High-Performance Nitrogen-Doped Intermetallic PtNi Catalyst for the Oxygen Reduction Reaction

Zhao, X; Xi, C.; Zhang, R.; Song, L.; Wang, C.; Spendelow, J.; Frenkel, A.; Yang, J.; Xin, H.; Sasaki, K.

doi:10.1021/acscatal.0c03036

High-Performance Nitrogen-Doped Intermetallic PtNi Catalyst for the Oxygen Reduction Reaction

Journal Article · 01 January 2022 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.0c03036· OSTI ID:1690150

Zhao, X; Xi, C.; Zhang, R.; Song, L.; Wang, C.; Spendelow, J.; Frenkel, A.; Yang, J.; Xin, H.; Sasaki, K.

Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Fuel Cell Technologies Office; USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Laboratory Directed Research and Development (LDRD) Program

DOE Contract Number:: SC0012704

OSTI ID:: 1690150

Report Number(s):: BNL-220473-2020-JACI

Journal Information:: ACS Catalysis, Vol. 10, Issue 18

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (54)

Core-Protected Platinum Monolayer Shell High-Stability Electrocatalysts for Fuel-Cell Cathodes No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.201004287		October 2010
Fine-grained and fully ordered intermetallic PtFe catalysts with largely enhanced catalytic activity and durability No authors listed Energy & Environmental Science https://doi.org/10.1039/c6ee01204c		January 2016
Atomic rearrangement from disordered to ordered Pd-Fe nanocatalysts with trace amount of Pt decoration for efficient electrocatalysis No authors listed Nano Energy https://doi.org/10.1016/j.nanoen.2018.05.032		August 2018
Effects of carbon supports on Pt distribution, ionomer coverage and cathode performance for polymer electrolyte fuel cells No authors listed Journal of Power Sources https://doi.org/10.1016/j.jpowsour.2016.02.091		May 2016
Bimetallic IrNi core platinum monolayer shell electrocatalysts for the oxygen reduction reaction No authors listed Energy Environ. Sci. https://doi.org/10.1039/c1ee02067f		January 2012
Lattice strains in disordered mixed salts No authors listed Solid State Communications https://doi.org/10.1016/s0038-1098(96)80051-2		July 1996
Elucidating Oxygen Reduction Active Sites in Pyrolyzed Metal–Nitrogen Coordinated Non-Precious-Metal Electrocatalyst Systems No authors listed The Journal of Physical Chemistry C https://doi.org/10.1021/jp500781v		April 2014
Recent Advances of Structurally Ordered Intermetallic Nanoparticles for Electrocatalysis No authors listed ACS Catalysis https://doi.org/10.1021/acscatal.7b04420		March 2018
High-Loading Intermetallic Pt ₃ Co/C Core–Shell Nanoparticles as Enhanced Activity Electrocatalysts toward the Oxygen Reduction Reaction (ORR) No authors listed Chemistry of Materials https://doi.org/10.1021/acs.chemmater.7b04201		February 2018
Differential Surface Elemental Distribution Leads to Significantly Enhanced Stability of PtNi-Based ORR Catalysts No authors listed Matter https://doi.org/10.1016/j.matt.2019.07.015		December 2019
Highly Durable and Active PtFe Nanocatalyst for Electrochemical Oxygen Reduction Reaction No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.5b09653		December 2015
Fe-N-C Oxygen Reduction Fuel Cell Catalyst Derived from Carbendazim: Synthesis, Structure, and Reactivity No authors listed Advanced Energy Materials https://doi.org/10.1002/aenm.201301735		March 2014
The Quasi‐Pt‐Allotrope Catalyst: Hollow PtCo@single‐Atom Pt ₁ on Nitrogen‐Doped Carbon toward Superior Oxygen Reduction No authors listed Advanced Functional Materials https://doi.org/10.1002/adfm.201807340		February 2019
Fe Stabilization by Intermetallic L1 ₀ -FePt and Pt Catalysis Enhancement in L1 ₀ -FePt/Pt Nanoparticles for Efficient Oxygen Reduction Reaction in Fuel Cells No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.7b12829		February 2018
Electrocatalyst approaches and challenges for automotive fuel cells No authors listed Nature https://doi.org/10.1038/nature11115		June 2012
Ga–Doped Pt–Ni Octahedral Nanoparticles as a Highly Active and Durable Electrocatalyst for Oxygen Reduction Reaction No authors listed Nano Letters https://doi.org/10.1021/acs.nanolett.8b00028		March 2018
