Near-Zero Power MOF-Based Sensors for NO2 Detection

Small, Leo J.; Henkelis, Susan E.; Rademacher, David X.; Schindelholz, Mara E.; Krumhansl, James L.; Vogel, Dayton J.; Nenoff, Tina M.

doi:10.1002/adfm.202006598

Title: Near-Zero Power MOF-Based Sensors for NO₂ Detection

Journal Article · Sun Sep 13 00:00:00 EDT 2020 · Advanced Functional Materials

DOI:https://doi.org/10.1002/adfm.202006598· OSTI ID:1667400

^[1];

^[1]; Schindelholz, Mara E. ^[1]; Krumhansl, James L. ^[1];

^[1];

^[1]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Abstract Detection and capture of toxic nitrogen oxides (NO _x ) is important for emissions control of exhaust gases and general public health. The ability to directly electrically detect trace (0.5–5 ppm) NO ₂ by a metal–organic framework (MOF)‐74‐based sensor at relatively low temperatures (50 °C) is demonstrated via changes in electrical properties of M‐MOF‐74, M = Co, Mg, Ni. The magnitude of the change is ordered Ni > Co > Mg and explained by each variant's NO ₂ adsorption capacity and specific chemical interaction. Ni‐MOF‐74 provides the highest sensitivity to NO ₂ ; a 725× decrease in resistance at 5 ppm NO ₂ and detection limit <0.5 ppm, levels relevant for industry and public health. Furthermore, the Ni‐MOF‐74‐based sensor is selective to NO ₂ over N ₂ , SO ₂ , and air. Linking this fundamental research with future technologies, the high impedance of MOF‐74 enables applications requiring a near‐zero power sensor or dosimeter, with the active material drawing <15 pW for a macroscale device 35 mm ² with 0.8 mg MOF‐74. This represents a 10 ⁴ –10 ⁶ × decrease in power consumption compared to other MOF sensors and demonstrates the potential for MOFs as active components for long‐lived, near‐zero power chemical sensors in smart industrial systems and the internet of things.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000; NA0003525

OSTI ID:: 1667400

Alternate ID(s):: OSTI ID: 1804206

Report Number(s):: SAND-2020-8671J; 690069

Journal Information:: Advanced Functional Materials, Vol. 30, Issue 50; ISSN 1616-301X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (39)

