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Title: Developing high safety Li-metal anodes for future high-energy Li-metal batteries: strategies and perspectives

Abstract

Developing high-safety Li-metal anodes (LMAs) are extremely important for the application of high-energy Li-metal batteries. The recently state-of-the-art technologies, strategies and perspectives for developing LMAs are comprehensively summarized in this review.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [3]; ORCiD logo [4]; ORCiD logo [4];  [4];  [2]; ORCiD logo [5]; ORCiD logo [6]; ORCiD logo [4]
  1. Henan Normal University (China); Univ. of Waterloo, ON (Canada)
  2. Henan Normal University (China)
  3. Univ. of Waterloo, ON (Canada) ; Argonne National Lab. (ANL), Argonne, IL (United States)
  4. Univ. of Waterloo, ON (Canada)
  5. Argonne National Lab. (ANL), Argonne, IL (United States)
  6. Argonne National Lab. (ANL), Argonne, IL (United States); Stanford Univ., CA (United States); Imam Abdulrahman Bin Faisal University (IAU), Dammam (Saudi Arabia)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
Natural Sciences and Engineering Research Council of Canada (NSERC); National Natural Science Foundation of China (NNSFC); USDOE Office of Science (SC)
OSTI Identifier:
1660542
Alternate Identifier(s):
OSTI ID: 1638299
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Chemical Society Reviews
Additional Journal Information:
Journal Volume: 49; Journal Issue: 15; Journal ID: ISSN 0306-0012
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

Citation Formats

Liu, Dai-Huo, Bai, Zhengyu, Li, Matthew, Yu, Aiping, Luo, Dan, Liu, Wenwen, Yang, Lin, Lu, Jun, Amine, Khalil, and Chen, Zhongwei. Developing high safety Li-metal anodes for future high-energy Li-metal batteries: strategies and perspectives. United States: N. p., 2020. Web. doi:10.1039/c9cs00636b.
Liu, Dai-Huo, Bai, Zhengyu, Li, Matthew, Yu, Aiping, Luo, Dan, Liu, Wenwen, Yang, Lin, Lu, Jun, Amine, Khalil, & Chen, Zhongwei. Developing high safety Li-metal anodes for future high-energy Li-metal batteries: strategies and perspectives. United States. doi:10.1039/c9cs00636b.
Liu, Dai-Huo, Bai, Zhengyu, Li, Matthew, Yu, Aiping, Luo, Dan, Liu, Wenwen, Yang, Lin, Lu, Jun, Amine, Khalil, and Chen, Zhongwei. Mon . "Developing high safety Li-metal anodes for future high-energy Li-metal batteries: strategies and perspectives". United States. doi:10.1039/c9cs00636b.
@article{osti_1660542,
title = {Developing high safety Li-metal anodes for future high-energy Li-metal batteries: strategies and perspectives},
author = {Liu, Dai-Huo and Bai, Zhengyu and Li, Matthew and Yu, Aiping and Luo, Dan and Liu, Wenwen and Yang, Lin and Lu, Jun and Amine, Khalil and Chen, Zhongwei},
abstractNote = {Developing high-safety Li-metal anodes (LMAs) are extremely important for the application of high-energy Li-metal batteries. The recently state-of-the-art technologies, strategies and perspectives for developing LMAs are comprehensively summarized in this review.},
doi = {10.1039/c9cs00636b},
journal = {Chemical Society Reviews},
issn = {0306-0012},
number = 15,
volume = 49,
place = {United States},
year = {2020},
month = {7}
}

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  • Merinov, Boris V.; Naserifar, Saber; Zybin, Sergey V.
  • The Journal of Chemical Physics, Vol. 152, Issue 3
  • DOI: 10.1063/1.5132566

Electrolyte additive enabled fast charging and stable cycling lithium metal batteries
journal, March 2017


Low-Polarization Lithium-Oxygen Battery Using [DEME][TFSI] Ionic Liquid Electrolyte
journal, November 2017

  • Ulissi, Ulderico; Elia, Giuseppe Antonio; Jeong, Sangsik
  • ChemSusChem, Vol. 11, Issue 1
  • DOI: 10.1002/cssc.201701696