Determination of Single- and Multi-Component Nanoparticle Sizes by X-ray Absorption Spectroscopy No authors listed Journal of The Electrochemical Society https://doi.org/10.1149/2.0281815jes		January 2018
Ligand-Effect-Induced Oxygen Reduction Reaction Activity Enhancement for Pt/Zr/Pt(111) Surfaces with Tensile Strain Relieved by Stacking Faults No authors listed ACS Applied Energy Materials https://doi.org/10.1021/acsaem.9b00873		June 2019
Linking structure to function: The search for active sites in non-platinum group metal oxygen reduction reaction catalysts No authors listed Nano Energy https://doi.org/10.1016/j.nanoen.2016.05.025		November 2016
Nanoscale Structure Design for High-Performance Pt-Based ORR Catalysts No authors listed Advanced Materials https://doi.org/10.1002/adma.201802234		December 2018
Unique Electrochemical Adsorption Properties of Pt-Skin Surfaces No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.201107668		February 2012
Enhanced Oxygen Reduction Reaction Activity on Pt-Monolayer-Shell PdIr/Ni-Core Catalysts No authors listed Journal of The Electrochemical Society https://doi.org/10.1149/2.0391815jes		January 2018
Hard-Magnet L10-CoPt Nanoparticles Advance Fuel Cell Catalysis No authors listed Joule https://doi.org/10.1016/j.joule.2018.09.016		January 2019
Comparative Study of the Electrocatalytically Active Surface Areas (ECSAs) of Pt Alloy Nanoparticles Evaluated by Hupd and CO-stripping voltammetry No authors listed Electrocatalysis https://doi.org/10.1007/s12678-014-0205-2		June 2014
Sub‐6 nm Fully Ordered L 1 ₀ ‐Pt–Ni–Co Nanoparticles Enhance Oxygen Reduction via Co Doping Induced Ferromagnetism Enhancement and Optimized Surface Strain No authors listed Advanced Energy Materials https://doi.org/10.1002/aenm.201803771		March 2019
Intermetallic hcp -PtBi/ fcc -Pt Core/Shell Nanoplates Enable Efficient Bifunctional Oxygen Reduction and Methanol Oxidation Electrocatalysis No authors listed ACS Catalysis https://doi.org/10.1021/acscatal.7b04406		May 2018
Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts No authors listed Nature Chemistry https://doi.org/10.1038/nchem.623		April 2010
Enhancement of the oxygen reduction on nitride stabilized pt-M (M=Fe, Co, and Ni) core–shell nanoparticle electrocatalysts No authors listed Nano Energy https://doi.org/10.1016/j.nanoen.2015.03.007		April 2015
First-Principle Study of the Adsorption and Dissociation of O ₂ on Pt(111) in Acidic Media No authors listed The Journal of Physical Chemistry C https://doi.org/10.1021/jp9059505		November 2009
Batteries and fuel cells for emerging electric vehicle markets No authors listed Nature Energy https://doi.org/10.1038/s41560-018-0108-1		April 2018
Ultrathin Icosahedral Pt-Enriched Nanocage with Excellent Oxygen Reduction Reaction Activity No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.5b12530		January 2016
Transition Metal Nitride Coated with Atomic Layers of Pt as a Low-Cost, Highly Stable Electrocatalyst for the Oxygen Reduction Reaction No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.5b11364		January 2016
Au-Doped Stable L1 ₀ Structured Platinum Cobalt Ordered Intermetallic Nanoparticle Catalysts for Enhanced Electrocatalysis No authors listed ACS Applied Energy Materials https://doi.org/10.1021/acsaem.8b00555		August 2018
Ionomer distribution control in porous carbon-supported catalyst layers for high-power and low Pt-loaded proton exchange membrane fuel cells No authors listed Nature Materials https://doi.org/10.1038/s41563-019-0487-0		September 2019
Structurally Ordered FePt Nanoparticles and Their Enhanced Catalysis for Oxygen Reduction Reaction No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja1009629		April 2010
Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis No authors listed Science https://doi.org/10.1126/science.aah6133		December 2016
Unconventional p–d Hybridization Interaction in PtGa Ultrathin Nanowires Boosts Oxygen Reduction Electrocatalysis No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.9b07238		October 2019