NO _x Adsorption and Optical Detection in Rare Earth Metal–Organic Frameworks Sava Gallis, Dorina F.; Vogel, Dayton J.; Vincent, Grace A. ACS Applied Materials & Interfaces, Vol. 11, Issue 46 https://doi.org/10.1021/acsami.9b16470	journal	October 2019
Redox couples in the selective catalytic reduction of NO _x with hydrocarbons over Co–ZSM-5 and Ni–ZSM-5 catalysts: an FT-IR study Mihaylov, Mihail; Hadjiivanov, Konstantin Chem. Commun., Issue 19 https://doi.org/10.1039/B408061K	journal	January 2004
Metal–Organic Framework Co-MOF-74-Based Host–Guest Composites for Resistive Gas Sensing Strauss, Ina; Mundstock, Alexander; Treger, Marvin ACS Applied Materials & Interfaces, Vol. 11, Issue 15 https://doi.org/10.1021/acsami.8b22002	journal	March 2019
Reversible adsorption of nitrogen dioxide within a robust porous metal–organic framework Han, Xue; Godfrey, Harry G. W.; Briggs, Lydia Nature Materials, Vol. 17, Issue 8 https://doi.org/10.1038/s41563-018-0104-7	journal	June 2018
Chemistry of SO2 and NO2 on ZnO(0001)-Zn and ZnO powders: changes in reactivity with surface structure and composition Rodriguez, José A.; Jirsak, Tomas; Chaturvedi, Sanjay Journal of Molecular Catalysis A: Chemical, Vol. 167, Issue 1-2 https://doi.org/10.1016/S1381-1169(00)00489-1	journal	February 2001
Vehicular Emissions in Review Johnson, Timothy SAE International Journal of Engines, Vol. 9, Issue 2 https://doi.org/10.4271/2016-01-0919	journal	April 2016
Interaction of Acid Gases SO ₂ and NO ₂ with Coordinatively Unsaturated Metal Organic Frameworks: M-MOF-74 (M = Zn, Mg, Ni, Co) Tan, Kui; Zuluaga, Sebastian; Wang, Hao Chemistry of Materials, Vol. 29, Issue 10 https://doi.org/10.1021/acs.chemmater.7b00005	journal	May 2017
IR spectroscopic study of NOxadsorption and NOx–O2coadsorption on Co2+/SiO2catalysts Djonev, Boyan; Tsyntsarski, Boyko; Klissurski, Dimitar Journal of the Chemical Society, Faraday Transactions, Vol. 93, Issue 22 https://doi.org/10.1039/a703955g	journal	January 1997
Van der Waals Heterostructured MOF‐on‐MOF Thin Films: Cascading Functionality to Realize Advanced Chemiresistive Sensing Yao, Ming‐Shui; Xiu, Jing‐Wei; Huang, Qing‐Qing Angewandte Chemie International Edition, Vol. 58, Issue 42 https://doi.org/10.1002/anie.201907772	journal	October 2019
Is iron unique in promoting electrical conductivity in MOFs? Sun, Lei; Hendon, Christopher H.; Park, Sarah S. Chemical Science, Vol. 8, Issue 6 https://doi.org/10.1039/C7SC00647K	journal	January 2017
Tuning the nitric oxide release from CPO-27 MOFs Cattaneo, Damiano; Warrender, Stewart J.; Duncan, Morven J. RSC Advances, Vol. 6, Issue 17 https://doi.org/10.1039/C5RA24023A	journal	January 2016
Kinetic stability of metal–organic frameworks for corrosive and coordinating gas capture Rieth, Adam J.; Wright, Ashley M.; Dincă, Mircea Nature Reviews Materials, Vol. 4, Issue 11 https://doi.org/10.1038/s41578-019-0140-1	journal	September 2019
A Calixarene-Based Metal-Organic Framework for Highly Selective NO ₂ Detection Schulz, Marcel; Gehl, Adrian; Schlenkrich, Jakob Angewandte Chemie International Edition, Vol. 57, Issue 39 https://doi.org/10.1002/anie.201805355	journal	August 2018
Impedance Spectroscopy Barsoukov, Evgenij; Macdonald, J. Ross https://doi.org/10.1002/0471716243	book	January 2005
Review of state of the art technologies of selective catalytic reduction of NOx from diesel engine exhaust Guan, Bin; Zhan, Reggie; Lin, He Applied Thermal Engineering, Vol. 66, Issue 1-2 https://doi.org/10.1016/j.applthermaleng.2014.02.021	journal	May 2014
