A periodic metallo-supramolecular polymer from a flexible building block: self-assembly and photocatalysis for organic dye degradation

Li, Xiong-Fei; Liu, Xu-Bo; Chao, Jin-Yu; Wang, Ze-Kun; Rahman, Faiz-Ur; Wang, Hui; Zhang, Dan-Wei; Liu, Yi; Li, Zhan-Ting

doi:10.1007/s11426-019-9600-2

Title: A periodic metallo-supramolecular polymer from a flexible building block: self-assembly and photocatalysis for organic dye degradation

Journal Article · Mon Nov 11 00:00:00 EST 2019 · Science China Chemistry

DOI:https://doi.org/10.1007/s11426-019-9600-2· OSTI ID:1661594

Li, Xiong-Fei ^[1]; Liu, Xu-Bo ^[1]; Chao, Jin-Yu ^[1]; Wang, Ze-Kun ^[1]; Rahman, Faiz-Ur ^[1]; Wang, Hui ^[1]; Zhang, Dan-Wei ^[1]; Liu, Yi ^[2]; Li, Zhan-Ting ^[1]

Fudan Univ., Shanghai (China). Dept. of Chemistry
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry

A water-soluble metallo-supramolecular polymer MSP-f-6Np, which possesses a regular pore aperture of 1.4 nm, has been assembled from a structurally flexible naphthalene-appended [Ru(bipy)₃]²⁺ complex and cucurbit[8]uril. As the first periodic metallo-supramolecular polymer formed by a flexible building block, MSP-f-6Np exhibits a hydrodynamic diameter of 122 and 164 nm at 0.1 and 2.0 mM of the monomer concentrations. Synchrotron small angle X-ray scattering experiments confirm that MSP-f-6Np possesses porosity periodicity in both the solution and solid states. Compared with a control, the new highly ordered porous system displays enhanced photocatalytic activity for the degradation of organic dyes.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Natural Science Foundation of China (NSFC); National Institutes of Health (NIH)

Grant/Contract Number:: AC02-05CH11231; 21432004; 21529201; 21890732; P30-GM124169; S10OD018483

OSTI ID:: 1661594

Journal Information:: Science China Chemistry, Vol. 62, Issue 12; ISSN 1674-7291

Publisher:: Science China Press and SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 14 works

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References (49)

