Rapid recovery of At-211 by extraction chromatography

Burns, Jonathan D.; Tereshatov, Evgeny E.; Avila, Geoffrey; Glennon, Kevin J.; Hannaman, Andrew; Lofton, Kylie N.; McCann, Laura A.; McCarthy, Mallory A.; McIntosh, Lauren A.; Schultz, Steven J.; Tabacaru, Gabriel C.; Vonder Haar, Amy L.; Yennello, Sherry J.

doi:10.1016/j.seppur.2020.117794

Title: Rapid recovery of At-211 by extraction chromatography

Journal Article · Mon Sep 28 00:00:00 EDT 2020 · Separation and Purification Technology

DOI:https://doi.org/10.1016/j.seppur.2020.117794· OSTI ID:1728681

Burns, Jonathan D. ^[1]; Tereshatov, Evgeny E. ^[1]; Avila, Geoffrey ^[1]; Glennon, Kevin J. ^[1]; Hannaman, Andrew ^[1]; Lofton, Kylie N. ^[1]; McCann, Laura A. ^[1]; McCarthy, Mallory A. ^[1]; McIntosh, Lauren A. ^[1]; Schultz, Steven J. ^[1]; Tabacaru, Gabriel C. ^[1]; Vonder Haar, Amy L. ^[1]; Yennello, Sherry J. ^[1]

Texas A & M Univ., College Station, TX (United States)

The near quantitative separation, purification, and recovery of ²¹¹At has been demonstrated through an extraction chromatography process which utilizes porous beads impregnated with 3-octanone, resulting in an elution yield of 92–95%. Moreover, the rapid nature of this process, <20 min, was achieved after dissolution of a Bi metal target in HNO₃ following retrieval from the beamline after α-particle bombardment. The solution was directly loaded onto the column with no volume or acidity adjustment. The column was washed with HNO₃ and H₂O, and ²¹¹At was eluted with ethanol, collecting roughly 87–93% in 1 mL. This process of recovering high purity ²¹¹At, in near quantitative yields, represents a significant advance in At separations.

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Research Organization:: Texas A & M Univ., College Station, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Nuclear Physics (NP)

Grant/Contract Number:: NA0003841; SC0020958; FG02-93ER40773

OSTI ID:: 1728681

Alternate ID(s):: OSTI ID: 1780311

Journal Information:: Separation and Purification Technology, Vol. 256; ISSN 1383-5866

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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Title: Rapid recovery of At-211 by extraction chromatography

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