Vertical Lamellae Formed by Two-Step Annealing of a Rod-Coil Liquid Crystalline Block Copolymer Thin Film

Shi, L; Lan, J.; Lee, S.; Cheng, L.; Yager, K.; Ross, C.

doi:10.1021/acsnano.9b09702

Vertical Lamellae Formed by Two-Step Annealing of a Rod-Coil Liquid Crystalline Block Copolymer Thin Film

Journal Article · 01 January 2022 · ACS Nano

DOI:https://doi.org/10.1021/acsnano.9b09702· OSTI ID:1690013

Shi, L; Lan, J.; Lee, S.; Cheng, L.; Yager, K.; Ross, C.

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: ~OTHER

DOE Contract Number:: SC0012704

OSTI ID:: 1690013

Report Number(s):: BNL-220341-2020-JACI

Journal Information:: ACS Nano, Journal Name: ACS Nano Journal Issue: 4 Vol. 14; ISSN 1936-0851

Country of Publication:: United States

Language:: English

References (48)

Multilayer block copolymer meshes by orthogonal self-assembly Tavakkoli K. G., Amir; Nicaise, Samuel M.; Gadelrab, Karim R. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10518	journal	January 2016
Mesogen-jacketed liquid crystalline polymers Chen, Xiao-Fang; Shen, Zhihao; Wan, Xin-Hua Chemical Society Reviews, Vol. 39, Issue 8 https://doi.org/10.1039/b814540g	journal	January 2010
Controlling Domain Spacing and Grain Size in Cylindrical Block Copolymer Thin Films by Means of Thermal and Solvent Vapor Annealing Gu, Xiaodan; Gunkel, Ilja; Hexemer, Alexander Macromolecules, Vol. 49, Issue 9 https://doi.org/10.1021/acs.macromol.6b00429	journal	April 2016
Defect Annihilation Pathways in Directed Assembly of Lamellar Block Copolymer Thin Films Hur, Su-Mi; Thapar, Vikram; Ramírez-Hernández, Abelardo ACS Nano, Vol. 12, Issue 10 https://doi.org/10.1021/acsnano.8b04202	journal	September 2018
Universal perpendicular orientation of block copolymer microdomains using a filtered plasma Oh, Jinwoo; Suh, Hyo Seon; Ko, Youngpyo Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-10907-5	journal	July 2019
Thin Film Self-Assembly of a Silicon-Containing Rod–Coil Liquid Crystalline Block Copolymer Shi, Ling-Ying; Lee, Sangho; Cheng, Li-Chen Macromolecules, Vol. 52, Issue 2 https://doi.org/10.1021/acs.macromol.8b01938	journal	January 2019
Block Copolymers—Designer Soft Materials Bates, Frank S.; Fredrickson, Glenn H. Physics Today, Vol. 52, Issue 2 https://doi.org/10.1063/1.882522	journal	February 1999
Evolution of Block Copolymer Lithography to Highly Ordered Square Arrays Tang, C.; Lennon, E. M.; Fredrickson, G. H. Science, Vol. 322, Issue 5900 https://doi.org/10.1126/science.1162950	journal	October 2008
Core–Shell and Zigzag Nanostructures from a Thin Film Silicon-Containing Conformationally Asymmetric Triblock Terpolymer Shi, Ling-Ying; Liao, Fen; Cheng, Li-Chen ACS Macro Letters, Vol. 8, Issue 7 https://doi.org/10.1021/acsmacrolett.9b00283	journal	June 2019
Controlling orientational order in block copolymers using low-intensity magnetic fields Gopinadhan, Manesh; Choo, Youngwoo; Kawabata, Kohsuke Proceedings of the National Academy of Sciences, Vol. 114, Issue 45 https://doi.org/10.1073/pnas.1712631114	journal	October 2017