Design and Preparation of Porous Polymers Wu, Dingcai; Xu, Fei; Sun, Bin Chemical Reviews, Vol. 112, Issue 7 https://doi.org/10.1021/cr200440z	journal	April 2012
Synthetic Two-dimensional Organic Structures Liu, Hui; Kan, Xiao-Nan; Wu, Chen-Yu Chinese Journal of Polymer Science, Vol. 36, Issue 4 https://doi.org/10.1007/s10118-018-2070-6	journal	December 2017
Ultrastable Host-Guest Complexes and Their Applications Ko, Young Ho; Hwang, Ilha; Lee, Don-Wook Israel Journal of Chemistry, Vol. 51, Issue 5-6 https://doi.org/10.1002/ijch.201100041	journal	May 2011
Fabrication of Neutral Supramolecular Polymeric Films via Post-electropolymerization of Discrete Metallacycles: Fabrication of Neutral Supramolecular Polymeric Films via Post-electropolymerization of Discrete Metallacycles Yin, Guangqiang; Chen, Lijun; Wang, Cuihong Chinese Journal of Chemistry, Vol. 36, Issue 2 https://doi.org/10.1002/cjoc.201700610	journal	December 2017
Supramolecular metal-organic frameworks that display high homogeneous and heterogeneous photocatalytic activity for H2 production Tian, Jia; Xu, Zi-Yue; Zhang, Dan-Wei Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11580	journal	May 2016
Postmodification of a supramolecular organic framework: visible-light-induced recyclable heterogeneous photocatalysis for the reduction of azides to amines Wu, Yi-Peng; Yang, Bo; Tian, Jia Chemical Communications, Vol. 53, Issue 100 https://doi.org/10.1039/C7CC08824H	journal	January 2017
Supramolecular delivery systems based on pillararenes Feng, Weiwei; Jin, Ming; Yang, Kui Chemical Communications, Vol. 54, Issue 97 https://doi.org/10.1039/C8CC08252A	journal	January 2018
Synthetic Strategies for Constructing Two-Dimensional Metal-Organic Layers (MOLs): A Tutorial Review: Synthetic Strategies for Constructing Two-Dimensional Metal-Organic Layers (MOLs): A Tutorial Review Cao, Lingyun; Wang, Tingting; Wang, Cheng Chinese Journal of Chemistry, Vol. 36, Issue 8 https://doi.org/10.1002/cjoc.201800144	journal	June 2018
Applications of covalent organic frameworks (COFs): From gas storage and separation to drug delivery Wu, Ming-Xue; Yang, Ying-Wei Chinese Chemical Letters, Vol. 28, Issue 6 https://doi.org/10.1016/j.cclet.2017.03.026	journal	June 2017
A supramolecular bottlebrush polymer assembled on the basis of cucurbit[8]uril-encapsulation-enhanced donor–acceptor interaction Yin, Zhi-Jian; Wu, Zong-Quan; Lin, Feng Chinese Chemical Letters, Vol. 28, Issue 6 https://doi.org/10.1016/j.cclet.2017.03.029	journal	June 2017
Fluorescence detecting of paraquat using host-guest chemistry with cucurbit[8]uril Sun, Shiguo; Li, Fusheng; Liu, Fengyu Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep03570	journal	January 2014
Molecular recognition directed self-assembly of supramolecular liquid crystalline polymers from complementary chiral components Fouquey, Claudine; Lehn, Jean-Marie; Levelut, Anne-Marie Advanced Materials, Vol. 2, Issue 5 https://doi.org/10.1002/adma.19900020506	journal	May 1990
Supramolecular Polymer Emulsifiers for One-step Complex Emulsions Wang, Zhen; Liao, Shenglong; Wang, Yapei Chinese Journal of Polymer Science, Vol. 36, Issue 3 https://doi.org/10.1007/s10118-018-2084-0	journal	December 2017
Controllable Preparation of Two Dimensional Metal- or Covalent Organic Frameworks for Chemical Sensing and Biosensing Yang, Tao; Cui, Yanan; Chen, Huaiyin Acta Chimica Sinica, Vol. 75, Issue 4 https://doi.org/10.6023/A16110592	journal	January 2017
A stable metal-covalent-supramolecular organic framework hybrid: enrichment of catalysts for visible light-induced hydrogen production Li, Xiong-Fei; Yu, Shang-Bo; Yang, Bo Science China Chemistry, Vol. 61, Issue 7 https://doi.org/10.1007/s11426-018-9234-2	journal	April 2018
Supramolecular Polymerization Promoted and Controlled through Self-Sorting Huang, Zehuan; Yang, Liulin; Liu, Yiliu Angewandte Chemie International Edition, Vol. 53, Issue 21 https://doi.org/10.1002/anie.201402817	journal	April 2014
