Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Heterometal incorporation in NH2-MIL-125(Ti) and its participation in the photoinduced charge-separated excited state

Journal Article · · ChemComm
DOI:https://doi.org/10.1039/d0cc05339b· OSTI ID:1688379

Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
~OTHER
DOE Contract Number:
SC0012704
OSTI ID:
1688379
Report Number(s):
BNL-220021-2020-JACI
Journal Information:
ChemComm, Vol. 56, Issue 78
Country of Publication:
United States
Language:
English

References (39)

The Chemistry and Applications of Metal-Organic Frameworks journal August 2013
Solid-state reactivity and structural transformations involving coordination polymers journal January 2013
Functional Hybrid Porous Coordination Polymers journal September 2013
Metal–Organic Frameworks as A Tunable Platform for Designing Functional Molecular Materials journal August 2013
Stable Metal-Organic Frameworks: Design, Synthesis, and Applications journal February 2018
A New Photoactive Crystalline Highly Porous Titanium(IV) Dicarboxylate
  • Dan-Hardi, Meenakshi; Serre, Christian; Frot, Théo
  • Journal of the American Chemical Society, Vol. 131, Issue 31, p. 10857-10859 https://doi.org/10.1021/ja903726m
journal July 2009
Synthesis and Characterization of Nitrogen-Doped TiO 2 Nanophotocatalyst with High Visible Light Activity journal May 2007
Photocatalytic degradation of organic compounds in aqueous systems by transition metal doped polycrystalline TiO2 journal July 2002
Visible-light-induced photodegradation of gas phase acetonitrile using aerosol-made transition metal (V, Cr, Fe, Co, Mn, Mo, Ni, Cu, Y, Ce, and Zr) doped TiO2 journal January 2014
Room-Temperature Ferromagnetism in Transparent Transition Metal-Doped Titanium Dioxide journal January 2001
Engineering the Optical Response of the Titanium-MIL-125 Metal–Organic Framework through Ligand Functionalization journal July 2013
Enhanced photocatalytic CO 2 reduction over Co-doped NH 2 -MIL-125(Ti) under visible light journal January 2017
Systematic variation of the optical bandgap in titanium based isoreticular metal–organic frameworks for photocatalytic reduction of CO 2 under blue light journal January 2017
Visible-light-driven photocatalytic degradation of pollutants over Cu-doped NH2-MIL-125(Ti) journal September 2018
Enhanced Photocatalytic Activity of MIL-125 by Post-Synthetic Modification with Cr III and Ag Nanoparticles journal June 2015
An Amine-Functionalized Titanium Metal-Organic Framework Photocatalyst with Visible-Light-Induced Activity for CO2 Reduction journal February 2012
Electronic origins of photocatalytic activity in d0 metal organic frameworks journal March 2016
Metal Substitution as the Method of Modifying Electronic Structure of Metal–Organic Frameworks journal March 2019
Analysis of electronic structures of 3d transition metal-doped TiO 2 based on band calculations journal October 2002
Femtosecond XANES Study of the Light-Induced Spin Crossover Dynamics in an Iron(II) Complex journal January 2009
Light-induced spin crossover in Fe(II)-based complexes: The full photocycle unraveled by ultrafast optical and X-ray spectroscopies journal November 2010
Capturing a Photoexcited Molecular Structure Through Time-Domain X-ray Absorption Fine Structure journal April 2001
MLCT State Structure and Dynamics of a Copper(I) Diimine Complex Characterized by Pump−Probe X-ray and Laser Spectroscopies and DFT Calculations journal June 2003
Ligand-field symmetry effects in Fe(ii) polypyridyl compounds probed by transient X-ray absorption spectroscopy journal January 2012
Structural Determination of a Short-Lived Excited Iron(II) Complex by Picosecond X-Ray Absorption Spectroscopy journal February 2007
Triplet Excited State Distortions in a Pyrazolate Bridged Platinum Dimer Measured by X-ray Transient Absorption Spectroscopy journal December 2010
New insight into metalloporphyrin excited state structures and axial ligand binding from X-ray transient absorption spectroscopic studies journal October 2014
Time-resolved X-ray absorption spectroscopy for the study of molecular systems relevant for artificial photosynthesis journal December 2015
Structural Determination of a Photochemically Active Diplatinum Molecule by Time-Resolved EXAFS Spectroscopy journal March 2009
Taking Snapshots of Photoexcited Molecules in Disordered Media by Using Pulsed Synchrotron X-rays journal May 2004
Highly Efficient Ultrafast Electron Injection from the Singlet MLCT Excited State of Copper(I) Diimine Complexes to TiO 2 Nanoparticles journal November 2012
Exceptionally Long-Lived Charge Separated State in Zeolitic Imidazolate Framework: Implication for Photocatalytic Applications journal June 2016
Probing the dynamics of plasmon-excited hexanethiol-capped gold nanoparticles by picosecond X-ray absorption spectroscopy journal January 2014
Visualizing Interfacial Charge Transfer in Ru-Dye-Sensitized TiO 2 Nanoparticles Using X-ray Transient Absorption Spectroscopy journal February 2011
Long-Lived Photoinduced Charge Separation in a Trinuclear Iron-μ 3 -oxo-based Metal–Organic Framework journal June 2017
Improved photocatalytic activity in a surfactant-assisted synthesized Ti-containing MOF photocatalyst under blue LED irradiation journal January 2015
Fe(II) adsorption on hematite (0001) journal August 2009
Characterization of Titanium Dioxide Nanoparticles Using Molecular Dynamics Simulations journal August 2005
Organic Linker Defines the Excited-State Decay of Photocatalytic MIL-125(Ti)-Type Materials journal February 2016