Million-Fold Electrical Conductivity Enhancement in Fe ₂ (DEBDC) versus Mn ₂ (DEBDC) (E = S, O) Sun, Lei; Hendon, Christopher H.; Minier, Mikael A. Journal of the American Chemical Society, Vol. 137, Issue 19 https://doi.org/10.1021/jacs.5b02897	journal	May 2015
An overview of different strategies to introduce conductivity in metal–organic frameworks and miscellaneous applications thereof Bhardwaj, Sanjeev K.; Bhardwaj, Neha; Kaur, Rajnish Journal of Materials Chemistry A, Vol. 6, Issue 31 https://doi.org/10.1039/C8TA04220A	journal	January 2018
Structural, elastic, thermal, and electronic responses of small-molecule-loaded metal–organic framework materials Canepa, Pieremanuele; Tan, Kui; Du, Yingjie Journal of Materials Chemistry A, Vol. 3, Issue 3 https://doi.org/10.1039/C4TA03968H	journal	January 2015
Water based scale-up of CPO-27 synthesis for nitric oxide delivery Cattaneo, Damiano; Warrender, Stewart J.; Duncan, Morven J. Dalton Transactions, Vol. 45, Issue 2 https://doi.org/10.1039/C5DT03955J	journal	January 2016
Editors’ Choice—Review—Recent Advances in Mixed Potential Sensors Ramaiyan, Kannan Pasupathikovil; Mukundan, Rangachary Journal of The Electrochemical Society, Vol. 167, Issue 3 https://doi.org/10.1149/1945-7111/ab67ab	journal	January 2020
Chemiresistive Sensing of Ambient CO ₂ by an Autogenously Hydrated Cu ₃ (hexaiminobenzene) ₂ Framework Stassen, Ivo; Dou, Jin-Hu; Hendon, Christopher ACS Central Science, Vol. 5, Issue 8 https://doi.org/10.1021/acscentsci.9b00482	journal	June 2019
Gradual Release of Strongly Bound Nitric Oxide from Fe ₂ (NO) ₂ (dobdc) Bloch, Eric D.; Queen, Wendy L.; Chavan, Sachin Journal of the American Chemical Society, Vol. 137, Issue 10 https://doi.org/10.1021/ja5132243	journal	March 2015
Direct Self-Assembly of Conductive Nanorods of Metal–Organic Frameworks into Chemiresistive Devices on Shrinkable Polymer Films Smith, Merry K.; Jensen, Kennedy E.; Pivak, Polina A. Chemistry of Materials, Vol. 28, Issue 15 https://doi.org/10.1021/acs.chemmater.6b02528	journal	July 2016
Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices Talin, A. Alec; Centrone, Andrea; Ford, Alexandra C. Science, Vol. 343, Issue 6166, p. 66-69 https://doi.org/10.1126/science.1246738	journal	December 2013
Metal–Organic Framework Materials as Chemical Sensors Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K. Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125 https://doi.org/10.1021/cr200324t	journal	September 2011
Direct Electrical Detection of Iodine Gas by a Novel Metal–Organic-Framework-Based Sensor Small, Leo J.; Nenoff, Tina M. ACS Applied Materials & Interfaces, Vol. 9, Issue 51 https://doi.org/10.1021/acsami.7b16381	journal	December 2017
Highly sensitive and selective SO ₂ MOF sensor: the integration of MFM-300 MOF as a sensitive layer on a capacitive interdigitated electrode Chernikova, Valeriya; Yassine, Omar; Shekhah, Osama Journal of Materials Chemistry A, Vol. 6, Issue 14 https://doi.org/10.1039/C7TA10538J	journal	January 2018
How Well Do Metal–Organic Frameworks Tolerate Flue Gas Impurities? Ding, Lifeng; Yazaydin, A. Özgür The Journal of Physical Chemistry C, Vol. 116, Issue 43 https://doi.org/10.1021/jp308717y	journal	October 2012
Low temperature synthesis study of metal–organic framework CPO-27: investigating metal, solvent and base effects down to −78 °C Vornholt, Simon M.; Henkelis, Susan E.; Morris, Russell E. Dalton Transactions, Vol. 46, Issue 25 https://doi.org/10.1039/C7DT01223C	journal	January 2017
