Mechanical, corrosion, and wear properties of biomedical Ti–Zr–Nb–Ta–Mo high entropy alloys

Hua, Nengbin; Wang, Wenjie; Wang, Qianting; Ye, Youxiong; Lin, Sihan; Zhang, Lei; Guo, Qiaohang; Brechtl, Jamieson; Liaw, Peter K.

doi:10.1016/j.jallcom.2020.157997

Title: Mechanical, corrosion, and wear properties of biomedical Ti–Zr–Nb–Ta–Mo high entropy alloys

Abstract

The microstructures, mechanical, corrosion, and wear behaviors of the Ti_xZrNbTaMo (x = 0.5, 1, 1.5, and 2, molar ratio) high entropy alloys (HEAs) were studied in this work. It was found that the Ti–Zr–Nb–Ta–Mo HEAs showed a dendrite structure with two body-centered-cubic (BCC) solid solution phases. The Ti_0.5ZrNbTaMo HEA exhibited a high hardness of about 500 HV, high compressive strength approaching 2,600 MPa, and large plastic strain of over 30%. Furthermore, the highly-protective oxide films formed on the surface of Ti–Zr–Nb–Ta–Mo HEAs in the phosphate buffer saline (PBS) solution, which resulted in the high corrosion resistance of the HEAs. The Ti–Zr–Nb–Ta–Mo HEAs exhibited the greater dry- and wet-wear resistance than that of the traditional biomedical Ti6Al4V alloy. The results also indicated that with the decrease in the Ti content, the wear resistance of the Ti–Zr–Nb–Ta–Mo HEAs in the PBS solution improved. Finally, the Ti_0.5ZrNbTaMo alloy presented the highest corrosive wear resistance among the four HEAs owing to its combination of good mechanical properties and high chemical stability.

Authors:

Hua, Nengbin ^[1]; Wang, Wenjie ^[1]; Wang, Qianting ^[1]; Ye, Youxiong ^[2]; Lin, Sihan ^[1]; Zhang, Lei ^[1]; Guo, Qiaohang ^[1]; Brechtl, Jamieson ^[2]; Liaw, Peter K. ^[2]

Fujian Univ. of Technology, Fuzhou (China)
Univ. of Tennessee, Knoxville, TN (United States)

Publication Date:: 2021-11-21

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE; National Natural Science Foundation of China (NNSFC); Natural Science Foundation of Fujian Province; New Century Excellent Talents in University of Fujian Province; National Science Foundation (NSF); US Army Research Office (ARO)

OSTI Identifier:: 1769231

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Journal Article: Accepted Manuscript

Journal Name:: Journal of Alloys and Compounds

Additional Journal Information:: Journal Volume: 861; Journal Issue: 1; Journal ID: ISSN 0925-8388

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; High entropy alloys; Wear; Corrosive wear; Polarization; Mechanical properties

Citation Formats


                    Hua, Nengbin, Wang, Wenjie, Wang, Qianting, Ye, Youxiong, Lin, Sihan, Zhang, Lei, Guo, Qiaohang, Brechtl, Jamieson, and Liaw, Peter K. Mechanical, corrosion, and wear properties of biomedical Ti–Zr–Nb–Ta–Mo high entropy alloys.  United States: N. p., 2021. 
        Web.  doi:10.1016/j.jallcom.2020.157997.

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                    Hua, Nengbin, Wang, Wenjie, Wang, Qianting, Ye, Youxiong, Lin, Sihan, Zhang, Lei, Guo, Qiaohang, Brechtl, Jamieson, & Liaw, Peter K. Mechanical, corrosion, and wear properties of biomedical Ti–Zr–Nb–Ta–Mo high entropy alloys.  United States.  https://doi.org/10.1016/j.jallcom.2020.157997

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                    Hua, Nengbin, Wang, Wenjie, Wang, Qianting, Ye, Youxiong, Lin, Sihan, Zhang, Lei, Guo, Qiaohang, Brechtl, Jamieson, and Liaw, Peter K. 2021.  
        "Mechanical, corrosion, and wear properties of biomedical Ti–Zr–Nb–Ta–Mo high entropy alloys".  United States.  https://doi.org/10.1016/j.jallcom.2020.157997.

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@article{osti_1769231,

  title        = {Mechanical, corrosion, and wear properties of biomedical Ti–Zr–Nb–Ta–Mo high entropy alloys},

  author       = {Hua, Nengbin and Wang, Wenjie and Wang, Qianting and Ye, Youxiong and Lin, Sihan and Zhang, Lei and Guo, Qiaohang and Brechtl, Jamieson and Liaw, Peter K.},

  abstractNote = {The microstructures, mechanical, corrosion, and wear behaviors of the TixZrNbTaMo (x = 0.5, 1, 1.5, and 2, molar ratio) high entropy alloys (HEAs) were studied in this work. It was found that the Ti–Zr–Nb–Ta–Mo HEAs showed a dendrite structure with two body-centered-cubic (BCC) solid solution phases. The Ti0.5ZrNbTaMo HEA exhibited a high hardness of about 500 HV, high compressive strength approaching 2,600 MPa, and large plastic strain of over 30%. Furthermore, the highly-protective oxide films formed on the surface of Ti–Zr–Nb–Ta–Mo HEAs in the phosphate buffer saline (PBS) solution, which resulted in the high corrosion resistance of the HEAs. The Ti–Zr–Nb–Ta–Mo HEAs exhibited the greater dry- and wet-wear resistance than that of the traditional biomedical Ti6Al4V alloy. The results also indicated that with the decrease in the Ti content, the wear resistance of the Ti–Zr–Nb–Ta–Mo HEAs in the PBS solution improved. Finally, the Ti0.5ZrNbTaMo alloy presented the highest corrosive wear resistance among the four HEAs owing to its combination of good mechanical properties and high chemical stability.},