Carbohydrate-Based Block Copolymer Thin Films: Ultrafast Nano-Organization with 7 nm Resolution Using Microwave Energy Liao, Yingjie; Chen, Wen-Chang; Borsali, Redouane Advanced Materials, Vol. 29, Issue 35 https://doi.org/10.1002/adma.201701645	journal	July 2017
Liquid crystal engineering – new complex mesophase structures and their relations to polymer morphologies, nanoscale patterning and crystal engineering Tschierske, Carsten Chemical Society Reviews, Vol. 36, Issue 12 https://doi.org/10.1039/b615517k	journal	January 2007
Orientation and Alignment Control of Microphase-Separated PS- b -PDMS Substrate Patterns via Polymer Brush Chemistry Borah, Dipu; Rasappa, Sozaraj; Senthamaraikannan, Ramsankar ACS Applied Materials & Interfaces, Vol. 5, Issue 1 https://doi.org/10.1021/am302150z	journal	December 2012
Defect-Free Nanoporous Thin Films from ABC Triblock Copolymers Bang, Joona; Kim, Seung Hyun; Drockenmuller, Eric Journal of the American Chemical Society, Vol. 128, Issue 23 https://doi.org/10.1021/ja0608141	journal	June 2006
Neutrality Conditions for Block Copolymer Systems on Random Copolymer Brush Surfaces Huang, E.; Pruzinsky, S.; Russell, T. P. Macromolecules, Vol. 32, Issue 16 https://doi.org/10.1021/ma990483v	journal	August 1999
Solvent-Vapor-Induced Tunability of Self-Assembled Block Copolymer Patterns Jung, Yeon Sik; Ross, Caroline A. Advanced Materials, Vol. 21, Issue 24 https://doi.org/10.1002/adma.200802855	journal	June 2009
Vertical Orientation of Nanocylinders in Liquid-Crystalline Block Copolymers Directed by Light Wang, Tianjie; Li, Xiao; Dong, Zhijiao ACS Applied Materials & Interfaces, Vol. 9, Issue 29 https://doi.org/10.1021/acsami.7b06086	journal	July 2017
Morphology Control in Block Copolymer Films Using Mixed Solvent Vapors Gotrik, Kevin W.; Hannon, Adam F.; Son, Jeong Gon ACS Nano, Vol. 6, Issue 9 https://doi.org/10.1021/nn302641z	journal	August 2012
Membranes with Highly Ordered Straight Nanopores by Selective Swelling of Fast Perpendicularly Aligned Block Copolymers Yin, Jun; Yao, Xueping; Liou, Jiun-You ACS Nano, Vol. 7, Issue 11 https://doi.org/10.1021/nn403847z	journal	October 2013
Unravelling inherent electrocatalysis of mixed-conducting oxide activated by metal nanoparticle for fuel cell electrodes Choi, Yoonseok; Cha, Seung Keun; Ha, Hyunwoo Nature Nanotechnology, Vol. 14, Issue 3 https://doi.org/10.1038/s41565-019-0367-4	journal	February 2019
Liquid Crystalline Orientation of Rod Blocks within Lamellar Nanostructures from Rod−Coil Diblock Copolymers Olsen, Bradley D.; Gu, Xun; Hexemer, Alexander Macromolecules, Vol. 43, Issue 16 https://doi.org/10.1021/ma101056r	journal	August 2010
Phase Diagram of Rod–Coil Diblock Copolymer Melts Tang, Jiuzhou; Jiang, Ying; Zhang, Xinghua Macromolecules, Vol. 48, Issue 24 https://doi.org/10.1021/acs.macromol.5b02235	journal	November 2015
Self-Assembled Smectic Phases in Rod-Coil Block Copolymers Chen, J. T.; Thomas, E. L.; Ober, C. K. Science, Vol. 273, Issue 5273 https://doi.org/10.1126/science.273.5273.343	journal	July 1996
