Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Molten salt synthesis of Ce doped zirconolite for the immobilisation of pyroprocessing wastes and separated plutonium

Journal Article · · Ceramics International

Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
~OTHER
DOE Contract Number:
SC0012704
OSTI ID:
1760494
Report Number(s):
BNL-220842-2021-JACI
Journal Information:
Ceramics International, Vol. 46, Issue 18
Country of Publication:
United States
Language:
English

References (38)

Development of an environmentally benign reprocessing technology—pyrometallurgical reprocessing technology journal January 1998
A preliminary investigation of chlorine XANES in silicate glasses: INVESTIGATION OF CHLORINE XANES journal October 2008
X-ray absorption studies of chlorine valence and local environments in borosilicate waste glasses journal January 2011
The exsolution of magmatic hydrosaline chloride liquids journal October 2004
The Incorporation of Cerium in Zirconolite journal January 1996
Synthesis and characterisation of Pu-doped zirconolites –(Ca 1−x Pu x )Zr(Ti 2-2x Fe 2x )O 7 journal March 2010
Zirconolite-Rich Ceramics for Actinide Wastes journal January 1994
Alpha-recoil damage in zirconolite (CaZrTi 2 O 7 ) journal August 1986
Geochemical alteration of pyrochlore group minerals; betafite subgroup journal October 1996
Retention of Actinides in Natural Pyrochlores and Zirconolites journal January 1994
Rapid low temperature synthesis of a titanate pyrochlore by molten salt mediated reaction journal September 2012
Molten Salt Synthesis of Zirconolite Polytypes journal January 2014
Low-Temperature Synthesis of CaZrO 3 Powder from Molten Salts journal February 2007
Molten Salt Synthesis of Magnesium Aluminate (MgAl2O4) Spinel Powder journal May 2006
Synthesis of Magnesium Aluminate Spinel Platelets from α-Alumina Platelet and Magnesium Sulfate Precursors journal November 2003
Low-Temperature Preparation of Titanium Carbide Coatings on Graphite Flakes from Molten Salts journal February 2008
The effect of pre-treatment parameters on the quality of glass-ceramic wasteforms for plutonium immobilisation, consolidated by hot isostatic pressing journal March 2017
Thermal Processing of Chloride-Contaminated Plutonium Dioxide journal July 2019
Interactions of HCl and H2O with the surface of PuO2 journal May 2019
Energetics of Ce and Pu incorporation into zirconolite waste-forms journal January 2011
Solubility of actinide surrogates in nuclear glasses journal January 2003
The Use of Surrogates in Waste Immobilization Studies: A Case Study of Plutonium journal January 2008
The T OPAS symbolic computation system journal December 2011
Performance of a four-element Si drift detector for X-ray absorption fine-structure spectroscopy: resolution, maximum count rate, and dead-time correction with incorporation into the ATHENA data analysis software journal April 2010
Reevaluation of X-Ray Atomic Energy Levels journal January 1967
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT journal June 2005
Charge Compensation and the Incorporation of Cerium in Zirconolite and Perovskite journal January 1997
Minimization of Eutectic Salt Waste from Pyroprocessing by Oxidative Precipitation of Lanthanides journal October 2009
The fluorite related modulated structures of the Gd2(Zr2−xCex)O7 solid solution: An analogue for Pu disposition journal July 2012
Crystal structure and non-stoichiometry of cerium brannerite: Ce0.975Ti2O5.95 journal August 2012
Crystal-structure effects in the Ce L 3 -edge x-ray-absorption spectrum of CeO 2 : Multiple-scattering resonances and many-body final states journal August 1994
Specific intermediate-valence state of insulating 4 f compounds detected by L 3 x-ray absorption journal January 1987
Role of Microstructure and Surface Defects on the Dissolution Kinetics of CeO 2 , a UO 2 Fuel Analogue journal April 2016
A systematic investigation of the phase assemblage and microstructure of the zirconolite CaZr1-xCexTi2O7 system journal July 2020
The formation and growth of CeOCl crystals in a molten KCl-LiCl flux journal September 2018
The crystal structure of nonmetamict Nb-rich zirconolite-3T from the Eifel paleovolcanic region, Germany journal July 2018
The durability of synroc journal August 1992
The HADES Facility for High Activity Decommissioning Engineering & Science: part of the UK National Nuclear User Facility journal April 2020