skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Investigating the effect of electric fields on lead halide perovskites by scanning tunneling microscopy

Authors:
ORCiD logo [1];  [2];  [2]; ORCiD logo [3]
  1. Florida State Univ., Tallahassee, FL (United States); Argonne National Lab. (ANL), Argonne, IL (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
  3. Florida State Univ., Tallahassee, FL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; Florida State University
OSTI Identifier:
1671776
Alternate Identifier(s):
OSTI ID: 1668883
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Journal of Applied Physics
Additional Journal Information:
Journal Volume: 128; Journal Issue: 12; Journal ID: ISSN 0021-8979
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English

Citation Formats

Wieghold, Sarah, Shirato, Nozomi, Rose, Volker, and Nienhaus, Lea. Investigating the effect of electric fields on lead halide perovskites by scanning tunneling microscopy. United States: N. p., 2020. Web. doi:10.1063/5.0011735.
Wieghold, Sarah, Shirato, Nozomi, Rose, Volker, & Nienhaus, Lea. Investigating the effect of electric fields on lead halide perovskites by scanning tunneling microscopy. United States. doi:10.1063/5.0011735.
Wieghold, Sarah, Shirato, Nozomi, Rose, Volker, and Nienhaus, Lea. Mon . "Investigating the effect of electric fields on lead halide perovskites by scanning tunneling microscopy". United States. doi:10.1063/5.0011735.
@article{osti_1671776,
title = {Investigating the effect of electric fields on lead halide perovskites by scanning tunneling microscopy},
author = {Wieghold, Sarah and Shirato, Nozomi and Rose, Volker and Nienhaus, Lea},
abstractNote = {},
doi = {10.1063/5.0011735},
journal = {Journal of Applied Physics},
issn = {0021-8979},
number = 12,
volume = 128,
place = {United States},
year = {2020},
month = {9}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on September 28, 2021
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Ionic transport in hybrid lead iodide perovskite solar cells
journal, June 2015

  • Eames, Christopher; Frost, Jarvist M.; Barnes, Piers R. F.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8497

Interpretation of inverted photocurrent transients in organic lead halide perovskite solar cells: proof of the field screening by mobile ions and determination of the space charge layer widths
journal, January 2017

  • Belisle, Rebecca A.; Nguyen, William H.; Bowring, Andrea R.
  • Energy & Environmental Science, Vol. 10, Issue 1
  • DOI: 10.1039/C6EE02914K

Elemental Fingerprinting of Materials with Sensitivity at the Atomic Limit
journal, October 2014

  • Shirato, Nozomi; Cummings, Marvin; Kersell, Heath
  • Nano Letters, Vol. 14, Issue 11
  • DOI: 10.1021/nl5030613

Critical Role of Grain Boundaries for Ion Migration in Formamidinium and Methylammonium Lead Halide Perovskite Solar Cells
journal, May 2016

  • Yun, Jae S.; Seidel, Jan; Kim, Jincheol
  • Advanced Energy Materials, Vol. 6, Issue 13
  • DOI: 10.1002/aenm.201600330

Enhanced charge carrier mobility and lifetime suppress hysteresis and improve efficiency in planar perovskite solar cells
journal, January 2018

  • Turren-Cruz, Silver-Hamill; Saliba, Michael; Mayer, Matthew T.
  • Energy & Environmental Science, Vol. 11, Issue 1
  • DOI: 10.1039/C7EE02901B

Recombination in Perovskite Solar Cells: Significance of Grain Boundaries, Interface Traps, and Defect Ions
journal, April 2017


Atomic Structures of CH 3 NH 3 PbI 3 (001) Surfaces
journal, December 2015


Homogenized halides and alkali cation segregation in alloyed organic-inorganic perovskites
journal, February 2019

  • Correa-Baena, Juan-Pablo; Luo, Yanqi; Brenner, Thomas M.
  • Science, Vol. 363, Issue 6427
  • DOI: 10.1126/science.aah5065

Precharging Photon Upconversion: Interfacial Interactions in Solution-Processed Perovskite Upconversion Devices
journal, January 2020


Grain boundary dominated ion migration in polycrystalline organic–inorganic halide perovskite films
journal, January 2016

  • Shao, Yuchuan; Fang, Yanjun; Li, Tao
  • Energy & Environmental Science, Vol. 9, Issue 5
  • DOI: 10.1039/C6EE00413J

Defect migration in methylammonium lead iodide and its role in perovskite solar cell operation
journal, January 2015

