall Q.; Park, Tae-Hong Journal of the American Chemical Society, Vol. 131, Issue 51 https://doi.org/10.1021/ja9057234	journal	December 2009
Metal-organic frameworks with high capacity and selectivity for harmful gases Britt, D.; Tranchemontagne, D.; Yaghi, O. M. Proceedings of the National Academy of Sciences, Vol. 105, Issue 33, p. 11623-11627 https://doi.org/10.1073/pnas.0804900105	journal	August 2008

Similar Records

Adsorption cooling system using metal organic frameworks

Patent · 2023 · OSTI ID:1998531

Adsorption cooling system using carbon aerogel

Patent · 2021 · OSTI ID:1840222

Adsorption cooling system using metal organic frameworks

Patent · 2021 · OSTI ID:1823913

Adsorption cooling system using metal organic frameworks

Citation Formats

References (31)

Similar Records

Related Subjects