Reversible Mn2+/Mn4+ double redox in lithium-excess cathode materials
journal, April 2018


Stabilization of Lithium Metal Anodes by Hybrid Artificial Solid Electrolyte Interphase
journal, July 2017


A Flexible Solid Electrolyte Interphase Layer for Long-Life Lithium Metal Anodes
journal, January 2018

  • Li, Nian-Wu; Shi, Yang; Yin, Ya-Xia
  • Angewandte Chemie International Edition, Vol. 57, Issue 6
  • DOI: 10.1002/anie.201710806

Toward high lithium conduction in solid polymer and polymer–ceramic batteries
journal, June 2018

  • Commarieu, Basile; Paolella, Andrea; Daigle, Jean-Christophe
  • Current Opinion in Electrochemistry, Vol. 9
  • DOI: 10.1016/j.coelec.2018.03.033

An Armored Mixed Conductor Interphase on a Dendrite-Free Lithium-Metal Anode
journal, September 2018


Tuning wettability of molten lithium via a chemical strategy for lithium metal anodes
journal, October 2019


Dual‐Layered Film Protected Lithium Metal Anode to Enable Dendrite‐Free Lithium Deposition
journal, April 2018


Behavior of Solid Electrolyte in Li-Polymer Battery with NMC Cathode via in-Situ Scanning Electron Microscopy
journal, February 2020


Ultrahigh–current density anodes with interconnected Li metal reservoir through overlithiation of mesoporous AlF 3 framework
journal, September 2017


Stable Metal Anode enabled by Porous Lithium Foam with Superior Ion Accessibility
journal, June 2018

  • Hafez, Ahmed M.; Jiao, Yucong; Shi, Jianjian
  • Advanced Materials, Vol. 30, Issue 30
  • DOI: 10.1002/adma.201802156

Reversible superdense ordering of lithium between two graphene sheets
journal, November 2018


Electroless Formation of Hybrid Lithium Anodes for Fast Interfacial Ion Transport
journal, September 2017

  • Choudhury, Snehashis; Tu, Zhengyuan; Stalin, Sanjuna
  • Angewandte Chemie International Edition, Vol. 56, Issue 42
  • DOI: 10.1002/anie.201707754

Lithium Silicide Surface Enrichment: A Solution to Lithium Metal Battery
journal, July 2018


Dendrite formation in Li-metal anodes: an atomistic molecular dynamics study
journal, January 2019

  • Selis, Luis A.; Seminario, Jorge M.
  • RSC Advances, Vol. 9, Issue 48
  • DOI: 10.1039/C9RA05067A

Garnet-rich composite solid electrolytes for dendrite-free, high-rate, solid-state lithium-metal batteries
journal, April 2020


Real-time mass spectrometric characterization of the solid–electrolyte interphase of a lithium-ion battery
journal, January 2020


High-Energy-Density Metal-Oxygen Batteries: Lithium-Oxygen Batteries vs Sodium-Oxygen Batteries
journal, September 2017

  • Song, Kyeongse; Agyeman, Daniel Adjei; Park, Mihui
  • Advanced Materials, Vol. 29, Issue 48
  • DOI: 10.1002/adma.201606572

Nitriding‐Interface‐Regulated Lithium Plating Enables Flame‐Retardant Electrolytes for High‐Voltage Lithium Metal Batteries
journal, May 2019

  • Tan, Shuang‐Jie; Yue, Junpei; Hu, Xin‐Cheng
  • Angewandte Chemie, Vol. 131, Issue 23
  • DOI: 10.1002/ange.201903466

Benchmarking the performance of all-solid-state lithium batteries
journal, March 2020


Interface Engineering for Garnet-Based Solid-State Lithium-Metal Batteries: Materials, Structures, and Characterization
journal, October 2018

  • Dai, Jiaqi; Yang, Chunpeng; Wang, Chengwei
  • Advanced Materials, Vol. 30, Issue 48
  • DOI: 10.1002/adma.201802068