  • Azpiroz, Jon M.; Mosconi, Edoardo; Bisquert, Juan
  • Energy & Environmental Science, Vol. 8, Issue 7
  • DOI: 10.1039/C5EE01265A

Transient Sub-Band-Gap States at Grain Boundaries of CH 3 NH 3 PbI 3 Perovskite Act as Fast Temperature Relaxation Centers
journal, June 2019


Giant switchable photovoltaic effect in organometal trihalide perovskite devices
journal, December 2014

  • Xiao, Zhengguo; Yuan, Yongbo; Shao, Yuchuan
  • Nature Materials, Vol. 14, Issue 2
  • DOI: 10.1038/nmat4150

Hybrid Organic–Inorganic Perovskites on the Move
journal, February 2016


Structural and electronic properties of the Bi/GaP(110) interface
journal, May 1991


Ion Migration in Organometal Trihalide Perovskite and Its Impact on Photovoltaic Efficiency and Stability
journal, January 2016


Metal Halide Perovskites as Mixed Electronic–Ionic Conductors: Challenges and Opportunities—From Hysteresis to Memristivity
journal, June 2017


Transient Sub-bandgap States in Halide Perovskite Thin Films
journal, January 2018


Plasmonic support-mediated activation of 1 nm platinum clusters for catalysis
journal, January 2017

  • Wieghold, S.; Nienhaus, L.; Knoller, F. L.
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 45
  • DOI: 10.1039/C7CP04882C

Photodriven Dipole Reordering: Key to Carrier Separation in Metalorganic Halide Perovskites
journal, March 2019


Surface and Interface Aspects of Organometal Halide Perovskite Materials and Solar Cells
journal, November 2016


Valence and Conduction Band Densities of States of Metal Halide Perovskites: A Combined Experimental–Theoretical Study
journal, June 2016

  • Endres, James; Egger, David A.; Kulbak, Michael
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 14
  • DOI: 10.1021/acs.jpclett.6b00946

Band Tailing and Deep Defect States in CH 3 NH 3 Pb(I 1– x Br x ) 3 Perovskites As Revealed by Sub-Bandgap Photocurrent
journal, February 2017


Electron-hole diffusion lengths > 175 μm in solution-grown CH 3 NH 3 PbI 3 single crystals
journal, January 2015


XTIP – the world's first beamline dedicated to the synchrotron X-ray scanning tunneling microscopy technique
journal, April 2020

  • Rose, Volker; Shirato, Nozomi; Bartlein, Michael
  • Journal of Synchrotron Radiation, Vol. 27, Issue 3
  • DOI: 10.1107/S1600577520003689

Unraveling the Impact of Halide Mixing on Perovskite Stability
journal, January 2019

  • Hieulle, Jeremy; Wang, Xiaoming; Stecker, Collin
  • Journal of the American Chemical Society, Vol. 141, Issue 8
  • DOI: 10.1021/jacs.8b11210

Transparent Metal Films for Detection of Single-Molecule Optical Absorption by Scanning Tunneling Microscopy
journal, June 2014

  • Nienhaus, Lea; Scott, Gregory E.; Haasch, Richard T.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 24
  • DOI: 10.1021/jp501811z

Microscopic Investigation of Grain Boundaries in Organolead Halide Perovskite Solar Cells
journal, December 2015

  • Li, Jiang-Jun; Ma, Jing-Yuan; Ge, Qian-Qing
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 51
  • DOI: 10.1021/acsami.5b09801

Electronic Structure of the Si(111)2 × 1 Surface by Scanning-Tunneling Microscopy
journal, November 1986


Atomistic Origins of Surface Defects in CH 3 NH 3 PbBr 3 Perovskite and Their Electronic Structures
journal, February 2017


Optoelectronic Switching of a Carbon Nanotube Chiral Junction Imaged with Nanometer Spatial Resolution
journal, September 2015


Influence of Triplet Diffusion on Lead Halide Perovskite-Sensitized Solid-State Upconversion
journal, June 2019

  • Wieghold, Sarah; Bieber, Alexander S.; VanOrman, Zachary A.
  • The Journal of Physical Chemistry Letters, Vol. 10, Issue 13
  • DOI: 10.1021/acs.jpclett.9b01526

How the formation of interfacial charge causes hysteresis in perovskite solar cells
journal, January 2018

  • Weber, Stefan A. L.; Hermes, Ilka M.; Turren-Cruz, Silver-Hamill
  • Energy & Environmental Science, Vol. 11, Issue 9
  • DOI: 10.1039/C8EE01447G

Benefit of Grain Boundaries in Organic–Inorganic Halide Planar Perovskite Solar Cells
journal, February 2015

