In Situ Identification of Non-Specific Adsorption of Alkali Metal Cations on Pt Surfaces and Their Catalytic Roles in Alkaline Solutions
- Authors:
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- ~OTHER
- OSTI Identifier:
- 1690166
- Report Number(s):
- BNL-220488-2020-JACI
Journal ID: 2155-5435
- DOE Contract Number:
- SC0012704
- Resource Type:
- Journal Article
- Journal Name:
- ACS Catalysis
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 19
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 99 GENERAL AND MISCELLANEOUS
Citation Formats
Jiao, L, Liu, E., Mukerjee, S., and Jia, Q. In Situ Identification of Non-Specific Adsorption of Alkali Metal Cations on Pt Surfaces and Their Catalytic Roles in Alkaline Solutions. United States: N. p., 2022.
Web. doi:10.1021/acscatal.0c02762.
Jiao, L, Liu, E., Mukerjee, S., & Jia, Q. In Situ Identification of Non-Specific Adsorption of Alkali Metal Cations on Pt Surfaces and Their Catalytic Roles in Alkaline Solutions. United States. https://doi.org/10.1021/acscatal.0c02762
Jiao, L, Liu, E., Mukerjee, S., and Jia, Q. 2022.
"In Situ Identification of Non-Specific Adsorption of Alkali Metal Cations on Pt Surfaces and Their Catalytic Roles in Alkaline Solutions". United States. https://doi.org/10.1021/acscatal.0c02762.
@article{osti_1690166,
title = {In Situ Identification of Non-Specific Adsorption of Alkali Metal Cations on Pt Surfaces and Their Catalytic Roles in Alkaline Solutions},
author = {Jiao, L and Liu, E. and Mukerjee, S. and Jia, Q.},
abstractNote = {},
doi = {10.1021/acscatal.0c02762},
url = {https://www.osti.gov/biblio/1690166},
journal = {ACS Catalysis},
number = 19,
volume = 10,
place = {United States},
year = {Sat Jan 01 00:00:00 EST 2022},
month = {Sat Jan 01 00:00:00 EST 2022}
}
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Works referenced in this record:
Site-Specific vs Specific Adsorption of Anions on Pt and Pt-Based Alloys
journal, July 2007
- Teliska, Maggie; Murthi, Vivek S.; Mukerjee, Sanjeev
- The Journal of Physical Chemistry C, Vol. 111, Issue 26
The role of non-covalent interactions in electrocatalytic fuel-cell reactions on platinum
journal, August 2009
- Strmcnik, D.; Kodama, K.; van der Vliet, D.
- Nature Chemistry, Vol. 1, Issue 6
The Effect of Noncovalent Interactions on the HOR, ORR, and HER on Ru, Ir, and Ru0.50Ir0.50 Metal Surfaces in Alkaline Environments
journal, June 2012
- Danilovic, N.; Subbaraman, Ram; Strmcnik, D.
- Electrocatalysis, Vol. 3, Issue 3-4
Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li+-Ni(OH)2-Pt Interfaces
journal, December 2011
- Subbaraman, R.; Tripkovic, D.; Strmcnik, D.
- Science, Vol. 334, Issue 6060
Unifying the Hydrogen Evolution and Oxidation Reactions Kinetics in Base by Identifying the Catalytic Roles of Hydroxyl-Water-Cation Adducts
journal, January 2019
- Liu, Ershuai; Li, Jingkun; Jiao, Li
- Journal of the American Chemical Society, Vol. 141, Issue 7
Recent advances in understanding the pH dependence of the hydrogen oxidation and evolution reactions
journal, November 2018
- Giles, Stephen A.; Wilson, Jon C.; Nash, Jared
- Journal of Catalysis, Vol. 367
On the presence of surface bound hydroxyl species on polycrystalline Pt electrodes in the “hydrogen potential region” (0–0.4 V-RHE)
journal, November 2018
- Janik, Michael J.; McCrum, Ian T.; Koper, Marc T. M.
- Journal of Catalysis, Vol. 367
pH and Alkali Cation Effects on the Pt Cyclic Voltammogram Explained Using Density Functional Theory
journal, December 2015
- McCrum, Ian T.; Janik, Michael J.
- The Journal of Physical Chemistry C, Vol. 120, Issue 1
Adsorbed Hydroxide Does Not Participate in the Volmer Step of Alkaline Hydrogen Electrocatalysis
journal, November 2017
- Intikhab, Saad; Snyder, Joshua D.; Tang, Maureen H.