Lithium-coated polymeric matrix as a minimum volume-change and dendrite-free lithium metal anode
journal, March 2016

  • Liu, Yayuan; Lin, Dingchang; Liang, Zheng
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10992

Fluorinated Solid-Electrolyte Interphase in High-Voltage Lithium Metal Batteries
journal, November 2019


Energy applications of ionic liquids
journal, January 2009

  • Wishart, James F.
  • Energy & Environmental Science, Vol. 2, Issue 9
  • DOI: 10.1039/b906273d

Lithium Nitrate Solvation Chemistry in Carbonate Electrolyte Sustains High-Voltage Lithium Metal Batteries
journal, September 2018

  • Yan, Chong; Yao, Yu-Xing; Chen, Xiang
  • Angewandte Chemie International Edition, Vol. 57, Issue 43
  • DOI: 10.1002/anie.201807034

Dendrite-Free Lithium Deposition Induced by Uniformly Distributed Lithium Ions for Efficient Lithium Metal Batteries
journal, February 2016

  • Cheng, Xin-Bing; Hou, Ting-Zheng; Zhang, Rui
  • Advanced Materials, Vol. 28, Issue 15
  • DOI: 10.1002/adma.201506124

Poly(dimethylsiloxane) Thin Film as a Stable Interfacial Layer for High-Performance Lithium-Metal Battery Anodes
journal, October 2016


A platinum nanolayer on lithium metal as an interfacial barrier to shuttle effect in Li-S batteries
journal, July 2019


Conductivity and lithiophilicity gradients guide lithium deposition to mitigate short circuits
journal, April 2019


Perspectives for restraining harsh lithium dendrite growth: Towards robust lithium metal anodes
journal, November 2018


Garnet Electrolyte with an Ultralow Interfacial Resistance for Li-Metal Batteries
journal, April 2018

  • Li, Yutao; Chen, Xi; Dolocan, Andrei
  • Journal of the American Chemical Society, Vol. 140, Issue 20
  • DOI: 10.1021/jacs.8b03106

Effect of the Electrolyte Composition on SEI Reactions at Si Anodes of Li-Ion Batteries
journal, March 2015

  • Martinez de la Hoz, Julibeth M.; Soto, Fernando A.; Balbuena, Perla B.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 13
  • DOI: 10.1021/acs.jpcc.5b01228

Mixed Ionic and Electronic Conductor for Li-Metal Anode Protection
journal, January 2018


Effect of Fluoroethylene Carbonate Electrolytes on the Nanostructure of the Solid Electrolyte Interphase and Performance of Lithium Metal Anodes
journal, June 2018

  • Brown, Zachary L.; Jurng, Sunhyung; Nguyen, Cao Cuong
  • ACS Applied Energy Materials, Vol. 1, Issue 7
  • DOI: 10.1021/acsaem.8b00705

Interface Stability in Solid-State Batteries
journal, December 2015


Stable Li Metal Anodes via Regulating Lithium Plating/Stripping in Vertically Aligned Microchannels
journal, September 2017

  • Wang, Shu-Hua; Yin, Ya-Xia; Zuo, Tong-Tong
  • Advanced Materials, Vol. 29, Issue 40
  • DOI: 10.1002/adma.201703729

Effects of Polymer Coatings on Electrodeposited Lithium Metal
journal, August 2018

  • Lopez, Jeffrey; Pei, Allen; Oh, Jin Young
  • Journal of the American Chemical Society, Vol. 140, Issue 37
  • DOI: 10.1021/jacs.8b06047

Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy
journal, October 2017


Regenerable Cu-intercalated MnO2 layered cathode for highly cyclable energy dense batteries
journal, March 2017

  • Yadav, Gautam G.; Gallaway, Joshua W.; Turney, Damon E.
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms14424

Oxidative-Stability Enhancement and Charge Transport Mechanism in Glyme–Lithium Salt Equimolar Complexes
journal, August 2011

  • Yoshida, Kazuki; Nakamura, Megumi; Kazue, Yuichi
  • Journal of the American Chemical Society, Vol. 133, Issue 33, p. 13121-13129
  • DOI: 10.1021/ja203983r