  • Yun, Jae S.; Ho-Baillie, Anita; Huang, Shujuan
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 5
  • DOI: 10.1021/acs.jpclett.5b00182

Real-Time Nanoscale Open-Circuit Voltage Dynamics of Perovskite Solar Cells
journal, March 2017


Halide Heterogeneity Affects Local Charge Carrier Dynamics in Mixed-Ion Lead Perovskite Thin Films
journal, April 2019


Microscopic Charge Transport and Recombination Processes behind the Photoelectric Hysteresis in Perovskite Solar Cells
journal, August 2016


Surface Restructuring of Hybrid Perovskite Crystals
journal, November 2016


Lattice dynamics and vibrational spectra of the orthorhombic, tetragonal, and cubic phases of methylammonium lead iodide
journal, October 2015


Precursor Concentration Affects Grain Size, Crystal Orientation, and Local Performance in Mixed-Ion Lead Perovskite Solar Cells
journal, October 2018

  • Wieghold, Sarah; Correa-Baena, Juan-Pablo; Nienhaus, Lea
  • ACS Applied Energy Materials, Vol. 1, Issue 12
  • DOI: 10.1021/acsaem.8b00913

Anharmonicity and Disorder in the Black Phases of Cesium Lead Iodide Used for Stable Inorganic Perovskite Solar Cells
journal, March 2018


Triplet Sensitization by Lead Halide Perovskite Thin Films for Efficient Solid-State Photon Upconversion at Subsolar Fluxes
journal, September 2019


Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber
journal, October 2013

  • Stranks, S. D.; Eperon, G. E.; Grancini, G.
  • Science, Vol. 342, Issue 6156, p. 341-344
  • DOI: 10.1126/science.1243982

Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH3NH3PbI3
journal, October 2013


Facet-dependent photovoltaic efficiency variations in single grains of hybrid halide perovskite
journal, July 2016


Probing Semiconductor Properties with Optical Scanning Tunneling Microscopy
journal, March 2020


Imaging Excited Orbitals of Quantum Dots: Experiment and Electronic Structure Theory
journal, November 2015

  • Nienhaus, Lea; Goings, Joshua J.; Nguyen, Duc
  • Journal of the American Chemical Society, Vol. 137, Issue 46
  • DOI: 10.1021/jacs.5b09272

Gwyddion: an open-source software for SPM data analysis
journal, January 2012


Verification and mitigation of ion migration in perovskite solar cells
journal, April 2019

  • Lee, Jin-Wook; Kim, Seul-Gi; Yang, June-Mo
  • APL Materials, Vol. 7, Issue 4
  • DOI: 10.1063/1.5085643

A mixed-cation lead mixed-halide perovskite absorber for tandem solar cells
journal, January 2016


Anomalous photovoltaic effect in organic-inorganic hybrid perovskite solar cells
journal, March 2017


Mapping the Photoresponse of CH 3 NH 3 PbI 3 Hybrid Perovskite Thin Films at the Nanoscale
journal, May 2016


Parameters Affecting IV Hysteresis of CH 3 NH 3 PbI 3 Perovskite Solar Cells: Effects of Perovskite Crystal Size and Mesoporous TiO 2 Layer
journal, August 2014

  • Kim, Hui-Seon; Park, Nam-Gyu
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 17
  • DOI: 10.1021/jz501392m

Growth and interfacial structure of methylammonium lead iodide thin films on Au(111)
journal, February 2017


Hybrid Organic-Inorganic Perovskites (HOIPs): Opportunities and Challenges
journal, July 2015

  • Berry, Joseph; Buonassisi, Tonio; Egger, David A.
  • Advanced Materials, Vol. 27, Issue 35
  • DOI: 10.1002/adma.201502294

Fermi-level pinning in methylammonium lead iodide perovskites
journal, January 2019

  • Gallet, Thibaut; Grabowski, David; Kirchartz, Thomas
  • Nanoscale, Vol. 11, Issue 36
  • DOI: 10.1039/C9NR02643F

Termination Dependence of Tetragonal CH 3 NH 3 PbI 3 Surfaces for Perovskite Solar Cells
journal, August 2014

  • Haruyama, Jun; Sodeyama, Keitaro; Han, Liyuan
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 16
  • DOI: 10.1021/jz501510v

Real-Space Imaging of the Atomic Structure of Organic–Inorganic Perovskite
journal, December 2015

  • Ohmann, Robin; Ono, Luis K.; Kim, Hui-Seon
  • Journal of the American Chemical Society, Vol. 137, Issue 51
  • DOI: 10.1021/jacs.5b08227