- ACS Catalysis, Vol. 7, Issue 12
Infrared Reflection Absorption Spectroscopy of OH Adsorption on the Low Index Planes of Pt
journal, December 2014
- Tanaka, Hiroyuki; Sugawara, Seiho; Shinohara, Kazuhiko
- Electrocatalysis, Vol. 6, Issue 3
Universal dependence of hydrogen oxidation and evolution reaction activity of platinum-group metals on pH and hydrogen binding energy
journal, March 2016
- Zheng, Jie; Sheng, Wenchao; Zhuang, Zhongbin
- Science Advances, Vol. 2, Issue 3
Correlation between CO Oxidation and H Adsorption/Desorption on Pt Surfaces in a Wide pH Range: The Role of Alkali Cations
journal, January 2017
- García, Gonzalo
- ChemElectroChem, Vol. 4, Issue 3
Co-adsorption of Cations as the Cause of the Apparent pH Dependence of Hydrogen Adsorption on a Stepped Platinum Single-Crystal Electrode
journal, October 2017
- Chen, Xiaoting; McCrum, Ian T.; Schwarz, Kathleen A.
- Angewandte Chemie International Edition, Vol. 56, Issue 47
Understanding the pH Dependence of Underpotential Deposited Hydrogen on Platinum
journal, December 2019
- Yang, Xuan; Nash, Jared; Oliveira, Nicholas
- Angewandte Chemie International Edition, Vol. 58, Issue 49
Investigation into the Competitive and Site-Specific Nature of Anion Adsorption on Pt Using In Situ X-ray Absorption Spectroscopy
journal, October 2008
- Arruda, Thomas M.; Shyam, Badri; Ziegelbauer, Joseph M.
- The Journal of Physical Chemistry C, Vol. 112, Issue 46
Determination of O and OH Adsorption Sites and Coverage in Situ on Pt Electrodes from Pt L 23 X-ray Absorption Spectroscopy
journal, April 2005
- Teliska, M.; O'Grady, W. E.; Ramaker, D. E.
- The Journal of Physical Chemistry B, Vol. 109, Issue 16
Determination of H Adsorption Sites on Pt/C Electrodes in HClO 4 from Pt L 23 X-ray Absorption Spectroscopy
journal, February 2004
- Teliska, M.; O'Grady, W. E.; Ramaker, D. E.
- The Journal of Physical Chemistry B, Vol. 108, Issue 7
Ab initio theory and calculations of X-ray spectra
journal, July 2009
- Rehr, John J.; Kas, Joshua J.; Prange, Micah P.
- Comptes Rendus Physique, Vol. 10, Issue 6
Huge Instability of Pt/C Catalysts in Alkaline Medium
journal, July 2015
- Zadick, Anicet; Dubau, Laetitia; Sergent, Nicolas
- ACS Catalysis, Vol. 5, Issue 8
Water Dissociation on Pt(111) and (100) Anodes: Molecular Orbital Theory
journal, January 1996
- Seong, Seeyearl; Anderson, Alfred B.
- The Journal of Physical Chemistry, Vol. 100, Issue 28
Parameter-free calculations of X-ray spectra with FEFF9
journal, January 2010
- Rehr, John J.; Kas, Joshua J.; Vila, Fernando D.
- Physical Chemistry Chemical Physics, Vol. 12, Issue 21
Bridge-bonded atomic oxygen on Pt(110)
journal, May 2000
- Janin, E.; von Schenck, H.; Göthelid, M.
- Physical Review B, Vol. 61, Issue 19
Explanation of Dramatic pH-Dependence of Hydrogen Binding on Noble Metal Electrode: Greatly Weakened Water Adsorption at High pH
journal, May 2018
- Cheng, Tao; Wang, Lu; Merinov, Boris V.
- Journal of the American Chemical Society, Vol. 140, Issue 25
Activity Descriptor Identification for Oxygen Reduction on Platinum-Based Bimetallic Nanoparticles: In Situ Observation of the Linear Composition–Strain–Activity Relationship
journal, January 2015
- Jia, Qingying; Liang, Wentao; Bates, Michael K.
- ACS Nano, Vol. 9, Issue 1
Experimental Proof of the Bifunctional Mechanism for the Hydrogen Oxidation in Alkaline Media
journal, November 2017
- Li, Jingkun; Ghoshal, Shraboni; Bates, Michael K.
- Angewandte Chemie International Edition, Vol. 56, Issue 49
Analysis of Double Layer and Adsorption Effects at the Alkaline Polymer Electrolyte-Electrode Interface
journal, January 2011
- Ünlü, Murat; Abbott, Daniel; Ramaswamy, Nagappan
- Journal of The Electrochemical Society, Vol. 158, Issue 11
Pt L 3 -edge XANES studies about the hydrogen adsorption on small Pt particles
journal, May 1999
- Asakura, K.; Kubota, T.; Chun, W. J.
- Journal of Synchrotron Radiation, Vol. 6, Issue 3
A new method for quantitative characterization of adsorbed hydrogen on Pt particles by means of Pt L-edge XANES
journal, July 1996
- Kubota, T.; Asakura, K.; Ichikuni, N.