Interactions of NO ₂ with Zr-Based MOF: Effects of the Size of Organic Linkers on NO ₂ Adsorption at Ambient Conditions Ebrahim, Amani M.; Levasseur, Benoit; Bandosz, Teresa J. Langmuir, Vol. 29, Issue 1 https://doi.org/10.1021/la302869m	journal	December 2012
Zero and Near Zero Power Intelligent Microsystems Olsson, R. H.; Gordon, C.; Bogoslovov, R. Journal of Physics: Conference Series, Vol. 1407 https://doi.org/10.1088/1742-6596/1407/1/012042	journal	November 2019
Exceptional Behavior over the Whole Adsorption−Storage−Delivery Cycle for NO in Porous Metal Organic Frameworks McKinlay, Alistair C.; Xiao, Bo; Wragg, David S. Journal of the American Chemical Society, Vol. 130, Issue 31 https://doi.org/10.1021/ja801997r	journal	August 2008
Metal-Organic Frameworks for Sensing Applications in the Gas Phase Achmann, Sabine; Hagen, Gunter; Kita, Jaroslaw Sensors, Vol. 9, Issue 3 https://doi.org/10.3390/s90301574	journal	March 2009
Reversible MOF-Based Sensors for the Electrical Detection of Iodine Gas Small, Leo J.; Hill, Ryan C.; Krumhansl, James L. ACS Applied Materials & Interfaces, Vol. 11, Issue 31 https://doi.org/10.1021/acsami.9b09938	journal	July 2019
An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors Stassen, Ivo; Burtch, Nicholas; Talin, Alec Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/C7CS00122C	journal	January 2017
Structural and electronic properties of M-MOF-74 (M = Mg, Co or Mn) de Oliveira, Aline; de Lima, Guilherme Ferreira; De Abreu, Heitor Avelino Chemical Physics Letters, Vol. 691 https://doi.org/10.1016/j.cplett.2017.11.027	journal	January 2018
Competitive Coadsorption of CO ₂ with H ₂ O, NH ₃ , SO ₂ , NO, NO ₂ , N ₂ , O ₂ , and CH ₄ in M-MOF-74 (M = Mg, Co, Ni): The Role of Hydrogen Bonding Tan, Kui; Zuluaga, Sebastian; Gong, Qihan Chemistry of Materials, Vol. 27, Issue 6 https://doi.org/10.1021/acs.chemmater.5b00315	journal	March 2015
Selective decontamination of the reactive air pollutant nitrous acid via node-linker cooperativity in a metal–organic framework McGrath, Devon T.; Ryan, Michaela D.; MacInnis, John J. Chemical Science, Vol. 10, Issue 21 https://doi.org/10.1039/C9SC01357A	journal	January 2019
Chemiresistive Detection of Gaseous Hydrocarbons and Interrogation of Charge Transport in Cu[Ni(2,3-pyrazinedithiolate) ₂ ] by Gas Adsorption Aubrey, Michael L.; Kapelewski, Matthew T.; Melville, Jonathan F. Journal of the American Chemical Society, Vol. 141, Issue 12 https://doi.org/10.1021/jacs.9b00654	journal	March 2019

Similar Records

Low power sensor for NO_x detection

Patent · Tue Feb 07 00:00:00 EST 2023 · OSTI ID:1667400

Small, Leo J.; Henkelis, Susan Elizabeth; Percival, Stephen J.; +2 more

Continuous MOF Membrane-Based Sensors via Functionalization of Interdigitated Electrodes

Journal Article · Sun Feb 28 00:00:00 EST 2021 · Membranes · OSTI ID:1667400

Henkelis, Susan Elizabeth; Percival, Stephen; Small, Leo J.; +2 more

Impedance-Based Detection of NO₂ Using Ni-MOF-74: Influence of Competitive Gas Adsorption

Journal Article · Thu Jul 27 00:00:00 EDT 2023 · ACS Applied Materials and Interfaces · OSTI ID:1667400

Small, Leo J.; Vornholt, Simon M.; Percival, Stephen J.; +4 more

Related Subjects

47 OTHER INSTRUMENTATION
impedance spectroscopy
metal-organic framework
nanoporous
near-zero power
NO2

Title: Near-Zero Power MOF-Based Sensors for NO2 Detection

Citation Formats

References (39)

Similar Records

Related Subjects

Title: Near-Zero Power MOF-Based Sensors for NO₂ Detection