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Title: Anthracene as a Launchpad for a Phosphinidene Sulfide and for Generation of a Phosphorus−Sulfur Material Having the Composition P2S, a Vulcanized Red Phosphorus That Is Yellow

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.8b10775· OSTI ID:1689948

Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
~OTHER
DOE Contract Number:
SC0012704
OSTI ID:
1689948
Report Number(s):
BNL-220277-2020-JACI
Journal Information:
Journal of the American Chemical Society, Vol. 141
Country of Publication:
United States
Language:
English

References (76)

7-Silanorbornadienes and their thermal cycloeliminations journal January 1980
Synthesis, Characterization, and Thermolysis of Dibenzo-7-dimethylgermanorbornadiene journal August 2015
Synthesis, characterization, and thermolysis of 7-amino-7-azabenzonorbornadienes journal May 1988
Facile Synthesis of Dibenzo-7λ 3 -phosphanorbornadiene Derivatives Using Magnesium Anthracene journal August 2012
Mechanism and Scope of Phosphinidene Transfer from Dibenzo-7-phosphanorbornadiene Compounds journal July 2017
A Molecular Precursor to Phosphaethyne and Its Application in Synthesis of the Aromatic 1,2,3,4-Phosphatriazolate Anion journal May 2016
Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity journal May 2018
A Retro Diels–Alder Route to Diphosphorus Chemistry: Molecular Precursor Synthesis, Kinetics of P 2 Transfer to 1,3-Dienes, and Detection of P 2 by Molecular Beam Mass Spectrometry journal September 2014
Phosphinidene Reactivity of a Transient Vanadium P≡N Complex journal December 2016
Revisiting the Chemistry of Phosphinidene Sulfides journal September 2014
Trapping Rare and Elusive Phosphinidene Chalcogenides journal January 2017
Addressing the Nature of Phosphinidene Sulfides via the Synthesis of P−S Heterocycles journal December 2017
Ylidylphosphorsulfide, ‐selenide, ‐disulfide, ‐sulfidselenide und ‐diselenide journal December 1995
A Stabilized Phosphinothioylidene Generated by Deselenation of a Selenoxothioxophosphorane journal October 1993
Phosphinidenes, Phosphiranes, and their Chalcogenides journal January 1999
2,6-Dimethoxyphenylphosphirane Oxide and Sulfide and their Thermolysis to Phosphinidene Chalcogenides—Kinetic and Mechanistic Studies journal January 2000
Phenylphosphinidene oxide. Thermal decomposition of 2,3-benzo-1,4,5,6,7-pentaphenyl-7-phosphabicyclo[2.2.1]hept-5-ene oxide journal June 1972
Das System Schwefel-Phosphor journal January 1965
Das System Schwefel—Phosphor* journal April 1966
Preparation of tertiary arsine sulphides. Crystal and molecular structures of the adduct of AsMePh2S and P(NMe2)3O journal January 1981
The ORCA program system: The ORCA program system journal June 2011
Software update: the ORCA program system, version 4.0: Software update journal July 2017
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu journal April 2010
Effect of the damping function in dispersion corrected density functional theory journal March 2011
Semiempirical hybrid density functional with perturbative second-order correlation journal January 2006
Methyl(thioxo)phosphane: Generation and Trapping Reaction with Mn2(CO)10 journal April 1984
Phosphorverbindungen ungewöhnlicher Koordination, 17 1) über die Abfangreaktion von Phenylthioxophosphan mit Hexacarbonylbis(cyclopentadienyl)dimolybdän journal July 1987
[Os(?2-PHS)(CO)2(PPh3)2], a Stable ?2-Thioxophosphane(H?P?S)-Metal Complex journal February 1988
Mono‐ und Diferriophosphane und ‐thioxophosphorane journal April 1995
High-Yield Synthesis and Reactivity of Stable Diiron Complexes with Bent-Phosphinidene Bridges journal October 2005
Complexes from Ring Opening of Lawesson's Reagent and Phosphorus−Phosphorus Coupling journal March 2003
The coordination chemistry of phosphinidene sulfides. Synthesis and catalytic properties of Pd 4 and Pt 4 clusters journal January 2018
Molecular Double-Bond Covalent Radii for Elements Li–E112 journal November 2009
Phosphinidenes and Related Intermediates. IV. Reactions of Phosphinothioylidenes with cis - and trans -Stilbene Oxides journal December 1975
New method for building carbon-phosphorus heterocycles journal October 1981