- Chemical Physics Letters, Vol. 256, Issue 4-5
Adsorption of water monomer and clusters on platinum(111) terrace and related steps and kinks
journal, October 2010
- Árnadóttir, Líney; Stuve, Eric M.; Jónsson, Hannes
- Surface Science, Vol. 604, Issue 21-22
Correlating hydrogen oxidation and evolution activity on platinum at different pH with measured hydrogen binding energy
journal, January 2015
- Sheng, Wenchao; Zhuang, Zhongbin; Gao, Minrui
- Nature Communications, Vol. 6, Issue 1
Water dissociation on well-defined platinum surfaces: The electrochemical perspective
journal, March 2013
- van der Niet, Maria J. T. C.; Garcia-Araez, Nuria; Hernández, Javier
- Catalysis Today, Vol. 202
The Fate of Water at the Electrochemical Interfaces: Electrochemical Behavior of Free Water Versus Coordinating Water
journal, November 2018
- Dubouis, Nicolas; Serva, Alessandra; Salager, Elodie
- The Journal of Physical Chemistry Letters, Vol. 9, Issue 23
Interfacial water reorganization as a pH-dependent descriptor of the hydrogen evolution rate on platinum electrodes
journal, March 2017
- Ledezma-Yanez, Isis; Wallace, W. David Z.; Sebastián-Pascual, Paula
- Nature Energy, Vol. 2, Issue 4
Electrochemistry of Methanol at Low Index Crystal Planes of Platinum: An Integrated Voltammetric and Chronoamperometric Study
journal, May 1994
- Herrero, E.; Franaszczuk, K.; Wieckowski, A.
- The Journal of Physical Chemistry, Vol. 98, Issue 19
Comparing Hydrogen Oxidation and Evolution Reaction Kinetics on Polycrystalline Platinum in 0.1 M and 1 M KOH
journal, March 2013
- Rheinlander, P.; Henning, S.; Herranz, J.
- ECS Transactions, Vol. 50, Issue 2
Electrocatalysis on Platinum Nanoparticles: Particle Size Effect on Oxygen Reduction Reaction Activity
journal, September 2011
- Shao, Minhua; Peles, Amra; Shoemaker, Krista
- Nano Letters, Vol. 11, Issue 9
Interfacial water shuffling the intermediates of hydrogen oxidation and evolution reactions in aqueous media
journal, January 2020
- Liu, Ershuai; Jiao, Li; Li, Jingkun
- Energy & Environmental Science, Vol. 13, Issue 9
Quaternary Ammonium Cation Specific Adsorption on Platinum Electrodes: A Combined Experimental and Density Functional Theory Study
journal, January 2018
- McCrum, I. T.; Hickner, M. A.; Janik, M. J.
- Journal of The Electrochemical Society, Vol. 165, Issue 2
Effect of Organic Cations on Hydrogen Oxidation Reaction of Carbon Supported Platinum
journal, January 2016
- Chung, Hoon Taek; Choe, Yoong-Kee; Martinez, Ulises
- Journal of The Electrochemical Society, Vol. 163, Issue 14
Best Practices and Testing Protocols for Benchmarking ORR Activities of Fuel Cell Electrocatalysts Using Rotating Disk Electrode
journal, May 2017
- Kocha, Shyam S.; Shinozaki, Kazuma; Zack, Jason W.
- Electrocatalysis, Vol. 8, Issue 4
Fundamental Aspects of Spontaneous Cathodic Deposition of Ru onto Pt/C Electrocatalysts and Membranes under Direct Methanol Fuel Cell Operating Conditions: An in Situ X-ray Absorption Spectroscopy and Electron Spin Resonance Study
journal, December 2009
- Arruda, Thomas M.; Shyam, Badri; Lawton, Jamie S.
- The Journal of Physical Chemistry C, Vol. 114, Issue 2
IFEFFIT : interactive XAFS analysis and FEFF fitting
journal, March 2001
- Newville, Matthew
- Journal of Synchrotron Radiation, Vol. 8, Issue 2
Atomic Structure and the Magnetic Properties of ZrDoped Sm2Co17
journal, January 2005
- Ravel, B.; Gallagher, K.
- Physica Scripta
Near-edge x-ray-absorption fine structure of Pb: A comparison of theory and experiment
journal, June 1993
- Newville, M.; Līviņš, P.; Yacoby, Y.
- Physical Review B, Vol. 47, Issue 21
Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure
journal, September 1998
- Ankudinov, A. L.; Ravel, B.; Rehr, J. J.
- Physical Review B, Vol. 58, Issue 12
Circumventing Metal Dissolution Induced Degradation of Pt-Alloy Catalysts in Proton Exchange Membrane Fuel Cells: Revealing the Asymmetric Volcano Nature of Redox Catalysis
journal, January 2016
- Jia, Qingying; Li, Jingkun; Caldwell, Keegan
- ACS Catalysis, Vol. 6, Issue 2