Silicon-containing block copolymers for lithographic applications Lo, Ting-Ya; Krishnan, Mohan Raj; Lu, Kai-Yuan Progress in Polymer Science, Vol. 77 https://doi.org/10.1016/j.progpolymsci.2017.10.002	journal	February 2018
Metal-Containing Block Copolymer Thin Films Yield Wire Grid Polarizers with High Aspect Ratio Kim, So Youn; Gwyther, Jessica; Manners, Ian Advanced Materials, Vol. 26, Issue 5 https://doi.org/10.1002/adma.201303452	journal	October 2013
Highly Tunable Self-Assembled Nanostructures from a Poly(2-vinylpyridine- b -dimethylsiloxane) Block Copolymer Jeong, Jae Won; Park, Woon Ik; Kim, Mi-Jeong Nano Letters, Vol. 11, Issue 10 https://doi.org/10.1021/nl2016224	journal	October 2011
Double-Layer Morphologies from a Silicon-Containing ABA Triblock Copolymer Lee, Sangho; Cheng, Li-Chen; Gadelrab, Karim R. ACS Nano, Vol. 12, Issue 6 https://doi.org/10.1021/acsnano.8b02851	journal	May 2018
Alignment of Self-Assembled Hierarchical Microstructure in Liquid Crystalline Diblock Copolymers Using High Magnetic Fields Osuji, Chinedum; Ferreira, Paulo J.; Mao, Guoping Macromolecules, Vol. 37, Issue 26 https://doi.org/10.1021/ma0483064	journal	December 2004
Templated Self-Assembly of a PS- Branch -PDMS Bottlebrush Copolymer Cheng, Li-Chen; Gadelrab, Karim R.; Kawamoto, Ken Nano Letters, Vol. 18, Issue 7 https://doi.org/10.1021/acs.nanolett.8b01389	journal	June 2018
Sub-10 nm Features Obtained from Directed Self-Assembly of Semicrystalline Polycarbosilane-Based Block Copolymer Thin Films Aissou, Karim; Mumtaz, Muhammad; Fleury, Guillaume Advanced Materials, Vol. 27, Issue 2 https://doi.org/10.1002/adma.201404077	journal	November 2014
Order-disorder-and order-order-transitions in AB and ABC block copolymers: description by a simple model Abetz, Volker; Stadler, Reimund; Leibler, Ludwik Polymer Bulletin, Vol. 37, Issue 1 https://doi.org/10.1007/BF00313829	journal	July 1996
Molecular Weight Dependence of Phase Structures and Transitions of Mesogen-Jacketed Liquid Crystalline Polymers Based on 2-Vinylterephthalic Acids Ye, Chun; Zhang, Hai-Liang; Huang, Yun Macromolecules, Vol. 37, Issue 19 https://doi.org/10.1021/ma049195b	journal	September 2004
Photoresponsive liquid crystalline block copolymers: From photonics to nanotechnology Yu, Haifeng Progress in Polymer Science, Vol. 39, Issue 4 https://doi.org/10.1016/j.progpolymsci.2013.08.005	journal	April 2014
Highly Asymmetric Phase Behaviors of Polyhedral Oligomeric Silsesquioxane-Based Multiheaded Giant Surfactants Huang, Mingjun; Yue, Kan; Huang, Jiahao ACS Nano, Vol. 12, Issue 2 https://doi.org/10.1021/acsnano.7b08687	journal	January 2018
Highly Ordered Nanoring Arrays Formed by Templated Si-Containing Triblock Terpolymer Thin Films Aissou, Karim; Mumtaz, Muhammad; Marcasuzaa, Pierre Small, Vol. 13, Issue 12 https://doi.org/10.1002/smll.201603184	journal	January 2017
Ordering Pathway of Block Copolymers under Dynamic Thermal Gradients Studied by in Situ GISAXS Samant, Saumil; Strzalka, Joseph; Yager, Kevin G. Macromolecules, Vol. 49, Issue 22 https://doi.org/10.1021/acs.macromol.6b01555	journal	October 2016