Cucurbituril Homologues and Derivatives: New Opportunities in Supramolecular Chemistry Lee, Jae Wook; Samal, S.; Selvapalam, N. Accounts of Chemical Research, Vol. 36, Issue 8 https://doi.org/10.1021/ar020254k	journal	August 2003
Cucurbit[8]uril-Based Polymers and Polymer Materials Zou, Hua; Liu, Jing; Li, Ying Small, Vol. 14, Issue 46 https://doi.org/10.1002/smll.201802234	journal	August 2018
Synthetic strategies for chiral metal-organic frameworks Han, Zongsu; Shi, Wei; Cheng, Peng Chinese Chemical Letters, Vol. 29, Issue 6 https://doi.org/10.1016/j.cclet.2017.09.050	journal	June 2018
Cucurbit[8]uril-Based Supramolecular Polymers Liu, Yiliu; Yang, Hui; Wang, Zhiqiang Chemistry - An Asian Journal, Vol. 8, Issue 8 https://doi.org/10.1002/asia.201300151	journal	April 2013
Supramolecular polymers constructed by orthogonal self-assembly based on host–guest and metal–ligand interactions Wei, Peifa; Yan, Xuzhou; Huang, Feihe Chemical Society Reviews, Vol. 44, Issue 3 https://doi.org/10.1039/C4CS00327F	journal	January 2015
Hydrogen-bonded rosettes comprising π-conjugated systems as building blocks for functional one-dimensional assemblies Adhikari, Bimalendu; Lin, Xu; Yamauchi, Mitsuaki Chemical Communications, Vol. 53, Issue 70 https://doi.org/10.1039/C7CC04172A	journal	January 2017
Supramolecular Metallopolymers: From Linear Materials to Infinite Networks Bentz, Kyle C.; Cohen, Seth M. Angewandte Chemie International Edition, Vol. 57, Issue 46 https://doi.org/10.1002/anie.201806912	journal	October 2018
In Situ Loading and Delivery of Short Single- and Double-Stranded DNA by Supramolecular Organic Frameworks Yang, Bo; Zhang, Xiao-Dan; Li, Jian CCS Chemistry, Vol. 1, Issue 2 https://doi.org/10.31635/ccschem.019.20180011	journal	January 2019
Modulation of Supramolecular Interactions of Urea-based Supramolecular Polymers via Molecular Structures Lu, Zhiyi; Tang, Liming Chemical Research in Chinese Universities, Vol. 34, Issue 5 https://doi.org/10.1007/s40242-018-8006-4	journal	September 2018
Chemistry of Covalent Organic Frameworks Waller, Peter J.; Gándara, Felipe; Yaghi, Omar M. Accounts of Chemical Research, Vol. 48, Issue 12 https://doi.org/10.1021/acs.accounts.5b00369	journal	November 2015
Cucurbit[10]uril-based chemistry Yang, Xiran; Liu, Fengbo; Zhao, Zhiyong Chinese Chemical Letters, Vol. 29, Issue 11 https://doi.org/10.1016/j.cclet.2018.01.032	journal	November 2018
Supramolecular hyperbranched polymers Tian, Wei; Li, Xuexiang; Wang, Jingxia Chemical Communications, Vol. 53, Issue 17 https://doi.org/10.1039/C6CC09678F	journal	January 2017
Covalent Organic Frameworks and Cage Compounds: Design and Applications of Polymeric and Discrete Organic Scaffolds Beuerle, Florian; Gole, Bappaditya Angewandte Chemie International Edition, Vol. 57, Issue 18 https://doi.org/10.1002/anie.201710190	journal	March 2018
Calixarene-based supramolecular polymerization in solution Guo, Dong-Sheng; Liu, Yu Chemical Society Reviews, Vol. 41, Issue 18 https://doi.org/10.1039/c2cs35075k	journal	January 2012
Morphology effect of metal-organic framework HKUST-1 as a catalyst on benzene oxidation Liu, Yanfeng; Liu, Boliang; Zhou, Qingfeng Chemical Research in Chinese Universities, Vol. 33, Issue 6 https://doi.org/10.1007/s40242-017-6468-4	journal	November 2017
Supramolecular Polymerizations and Main-Chain Supramolecular Polymers Fox, Justin D.; Rowan, Stuart J. Macromolecules, Vol. 42, Issue 18 https://doi.org/10.1021/ma901144t	journal	September 2009
A supramolecular miktoarm star polymer based on porphyrin metal complexation in water Hou, Zhanyao; Dehaen, Wim; Lyskawa, Joël Chemical Communications, Vol. 53, Issue 60 https://doi.org/10.1039/C7CC03128A	journal	January 2017
Multivalency in supramolecular chemistry and nanofabrication Mulder, Alart; Huskens, Jurriaan; Reinhoudt, David N. Organic & Biomolecular Chemistry, Vol. 2, Issue 23 https://doi.org/10.1039/b413971b	journal	January 2004