Atomically Dispersed Fe-N _x /C Electrocatalyst Boosts Oxygen Catalysis via a New Metal-Organic Polymer Supramolecule Strategy No authors listed Advanced Energy Materials https://doi.org/10.1002/aenm.201801226		July 2018
Highly stable Pt monolayer on PdAu nanoparticle electrocatalysts for the oxygen reduction reaction No authors listed Nature Communications https://doi.org/10.1038/ncomms2124		January 2012
Relationship between the area of L _2,3 x‐ray absorption edge resonances and the d orbital occupancy in compounds of platinum and iridium No authors listed The Journal of Chemical Physics https://doi.org/10.1063/1.443105		February 1982
Effect of chemical environment on magnitude of x‐ray absorption resonance at L _{I I I} edges. Studies on metallic elements, compounds, and catalysts No authors listed The Journal of Chemical Physics https://doi.org/10.1063/1.437376		June 1979
Nitride Stabilized PtNi Core–Shell Nanocatalyst for high Oxygen Reduction Activity No authors listed Nano Letters https://doi.org/10.1021/nl303362s		February 2012
Oxygen Reduction on Well-Defined Core−Shell Nanocatalysts: Particle Size, Facet, and Pt Shell Thickness Effects No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja9067645		December 2009
Dealloyed binary PtM3 (M=Cu, Co, Ni) and ternary PtNi3M (M=Cu, Co, Fe, Cr) electrocatalysts for the oxygen reduction reaction: Performance in polymer electrolyte membrane fuel cells No authors listed Journal of Power Sources https://doi.org/10.1016/j.jpowsour.2010.07.047		January 2011
Oxygen Reduction Activity of Dealloyed Pt1–xNix Catalysts No authors listed Journal of The Electrochemical Society https://doi.org/10.1149/1.3595749		January 2011
Improving the Performance of a PEMFC with Ketjenblack EC-600JD Carbon Black as the Material of the Microporous Layer No authors listed Electrochemical and Solid-State Letters https://doi.org/10.1149/1.1904504		January 2005
Transformation of molecular oxygen on a platinum surface: A theoretical calculation of STM images No authors listed Physical Review B https://doi.org/10.1103/PhysRevB.59.15437		June 1999
Phase Transformation, Coalescence, and Twinning of Monodisperse FePt Nanocrystals No authors listed Nano Letters https://doi.org/10.1021/nl0100421		July 2001
Recent Development of Active Nanoparticle Catalysts for Fuel Cell Reactions No authors listed Advanced Functional Materials https://doi.org/10.1002/adfm.200902293		April 2010
Synchrotron-Based In Situ Characterization of Carbon-Supported Platinum and Platinum Monolayer Electrocatalysts No authors listed ACS Catalysis https://doi.org/10.1021/acscatal.5b01862		December 2015
Direct Enumeration of the Geometrical Characteristics of Clusters No authors listed Nanostructured Materials https://doi.org/10.1016/s0965-9773(97)00168-2		May 1997
Unusual strain effect of a Pt-based L1 ₀ face-centered tetragonal core in core/shell nanoparticles for the oxygen reduction reaction No authors listed Physical Chemistry Chemical Physics https://doi.org/10.1039/c8cp06756b		January 2019
Rapid Room-Temperature Synthesis of a Metastable Ordered Intermetallic Electrocatalyst No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.8b09919		January 2019
Rh-Doped Pt–Ni Octahedral Nanoparticles: Understanding the Correlation between Elemental Distribution, Oxygen Reduction Reaction, and Shape Stability No authors listed Nano Letters https://doi.org/10.1021/acs.nanolett.5b04636		February 2016

Similar Records

Nitrogen-Doped PtNi Catalysts on Polybenzimidazole-Functionalized Carbon Support for the Oxygen Reduction Reaction in Polymer Electrolyte Membrane Fuel Cells

Journal Article · 2022 · ACS Applied Materials and Interfaces · OSTI ID:1879430

Li, Chenzhao; Song, Liang; Zhao, Xueru; +2 more

Related Subjects

30 DIRECT ENERGY CONVERSION
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

High-Performance Nitrogen-Doped Intermetallic PtNi Catalyst for the Oxygen Reduction Reaction

Citation Formats

References (54)

Similar Records

Related Subjects