Widely Tunable Morphologies in Block Copolymer Thin Films Through Solvent Vapor Annealing Using Mixtures of Selective Solvents Chavis, Michelle A.; Smilgies, Detlef-M.; Wiesner, Ulrich B. Advanced Functional Materials, Vol. 25, Issue 20 https://doi.org/10.1002/adfm.201404053	journal	April 2015
3D Orientational Control in Self-Assembled Thin Films with Sub-5 nm Features by Light Nickmans, Koen; Bögels, Gerardus M.; Sánchez-Somolinos, Carlos Small, Vol. 13, Issue 33 https://doi.org/10.1002/smll.201701043	journal	July 2017
Perforated Layer Structures in Liquid Crystalline Rod−Coil Block Copolymers Tenneti, Kishore K.; Chen, Xiaofang; Li, Christopher Y. Journal of the American Chemical Society, Vol. 127, Issue 44 https://doi.org/10.1021/ja053548k	journal	November 2005
50th Anniversary Perspective : Putting the Squeeze on Polymers: A Perspective on Polymer Thin Films and Interfaces Russell, Thomas P.; Chai, Yu Macromolecules, Vol. 50, Issue 12 https://doi.org/10.1021/acs.macromol.7b00418	journal	May 2017
Lateral Ordering of Cylindrical Microdomains Under Solvent Vapor Park, Soojin; Kim, Bokyung; Xu, Ji Macromolecules, Vol. 42, Issue 4 https://doi.org/10.1021/ma802480s	journal	February 2009
Laterally Ordered Sub-10 nm Features Obtained From Directed Self-Assembly of Si-Containing Block Copolymer Thin Films Rho, Yecheol; Aissou, Karim; Mumtaz, Muhammad Small, Vol. 11, Issue 48 https://doi.org/10.1002/smll.201500439	journal	November 2015
Effect of Entrapped Solvent on the Evolution of Lateral Order in Self-Assembled P(S- r -MMA)/PS- b -PMMA Systems with Different Thicknesses Giammaria, Tommaso Jacopo; Ferrarese Lupi, Federico; Seguini, Gabriele ACS Applied Materials & Interfaces, Vol. 9, Issue 37 https://doi.org/10.1021/acsami.6b14332	journal	February 2017
Measurement of isothermal vapor-liquid equilibriums for acetone-n-heptane mixtures using modified Gillespie still Maripuri, Venkatachalapati O.; Ratcliff, Gerald A. Journal of Chemical & Engineering Data, Vol. 17, Issue 3 https://doi.org/10.1021/je60054a031	journal	July 1972
Remarkably Rich Variety of Nanostructures and Order–Order Transitions in a Rod–Coil Diblock Copolymer Shi, Ling-Ying; Zhou, Yu; Fan, Xing-He Macromolecules, Vol. 46, Issue 13 https://doi.org/10.1021/ma400944z	journal	June 2013
Block Copolymer Self-Assembly–Directed Single-Crystal Homo- and Heteroepitaxial Nanostructures Arora, Hitesh; Du, Phong; Tan, Kwan W. Science, Vol. 330, Issue 6001, p. 214-219 https://doi.org/10.1126/science.1193369	journal	October 2010
Monodisperse Pattern Nanoalloying for Synergistic Intermetallic Catalysis Mun, Jeong Ho; Chang, Yun Hee; Shin, Dong Ok Nano Letters, Vol. 13, Issue 11 https://doi.org/10.1021/nl403542h	journal	October 2013
Reversible Morphology Control in Block Copolymer Films via Solvent Vapor Processing: An in Situ GISAXS Study Paik, Marvin Y.; Bosworth, Joan K.; Smilges, Detlef-M. Macromolecules, Vol. 43, Issue 9 https://doi.org/10.1021/ma902646t	journal	May 2010

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