Radiation-induced solid-state polymerization in an acrylamide-water system: The effect of phase transformations of metastable high-pressure ice VIII
Journal Article
·
· High Energy Chemistry
OSTI ID:171684
- Institute of Chemical Physics in Chernogolovka, Chernogolovka (Russian Federation)
- Institute of Solid-State Physics, Chernogolovka (Russian Federation)
A drastic suppression of the chain post polymerization process in the quenched high-pressure phase of an acrylamide-water eutectic mixture was observed upon warming of the samples irradiated with {gamma}-rays at 77 K. This effect is explained by dispersion of the samples in the temperature region of the transition of the quenched high-pressure phase into the equilibrium phase ({approximately}150K). The size of the resulting microcrystals of monomer was estimated to be approximately 0.1 {mu}m.
- OSTI ID:
- 171684
- Journal Information:
- High Energy Chemistry, Vol. 29, Issue 4; Other Information: PBD: Jul-Aug 1995; TN: Translated from Khimiya Vysokikh Energii; 29: No. 4, 271-273(1995)
- Country of Publication:
- United States
- Language:
- English
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