  doi          = {10.1016/j.jallcom.2020.157997},

  url          = {https://www.osti.gov/biblio/1769231},
  journal      = {Journal of Alloys and Compounds},

  issn         = {0925-8388},

  number       = 1,

  volume       = 861,

  place        = {United States},

  year         = {2021},

  month        = {11}

}

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Analysis of Microstructure and Sliding Wear Behavior of Co{sub 1.5}CrFeNi{sub 1.5}Ti{sub 0.5} High-Entropy Alloy

Journal Article Poulia, A.; Georgatis, E.; Lekatou, A.; ... - Journal of Materials Engineering and Performance

Α Co{sub 1.5}CrFeNi{sub 1.5}Ti{sub 0.5} high-entropy alloy (HEA) of the well-known family of CoCrFeNiTi has been designed using empirical parameters. The aim of this design was the production of a HEA with fcc structure that gives ductile behavior and also high strength because of the solid solution effect. The VEC calculations (8.1) supported the fcc structure while the δ factor calculations (4.97) not being out of the limit values, advised a significant lattice distortion. From the other hand, the ΔΗ{sub mix} calculations (− 9.64 kJ/mol) gave strong indications that no intermetallic would be formed. In order to investigate its potential application,more »« less
https://doi.org/10.1007/S11665-018-3374-Y

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journal, February 2012

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journal, September 2014

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journal, November 2018

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journal, February 2017

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journal, May 2015

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journal, February 2019

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journal, March 2017

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journal, January 2015

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journal, July 2011

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journal, October 2019

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journal, July 2015

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journal, June 2013

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journal, March 2019

New Ti-based Ti–Cu–Zr–Fe–Sn–Si–Ag bulk metallic glass for biomedical applications
journal, March 2015

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journal, May 2011

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journal, May 2020

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journal, October 2018

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journal, January 2014

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journal, January 2019

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journal, August 2018

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journal, March 2018

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journal, September 2015

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journal, September 2007

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journal, June 2019

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journal, April 2017

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journal, May 2018

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journal, May 2009

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journal, March 2006

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journal, September 2007

A novel quaternary equiatomic Ti-Zr-Nb-Ta medium entropy alloy (MEA)
journal, October 2018

Review on the Research and Development of Ti-Based Bulk Metallic Glasses
journal, November 2016

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journal, September 2011

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journal, September 2014

Corrosion-wear of β-Ti alloy TMZF (Ti-12Mo-6Zr-2Fe) in simulated body fluid
journal, September 2016

Pin-on-disk wear behavior in a like-on-like configuration in a biological environment of high carbon cast and low carbon forged Co–29Cr–6Mo alloys
journal, February 2007

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journal, May 2018

An assessment on the future development of high-entropy alloys: Summary from a recent workshop
journal, November 2015

Wear-Corrosion Synergism in a CoCrMo Hip Bearing Alloy Is Influenced by Proteins
journal, January 2012

Long-term corrosion resistance of new Ti–Ta–Zr alloy in simulated physiological fluids by electrochemical and surface analysis methods
journal, April 2015

A refractory Hf25Nb25Ti25Zr25 high-entropy alloy with excellent structural stability and tensile properties
journal, September 2014

Contact and Rubbing of Flat Surfaces
journal, August 1953

Microabrasion–corrosion of cast CoCrMo alloy in simulated body fluids
journal, January 2009

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journal, May 2005

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journal, September 2020

Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes
journal, May 2004

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journal, December 2017

A critical review of high entropy alloys and related concepts
journal, January 2017

Cytotoxicity evaluation of 43 metal salts using murine fibroblasts and osteoblastic cells
journal, February 1998

Friction and wear behavior of a single-phase equiatomic TiZrHfNb high-entropy alloy studied using a nanoscratch technique
journal, April 2018

Composition dependence of the microstructure and the mechanical properties of nano/ultrafine-structured Ti–Cu–Ni–Sn–Nb alloys
journal, June 2004

Effects of noble elements on the glass-forming ability, mechanical property, electrochemical behavior and tribocorrosion resistance of Ni- and Cu-free Zr-Al-Co bulk metallic glass
journal, November 2017

Corrosive wear behaviors and mechanisms of a biocompatible Fe-based bulk metallic glass
journal, August 2020

Biomedical materials and techniques to improve the tribological, mechanical and biomedical properties of orthopedic implants – A review article
journal, August 2017

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journal, August 2013

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journal, July 1975

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journal, May 2018

Reciprocating sliding wear behavior of high entropy alloys in dry and marine environments
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journal, May 2018

Dry sliding and tribocorrosion behaviour of hot pressed CoCrMo biomedical alloy as compared with the cast CoCrMo and Ti6Al4V alloys
journal, December 2013

Correlations between the wear resistance and properties of bulk metallic glasses
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journal, September 2020