Assemblies of covalent organic framework microcrystals: multiple-dimensional manipulation for enhanced applications Yuan, Fuyu; Tan, Jing; Guo, Jia Science China Chemistry, Vol. 61, Issue 2 https://doi.org/10.1007/s11426-017-9162-3	journal	January 2018
Chiral covalent organic frameworks for asymmetric catalysis and chiral separation Liu, Guofeng; Sheng, Jianhui; Zhao, Yanli Science China Chemistry, Vol. 60, Issue 8 https://doi.org/10.1007/s11426-017-9070-1	journal	July 2017
Controllable macrocyclic supramolecular assemblies in aqueous solution Chen, Yong; Huang, Feihe; Li, Zhan-Ting Science China Chemistry, Vol. 61, Issue 8 https://doi.org/10.1007/s11426-018-9337-4	journal	July 2018
Supramolecular polymeric hydrogels Appel, Eric A.; del Barrio, Jesús; Loh, Xian Jun Chemical Society Reviews, Vol. 41, Issue 18 https://doi.org/10.1039/c2cs35264h	journal	January 2012
Complexation and Fluorescence of Tricyclic Basic Dyes Encapsulated in Cucurbiturils Montes-Navajas, Pedro; Corma, Avelino; Garcia, Hermenegildo ChemPhysChem, Vol. 9, Issue 5 https://doi.org/10.1002/cphc.200700735	journal	March 2008
How to Make Weak Noncovalent Interactions Stronger Xu, Jiang-Fei; Chen, Linghui; Zhang, Xi Chemistry - A European Journal, Vol. 21, Issue 34 https://doi.org/10.1002/chem.201500568	journal	June 2015
The Hydrophobic Effect Revisited-Studies with Supramolecular Complexes Imply High-Energy Water as a Noncovalent Driving Force Biedermann, Frank; Nau, Werner M.; Schneider, Hans-Jörg Angewandte Chemie International Edition, Vol. 53, Issue 42 https://doi.org/10.1002/anie.201310958	journal	July 2014
Supramolecular Polymers Brunsveld, L.; Folmer, B. J. B.; Meijer, E. W. Chemical Reviews, Vol. 101, Issue 12 https://doi.org/10.1021/cr990125q	journal	December 2001
Effects of inclusion of chrysin in cucurbit[8]uril on its stability, solubility and antioxidant potential Xu, Zhiling; Lian, Xiaowei; Li, Mengjie Chemical Research in Chinese Universities, Vol. 33, Issue 5 https://doi.org/10.1007/s40242-017-7096-8	journal	August 2017
Supramolecular organic frameworks (SOFs): homogeneous regular 2D and 3D pores in water Tian, Jia; Wang, Hui; Zhang, Dan-Wei National Science Review, Vol. 4, Issue 3 https://doi.org/10.1093/nsr/nwx030	journal	March 2017
Detection of Picric Acid by Terpy-Based Metallo-Supramolecular Fluorescent Coordination Polymers in Aqueous Media Ding, Zhongyu; Li, Hongqing; Gao, Wanqing Chinese Journal of Chemistry, Vol. 35, Issue 4 https://doi.org/10.1002/cjoc.201600885	journal	April 2017
Controlling and tuning the dynamic nature of supramolecular polymers in aqueous solutions Hendrikse, Simone I. S.; Wijnands, Sjors P. W.; Lafleur, René P. M. Chemical Communications, Vol. 53, Issue 14 https://doi.org/10.1039/C6CC10046E	journal	January 2017
Supramolecular organic frameworks: engineering periodicity in water through host–guest chemistry Tian, Jia; Chen, Lan; Zhang, Dan-Wei Chemical Communications, Vol. 52, Issue 38 https://doi.org/10.1039/C6CC02331B	journal	January 2016
Synthesis and characterization of metallo-supramolecular polymers Winter, Andreas; Schubert, Ulrich S. Chemical Society Reviews, Vol. 45, Issue 19 https://doi.org/10.1039/C6CS00182C	journal	January 2016
Water-soluble supramolecular polymers constructed by macrocycle-based host-guest interactions Chen, Yanmei; Sun, Siyu; Lu, Dou Chinese Chemical Letters, Vol. 30, Issue 1 https://doi.org/10.1016/j.cclet.2018.10.022	journal	January 2019

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
supramolecular polymer
structural flexibility
porosity periodicity
cucurbit[8]uril
photocatalysis
organic dye degradation

Title: A periodic metallo-supramolecular polymer from a flexible building block: self-assembly and photocatalysis for organic dye degradation

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