Synthesis and photochemical reaction of diels-alder adduct of phosphole oxide and cyclopentadiene journal January 1983
The thioxophosphane HP:S and its tautomer HSP, (thiohydroxy)phosphinidene, are stable in the gas phase journal October 1992
Phosphorus in circumstellar envelopes journal August 2001
The pure rotational spectrum of HPS (X̃1A′): Chemical bonding in second-row elements journal April 2011
An experimental and theoretical study of the electronic spectrum of HPS, a second row HNO analog journal November 2013
Organophosphorus Compounds, 118. Reactions of 1‐Chloro‐1 H ‐phosphirenes with Nucleophiles journal June 1997
Synthese und Reaktivität eines 1‐Chlor‐λ 3 ‐phosphirans journal March 1989
Reactivity of R 2 AlH (R = Me, Bu i ) with Selected Aminoarsines and Secondary Amines journal May 1996
Stability of phosphinidenes—Are they synthetically accessible? journal January 2006
Ab initio structural and spectroscopic study of HPS x and HSP x (x = 0,+1,−1) in the gas phase journal November 2013
Decomposition of P 4 O 10 in DMSO journal January 2018
Matrix infrared spectra of the phosphorus sulfides PS, P2S and PS2 journal January 1991
Molecular fragmentations journal January 1982
The Thermodynamic Properties of Phosphorus and Solid Binary Phosphides journal November 2002
Pr�paration und thermochemische Untersuchung von Verbindungen der Systeme Phosphor-Schwefel und Phosphor-Selen journal October 1979
P-S (Phosphorus-sulfur) journal December 1991
Phosphorus Compounds with the VI B Group Elements journal May 1976
Intensité d'absorption de la vibration de valence PH dans des composés organiques du phosphore: et journal October 1967
Phosphine Sulfides and Selenides: The Phosphorus-Sulfur and Phosphorus-Selenium Stretching Frequencies journal February 1963
Raman spectra of single crystals of α-P4S3 journal August 1988
The microscopic structure of bulk amorphous red phosphorus: A Raman scattering investigation journal October 1984
Raman spectra and short-range order in P x S1−x glasses journal August 1989
Phosphorus-31 magic angle spinning NMR of crystalline phosphorus sulfides: correlation of phosphorus-31 chemical shielding tensors with local environments journal January 1989
31P solid-state NMR studies of the short-range order in phosphorus–selenium glasses journal January 2010
Solid-state phosphorus-31 nuclear magnetic resonance spectroscopy of phosphorus sulphides journal January 1989
Chemical disorder in non-oxide chalcogenide glasses. Site speciation in the system phosphorus-selenium by magic angle spinning NMR at very high spinning speeds journal November 1989
Glasses in the system phosphorus-sulfur: a phosphorus-31 spin-echo and high-speed MAS-NMR study of atomic distribution and local order journal March 1990
31 P Chemical Shielding Anisotropy in Solids. Single Crystal and Powder Studies at 99.4 MHz journal January 1972
Phosphorus 2p electron binding energies. Correlation with extended Hueckel charges journal March 1970
Relaxation energies in XPS and XAES of solid sulfur compounds journal May 1994
In situ X-ray absorption spectroscopy at the K-edge of red phosphorus in polyamide 6,6 during a thermo-oxidative degradation journal May 1994
A XANES and Raman investigation of sulfur speciation and structural order in Murchison and Allende meteorites journal February 2017
Dynamics and Counterion-Dependence of the Structures of Weakly Bound Ag+–P4S3 Complexes journal September 2007
Structural analysis of complex materials using the atomic pair distribution function — a practical guide journal January 2003
Darstellung und Kristallstruktur des ersten polymeren Phosphorselenidscatena-(P4Se4)x journal October 1994
The structure of phosphorus selenide glasses journal December 1988
Structure of phosphorus selenide glasses journal December 1989
Observation of discrete molecular structures in glassy P x Se 1 x by Raman spectroscopy journal December 1989
First-principles simulation of phosphorus-selenium systems journal September 1996
Structure of phosphorus-selenium glasses: results from ab initio molecular dynamics simulations journal June 2000
An Elemental Phosphorus Photocatalyst with a Record High Hydrogen Evolution Efficiency journal May 2016