Addressing the Stability Gap in Photoelectrochemistry: Molybdenum Disulfide Protective Catalysts for Tandem III–V Unassisted Solar Water Splitting

Ben-Naim, Micha; Britto, Reuben J.; Aldridge, Chase W.; Mow, Rachel; Steiner, Myles A.; Nielander, Adam C.; King, Laurie A.; Friedman, Daniel J.; Deutsch, Todd G.; Young, James L.; Jaramillo, Thomas F.

doi:10.1021/acsenergylett.0c01132

Title: Addressing the Stability Gap in Photoelectrochemistry: Molybdenum Disulfide Protective Catalysts for Tandem III–V Unassisted Solar Water Splitting

Journal Article · Thu Jul 30 00:00:00 EDT 2020 · ACS Energy Letters

DOI:https://doi.org/10.1021/acsenergylett.0c01132· OSTI ID:1660055

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Stanford Univ., CA (United States)
National Renewable Energy Lab. (NREL), Golden, CO (United States). Chemistry and Nanoscience Center
Stanford Univ., CA (United States); Manchester Metropolitan Univ. (United Kingdom)

While photoelectrochemical (PEC) solar-to-hydrogen efficiencies have greatly improved over the past few decades, advances in PEC durability have lagged behind. Corrosion of semiconductor photoabsorbers in the aqueous conditions needed for water splitting is a major challenge that limits device stability. In addition, a precious-metal catalyst is often required to efficiently promote water splitting. In this work, we demonstrate unassisted water splitting using a nonprecious metal molybdenum disulfide nanomaterial catalytic protection layer paired with a GaInAsP/GaAs tandem device. This device was able to achieve stable unassisted water splitting for nearly 12 h, while a sibling sample with a PtRu catalyst was only stable for 2 h, highlighting the advantage of the nonprecious metal catalyst. In situ optical imaging illustrates the progression of macroscopic degradation that causes device failure. Furthermore, this work compares unassisted water splitting devices across the field in terms of the efficiency and stability, illustrating the need for improved stability.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States); Stanford Univ., CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office (HFTO); National Science Foundation (NSF)

Grant/Contract Number:: AC36-08GO28308; FOA-0001647; ECCS-154215; EE0008084

OSTI ID:: 1660055

Alternate ID(s):: OSTI ID: 2305592

Report Number(s):: NREL/JA-5900-76771; MainId:9432; UUID:eaa4d4a9-02ef-41a4-bed1-918c39d58cf2; MainAdminID:13838

Journal Information:: ACS Energy Letters, Vol. 5, Issue 8; ISSN 2380-8195

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 37 works

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Title: Addressing the Stability Gap in Photoelectrochemistry: Molybdenum Disulfide Protective Catalysts for Tandem III–V Unassisted Solar Water Splitting

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